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Institut
- Fakultät Nachhaltigkeit (165) (entfernen)
Nachhaltigkeitsziele im Sinne einer Ökologie, Ökonomie und Soziokultur lassen sich im Bauwesen auf verschiedene Instrumente zurückführen. Optimierung des Wärmeschutzes durch die Energieeinsparverordnung (Effizienz) oder Minimierung von Abfall im Kreislaufwirtschaftsgesetz (Suffizienz). Um jedoch eine neue Qualität der Nachhaltigkeit zu schaffen, ist ein Paradigmenwechsel notwendig. Dabei können Cradle to Cradle Prinzipien als ökoeffektive Methode angewandt werden, in dem exemplarisch die Biodiversität eingebunden, gesunde Bauprodukte verbaut und erneuerbare Energien genutzt werden. Die Natur dient als Vorbild (Konsistenz). Demnach werden Gebäude nützlich für Mensch, Umwelt und Gesellschaft umgesetzt und gleichzeitig Werte geschaffen. Für den deutschen Einzelhandel bestehen vielschichtige Potenziale, da der Gebäudebestand mit mehreren Millionen Quadratmetern bedeutend ist und die Bauwerke aufgrund von Konzeptänderungen oder Verschleiß der Ladenflächen regelmäßig umgebaut werden. Die Forschung beginnt mit einer Bestandsaufnahme von Cradle to Cradle Bauprodukten und Analyse eines real umgesetzten Einkaufszentrums. Um Einflussfaktoren von Stakeholdern zu identifizieren, wurden qualitative Experteninterviews mit ausgewählten Projektbeteiligten aus Bauherrn, Betreibern, Beratern, Mietparteien und Herstellern durchgeführt. Im Rahmen des Forschungsvorhabens wurde untersucht, inwieweit sich Bauprodukte aus der Gebäudeplanung in wissenschaftlicher Theorie und praktischer Bauwirtschaft umsetzen lassen, Geschäftsmodelle anwendbar sind, Trends und Innovationen im Zusammenhang stehen oder Änderungen in Politik oder Wirtschaft notwendig sind. Im Ergebnis wurden Maßnahmen für eine neue Qualität der Nachhaltigkeit bei Einzelhandelsgebäuden identifiziert. Exemplarisch wird anhand der Interviews deutlich, dass neben einem staatlichen Umweltzeichen oder einer Green Building Planungsdisziplin, insbesondere die Ökonomie in Form von Investitions- und Betriebskosten den größten Stellenwert besitzt. Es braucht einen staatlichen Regulierungsrahmen und neue Geschäftsmodelle, damit nachhaltige Bauprodukte wirtschaftlich werden und durch Stakeholder in den Prozessen der Planung, Bauausführung und dem Betrieb berücksichtigt werden.
A Matter of Connection: Competence Development in Teacher Education for Sustainable Development
(2021)
Based on a dual case study, this cumulative dissertation investigates how individual "education for sustainable development" (ESD) courses, as part of the teacher education programs at Leuphana University in Lüneburg/Germany and Arizona State University (ASU)/USA, actually foster students' ESD-specific professional action competence. Furthermore, this work sheds light on the link between learning processes and outcomes, to reveal which factors actually affect the achievement of ILOs and competence development. The findings of this study indicate that both courses under investigation eventually live up to their role and increased student teachers' competence and commitment to implement ESD in their future careers; yet, mainly due to their different thematic foci, to varying degrees. Additionally, the four Cs (personal, professional, social, and structural connections) were revealed as significant factors that support students' learning and should be considered when planning and designing course offerings in TESD, with the goal of developing students' knowledge, skills, and attitudes.
Das Promotionsprojekt, das in das Forschungsprojekt Nawi-In (Naturwissenschaftlichen Unterricht inklusiv gestalten – Kompetenzentwicklung von Lehramtsstudierenden für und mit der Praxis) eingebettet ist, fokussiert die Entwicklung von Analysekompetenzen Masterstudierender der Sekundarstufe I mit naturwissenschaftlichem Fach, inklusiven naturwissenschaftlichen Unterricht zu identifizieren und zu analysieren. Hierfür analysierten die Masterstudierenden (N=5) sowohl eigenen videografierten als auch fremden inklusiven naturwissenschaftlichen Unterricht im Rahmen eines dreisemestrigen Projektseminars. Die Begleitforschung, die im ersten und zweiten Semester des Projektseminars stattfand, untersuchte die Entwicklung der Merkmalsausprägungen der Selbstwirksamkeit, Einstellungen und des selbsteingeschätzten fachdidaktischen Wissens (PCK) in Bezug zu inklusivem naturwissenschaftlichen Unterricht. Der Kern der Forschung ist die Entwicklung eines Modells, um die video-stimulierten Reflexionen zum eigenen (pre und post) und fremden inklusiven naturwissenschaftlichen Unterricht (pre, re und post), die audiografiert und transkribiert wurden, auszuwerten und so eine Entwicklung der Analysekompetenzen über die verschiedenen Erhebungszeitpunkte hinweg feststellen und abbilden zu können. Das Analytical Competency Model (ACM) ist ein Kategoriensystem, das aus verschiedenen Forschungen zu Professionalisierung, Expertiseforschung über Lehrpersonen und professioneller Unterrichtswahrnehmung besteht. Validiert wurde das ACM durch das Erstellen eines Expertenratings. Die Ergebnisse zeigen eine deutliche Entwicklung der Analysekompetenzen in der Studierendenstichprobe. Es wurden über den Erhebungszeitraum hinweg mehr Momente als inklusiver naturwissenschaftlicher Unterricht identifiziert und die identifizierten Momente in übergeordnete Konzepte zu inklusivem naturwissenschaftlichen Unterricht eingeordnet.
