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Educational research has shown that reflection and feedback are crucial for substantial development of pre-service teachers' professional competence. However, reflection and feedback sessions are not a standard element of teaching practicums due to time- and location-constraints. Digital practicum environments can lift these constraints. Digital reflection and feedback environments have typically applied either textual accounts or video sequences of classroom practice, with varying effects. Consequently, the studies presented in this cumulative dissertation are focused on how the use of text- or video-based digital reflection and feedback environments during a practicum influence specific components of pre-service teachers' professional competence (i.e., beliefs about teaching and learning, self-efficacy, professional vision of classroom management, feedback competence). All studies followed a quasi-experimental, pre-test-post-test design. Pre-service teachers at the fourth-semester bachelor level in a German university took part in the studies. Pre-service teachers participated in a four-week teaching practicum at local schools. During the teaching practicum, pre-service teachers were divided into five different groups. The control group (CG) took part in a traditional practicum with live observations and face-to-face reflection and feedback with peers and experts. Pre-service teachers of the intervention groups (IG 1, IG 2, IG 3, IG 4) reflected and received feedback in highly structured text- or video-based digital environments. Intervention groups 1 (IG 1) and 2 (IG 2) participated in a text-based digital reflection and feedback environment. While IG 1 participants only received feedback from peers, IG 2 pre-service teachers also received expert feedback. Intervention groups 3 (IG 3) and 4 (IG 4) took part in a video-based digital reflection and feedback environment. IG 3 pre-service teachers only received peer feedback, whereas IG 4 participants also received expert feedback. Mixed methods were applied by generating quantitative and quantitative-qualitative data was with questionnaires, a standardized video-based test and content analysis. The studies demonstrated that classroom videos and video-based digital reflection and feedback environments can effectively enhance pre-service teachers' professional competence. This finding can be predominantly attributed to two characteristics of the application in the digital reflection and feedback environments: (a) being able to revisit a multitude of authentic teaching situations without time pressure and (b) the degree of decomposition by deliberate, focused practice and scaffolding elements. Furthermore, expert feedback seemed to be of better quality and entailed more substantial effects than peer feedback. The results of the conducted studies on professional vision of classroom management, beliefs about teaching and learning and feedback competence showed that expert feedback can be seen as a lens reducing and focusing classroom complexity, enabling pre-service teachers to perceive crucial teaching situations that would have otherwise gone unnoticed and to benefit from expert modelling of high-quality feedback. Consequently, video-based digital reflection and feedback environments with expert feedback can significantly improve pre-service teachers' professional competence during teaching practicums and, thus, better prepare pre-service teachers for future classroom challenges, leading to better learning environments for school students.
In this dissertation, a multi-proxy study, which included palaeoecological, lithological, geochemical and geochronological methods, was carried out to investigate climatic and environmental changes and their interaction during the Quaternary in formerly glaciated and non-glaciated areas. The information obtained will be used to provide a better understanding of the regional stratigraphic framework and to establish broader regional terrestrial correlations within the global marine isotope stage (MIS) framework. This study was conducted on two key drillings, the Garding-2 research drill core in the German North Sea coastal area of Schleswig-Holstein and the GBY#2 archaeological core at the Gesher Benot Ya'aqov (GBY) site, in the Upper Jordan Valley in Israel. The results of this study are presented in three papers. Papers I and II focus on the study of the Garding-2 core, while the multi-proxy study of the GBY#2 core is presented in Paper III. The results of a variety of analyses conducted on the 240 m long Garding-2 sequence show interglacial-glacial cycles that are mainly controlled by variations in temperature. This sequence is composed of mainly fluvial-shallow marine sediments intercalated by muddy-peaty deposits. Based on the palynological and lithological findings, the Pliocene-Pleistocene transition was observed at 182.87 m. It is overlain by Praetiglian and the subsequent sediments of the Waalian and Bavelian Complexes. The boundary of either the second or third Cromerian Interglacial with younger sediments, which still belong to MIS 19, is marked by the last occurrence of Tsuga at 119.50 m and the development of mixed-deciduous forests. The palynologically equivalent sediments of the Bilshausen Interglacial were found below two Elsterian till layers, at 89.00 m-82.00 m. These sediments showed high and increased percentages of Pinus and Picea and scattered occurrences of Abies and Carpinus, which are similar to the features of the beginning of the Bilshausen or Rhume interglacial. An unconformity occurred at 80.29 m, at the bottom of late Holsteinian deposits, characterised by the occurrences of Fagus and Pterocarya, with low percentages of Abies and Carpinus and the absence of Buxus. These deposits are succeeded by sediments of the Fuhne cold period that shows higher percentages of NAP and occurrences of Ericales, Helianthemum and Selaginella selaginoides, which are unconformably overlain by Drenthian till at 73.00 m-71.00 m. A single peaty sample at 69.25 m with Pinus-Picea-Abies assemblage is correlated with the late Eemian Interglacial. This deposit is overlain by Weichselian glaciofluvial sediments. Middle-late Holocene sediments occurred from 20 m upwards, following a hiatus, which was caused by the Early Holocene transgression. A subsequent thin layer of marine Atlantic sediments is unconformably overlain by marine-tidal flat deposits up to 11.00 m. The first occurrence of Fagus (at 15.97 m) and Carpinus (at 15.03 m), which was optically stimulated luminescence (OSL)-dated to 3130 +/- 260 BP (at 16.22 m, Zhang et al., 2014), gives evidence for a Subboreal age for these deposits. Sandy sediments of the early Subatlantic, which were deposited between 11.00 m and the top of the Garding-2 sequence, indicate that local salt marshes, dunes and tidal flat vegetation expanded during this period. Due to regional features and the peculiarities of the local coastal environment, the expansions of Fagus and Carpinus, which are characteristic for the Subboreal-Subatlantic transition at about 2700 BP in northern Germany, are not clearly reflected in the Garding-2 pollen diagram. In the Mediterranean area, a 50 m long core of GBY#2, was drilled at the Acheulian site of Gesher Benot Ya'akov. The GBY#2 core provides a long Early-Middle Pleistocene geological, environmental and climatological record, which also