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Educational research has shown that reflection and feedback are crucial for substantial development of pre-service teachers' professional competence. However, reflection and feedback sessions are not a standard element of teaching practicums due to time- and location-constraints. Digital practicum environments can lift these constraints. Digital reflection and feedback environments have typically applied either textual accounts or video sequences of classroom practice, with varying effects. Consequently, the studies presented in this cumulative dissertation are focused on how the use of text- or video-based digital reflection and feedback environments during a practicum influence specific components of pre-service teachers' professional competence (i.e., beliefs about teaching and learning, self-efficacy, professional vision of classroom management, feedback competence). All studies followed a quasi-experimental, pre-test-post-test design. Pre-service teachers at the fourth-semester bachelor level in a German university took part in the studies. Pre-service teachers participated in a four-week teaching practicum at local schools. During the teaching practicum, pre-service teachers were divided into five different groups. The control group (CG) took part in a traditional practicum with live observations and face-to-face reflection and feedback with peers and experts. Pre-service teachers of the intervention groups (IG 1, IG 2, IG 3, IG 4) reflected and received feedback in highly structured text- or video-based digital environments. Intervention groups 1 (IG 1) and 2 (IG 2) participated in a text-based digital reflection and feedback environment. While IG 1 participants only received feedback from peers, IG 2 pre-service teachers also received expert feedback. Intervention groups 3 (IG 3) and 4 (IG 4) took part in a video-based digital reflection and feedback environment. IG 3 pre-service teachers only received peer feedback, whereas IG 4 participants also received expert feedback. Mixed methods were applied by generating quantitative and quantitative-qualitative data was with questionnaires, a standardized video-based test and content analysis. The studies demonstrated that classroom videos and video-based digital reflection and feedback environments can effectively enhance pre-service teachers' professional competence. This finding can be predominantly attributed to two characteristics of the application in the digital reflection and feedback environments: (a) being able to revisit a multitude of authentic teaching situations without time pressure and (b) the degree of decomposition by deliberate, focused practice and scaffolding elements. Furthermore, expert feedback seemed to be of better quality and entailed more substantial effects than peer feedback. The results of the conducted studies on professional vision of classroom management, beliefs about teaching and learning and feedback competence showed that expert feedback can be seen as a lens reducing and focusing classroom complexity, enabling pre-service teachers to perceive crucial teaching situations that would have otherwise gone unnoticed and to benefit from expert modelling of high-quality feedback. Consequently, video-based digital reflection and feedback environments with expert feedback can significantly improve pre-service teachers' professional competence during teaching practicums and, thus, better prepare pre-service teachers for future classroom challenges, leading to better learning environments for school students.
In this dissertation, a multi-proxy study, which included palaeoecological, lithological, geochemical and geochronological methods, was carried out to investigate climatic and environmental changes and their interaction during the Quaternary in formerly glaciated and non-glaciated areas. The information obtained will be used to provide a better understanding of the regional stratigraphic framework and to establish broader regional terrestrial correlations within the global marine isotope stage (MIS) framework. This study was conducted on two key drillings, the Garding-2 research drill core in the German North Sea coastal area of Schleswig-Holstein and the GBY#2 archaeological core at the Gesher Benot Ya'aqov (GBY) site, in the Upper Jordan Valley in Israel. The results of this study are presented in three papers. Papers I and II focus on the study of the Garding-2 core, while the multi-proxy study of the GBY#2 core is presented in Paper III. The results of a variety of analyses conducted on the 240 m long Garding-2 sequence show interglacial-glacial cycles that are mainly controlled by variations in temperature. This sequence is composed of mainly fluvial-shallow marine sediments intercalated by muddy-peaty deposits. Based on the palynological and lithological findings, the Pliocene-Pleistocene transition was observed at 182.87 m. It is overlain by Praetiglian and the subsequent sediments of the Waalian and Bavelian Complexes. The boundary of either the second or third Cromerian Interglacial with younger sediments, which still belong to MIS 19, is marked by the last occurrence of Tsuga at 119.50 m and the development of mixed-deciduous forests. The palynologically equivalent sediments of the Bilshausen Interglacial were found below two Elsterian till layers, at 89.00 m-82.00 m. These sediments showed high and increased percentages of Pinus and Picea and scattered occurrences of Abies and Carpinus, which are similar to the features of the beginning of the Bilshausen or Rhume interglacial. An unconformity occurred at 80.29 m, at the bottom of late Holsteinian deposits, characterised by the occurrences of Fagus and Pterocarya, with low percentages of Abies and Carpinus and the absence of Buxus. These