The world wide population growth and the increasing water scarcity endanger more and more the human society. Water saving measures alone will not be sufficient to solve all associated problems. Therefore, people in arid countries might come back to any kind of water available. In this context the way people regard wastewater must change in terms that it has to be recognized as a water resource. The reuse of wastewater, treated and untreated, for irrigation purposes in agriculture is already established in some semi-arid and arid countries. Countries with absolute water scarcity like Israel might not only be forced to reduce their water consumption, but even to transfer reused water to other sectors. Concerns of authorities and the general public about potential health risks are completely understandable. The health risks of wastewater are mainly originating from pathogens which are negatively correlated with its treatment. Therefore, the quality of a wastewater effluent derived from mechanical-biological treatment can be further improved by additional treatment steps like soil aquifer treatment (SAT). This process is adopted at the Israeli Shafdan facility in the south of Tel Aviv. Conventionally treated wastewater is applied on surface basins from where it percolates into the coastal plain aquifer which supplies approximately one quarter of Israel ́s drinking water. After a certain residence time in the subsurface the water is recovered by wells surrounding the recharge area. Although the pumping regime creates a hydraulic barrier to the pristine groundwater, concerns exist that a contamination of the surrounding drinking water wells could occur. So far, little is known about the removal of organic trace pollutants during the SAT process in general and for the Shafdan site in particular. Consequently, the need arose to study the purification power of the SAT process in terms of the removal of organic trace pollutants. For this purpose reliable wastewater tracers are essential to be able to differentiate between degradation and sorption processes on the one hand and dilution with pristine groundwater on the other hand. Based on their chemical properties, their worldwide usage in a variety of foodstuffs and beverages, and first data about the fate and occurrence of sucralose, artificial sweeteners came into the focus as promising tracer candidates.
Thus, in the present work an analytical method for the simultaneous determination of seven commonly used artificial sweeteners in different water matrices, like surface water and wastewater, was developed (see chapter 2). The method is based on the solid phase extraction (SPE) of the analytes by a styrene-divinylbenzene (SDB) copolymer material, and the analysis by liquid chromatography-electrospray ionization tandem mass-spectrometry (LC-ESI- MS/MS). The sensitivity in negative ionization mode was considerably enhanced by postcolumn addition of the alkaline modifier tris(hydroxymethyl) aminomethane. In potable water, except for aspartame and neohesperidine dihydrochalchone, absolute recoveries >75 % were obtained for all analytes under investigation, but were considerably reduced due to matrix effects in treated wastewater. The widespread distribution of the artificial sweeteners acesulfame, saccharin, cyclamate, and sucralose in the aquatic environment was proven. Concentrations in two German wastewater treatment plant (WWTP) influents ranged up to 190 μg/L for cyclamate, several tens of μg/L for acesulfame and saccharin, and about 1 μg/L for sucralose. For saccharin and cyclamate removal rates >90 % during wastewater treatment were observed, whereas acesulfame and sucralose turned out to be very persistent. As a result of high influent concentrations and low removal rates in WWTPs, acesulfame was the dominant sweetener in German surface waters with concentrations up to 2.7 μg/L. The detection of acesulfame and sucralose in recovery wells in the Shafdan SAT site in Israel in the μg/L range was a promising sign for their possible use as anthropogenic markers. As acesulfame and sucralose showed a pronounced stability in WWTPs and were detected in recovery wells of the SAT site in Israel it became worthwhile to assess their tracer suitability compared to other organic trace pollutants suggested as anthropogenic markers in the past (see chapter 3). Therefore, the prediction power of the two sweeteners was evaluated in comparison with the antiepileptic drug carbamazepine (CBZ), the X-ray contrast medium diatrizoic acid (DTA) and two benzotriazoles (1H-benzotriazole (BTZ) and its 4-methyl analogue (4TTri)). The concentrations of these compounds and their ratios were tracked from WWTPs with different treatment technologies, to recipient waters and further to river bank filtration (RBF) wells. Additionally, acesulfame and sucralose were compared with CBZ during advanced wastewater treatment by SAT in Israel. Only the persistent compounds acesulfame, sucralose, and CBZ showed stable ratios when comparing influent and effluent
concentrations of four German WWTPs with conventional wastewater treatment. However, by the additional application of powdered activated carbon in a fifth WWTP CBZ, BTZ, and 4-TTri were selectively removed resulting in a pronounced shift of the concentration ratios towards the nearly unaffected sweeteners. Results of a seven months monitoring program along the rivers Rhine and Main showed an excellent correlation between CBZ and acesulfame concentrations (r2 = 0.94), and still good values when correlating the concentrations with both benzotriazoles (r2 = 0.66 - 0.82). In RBF wells acesulfame and CBZ were again the compounds with the best concentration correlation (r2 = 0.85).