enriches the knowledge of hominin-habitat relationships documented at the margins of the Hula Palaeo-lake. The sediment sequence of GBY#2 is under- and overlain by two basalt flows that are 40Ar/39Ar dated: two samples at the bottom of the core dated to 1195 +/- 67 ka (at 48.30 m) and 1137 +/- 69 ka (at 45.30 m), and another one at the top dated to 659 +/- 85 ka (at 14.90 m). With the additional chronological identification of the Matuyama Brunhes Boundary (MBB) and the correlation with the GBY excavation sites, the sedimentary sequence of GBY#2 provides the climatic history during the late part of the mid-Pleistocene transition (MPT, 1.2 Ma-0.5 Ma). Multi-proxy analyses including those of pollen and non-pollen palynomorphs, macro botanical remains, molluscs, ostracods, fish, amphibians and micromammals provide evidence for lake and lake-margin environments during MIS 20 and MIS 19. During MIS 20, relatively cool semi-moist conditions were followed by a pronounced dry phase. During the subsequent MIS 19, warm and moist interglacial conditions were characterised by Quercus-Pistacia woodlands in this area. The depositional environment changed from an open water lake during MIS 20 to a lake margin environment in MIS 19. This finding is at odds with changing climate conditions from relatively dry to moist. This discrepancy could be explained by the prograding pattern of the lake shore due to the infilling of the basin, which resulted in shallower water. Climatic changes during the Late Tertiary and the Quaternary in the high latitude regions in northwest Europe and during the Early-Middle Pleistocene in the mid latitude regions of the Middle East follow the patterns of global climatic changes, which are mainly controlled by orbital obliquity (+/-41 ka cycle) during the Early Pleistocene and by orbital eccentricity (+/-100 ka cycle) during the MPT (1.2 Ma-0.5 Ma) and the younger periods of the Quaternary. The results of this study also provide reliable evidence for long distance correlation of stratigraphic and climatic events of the Quaternary, which extends knowledge of regional and global impact of climatic fluctuations on the environment.
Organizational culture is widely acknowledged to be a driver of organizational effectiveness. However, existing empirical research tends to focus on investigating the links between individual, isolated culture dimensions and effectiveness outcomes. This approach is at odds with the theoretical roots of organizational culture and does not do justice to the complex reality that most organizations face. This issue is addressed by this dissertation, which is comprised of four studies. Study 1 investigated the psychometric quality and cultural equivalence of three culture measures in a German context, based on a sample of 172 employees in a bank. The results suggested that the German versions of the Denison Organizational Culture Survey and the Organizational Culture Profile performed satisfactorily, while results regarding the GLOBE survey fell short of expectations. Study 2 reviewed the literature on the link between culture and effectiveness with a focus on studies that treat organizational culture as a holistic phenomenon. The review yielded four kinds of holistic approaches (aggregation-based, agreement-based, moderation- or mediation-based, and configuration-based). Study 3 investigated how a change in organizational culture induced by an M&A project impacts employee commitment. Based on a sample of 180 employees in a German organization, the findings suggest that individuals perceive cultural change differently, that cultural stability is positively related to employee commitment, and that group-level leader-member exchange and individual self-efficacy moderate this relationship. Study 4 introduced a new theoretical perspective (set theory) and a novel methodology (fuzzy set qualitative comparative analysis) to the field of organizational culture. Across two samples (1170 employees in a financial service provider and 998 employees in fashion retailer), results indicated that culture dimensions do not operate in isolation, but jointly work together in achieving different effectiveness outcomes.
The transition of our energy system towards a generation by renewables, and the corresponding developments of wind power technology enlarge the requirements that must be met by a wind turbine control scheme. Within this thesis, the role of modern, model-based control approaches in providing an answer to present and future challenges faced by wind energy conversion systems is discussed. While many different control loops shape the power system in general, and the energy conversion process from the wind to the electrical grid specifically, this work addresses the problem of power output regulation of an individual turbine. To this end, the considered control task focuses on the operation of the turbine on the nonlinear power conversion curve, which is dictated by the aerodynamic interaction of the wind turbine structure and the current inflow. To enable a power tracking functionality, and thereby account for requirements of the electrical grid instead of operating the turbine at maximum efficiency constantly, an extended operational range is explicitly considered in the implemented control scheme. This allows for an adjustment of the produced power depending on the current state of the electrical grid and is one component in constructing a reliable and stable power system based on renewable generation. To account for the nonlinear dynamics involved, a linear matrix inequalities approach to control based on Takagi-Sugeno modeling is investigated. This structure is capable of integrating several degrees of freedom into an automated control design, where, additionally to stability, performance constraints are integrated into the design to account for the sensitive dynamical behavior of turbines in operation and the loading experienced by the turbine components. For this purpose, a disturbance observer is designed that provides an estimate of the current effective wind speed from the evolution of the measurements. This information is used to adjust the control scheme to the varying operating points and dynamics. Using this controller, a detailed simulation study is performed that illustrates the experienced loading of the turbine structure due to a dynamic variation of the power output. It is found that a dedicated controller allows wind turbines to provide such functionality. Additionally to the conducted simulations, the control scheme is validated experimentally. For this purpose, a fully controllable wind turbine is operated in a wind tunnel setup that is capable of generating reproducible wind conditions, including turbulence, in a wide operational range. This allows for an assessment of the power tracking performance enforced by the controller and analysis of the wind speed estimation error with the uncertainties present in the physical application. The controller showed to operate the turbine smoothly in all considered operating scenarios, while the implementation in the real-time environment revealed no limitations in the application of the approach within the experiments. Hence, the high flexibility in adjusting the turbine operating trajectories and structural design characteristics within the model-based design allows for efficient controller synthesis for wind turbines with increasing functionality and complexity.