deposits are succeeded by sediments of the Fuhne cold period that shows higher percentages of NAP and occurrences of Ericales, Helianthemum and Selaginella selaginoides, which are unconformably overlain by Drenthian till at 73.00 m-71.00 m. A single peaty sample at 69.25 m with Pinus-Picea-Abies assemblage is correlated with the late Eemian Interglacial. This deposit is overlain by Weichselian glaciofluvial sediments. Middle-late Holocene sediments occurred from 20 m upwards, following a hiatus, which was caused by the Early Holocene transgression. A subsequent thin layer of marine Atlantic sediments is unconformably overlain by marine-tidal flat deposits up to 11.00 m. The first occurrence of Fagus (at 15.97 m) and Carpinus (at 15.03 m), which was optically stimulated luminescence (OSL)-dated to 3130 +/- 260 BP (at 16.22 m, Zhang et al., 2014), gives evidence for a Subboreal age for these deposits. Sandy sediments of the early Subatlantic, which were deposited between 11.00 m and the top of the Garding-2 sequence, indicate that local salt marshes, dunes and tidal flat vegetation expanded during this period. Due to regional features and the peculiarities of the local coastal environment, the expansions of Fagus and Carpinus, which are characteristic for the Subboreal-Subatlantic transition at about 2700 BP in northern Germany, are not clearly reflected in the Garding-2 pollen diagram. In the Mediterranean area, a 50 m long core of GBY#2, was drilled at the Acheulian site of Gesher Benot Ya'akov. The GBY#2 core provides a long Early-Middle Pleistocene geological, environmental and climatological record, which also enriches the knowledge of hominin-habitat relationships documented at the margins of the Hula Palaeo-lake. The sediment sequence of GBY#2 is under- and overlain by two basalt flows that are 40Ar/39Ar dated: two samples at the bottom of the core dated to 1195 +/- 67 ka (at 48.30 m) and 1137 +/- 69 ka (at 45.30 m), and another one at the top dated to 659 +/- 85 ka (at 14.90 m). With the additional chronological identification of the Matuyama Brunhes Boundary (MBB) and the correlation with the GBY excavation sites, the sedimentary sequence of GBY#2 provides the climatic history during the late part of the mid-Pleistocene transition (MPT, 1.2 Ma-0.5 Ma). Multi-proxy analyses including those of pollen and non-pollen palynomorphs, macro botanical remains, molluscs, ostracods, fish, amphibians and micromammals provide evidence for lake and lake-margin environments during MIS 20 and MIS 19. During MIS 20, relatively cool semi-moist conditions were followed by a pronounced dry phase. During the subsequent MIS 19, warm and moist interglacial conditions were characterised by Quercus-Pistacia woodlands in this area. The depositional environment changed from an open water lake during MIS 20 to a lake margin environment in MIS 19. This finding is at odds with changing climate conditions from relatively dry to moist. This discrepancy could be explained by the prograding pattern of the lake shore due to the infilling of the basin, which resulted in shallower water. Climatic changes during the Late Tertiary and the Quaternary in the high latitude regions in northwest Europe and during the Early-Middle Pleistocene in the mid latitude regions of the Middle East follow the patterns of global climatic changes, which are mainly controlled by orbital obliquity (+/-41 ka cycle) during the Early Pleistocene and by orbital eccentricity (+/-100 ka cycle) during the MPT (1.2 Ma-0.5 Ma) and the younger periods of the Quaternary. The results of this study also provide reliable evidence for long distance correlation of stratigraphic and climatic events of the Quaternary, which extends knowledge of regional and global impact of climatic fluctuations on the environment.
Organizational culture is widely acknowledged to be a driver of organizational effectiveness. However, existing empirical research tends to focus on investigating the links between individual, isolated culture dimensions and effectiveness outcomes. This approach is at odds with the theoretical roots of organizational culture and does not do justice to the complex reality that most organizations face. This issue is addressed by this dissertation, which is comprised of four studies. Study 1 investigated the psychometric quality and cultural equivalence of three culture measures in a German context, based on a sample of 172 employees in a bank. The results suggested that the German versions of the Denison Organizational Culture Survey and the Organizational Culture Profile performed satisfactorily, while results regarding the GLOBE survey fell short of expectations. Study 2 reviewed the literature on the link between culture and effectiveness with a focus on studies that treat organizational culture as a holistic phenomenon. The review yielded four kinds of holistic approaches (aggregation-based, agreement-based, moderation- or mediation-based, and configuration-based). Study 3 investigated how a change in organizational culture induced by an M&A project impacts employee commitment. Based on a sample of 180 employees in a German organization, the findings suggest that individuals perceive cultural change differently, that cultural stability is positively related to employee commitment, and that group-level leader-member exchange and individual self-efficacy moderate this relationship. Study 4 introduced a new theoretical perspective (set theory) and a novel methodology (fuzzy set qualitative comparative analysis) to the field of organizational culture. Across two samples (1170 employees in a financial service provider and 998 employees in fashion retailer), results indicated that culture dimensions do not operate in isolation, but jointly work together in achieving different effectiveness outcomes.