Das ubiquitäre Vorkommen von Arzneimittelrückständen ist eng mit möglichen Risiken für Mensch und Umwelt verbunden. Das übergeordnete Ziel dieser Forschungsarbeit ist die Weiterentwicklung methodischer Ansätze für die Identifizierung prioritärer Arzneimittelrückstände vor dem Hintergrund bestehender Wissens- und Regulierungslücken. Unter diesem Gesichtspunkt wurden drei aktuelle Problemfelder aus dem Themenkomplex "Arzneimittel in der Umwelt " ausgewählt und anhand konkreter Fallbeispiele betrachtet. Tierarzneimittel werden häufig mit der Ausbringung von Wirtschaftsdünger in landwirtschaftlich genutzte Böden eingetragen. Gegenstand der ersten Publikation ist die Frage, inwiefern Anwendungsschemata aus der Nutztierhaltung für die retrospektive Identifizierung prioritärer Tierarzneimittelrückstände genutzt werden können. Hierzu wurde eine spezielle Herangehensweise entwickelt und am Beispiel von Antibiotika erprobt. Die durchgeführte Eintragsabschätzung ermöglichte erstmalig eine umfassende Einschätzung der potenziellen Antibiotikabelastung in Wirtschaftsdünger und landwirtschaftlich genutzten Böden im nordwestdeutschen Raum. Die Ergebnisse deuten auf erhebliche Umwelteinträge hin, die eine Neubewertung bestehender Wirkstoffzulassungen notwendig erscheinen lassen. In der zweiten Publikation wurden am Beispiel einer Mischung aus 18 Arzneistoffen verschiedene Bewertungsansätze verfolgt, um das Risiko einer kombinierten antimikrobiellen Wirkung genauer zu charakterisieren und prioritäre Mischungsbestandteile zu identifizieren. Das Risiko einer antimikrobiellen Wirkung wurde sowohl durch eine experimentelle Prüfung der Mischung als auch durch einen komponentenbasierten Berechnungsansatz bestätigt. Der komponentenbasierte Ansatz verdeutlichte zudem die besondere Relevanz der in der Mischung enthaltenen Fluorchinolon-Antibiotika. Die notwendige Grundlage für eine belastbare Abschätzung von Kombinationseffekten sind jedoch harmonisierte Einzelstoffdaten, die bisher nicht im benötigten Umfang zur Verfügung stehen. Deshalb sollte speziell für Antibiotika eine systematische Prüfung der Wirkung auf Umweltmikroorganismen durchgeführt werden. Arzneistoffe können entlang ihres Lebenszyklus verschiedene biotische und abiotische Transformationsprozesse durchlaufen, die oft zur Bildung von unvollständig charakterisierten Transformationsprodukten (TPs) führen. Die Publikationen 3-7 leisten einen allgemeinen Beitrag zur Einschätzung des möglichen Gefahrenpotenzials von pharmazeutischen TPs im Wasserkreislauf und generieren neue methodische Erkenntnisse vor dem Hintergrund einer vorausschauenden Identifizierung von prioritären Abbauprodukten. Die durchgeführten Fallstudien bestätigten, dass photochemische Transformationsprozesse nicht nur zur Abschwächung bereits vorhandener, sondern im Gegenteil auch zur Entstehung gänzlich neuer Gefahrenpotenziale beitragen können. Es ist somit stark in Frage zu stellen, ob die alleinige Fokussierung auf bekannte Aktivitäten der Muttersubstanz für eine sichere Bewertung von TPs ausreicht.