In the face of uncertainty, ecosystems can provide natural insurance to risk averse users of ecosystem services. We employ a conceptual ecological-economic model to analyze the allocation of (endogenous) risk and ecosystem quality by risk averse ecosystem managers who have access to financial insurance, and study the implications for individually and socially optimal ecosystem management, and policy design. We show that while an improved access to financial insurance leads to lower ecosystem quality, the effect on the free-rider problem and on welfare is determined by ecosystem properties. We derive conditions on ecosystem functioning under which, if financial insurance becomes more accessible, (i) the extent of optimal regulation increases or decreases; and (ii) welfare, in the absence of environmental regulation, increases or decreases.
Maximizing the value from data has become a key challenge for companies as it helps improve operations and decision making, enhances products and services, and, ultimately, leads to new business models. While enterprise architecture (EA) management and modeling have proven their value for IT-related projects, the support of enterprise architecture for data-driven business models (DDBMs) is a rather new and unexplored field. The research group argues that the current understanding of the intersection of data-driven business model innovation and enterprise architecture is incomplete because of five challenges that have not been addressed in existing research: (1) lack of knowledge of how companies design and realize data-driven business models from a process perspective, (2) lack of knowledge on the implementation phase of data-driven business models, (3) lack of knowledge on the potential support enterprise architecture modeling and management can provide to data-driven business model endeavors, (4) lack of knowledge on how enterprise architecture modeling and management support data-driven business model design and realization in practice, (5) lack of knowledge on how to deploy data-driven business models. The researchers address these challenges by examining how enterprise architecture modeling and management can benefit data-driven business model innovation. The mixed-method approach of this thesis draws on a systematic literature review, qualitative empirical research as well as the design science research paradigm. The investigators conducted a systematic literature search on data-driven business models and enterprise architecture. Considering the novelty of data-driven business models for academia and practice, they conducted explorative qualitative research to explain "why" and "how" companies embark on realizing data-driven business models. Throughout these studies, the primary data source was semi-structured interviews. In order to provide an artifact for DDBM innovation, the researchers developed a theory for design and action. The data-driven business model innovation artifact was inductively developed in two design iterations based on the design science paradigm and the design science research framework.
Recent studies have confirmed that the aquatic ecosystem is being polluted with an unknown cocktail of pharmaceuticals, their metabolites and/or their transformation products (TPs). Although individual pharmaceuticals are typically present at low concentrations, their continuous input into the aquatic ecosystem and their toxic and persistent presence are the major environmental concerns. Therefore, it is necessary to assess the environmental risk caused by these aquatic pollutants. Data on exposure are required for quantitative risk assessment of parent compounds and their transformation products (TPs) and/or metabolites. Such data are mostly missing, especially for TPs, because of the non-availability of TPs and very often metabolites for experimental testing. Therefore, the application of different in silico tools for qualitative risk assessment can be used. Also, the presence of these micro-pollutants (active pharmaceutical ingredients, APIs) in the aquatic cycle are increasingly seen as a challenge to the sustainable management of water resources worldwide due to ineffective effluent treatment and other measures for their input prevention. Given the poor prognosis for effluent treatment (‘end of the pipe’ approach) for input prevention of APIs in the environment, it is necessary to focus on the ‘beginning of the pipe’ strategy. The very beginning of the pipe is the molecules themselves. Therefore, novel approaches are needed like designing greener pharmaceuticals, i.e. better biodegradable ones in the aquatic environment after their release. Therefore, the present research work focused on two important topics a) assessment of the environmental risk associated with the presence of highly prescribed drugs and their TPs; b) demonstrating the feasibility of the ‘benign by design’ concept for designing biodegradable drug derivatives, which will have the better biodegradability in the environment after their release. The present thesis includes four research articles (1-4) which address these approaches. The first article is about the qualitative environmental risk assessment using the example of transformation products formed during photolysis (photo-TPs) of Diatrizoic acid (DIAT). Photolysis is the chemical reaction in which the compound is broken down by photons and often in combination with hydroxyl radicals. Photolysis is the most common abatement process of micro-pollutants in the environment. The qualitative risk assessment of DIAT and selected photo-TPs was performed by the PBT approach (i.e. Persistence, Bioaccumulation and Toxicity), using chemical analysis, experimental biodegradation test assays, QSAR models with several different toxicological endpoints and in silico read-across approaches. The second article addresses a tiered approach of implementing green and sustainable chemistry principles for theoretically designing better biodegradable and pharmacologically potent pharmaceuticals derivatives. Photodegradation process coupled with LC-MSn analysis, biodegradability testing and in silico tools such as quantitative structure-activity relationships (QSAR) analysis and molecular docking proved to be a very significant approach for the preliminary stages of designing chemical structures that would fit into the ´benign by design´ concept in the direction of green and sustainable pharmacy. Metoprolol (MTL) was used as an example. The third article was also the conceptual framework to get new drug derivatives that are biodegradable in order to tackle the global challenge of micro-pollutants in the aquatic cycle. This study increased the knowledge about the role of the attachment of certain functionalities to the parent drug molecule for its biodegradability whilst conserving drug-likeness. This approach was in the past a totally neglected issue within drug development. Atenolol (ATL), a selective β1 blocker, was selected as an example to incorporate the additional attribute such as biodegradability into its molecular structure while conserving its substructures responsible for β adrenergic receptor blocker activity. In fourth article, the concept of designing green biodegradable pharmaceuticals has been proven through expanded experimental analysis setting out from the experiences collected as described in article two and three. This study could be considered as a more extensive feasibility study of rational design of green drug derivatives. The non-selective β-blocker Propranolol (PPL) was used as an example. The risk assessment study (Article #1) contributes in enhancing the existing knowledge about the life cycle and behavior (fate) of pharmaceuticals with a special focus on photo-TPs which are generally formed during advanced effluent treatment and enter as such into the environment. Based on the obtained results, the application of the in silico tools for qualitative risk assessment analysis increased knowledge space about the environmental fate of TPs in case of their non-availability for experimental testing. The benign by design studies (Article #2-4) were based on the knowledge and experience collected during the work on DIAT. It demonstrated the feasibility of a novel approach of designing comparatively better degradable and pharmacological potent derivatives through the implementation of ´green chemistry´ principles. However, the present approach is in the juvenile stage and further knowledge has to be collected beforehand for the full implementation of this approach into drug development.