The transition of our energy system towards a generation by renewables, and the corresponding developments of wind power technology enlarge the requirements that must be met by a wind turbine control scheme. Within this thesis, the role of modern, model-based control approaches in providing an answer to present and future challenges faced by wind energy conversion systems is discussed. While many different control loops shape the power system in general, and the energy conversion process from the wind to the electrical grid specifically, this work addresses the problem of power output regulation of an individual turbine. To this end, the considered control task focuses on the operation of the turbine on the nonlinear power conversion curve, which is dictated by the aerodynamic interaction of the wind turbine structure and the current inflow. To enable a power tracking functionality, and thereby account for requirements of the electrical grid instead of operating the turbine at maximum efficiency constantly, an extended operational range is explicitly considered in the implemented control scheme. This allows for an adjustment of the produced power depending on the current state of the electrical grid and is one component in constructing a reliable and stable power system based on renewable generation. To account for the nonlinear dynamics involved, a linear matrix inequalities approach to control based on Takagi-Sugeno modeling is investigated. This structure is capable of integrating several degrees of freedom into an automated control design, where, additionally to stability, performance constraints are integrated into the design to account for the sensitive dynamical behavior of turbines in operation and the loading experienced by the turbine components. For this purpose, a disturbance observer is designed that provides an estimate of the current effective wind speed from the evolution of the measurements. This information is used to adjust the control scheme to the varying operating points and dynamics. Using this controller, a detailed simulation study is performed that illustrates the experienced loading of the turbine structure due to a dynamic variation of the power output. It is found that a dedicated controller allows wind turbines to provide such functionality. Additionally to the conducted simulations, the control scheme is validated experimentally. For this purpose, a fully controllable wind turbine is operated in a wind tunnel setup that is capable of generating reproducible wind conditions, including turbulence, in a wide operational range. This allows for an assessment of the power tracking performance enforced by the controller and analysis of the wind speed estimation error with the uncertainties present in the physical application. The controller showed to operate the turbine smoothly in all considered operating scenarios, while the implementation in the real-time environment revealed no limitations in the application of the approach within the experiments. Hence, the high flexibility in adjusting the turbine operating trajectories and structural design characteristics within the model-based design allows for efficient controller synthesis for wind turbines with increasing functionality and complexity.
In the face of uncertainty, ecosystems can provide natural insurance to risk averse users of ecosystem services. We employ a conceptual ecological-economic model to analyze the allocation of (endogenous) risk and ecosystem quality by risk averse ecosystem managers who have access to financial insurance, and study the implications for individually and socially optimal ecosystem management, and policy design. We show that while an improved access to financial insurance leads to lower ecosystem quality, the effect on the free-rider problem and on welfare is determined by ecosystem properties. We derive conditions on ecosystem functioning under which, if financial insurance becomes more accessible, (i) the extent of optimal regulation increases or decreases; and (ii) welfare, in the absence of environmental regulation, increases or decreases.
Maximizing the value from data has become a key challenge for companies as it helps improve operations and decision making, enhances products and services, and, ultimately, leads to new business models. While enterprise architecture (EA) management and modeling have proven their value for IT-related projects, the support of enterprise architecture for data-driven business models (DDBMs) is a rather new and unexplored field. The research group argues that the current understanding of the intersection of data-driven business model innovation and enterprise architecture is incomplete because of five challenges that have not been addressed in existing research: (1) lack of knowledge of how companies design and realize data-driven business models from a process perspective, (2) lack of knowledge on the implementation phase of data-driven business models, (3) lack of knowledge on the potential support enterprise architecture modeling and management can provide to data-driven business model endeavors, (4) lack of knowledge on how enterprise architecture modeling and management support data-driven business model design and realization in practice, (5) lack of knowledge on how to deploy data-driven business models. The researchers address these challenges by examining how enterprise architecture modeling and management can benefit data-driven business model innovation. The mixed-method approach of this thesis draws on a systematic literature review, qualitative empirical research as well as the design science research paradigm. The investigators conducted a systematic literature search on data-driven business models and enterprise architecture. Considering the novelty of data-driven business models for academia and practice, they conducted explorative qualitative research to explain "why" and "how" companies embark on realizing data-driven business models. Throughout these studies, the primary data source was semi-structured interviews. In order to provide an artifact for DDBM innovation, the researchers developed a theory for design and action. The data-driven business model innovation artifact was inductively developed in two design iterations based on the design science paradigm and the design science research framework.