Wind energy is expected to become the largest source of electricity generation in Europe's future energy mix. As a consequence, future electricity generation will be exposed to an increasing degree to weather and climate. With planning and operational lifetimes of wind energy infrastructure reaching climate time scales, adaptation to changing climate conditions is of relevance to support secure and sustainable energy supply. Premise for success of wind energy projects is the ability to service financial obligations over the project lifetime. Though, revenues(viaelectricity generation) are exposed to changing climate conditions affecting the wind resource, operating conditions or hazardous events interfering with the wind energy infrastructure. For the first time, a procedure is presented to assess such climate change impacts specifically for wind energy financing. At first, a generalised financing chain for wind energy is prepared to (qualitatively) trace the exposure of individual cost elements to physical climate change. In this regard, the revenue through wind power production is identified as the essential component within wind energy financing being exposed to changing climate conditions. This implies the wind resource to be of crucial interest for an assessment of climate change impacts on the financing of wind energy. Therefore, secondly, a novel high-resolution experimental modelling framework with the non-hydrostatic extension of the regional climate model REMO is set up to generate physically consistent climate and climate change information of the wind resource across wind turbine operating altitudes. With this setup, enhanced simulated intra-annual and inter-annual variability across the lower planetary boundary layer is achieved, being beneficial for wind energy applications, compared to state-of-the-art regional climate model configurations. In addition, surrogate climate change experiments with this setup disclose vertical wind speed changes in the lower planetary boundary layer to be indirectly affected by temperature changes through thermodynamically-induced atmospheric stability alterations. Moreover, air density changes are identified to occasionally exceed the net impact of wind energy density changes originating from changes in wind speed. This supports the consideration of air density information (in addition to wind speed) for wind energy yiel assumptions. Thirdly, the generated climate and climate change information of the wind resource are transferred to a simplified but fully-fledged financial model to assess the financial risk of wind energy project financing with respect to changing climate conditions. Sensitivity experiments for an imaginary offshore wind farm located in the German Bight reveal the long-term profitability of wind energy project financing not to be substantially affected by changing wind resource conditions, but incidents with insufficient servicing of financial obligations experience changes exceeding -10% to 14%. The integration of wind energy-specific climate and climate change information into existing financial risk assessment procedures would illustrate a valuable contribution to enable climate change adaptation for wind energy.
In response to the challenges of the energy transition, the German electricity network is subjected to a process of substantial transformation. Considering the long latency periods and lifetimes of electricity grid infrastructure projects, it is more cost-efficient to combine this need for transformation with the need to adapt the grid to future climate conditions. This study proposes the spatially varying risk of electricity grid outages as a guiding principle to determine optimal levels of security of electricity supply. Therefore, not only projections of future changes in the likelihood of impacts on the grid infrastructure were analyzed, but also the monetary consequences of an interruption. Since the windthrow of trees was identified a major source for atmospherically induced grid outages, a windthrow index was developed, to regionally assess the climatic conditions for windthrow. Further, a concept referred to as Value of Lost Grid was proposed to quantify the impacts related to interruptions of the distribution grid. In combination, the two approaches enabled to identify grid entities, which are of comparably high economic value and subjected to a comparably high likelihood of windthrow under future climate conditions. These are primarily located in the mid-range mountain areas of North-Rhine Westphalia, Baden-Württemberg and Bavaria. In comparison to other areas of less risk, the higher risk in these areas should be reflected in comparably more resilient network structures, such as buried lines instead of overheadlines, or more comprehensive efforts to prevent grid interruptions, such as structural reinforcements of pylons or improved vegetation management along the power lines. In addition, the outcomes provide the basis for a selection of regions which should be subjected to a more regionally focused analysis inquiring spatial differences (with respect to the identified coincidence of high windthrow likelihoods and high economic importance of the grid) among individual power lines or sections of a distribution network.
This thesis aims to contribute to a better understanding of the actual implementation of transdisciplinary research in sustainability science. Following three aims, this work likes to (1) contribute to the measurability of transdisciplinary research processes as well as their societal and academic outputs and impacts, to (2) demarcate transdisciplinary research from other modes of research in sustainability science and to (3) identify and examine the determinants that shape the contribution of transdisciplinary research to societal action for sustainable development and to scientific knowledge production. To serve these aims a mixed methods approach is applied that combines strong quantitative elements with in-depth qualitative analyses that integrate the perspectives of practitioners. This thesis provides a broad set of indicators to describe and assess transdisciplinary research that translate theoretical concepts form transdisciplinarity theory into observable variables. The indicators offer a holistic perspective on transdisciplinary research by representing research mode characteristics, societal as well as scientific outcomes of research projects and their specific context. To theoretically demarcate transdisciplinary research from other forms of research, a narrative literature review first elaborates the differences between "normal science", political use of scientific knowledge and transdisciplinarity in their underlying logics of problem definition, knowledge production and research utilization. Subsequently, these concepts were compared with perspectives and expectations of practitioners in the forest sector on integrative research settings. Moreover, a cluster analysis of data from 59 research projects identified five research modes that empirically demarcate ideal-typical transdisciplinary research from other research modes within sustainability science: (1) purely academic research, (2) practice consultation, (3) selective practitioner involvement, (4) ideal-typical transdisciplinary research and (5) practice-oriented research. Based on this finding, transdisciplinary research can be characterized as an intensive, but balanced involvement of practitioners. It incorporates not only the needs and goals of the practitioners but also their norms and values. Ideal-typical transdisciplinary research goes beyond mere consultatory research approaches and must be distinguished from what is conceptualized as applied research. Regression analysis of 81 research projects and statistical group comparisons of the five research mode clusters show that societal and academic outputs and impacts vary with specific project characteristics and combinations of project characteristics defined as research modes. The findings indicate that more interactive research modes reach more societal impacts. In particular, the involvement of practitioners in early project phases and the targeted dissemination of the research results positively affect societal impacts. This finding also aligns with practitioner expectations on integrative research and research utilization, provided by qualitative analysis. Moreover, the quantitative results show that scientific outputs and impacts decrease with the intensity of interactions, indicating a trade-off between societal and scientific outcomes and impacts. Overall, the empirical results of this thesis support the claimed effectiveness of transdisciplinary research in providing societally relevant, applicable knowledge and encourage further funding of transdisciplinary research by funding agencies.