The global coffee market is connected to many sustainability issues like the persisting poverty of coffee farmers, and degrading ecosystems. Many interventions, from state-led regulation to industry-led certification processes, exist, that try to change global value chains to shift societies back on more sustainable trajectories. To this date, it is still under debate if these interventions are an effective means to change global value chains. With climate change and persisting issues of social justice as strong accelerators, calls are increasingly made for a radical transformation of global production and consumption patterns. Many frameworks try to inform research and real-world policies for a transformation of global value chains. In this dissertation, the author uses the framework of the practical, political and personal sphere proposed by O'Brien and Sygna (2013) highlighting that the interactions between these three spheres bare the greatest potential for a transformation towards sustainability. However, in this dissertation, the author argues that it is exactly at the nexus between the three spheres of transformation where barriers towards a fundamental shift of systems occur. He, therefore, uses three perspectives to bring empirical nuance to the problems that arise on the interplay between the different spheres of transformation. (1) The scientific perspective: using a systematic review of alternative trade arrangements; (2) the producer perspective: facilitating a participatory network analysis of social-ecological challenges of Ugandan coffee farmers and their adaptive management practices; (3) the consumer perspective: through the use of a German consumer survey and a structural equation model to investigate into the Knowledge-Doing-Gap end-consumers are facing. Through the results from the scientific perspective, the author is able to show that most of the research is investigating the certified market and that the effectiveness of labels rarely exceeding the practical sphere. His empirical research on the producer perspective highlights that Ugandan coffee farmers facilitate a variety of on-farm crop management (practical sphere) but their support structures rarely exceed informal exchange with neighboring communities (political sphere). Exchange with governmental actors and global traders is happening but has been assessed as not sufficient to cope with the social-ecological challenges the producers are facing. Through the results of the consumer perspective, the author is able to highlight that even though end-consumers have pro-sustainable attitudes (personal sphere) they are facing situational constraints (political sphere) that create a gap between their attitudes and the respective behavior. Using these empirical insights about drivers and barriers for a transformation he proposes that frameworks, aiming to inform research and policies, need to include two aspects: (1) the notion of a forced transformation; and (2) the translational capacity of the frameworks to create meaningful interdisciplinary discourses in different contexts. The author, therefore, propose two approaches:(1) a fourth sphere, called the "planetary force" to include the notion of a forced transformation that is already happening in different contexts, highlighted by the producer perspective in this dissertation; and (2) the consequent use of methods that create interdisciplinary exchange and rigorous testing.
Since the early 2000s, ecosystem services strongly gained significance as a research topic. However, the temporal dimension of ecosystem services has not been taken into consideration, although this should be the basis for a sustainable long-term management of ecosystems and their services. Therefore, the author presents three articles in this thesis that deal with temporal aspects of ecosystem services. In two of them she also present a proposal for a framework for the classification of ecosystem services based on their temporal dynamics. In this dissertation she differentiates between two types of temporal aspects, both of which have in common that change takes place over a certain period of time. The concepts of transformation, transition and regime shift are used to describe changes in social or ecological systems as a whole, for example the transformation towards a more sustainable society. The temporal dynamics, on the other hand, relate to the temporal changes in ecosystem services themselves. The first article focuses on how the literature on ecosystem services incorporates social and ecological change. The second and third articles deal with the temporal dynamics of ecosystem services. While the second article presents a preliminary framework for categorizing the temporal dynamics of ecosystem services, the third article uses this framework to test how the temporal dynamics of ecosystem services are represented in the literature. Based on the insights from the three articles, the author concludes that most of the studies on ecosystem services only focus on one point in time. One reason for this is that most studies are conducted over a maximum of a four-year time span which does not allow to monitor dynamics over longer time spans.
This thesis aims to provide a quantitative, cross-nationally comparative, longitudinal and multilevel study of the drivers and hindrances of national governments' anti-trafficking measures. In this research, both macro-level determinants of anti-trafficking enforcement and micro-level foundations of human trafficking are explored. In the manuscript, large-N comparative research examines how characteristics of countries interact with people's attitudes towards violence to better understand what creates environments that are more or less supportive of governments' anti-trafficking efforts. The results presented in the thesis speak not only in favor of studying this topic systematically and cross-nationally, addressing existing gaps in the literature but also in favor of combining macro- and micro-level evidence for developing more effective policy responses against human trafficking.