Recent studies have confirmed that the aquatic ecosystem is being polluted with an unknown cocktail of pharmaceuticals, their metabolites and/or their transformation products (TPs). Although individual pharmaceuticals are typically present at low concentrations, their continuous input into the aquatic ecosystem and their toxic and persistent presence are the major environmental concerns. Therefore, it is necessary to assess the environmental risk caused by these aquatic pollutants. Data on exposure are required for quantitative risk assessment of parent compounds and their transformation products (TPs) and/or metabolites. Such data are mostly missing, especially for TPs, because of the non-availability of TPs and very often metabolites for experimental testing. Therefore, the application of different in silico tools for qualitative risk assessment can be used. Also, the presence of these micro-pollutants (active pharmaceutical ingredients, APIs) in the aquatic cycle are increasingly seen as a challenge to the sustainable management of water resources worldwide due to ineffective effluent treatment and other measures for their input prevention. Given the poor prognosis for effluent treatment (‘end of the pipe’ approach) for input prevention of APIs in the environment, it is necessary to focus on the ‘beginning of the pipe’ strategy. The very beginning of the pipe is the molecules themselves. Therefore, novel approaches are needed like designing greener pharmaceuticals, i.e. better biodegradable ones in the aquatic environment after their release. Therefore, the present research work focused on two important topics a) assessment of the environmental risk associated with the presence of highly prescribed drugs and their TPs; b) demonstrating the feasibility of the ‘benign by design’ concept for designing biodegradable drug derivatives, which will have the better biodegradability in the environment after their release. The present thesis includes four research articles (1-4) which address these approaches. The first article is about the qualitative environmental risk assessment using the example of transformation products formed during photolysis (photo-TPs) of Diatrizoic acid (DIAT). Photolysis is the chemical reaction in which the compound is broken down by photons and often in combination with hydroxyl radicals. Photolysis is the most common abatement process of micro-pollutants in the environment. The qualitative risk assessment of DIAT and selected photo-TPs was performed by the PBT approach (i.e. Persistence, Bioaccumulation and Toxicity), using chemical analysis, experimental biodegradation test assays, QSAR models with several different toxicological endpoints and in silico read-across approaches. The second article addresses a tiered approach of implementing green and sustainable chemistry principles for theoretically designing better biodegradable and pharmacologically potent pharmaceuticals derivatives. Photodegradation process coupled with LC-MSn analysis, biodegradability testing and in silico tools such as quantitative structure-activity relationships (QSAR) analysis and molecular docking proved to be a very significant approach for the preliminary stages of designing chemical structures that would fit into the ´benign by design´ concept in the direction of green and sustainable pharmacy. Metoprolol (MTL) was used as an example. The third article was also the conceptual framework to get new drug derivatives that are biodegradable in order to tackle the global challenge of micro-pollutants in the aquatic cycle. This study increased the knowledge about the role of the attachment of certain functionalities to the parent drug molecule for its biodegradability whilst conserving drug-likeness. This approach was in the past a totally neglected issue within drug development. Atenolol (ATL), a selective β1 blocker, was selected as an example to incorporate the additional attribute such as biodegradability into its molecular structure while conserving its substructures responsible for β adrenergic receptor blocker activity. In fourth article, the concept of designing green biodegradable pharmaceuticals has been proven through expanded experimental analysis setting out from the experiences collected as described in article two and three. This study could be considered as a more extensive feasibility study of rational design of green drug derivatives. The non-selective β-blocker Propranolol (PPL) was used as an example. The risk assessment study (Article #1) contributes in enhancing the existing knowledge about the life cycle and behavior (fate) of pharmaceuticals with a special focus on photo-TPs which are generally formed during advanced effluent treatment and enter as such into the environment. Based on the obtained results, the application of the in silico tools for qualitative risk assessment analysis increased knowledge space about the environmental fate of TPs in case of their non-availability for experimental testing. The benign by design studies (Article #2-4) were based on the knowledge and experience collected during the work on DIAT. It demonstrated the feasibility of a novel approach of designing comparatively better degradable and pharmacological potent derivatives through the implementation of ´green chemistry´ principles. However, the present approach is in the juvenile stage and further knowledge has to be collected beforehand for the full implementation of this approach into drug development.