Assessment of forest functionality and the effectiveness of forest management and certification
(2021)
Forest ecosystems are complex systems that develop inherent structures and processes relevant for their functioning and the provisioning of ecosystem services that contribute to human wellbeing. With increasing climate change impacts, especially regulating ecosystem services such as microclimate regulation are ever more relevant to maintain forest functions and services. A key question is how forest management supports or undermines the ecosystems’ capacity to maintain those functions and services. The main objective of this thesis is the development of a concept to assess the functionality of forests and to evaluate the effectiveness of forest ecosystem management including certification. An ecosystem-based and participatory methodology, named ECOSEFFECT, was developed. The method comprises a theoretical and an empirical plausibility analysis. It was applied to the Russian National FSC Standard in the Arkhangelsk Region of the Russian Federation - where boreal forests are exploited to meet Europe's demand for timber. In addition, the influence of forestry interventions on temperature regulation in Scots pine and European beech forests in Germany was assessed during two extreme hot and dry years in 2018 and 2019. Microclimate regulation is a suitable proxy for forest functionality and can be applied easily to evaluate the effectiveness of forest management in safeguarding regulating forest functions relevant under climate change. Thus, the assessment of forest microclimate regulation serves as convenient tool to illustrate forest functionality. In the boreal and temperate forests studied in the frame of this thesis, timber harvesting reduced the capacity to self-regulate forests’ microclimate and thus impair a crucial part of ecosystem functionality. Changes in structural forest characteristics influenced by forest management and silviculture significantly affect microclimatic conditions and therefore forest ecosystems' vulnerability to climate change. Canopy coverage and the number of cut trees were most relevant for cooling maximum summer temperature in pine and beech forests in northern Germany. The Russian FSC standard has the potential to improve forest management and ecological outcomes, but there are shortcomings in the precision of targeting actual problems and ecological commitment. It is theoretically plausible that FSC prevents logging in high conservation value forests and intact forest landscapes, reduces the size and number of clearcuts, and prevents hydrological changes in the landscape. However, the standard was not sufficiently explicit and compulsory to generate a strong and positive influence on the identified problems and their drivers. Moreover, spatial data revealed, that the typical regular clearcut patterns of conventional timber harvesting continue to progress into the FSC-certified boreal forests, also if declared as "Intact Forest Landscape". This results in the need to verify the assumptions and postulates on the ground as it remains unclear and questionable if functions and services of boreal forests are maintained when FSC-certified clearcutting continues.The analysis of satellite-based data on tree cover loss showed that clearcutting causes secondary dieback in the surrounding of the cleared area. FSC-certification does not prevent the various negative impacts of clearcutting and thus fails to safeguard ecosystem functions. The postulated success in reducing identified environmental threats and stresses, e. g. through a smaller size of clearcuts, could not be verified on site. The empirical assessment does not support the hypothesis of effective improvements in the ecosystem. In practice, FSC-certification did not contribute to change clearcutting practices sufficiently to effectively improve the ecological performance. Sustainability standards that are unable to translate principles into effective outcomes fail in meeting the intended objectives of safeguarding ecosystem functioning. Clearcuts that carry sustainability labels are ecologically problematic and ineffective for the intended purpose of ecological sustainability.The overexploitation of provisioning services, i.e. timber extraction, diminishes the ecosystems' capacity to maintain other services of global significance. It also impairs ecosystem functions relevant to cope with and adapt to other stresses and disturbances that are rapidly increasing under climate change.
The agreement on the 17 Sustainable Development Goals (SDGs) by the UN General Assembly in September 2015 was a milestone in the common history of international development and sustainability governance. However, in order to be effective, it is necessary to identify and to define suitable instruments that can be applied in order to fulfill the ambitious goal catalogue. Therefore, the underlying thesis examines the concept of Village Savings and Loan associations (VSLAs) with regard to its mechanisms that operate towards an attainment of the respective goal category. VSLAs are self-government, autonomous and democratically organized Microfinance Institutions (MFIs). They consist of a maximum of 25 mostly female members, who know and trust each other. The work is carried out within a qualitative-empirical research design applied in central Cameroon, which has to some extent exemplary character for sub-Saharan Africa. In this manner, guided experts interviews were conducted with VSLA-presidents as well as with field officers that are creating and accompanying VSLAs. A first part addresses the historical evolution of the SDGs and the theoretical and actual implications of Microfinance and the VSLA-methodology. After considering the methodological proceeding, the results are presented, discussed and summarized in a conclusion. All in all, 22 mechanisms for the attainment of nine SDG-categories are identified and described. Of particular importance is the key role of the credits to trigger fruitful activities that generate financial wealth, economic growth and employment. Furthermore, the savings of the members are an important factor for the school enrollment of the members´ children. Additionally, a combination of the credits and the solidarity fund improves the medical treatment of the members and their families. In contrast to that, direct mechanisms supporting the nutritional situation or gender equality in the research field are found to have a limited importance. Moreover, none of the identified mechanisms targets the environmental sphere of the SDG-catalogue. This is weighty in light of an increasing noticeability of the impacts of climate change for the involved population group. Nonetheless, the VSLA-concept is a simple way to effectively address the social and the economic aspects of the SDG-catalogue. In this manner, a further development of the instrument could include the canalization of the capital of international de-velopment cooperation through the VSLAs as democratic and transparent grassroots-institutions.