Despite the great progress that has been made in the prophylaxis of oral diseases over the past decades, dental caries and periodontal diseases remain major challenges in the field of dentistry. Biofilm formation on dental hard tissues is strongly associated with the etiology of these oral diseases. Therefore, the process of bioadhesion and biofilm formation on tooth surfaces is of particular interest for dental research. The first stage of bioadhesion on dental surfaces is the formation of the pellicle layer. This mainly acellular film, composed largely of adsorbed proteins, glycoproteins, and lipids, is distinguished from the microbial biofilm (plaque). As the interface between teeth and the oral environment, the pellicle plays a key role in the maintenance of oral health and is of great physiological and pathophysiological importance. On the one hand, the pellicle shows protective properties for the underlying dental hard tissues. On the other hand, it also serves as the basis for dental plaque and therefore, for the development of oral diseases such as caries and periodontitis. Hydrophobic interactions, which are governed by lipophilic substances, are of high relevance for bacterial adherence. Therefore, pellicle lipids, which are a significant constituent of this biological structure, are an interesting target for dental research, as they could modulate oral surfaces, influence microbial interactions, and potentially impede bacterial adherence. Compared to the extensive work on the pellicle´s ultrastructure and protein/amino acid composition, little attention has been given to its lipid profile. Knowledge of the lipid composition of the pellicle may provide insight into several oral pathological states, including caries, dental erosion, and periodontal disease processes and could contribute to novel approaches in preventive dentistry. The principle aim of this thesis was the comprehensive characterization of the fatty acid (FA) profile of the in situ formed pellicle layer. This includes the influence of pellicle maturation on the FA profile as well as intra- and interindividual differences. Furthermore, investigations on the effect of rinses with edible oils on the pellicle´s FA composition were a focus of this work. For these purposes, an analytical method based on a combination of innovative specimen generation and convenient sample preparation with sensitive mass spectrometric analysis was successfully developed and comprehensively validated within this thesis. Pellicle samples were formed in situ on bovine enamel slabs mounted on individual upper jaw splints. After a comprehensive sample preparation, gas chromatography coupled with electron impact ionization mass spectrometry (GC-EI/MS) was used in order to characterize qualitatively and quantitatively a wide range of FA (C12-C24). The individual FA profiles of pellicle and saliva samples collected from ten research participants were investigated. The relative FA profiles of the pellicle samples gained from the different subjects were very similar, whereas the amount of FAs showed significant interindividual variability. Compared to the pellicle´s characteristic FA profile, higher proportions of unsaturated FAs were detected in the saliva samples, highlighting that FAs available in saliva are not adsorbed equivalently to the pellicle layer. This, in turn, shows that pellicle formation is a highly selective process that does not correlate directly with salivary composition. Additionally, pellicle samples collected after 3, 30, 60, 120, and 240 min of intraoral exposure were analyzed. It could be shown that pellicle maturation has only a minor impact on the FA composition. However, the FA content increased substantially with increasing oral exposure time. Modifying the pellicle´s lipid composition by using edible oils as a mouthwash could alter the physicochemical characteristics of the pellicle and strengthen its protective properties by delaying bacterial adhesion. Therefore, the impact of rinses with safflower oil on the pellicle´s FA composition was determined. The application of rinses with safflower oil resulted in an accumulation of its specific FAs in the pellicle, thus representing a possibility for modifying the pellicle´s lipid profile. The present work is the first to apply a validated method that combines in situ pellicle formation, sample preparation, and the comprehensive determination of FAs via a sensitive analytical method. The results provide valuable information regarding the pellicle´s FA composition which closes an existing knowledge gap in pellicle research. A broader knowledge of the lipid composition of the pellicle contributes to the understanding of oral bioadhesion processes and may help facilitate novel approaches in preventive dentistry.
Wind energy is expected to become the largest source of electricity generation in Europe's future energy mix. As a consequence, future electricity generation will be exposed to an increasing degree to weather and climate. With planning and operational lifetimes of wind energy infrastructure reaching climate time scales, adaptation to changing climate conditions is of relevance to support secure and sustainable energy supply. Premise for success of wind energy projects is the ability to service financial obligations over the project lifetime. Though, revenues(viaelectricity generation) are exposed to changing climate conditions affecting the wind resource, operating conditions or hazardous events interfering with the wind energy infrastructure. For the first time, a procedure is presented to assess such climate change impacts specifically for wind energy financing. At first, a generalised financing chain for wind energy is prepared to (qualitatively) trace the exposure of individual cost elements to physical climate change. In this regard, the revenue through wind power production is identified as the essential component within wind energy financing being exposed to changing climate conditions. This implies the wind resource to be of crucial interest for an assessment of climate change impacts on the financing of wind energy. Therefore, secondly, a novel high-resolution experimental modelling framework with the non-hydrostatic extension of the regional climate model REMO is set up to generate physically consistent climate and climate change information of the wind resource across wind turbine operating altitudes. With this setup, enhanced simulated intra-annual and inter-annual variability across the lower planetary boundary layer is achieved, being beneficial for wind energy applications, compared to state-of-the-art regional climate model configurations. In addition, surrogate climate change experiments with this setup disclose vertical wind speed changes in the lower planetary boundary layer to be indirectly affected by temperature changes through thermodynamically-induced atmospheric stability alterations. Moreover, air density changes are identified to occasionally exceed the net impact of wind energy density changes originating from changes in wind speed. This supports the consideration of air density information (in addition to wind speed) for wind energy yiel assumptions. Thirdly, the generated climate and climate change information of the wind resource are transferred to a simplified but fully-fledged financial model to assess the financial risk of wind energy project financing with respect to changing climate conditions. Sensitivity experiments for an imaginary offshore wind farm located in the German Bight reveal the long-term profitability of wind energy project financing not to be substantially affected by changing wind resource conditions, but incidents with insufficient servicing of financial obligations experience changes exceeding -10% to 14%. The integration of wind energy-specific climate and climate change information into existing financial risk assessment procedures would illustrate a valuable contribution to enable climate change adaptation for wind energy.
Smartphones make intensive use of precious metals and so called conflict minerals in order to reach their high performance in a compact size. In recent times, sustainability challenges related to production, use and disposal of smartphones are increasingly a topic of public debate. Thus, established industry actors and newly emerging firms are driven to engage in more sustainable practices, such as sustainable sourcing of materials, maintenance services or take-back schemes for discarded mobile phones. Many of these latter efforts can be related to the concept of a circular economy (CE). This thesis explores how CE-related value creation architectures (VCAs) in the smartphone industry contribute to slowing and closing resource loops in a CE. In order to analyze these new industry arrangements, transaction cost theory (TCT) is used as a guiding theory for a make-or-buy analysis. Combining TCT with the concept of a CE is a novel research approach that enables the empirical analysis of relationships between focal actors (e.g. manufacturers) and newly emerging loop operators (e.g. recycling firms) in the smartphone industry. Case studies of such VCAs are conducted with case companies drawn from the Innovation Network on Sustainable Smartphones (INaS) at Leuphana Universtity of Lüneburg and analyzed regarding their involved actors, partnerships, circular activities, motivation and perceived barriers. Evidence from the conducted case studies suggests that asset specificity for circular practices increases for higher order CE-loops such as maintenance or reuse, therefore long-term partnerships between focal actors and loop operators or vertical integration of CE practices are beneficial strategies to reach a sophisticated CE. Similarly, circular practices that go beyond recycling require a strong motivation, either through integration in the focal firm´s quality commitment or through business model recognition. It is further suggested that the circular design of products and services could reduce necessary transaction costs and thus overall costs of a circular economy. Four different integration strategies for circular economy practices have been derived from the conducted case studies. These are: 1) vertically integrated loops, 2) cooperative loop-networks, 3) outsourcing to loop operators and 4) independent loop operators. This work thus provides evidence that circular economy activities do not necessarily have to be managed by focal actors in the value chain. Rather, circular practices can also be put forward by specialized loop operators or even independent actors such as repair shops.