The global coffee market is connected to many sustainability issues like the persisting poverty of coffee farmers, and degrading ecosystems. Many interventions, from state-led regulation to industry-led certification processes, exist, that try to change global value chains to shift societies back on more sustainable trajectories. To this date, it is still under debate if these interventions are an effective means to change global value chains. With climate change and persisting issues of social justice as strong accelerators, calls are increasingly made for a radical transformation of global production and consumption patterns. Many frameworks try to inform research and real-world policies for a transformation of global value chains. In this dissertation, the author uses the framework of the practical, political and personal sphere proposed by O'Brien and Sygna (2013) highlighting that the interactions between these three spheres bare the greatest potential for a transformation towards sustainability. However, in this dissertation, the author argues that it is exactly at the nexus between the three spheres of transformation where barriers towards a fundamental shift of systems occur. He, therefore, uses three perspectives to bring empirical nuance to the problems that arise on the interplay between the different spheres of transformation. (1) The scientific perspective: using a systematic review of alternative trade arrangements; (2) the producer perspective: facilitating a participatory network analysis of social-ecological challenges of Ugandan coffee farmers and their adaptive management practices; (3) the consumer perspective: through the use of a German consumer survey and a structural equation model to investigate into the Knowledge-Doing-Gap end-consumers are facing. Through the results from the scientific perspective, the author is able to show that most of the research is investigating the certified market and that the effectiveness of labels rarely exceeding the practical sphere. His empirical research on the producer perspective highlights that Ugandan coffee farmers facilitate a variety of on-farm crop management (practical sphere) but their support structures rarely exceed informal exchange with neighboring communities (political sphere). Exchange with governmental actors and global traders is happening but has been assessed as not sufficient to cope with the social-ecological challenges the producers are facing. Through the results of the consumer perspective, the author is able to highlight that even though end-consumers have pro-sustainable attitudes (personal sphere) they are facing situational constraints (political sphere) that create a gap between their attitudes and the respective behavior. Using these empirical insights about drivers and barriers for a transformation he proposes that frameworks, aiming to inform research and policies, need to include two aspects: (1) the notion of a forced transformation; and (2) the translational capacity of the frameworks to create meaningful interdisciplinary discourses in different contexts. The author, therefore, propose two approaches:(1) a fourth sphere, called the "planetary force" to include the notion of a forced transformation that is already happening in different contexts, highlighted by the producer perspective in this dissertation; and (2) the consequent use of methods that create interdisciplinary exchange and rigorous testing.
Since the early 2000s, ecosystem services strongly gained significance as a research topic. However, the temporal dimension of ecosystem services has not been taken into consideration, although this should be the basis for a sustainable long-term management of ecosystems and their services. Therefore, the author presents three articles in this thesis that deal with temporal aspects of ecosystem services. In two of them she also present a proposal for a framework for the classification of ecosystem services based on their temporal dynamics. In this dissertation she differentiates between two types of temporal aspects, both of which have in common that change takes place over a certain period of time. The concepts of transformation, transition and regime shift are used to describe changes in social or ecological systems as a whole, for example the transformation towards a more sustainable society. The temporal dynamics, on the other hand, relate to the temporal changes in ecosystem services themselves. The first article focuses on how the literature on ecosystem services incorporates social and ecological change. The second and third articles deal with the temporal dynamics of ecosystem services. While the second article presents a preliminary framework for categorizing the temporal dynamics of ecosystem services, the third article uses this framework to test how the temporal dynamics of ecosystem services are represented in the literature. Based on the insights from the three articles, the author concludes that most of the studies on ecosystem services only focus on one point in time. One reason for this is that most studies are conducted over a maximum of a four-year time span which does not allow to monitor dynamics over longer time spans.
This thesis aims to provide a quantitative, cross-nationally comparative, longitudinal and multilevel study of the drivers and hindrances of national governments' anti-trafficking measures. In this research, both macro-level determinants of anti-trafficking enforcement and micro-level foundations of human trafficking are explored. In the manuscript, large-N comparative research examines how characteristics of countries interact with people's attitudes towards violence to better understand what creates environments that are more or less supportive of governments' anti-trafficking efforts. The results presented in the thesis speak not only in favor of studying this topic systematically and cross-nationally, addressing existing gaps in the literature but also in favor of combining macro- and micro-level evidence for developing more effective policy responses against human trafficking.