Der hohe Verbrauch von Antibiotika führt zu stetig steigenden Konzentrationen der Wirkstoffe und ihrer Transformationsprodukte in der Umwelt. Antibiotika in der Umwelt haben das Potential Funktionen von Ökosystemen zu stören und tragen zur Entwicklung und Selektion von resistenten Bakterien bei. Um diese negativen Auswirkungen auf Mensch und Umwelt zu reduzieren, sind vielseitige Lösungen notwendig. Benign by Design (BbD) ist ein wichtiger Baustein dafür. Daher ist es wichtig zu verstehen, inwiefern das BbD Prinzip auf verschiedene Substanzgruppen anwendbar ist und welche Limitierungen zu berücksichtigen sind. Mit dieser Arbeit soll ein Beitrag zur Entwicklung von in der Umwelt mineralisierbaren Antibiotika entsprechend des Benign by Design Konzeptes geliefert werden. Dies wurde am Beispiel der Fluorchinolonantibiotika durchgeführt, da diese sehr wichtige, aber auch sehr persistente Wirkstoffe sind. Ziel war es, zu verstehen, welche Veränderungen an der Grundstruktur vorgenommen werden können, um Derivate zu erzeugen, die während der Wirkdauer und Lagerung ausreichend stabil bleiben, aber anschließend in der Umwelt möglichst schnell und vollständig mineralisiert werden können. Im ersten Teil der Arbeit wurden die BbD Ansätze des targeted und non-targeted Re-Designs und de novo Designs, sowie die Verwendung von in silico Tools zu deren Umsetzung, untersucht. Basierend darauf wurde ein Workflow entwickelt, der eine mögliche Verwendung von computergestützten Methoden innerhalb des BbD Frameworks aufzeigt. Der Ansatz des non-targeted Re-Designs wurde für neun verschiedene Substanzen aus der Klasse der Fluorchinolone angewandt. Dafür wurden Transformationsprodukte der Muttersubstanzen mittels Photolyse und Photokatalyse erzeugt. Das resultierende Substanzgemisch wurde hinsichtlich der biologischen Abbaubarkeit und Toxizität untersucht. Es konnte gezeigt werden, dass durch die Bestrahlung mit UV-Licht eine Vielzahl an neuen Strukturen entstehen und das Gemisch oft eine gesteigerte biologische Abbaubarkeit im Vergleich zur Muttersubstanz aufweist. Das targeted Re-Design wurde am Beispiel von Fluorchinolon-Glucosamin-Derivaten untersucht. Dabei galt es zu verstehen, inwiefern Glucosamin-Substituenten die biologische Abbaubarkeit beeinflusst. Es konnte gezeigt werden, dass durch die Verwendung von acetylierten Glucosamin-Substituenten ein partieller Abbau stattfindet. Diese Erkenntnisse können zukünftig in das gezielte, fragment-basierte Design von grüneren Strukturen einfließen. Im letzten Teil der Arbeit wurden die Struktur-Bioabbau-Beziehungen von N-hetero-zyklischen Verbindungen, welche auch die Basis des Fluorchinolon-Grundgerüstes sind, untersucht und leicht biologisch abbaubare Leitstrukturen identifiziert. Dafür wurden 84 verschiedene N-Heterozyklen nach OECD 301 Richtlinien getestet. Basierend darauf wurde zum einen ein lokales 3D-QSAR Modell, insbesondere zur Visualisierung der Effekte der Substituenten im dreidimensionalen Raum, erstellt, als auch Regeln für das Design von umweltfreundlicheren Chinolonen und verwandten Strukturen abgeleitet. Weiterhin wurden abbaubare Strukturen aus der Gruppe der Chinazoline identifiziert, welche vielversprechende Leitstrukturen für das Design von Topoisomerase-Inhibitoren oder anderer Chemikalien darstellen. Insgesamt zeigen die Ergebnisse, dass die Umsetzung von BbD im Wirkstoffdesign möglich ist und wie potentielle Vorgehensweisen aussehen können. Dabei konnte gezeigt werden, dass selbst die als besonders persistent geltenden Fluorchinolonantibiotika das Potential bieten, zu besser abbaubaren Derivaten re-designt zu werden. Es wurde jedoch auch deutlich, dass es keine allgemeingültige Herangehensweise gibt und Methoden den entsprechenden Substanzklassen und Anforderungen angepasst werden müssen.