Despite warnings from scientists and from society starting in the 1970s, we have long overshot our planetary boundaries – eroding biodiversity, changing our landscapes, and polluting our soil and atmosphere. Yes, efforts to change the unsustainable trajectories of our Earth system have increased through, for example, the Millennium Goals, the Sustainable Development Goals, or the Aichi Targets, but to no avail. The interventions to increase sustainability are conflicting on local, national and global levels, and often prioritise quick-fixes and short-term solutions instead of tackling the root causes of the “sustainability gap”. We, hence, need to find “places to intervene in complex systems that bring about transformative change” (Meadows 1999) – a premise and concept that Donella Meadows calls “leverage points”. Based on her seminal work, a team from the Leuphana University has identified three “realms of leverage” in which changes may lead to system transformation (Abson et al. 2017). One of these realms is the reconnection of humans to nature. In this habilitation, I focus on this realm of leverage and aim to (1) enhance the understanding of the influence of landscape change on human-nature relations through empirical, place-based research and comparisons across landscapes in different countries and continents; (2) identify and clarify the new concepts of relational values and leverage points; and (3) highlight empirical evidence on leverage points to foster human-nature relations for sustainability transformation, building mainly on empirical work done in six landscapes in Transylvania, Romania and Lower Saxony, Germany, but also including case studies from Ethiopia and India, systematic literature reviews and conceptual pieces. This thesis showed that cultural landscapes are changing with astonishingly comparable trajectories toward unsustainable futures. Our earth’s current environmental and climate crisis will continue to erode the fundaments of sustainability, hence, re-connecting humans to nature is of outstanding significance for transformative change. Identifying leverage points and implementing an intervention to strengthen human–nature relations will be a great challenge in the coming years. One possible leverage point can be strengthening experiential and emotional dimensions, as they specifically shape the connections people have with cultural landscapes. Further, this thesis highlighted the importance of the interlinkages between shallow and deep leverage points. Our results show that structurally complex landscapes and structurally rich social relations mediated by nature are interlinked and strengthening one, may strengthen the other. Moreover, strengthening sense of place and a sense of agency may enable self- and re-organization of cultural landscapes by opening the possibility to renegotiate people’s values for values and the goals of the social-ecological system, which, in turn, may enhance the structural diversity of landscapes and small-scale agriculture. Our results presented in this thesis also lay the ground for the hypothesis that degrading landscapes might also degrade social relations, which, in turn, can lead to contrasts and conflicts between actors and social groups. Although much work is still necessary to foster transformative change, this thesis offers innovative approaches. This thesis created and popularised the “Leverage points perspective”, including “chains of leverage”, as well as producing novel insights on human-nature relations – such as the distinction of human-nature connectedness and relational values, classifying relational value groups and empirically assessing dimensions of human-nature connectedness and relational values concerning landscape change and landscape features. These novel contributions can have wide-ranging impacts on the scientific discussions and societal implementation of interventions for sustainability.
Leverage points to foster human-nature relations for sustainability transformation
Fostering socio-economic development throughout all Member States is a fundamental goal of the European Union. With one third of its budget, the EU tries to support regional development in lessdeveloped regions and improve the life of its citizens. To reach its goal, a shift can be observed from a single sided focus on factor mobility and thus transportation and other infrastructure facilities to a higher diversity in approaches, including culture, the arts and creativity. Here, creative industries and innovation are keywords within Structural Funds, the main instrument of EU regional policies. However, very little is known on how cultural operators in the form of artists, opera houses etc. contribute to regional development by implementing Structural Funds projects. The framework conditions set on EU level are very open, allowing the sector to contribute in their own way to socioeconomic development. To improve the understanding of how cultural operators access Structural Funds this dissertation was guided by the question: What kind of strategies do cultural operators use to access Structural Funds in Poland? Or on a more abstract level: What are the formal and informal norms within the application process for cultural operators, and in which way do they impact the application strategies of cultural operators in Poland? By working on those questions, this dissertation is providing an insight into how cultural operators on the ground approach Structural Funds. The case study on cultural operators in Poland serves as a concrete example and gives a clearer picture of access strategies, barriers and facilitators within this process. Because research is scarce on this subject, a choice for an in-depth case study analysis within one country was taken. With a theoretical framework of sociological Neo Institutionalism, especially a model developed by Victor Nee and Paul Ingram (1998), the research focusses on different levels of interaction and the role of formal and informal norms. The model was modified to support the analysis of actors’ strategies, and explain the application process of cultural operators. Here, the focus was on the micro level (cultural operators) and its interaction with the meso level (national). The model was enriched at the end of the research with elements of Bourdieu’s theory of practise, namely his concepts of fields and capital. Poland was selected as case study country due to its unique position as the biggest new Member State with its long cultural tradition at the heart of Europe and a very positive formal framework for cultural projects within Structural Funds. The focus was on the years 2004-2007 and thus covered mainly the first funding period for Poland. As empirical evidence, 27 expert interviews were carried out with cultural operators and their environment in Poland. They were analysed on a qualitative basis, using Atlas.ti, and co-occurrence network views. The author conducted all interviews within a period of two months, and most of the interviews were conducted in English. Important steps within the analysis were the emergence of a project idea, the ‘melting’ of this idea into a project application, different challenges linked to the application process and information gathering as a crucial factor within this process. In the end, the findings were validated by three EU experts from the Commission and the European Parliament. Conclusions: Findings show that the application strategy is driven by a set of formal and informal norms. Among them one can find elements linked to financing and co-financing, access and distribution of information and capacity building in the form of knowledge gathering and experience. The informal channels proved to be especially valuable. Further, the organisation resources have a significant impact when applying for Structural Funds. This is not limited to sufficient financial means but also related to existing networks and knowledge of whom to ask for information and support. Here, reference can be made e.g. to Bourdieu’s concept of capitals. Based on those findings, a typology of three different actors’ groups with different challenges and project profiles was developed. It can be shown that their positions and strategies are influenced, not only by formal rules and norms, but also to a high level, by informal norms and structures. As a result, projects were generally implemented by rather big and well-established organisations. Most of them focussed on the conservation of cultural heritage or the construction of new, ‘classical’ cultural infrastructure such as museums and opera houses. However, innovation and creativity are thought to grow especially in smaller, often younger and ‘different’ settings. As the EU is interested in those elements to find a region-tailored solution to socio-economic development needs, a nearly exclusive focus on rather traditional flagship projects implemented by well-established organisations appears insufficient: In other words, there is a discrepancy between proclaimed possibilities and attempts within political statements and Structural Funds rules on one side and the picture on the ground on the other side. Thus, if the fostering of socio-economic development through innovation and new approaches is to emerge, attempts need to be taken to increasingly support cultural operators with less favourable given capital. The thesis presented enhances knowledge within these processes and therefore contributes to the improvement of the situation. Because only if conditions are analysed and known, processes on national and EU level can change and alternatives be considered. As a conclusion for the micro level, a strong networking and gathering of know-how independently from formal structures seems the most promising short-term approach. From a long-term perspective, a formalisation of networks and stronger lobbying, especially on national level but also on EU level will be needed if framework conditions are to change in favour of a more diversified and flexible approach.
Tropical forests worldwide support high biodiversity and contribute to the sustenance of local people’s livelihoods. However, the conservation and sustainability of these forests are threatened by land-use changes and a rapidly increasing human population. This dissertation, therefore, aimed to characterize biodiversity patterns in the moist Afromontane forests of southwestern Ethiopia and to examine how biodiversity patterns are affected by land-use and land-use changes (mediated by coffee management intensity, landscape attributes and housing development) in a context of a rapidly growing rural population. To achieve this goal, the author takes an interdisciplinary approach where, first, she examined the effects of coffee management intensity on diversity patterns of woody plants and birds, spanning a gradient of site-level disturbance from nearly undisturbed forest interior to highly managed shade coffee forests. Results showed that specialized species of woody plants (forest specialists) and birds (forest specialists, insectivores and frugivores) were affected by coffee management intensity. The richness of forest specialist trees and the richness and/or abundance of insectivores, frugivores and forest specialist birds decrease with increasing levels of disturbance. Second, the author investigated the effects of landscape context on woody plants, birds and mammals. Community composition and specialist species of woody plants and birds were sensitive to landscape context, where woody plants responded positively to gradients of edge-interior and birds to gradients of edge-interior and forest cover. Further results showed that a diverse mammal community, with 26 species, occurs at the forest edge of shade coffee forests and that the leopard, an apex predator in the region depended on large areas of natural forest. A closer examination of leopard activity patterns revealed a shift in the diel activity as a response to human disturbance inside the forest, further highlighting the importance of natural undisturbed forests for leopards in the region. Together, these findings demonstrate the value of low managed shade coffee forests for biodiversity, and importantly, emphasize the irreplaceable value of undisturbed natural forests for biodiversity. Third, the researcher investigated the effects of prospective rural population growth (mediated by housing development) on the forest mammal community. Here, population growth was projected to negatively influence several mammal species, including the leopard. Housing development that encroached the forest entailed worse outcomes for biodiversity than a combination of prioritized development in already developed areas and coffee forest protection. Fourth, to understand the motivations behind high human fertility rates in the region, she examined the determinants of women fertility preferences, including their perceptions on social and biophysical stressors affecting local livelihoods such as food insecurity and environmental degradation. Fertility preferences were influenced by underlying social norms and mindsets, a perceived utilitarian value of children and male dominance within the household, and were only marginally affected by perceptions of social and biophysical stressors. The findings suggest the need for new deliberative and culturally sensitive approaches that engage with pervasive social norms to slow down population growth. Overall, this dissertation demonstrates the key value of moist Afromontane forests in southwestern Ethiopia for biodiversity conservation. It indicates the need to promote coffee management practices that reduce forest degradation and highlights that high priority should be given to the conservation of undisturbed natural forests. It also suggests the need to integrate conservation goals with housing development in landscape planning. A promising approach to achieve the above conservation priorities would be the creation of a Biosphere Reserve and to promote the ecological connectivity between the larger forest remnants in the region. Finally, this dissertation demonstrates the importance of placed-based holistic approaches in conservation that consider both proximate and distal drivers of forest biodiversity decline.
Transformative learning is increasingly set to become an essential component in sustainability transformation. Despite, little has been done to systematically explore the contribution to sustainability transformation. This learning theory developed decades ago independently of sustainability discourses; however, it provides an analytical framework for understanding the learning processes, outcomes and conditions in individual and social learning towards sustainability transformation. Against this background, the following research question arises: To which extent can transformative learning lead to sustainability transformation? This doctoral work aims to explore transformative learning processes, outcomes, and conditions occurring and advancing towards sustainability transformation of the textile-fashion industry in Mexico. Taking an exploratory approach, the methods employed were literature reviews to untangle concepts and to construct theoretical pillars to support the empirical research design and data analysis. For data collection, snowball-sampling techniques were used to explore the practice field of the textile-fashion industry in Mexico. Qualitative interviews were employed to gather data about the learning experiences of actors. Qualitative and quantitative methods were required to perform the respective data analysis, the qualitative codification of interviewees' responses. Analysis of social media content was also utilised to understand the communication and business practices of projects involved in the transformation of the textile-fashion sector. As a result, this work comprises three articles, one a systematic literature review and two empirical research articles, investigating the transformative learning processes of entrepreneurs in the development of sustainability niches. As for the findings of this doctoral work, the use of transformative learning in sustainability transformation requires a careful study of the theory and its conceptual elements. Regarding the case study, transformative learning is inherent in forming and developing sustainability niches as entrepreneurs venture into them: It is individual prior learning, expectations and actions that initiate the path of sustainability transformation while disorienting dilemmas, critical reflection, and discourse accelerate them. Through these stages, it is when individual learning turns into social learning. On the other hand, based on the multi-level perspective, the interplay between the niche, regime and landscape levels generates a space for sustainability transformation and transformative learning.