Water is an essential natural resource, yet we are experiencing a global water crisis. This crisis is first and foremost a crisis of governance rather than of actual physical resources. Capacities of single, unitary states are severely challenged by the complex, multi-scalar, and dynamic structure of contemporary problems in water resource management. New modes of governance stress the potential of public participation and scalar restructuring for effective and legitimate environmental decision-making. However, a lack evidence on the actual implementation and instrumental value of novel governance modes stands in stark contrast to the strong beliefs and assumptions that often see these being propagated as ´panaceas´ or ´universal remedies´. With this doctoral dissertation I aim to contribute to a deeper understanding of the implementation and performance of public participation and scalar restructuring in environmental governance, and particularly to engage in systematic research into the contextual factors that shape the performance of such governance innovations. Based on the conceptual approaches of participatory, multi-level governance and scale, I advance a conceptual framework specifying mechanisms and important contextual factors describing the potential of participation and rescaling to impact on the efficacy of environmental decision-making. Applying this framework, I employ a mixed-methods approach combining qualitative, quantitative, set-theoretic, and review methods, with the aim of maximising the validity of results. Drawing on the institutional frame of the European Water Framework Directive (WFD), I first assess the extent and conditions under which participation and rescaling are actually implemented in the European water resource management regime. Subsequent analyses examine whether these governance shifts, where implemented, actually lead to environmentally effective and legitimate political decisions, and foster social outcomes. Results indicate that actual changes in governance structures remain modest, whereas previous institutional structures and experiences prove rather durable. Hence, despite recent shifts distributing authority towards alternative actors and scales, the state has persisted in its role as central authority in the European water resource management regime. To the extent that they were implemented, public participation and rescaling were generally positively related with the environmental effectiveness and legitimacy of political outcomes. The analysis provides a context-sensitive understanding, by unravelling the supposedly linear relationship between governance inputs and outputs to develop a more nuanced picture of the governance process rather as a composition of multiple, interdependent causal mechanisms that, depending on their actual configuration, lead to various outcomes. In this way, particularly the tension between legitimacy and effectiveness of political outcomes is disentangled, with both being seen as the result of distinct but interrelated properties of the governance system and its contextual circumstances. The thesis furthermore provides insights of practical and policy relevance, highlighting the need and potential to take a context-sensitive perspective in policy design and decision-making. The framework paper and the Ph.D. thesis thus together enhance academic understanding of environmental governance and its potential contributions to sustainability transitions.
Tropical ecosystems are critical for biodiversity conservation and local people’s livelihood sustenance. However, these ecosystems are under high pressure from land-use and land cover (LULC) change, which is further projected to intensify and increase rapidly, thereby affecting biodiversity and the provisioning of vital ecosystem services (ES). It is thus important to understand how LULC might change in the future and how such changes could affect biodiversity and ES provisioning in a given landscape of tropical ecosystems. Scenario planning has become an increasingly popular tool and technique to produce narrative scenarios of the future landscape change. Thus, quantifying changes under different land-use scenarios could be a means to elucidate the synergies and trade-offs within the scenarios. In this dissertation, the author examines the future of biodiversity and ES provisioning for different plausible land-use scenarios in southwestern Ethiopia. First, he translates four future plausible narrative social-ecological land-use scenarios ("Gain over grain", "Coffee and conservation", "Mining green gold" and "Food first") developed for southwestern Ethiopia by participatory scenario planning into spatially explicit LULC scenario maps. Results showed distinct LULC changes under each scenario. Second, the author investigates the impact of these land-use scenarios on biodiversity by specifically modelling woody plant species richness in farmland and forest. Both indicators of human disturbance and environmental conditions were used. Third, he also investigates the effect of these land-use scenarios on woody plant-based ES provisioning by combining woody plant species with household surveys on how woody plants were used by the local community. He models and predicts the current and future availability of woody plant-based ES under the four scenarios of landscape change. Overall, the findings of this dissertation show the importance of integrating future land-use mapping with participatory, narrative-based scenarios to assess the social-ecological outcomes of alternative futures. The spatially explicit maps of LULC change, biodiversity and ES (at different scales) could be used as a valuable input to support stakeholders and decision-makers to weigh the advantages and disadvantages of different development trajectories on ecosystems and human well-being and to avoid or minimize future undesirable consequences. To this end, apart from the benefits of coffee production under "Mining green gold" and crop production under "Food first" scenarios, the findings under these scenarios of large-scale agricultural intensification point to a potentially high loss of biodiversity and ES. These two scenarios could have a negative long-term impact on ecosystems and human well-being. Finally, the "Coffee and conservation" scenario, which involves the creation of a new biosphere reserve, appears to be the most sustainable scenario. This scenario could result in a sustainably managed, diversified landscape which could make major contributions to biodiversity conservation and human well-being in the region and beyond.