Wood-pastures have been present in Europe for thousands of years. This form of grazed landscape, combining herbaceous vegetation with trees and shrubs, has often co-evolved with its human users into complex social-ecological systems (SES). Wood-pastures are associated with high cultural and biodiversity values and are an example of the sustainable use of resources. However, due to their often relatively labour-intensive management and low productivity, large areas of wood-pastures have been lost over the last century. The loss of these areas means not only the loss of biodiversity on both local and landscape scales, but also the loss of traditional farming and cultural heritage in some regions. Across the European Union, wood-pastures are facing different problems and are embedded in different social systems and ecological environments. Yet they are all affected by global change and common European policies. To understand the challenges for wood-pastures in a changing world, a holistic approach combining different disciplines is needed. This dissertation therefore is analyzing wood-pastures across Europe as a Social-ecological System, combining ecology and social science with the aim to identify the barriers and drivers for wood-pastures persistence into the future.
Human activities have become a major driver of global change, so that global society and economy are facing consequences such as climate change, increasing scarcity of resources, environmental pollution and degradation as well as disturbances of ecosystem functioning and services.In order to meet these main challenges in an appropriate way, adequate starting points and solutions must be pursued at all levels to shift the current socio-economic pathway from an unsustainable to a safe operating and thus sustainable development within the planetary boundaries. One of the application concepts in industrial contexts is Industrial Symbiosis (IS), which deals with the set-up of advanced circular/cascading systems, in which the energy and material flows are prolonged for multiple material and energetic (re-)utilization within industrial systems in order to increase resource productivity and efficiency, while reducing environmental impacts. The overarching goal of the research project was to identify and develop approaches to enable the evolution of Industrial Symbiosis (IS) in Industrial Parks (IPs). IS is a collaborative cross-sectoral approach to connect the resource supply and demand of various industries in order to optimize the resource use through exchange of materials, energy, water and human resources across different companies, while generating ecological, technical, social and economic benefits. Many Information Communication Technology (ICT) tools have been developed to facilitate IS, but they predominantly focus on the as-is analysis of the IS system, and do not consider the development of a common desired target vision or corresponding possible future scenarios as well as conceivable transformation paths from the actual to the defined (sustainability) target state. This gap shall be addressed in this work, presenting the software requirements engineering results for a holistic IT-supported IS tool covering system analysis, transformation simulation and goal-setting. This study also aims to present the conceptual IT-supported IS tool and its corresponding prototype, developed for the identification of IS opportunities in IPs. This IS tool serves as an IS facilitating platform, providing transparency among market players and proposing potential cooperation partners according to selectable criteria (e.g. geographical radius, material properties, material quality, purchase quantity, delivery period). Therefore a quantitative indicator system was compiled and recurring patterns were identified to utilize this knowledge in the comprehensive IT-supported IS tool. So this IS tool builds the technology-enabled environment for the processes of first screening of IS possibilities and initiation for further complex business-driven negotiations and agreements for long-term IS business relationships.
Determinants of Emotional Experiences in Traffic Situations and Their Impact on Driving Behaviour
(2013)
Emotions play a prominent role in explaining maladaptive driving and resulting motor vehicle accidents (MVAs). Above all, traffic psychologists have focussed their attention on anger and anxiety, including the origins and influence of these emotions on driving behaviours. This dissertation contributes to the field with three manuscripts that build upon each other. Those manuscripts have three separate objectives. The first identifies the broad range of emotions in traffic that should be analysed. Second, the impact of specific emotions on driving behaviour is focussed. Finally, the research investigates how situational and personal factors can influence emotional experiences and influence driving behaviour. The first article tackles the bandwidth of emotions in traffic. In two consecutive online studies (study one: = 100; study two: n = 187), different emotional experiences were assessed using the Geneva Emotion Wheel (and an advanced version). The stimulus material consisted of written traffic situations structured around specific factors (in these studies, predominantly goal congruence, goal relevance and blame). It could be shown that the properties of the situation can elicit emotions such as anger, anxiety and happiness, but also pride, guilt and shame. The second article saw a transfer of those situational factor structures from online-presented text to simulated driving. At this time, the focus of interest was the driving behaviour influenced by the elicited emotions. The simulator study (n = 79) revealed that anger, contempt and anxiety led to similar declines in driving performance profiles. Performance declines included driving at higher speeds, more frequent speeding and worse lateral control. The third article examined to what extent anger and personal characteristics could negatively influence driving behaviour. Two studies were conducted (study one: n = 74; study two; n = 80). The results indicated that specific characteristics of the person (male, little driving experience, high driving motivation, high trait-driving anger) could influence driving behaviour in negative ways, both directly and indirectly, via triggered anger emotions. It can be concluded from these results that the range of emotions in traffic encompasses much more than just anger and anxiety. Furthermore, the second and third articles show that within simulated environments, minimal but effective emotional intensities can be triggered, and those emotions (especially anger and anxiety) create similar performance patterns. Personal characteristics should be considered when explaining the elicitations of emotion and subsequent driving behaviour. The papers of this dissertation echo the call for new comprehensive models to explain the relationships among emotions and traffic behaviours.