Protected areas are an essential tool for conserving biodiversity. However, their ecological effectiveness is contested and their capacity to resist human pressures differ. This dissertation aimed to assess the ecological effectiveness of different protection levels (from strict to less strictly protected: national park, game reserve, forest reserve, game-controlled area, and unprotected areas) in biodiversity (both mega diverse butterflies and mammals), maintaining habitat connectivity, and reducing anthropogenic threats at the wider landscape in the Katavi-Rukwa Ecosystem of southwestern Tanzania. To achieve this overarching goal, the researcher employed an interdisciplinary approach. First, he analyzed butterfly diversity and community composition patterns across protection levels in the Katavi-Rukwa Ecosystem. He found that species richness and abundance were highest in the game reserves and game-controlled areas, intermediate in the forest reserves, national park and unprotected areas. Species composition differed significantly among protection levels. Landscape heterogeneity, forest cover, and primary productivity influenced species composition. Land-use, burned areas, forest cover, and primary productivity explained the richness of species and functional traits. Game reserves hosted most indicator species. Second, the author modelled the spatial distribution of six large mammal target species (buffalo Syncerus caffer, elephant Loxodonta africana, giraffe Giraffa camelopardalis, hartebeest Alcelaphus buselaphus, topi Damaliscus korrigum, and zebra Equus burchellii) across environmental and protection gradients in the Katavi-Rukwa Ecosystem. Based on species-specific density surface models, he found relatively consistent effects of protection level and land-use variables on the spatial distribution of the target mammal species: relative densities were highest in the national park and game reserves, intermediate in forest reserves and game-controlled areas and lowest in un-protected areas. Beyond species-specific environmental predictors for relative densities, the results highlight consistent negative associations between relative densities of the target species and distance to cropland and avoidance of areas in proximity to houses. Third, the author examined temporal changes in land-use, population densities and distribution of six large mammal target species across protection levels between 1991 and 2018. During the surveyed period, cropland increased. Wildlife densities of most, but not all target species declined across the entire landscape. Based on logistic regression models, target species preferred the national park over less strictly protection levels and areas distant to cropland. Fourth, he quantified land-use changes, modelled habitat suitability and connectivity of elephant over time across a large protected area network in southwestern Tanzania. Based on analyses of remotely-sensed data, cropland increased from 7% in 2000 to 13% in 2019. Based on ensemble models, distance from cropland influenced survey-specific habitat suitability for elephant the most. Despite cropland expansion, the locations of the modelled elephant corridors (n=10) remained similar throughout the survey period. Based on circuit theory, the author prioritizes three corridors for protected area connectivity. Key indicators of corridor quality varied over time, whereas elephant movement through some corridors appears to have increased over time. Overall, this dissertation underpins differences in ecological effectiveness of protected areas within one ecosystem. It highlights the need to utilize a landscape conservation approach to guide effective conservation across the entire protection gradient. It also suggests the need to enforcing land use plans and having alternative and sustainable forms for generating income from the land without impairing wildlife habitat.
Biozide Wirkstoffe sind Chemikalien, die zum Schutz der menschlichen oder tierischen Gesundheit oder zum Schutz von Materialien vor Schädlingen eingesetzt werden. Monitoringergebnisse lassen vermuten, dass diese Wirkstoffe auch häufig im Innenraum von Haushalten eingesetzt werden und von dort vor allem über Abwasserleitungen und Kläranlagen in die Umwelt gelangen, wenn sie in Kläranlagen nicht eliminiert werden. Die Produkte, aus denen die Wirkstoffe aus Haushalten in das Abwasser gelangen, sind bislang jedoch nicht identifiziert worden. Aus diesem Grund konnten die daraus resultierenden Umweltbelastungen nicht eingeschätzt und keine entsprechenden Emissionsminderungsmaßnahmen umgesetzt werden. In dieser Arbeit wurde deshalb untersucht, in welchen Haushaltsprodukten biozide Wirkstoffe eingesetzt werden und in das Abwasser gelangen. Zudem sollte erforscht werden, was die Haushaltsmitglieder über Biozidprodukte wissen und wie sie mit ihnen umgehen. Ziel war es, die Anwendungen von bioziden Wirkstoffen in Haushalten zu identifizieren, von denen die höchsten Umweltbelastungen zu erwarten sind, und geeignete Emissionsminderungsmaßnahmen abzuleiten. Um die Anwendung biozider Wirkstoffe in Haushalten zu untersuchen, wurde zunächst durch eine Befragung in Haushalten eines dörflichen Wohngebietes ermittelt, was die Haushaltsmitglieder über Biozidprodukte wissen und wie sie die damit verbundenen Risiken im Vergleich zu anderen Haushaltsprodukten einschätzen. Zudem wurde für jeden der teilnehmenden Haushalte ein Inventar der vorhandenen Produkte erstellt. Dabei wurden neben den Biozidprodukten auch Wasch- und Reinigungsmittel und Körperpflegeprodukte untersucht. Ähnliche Erhebungen fanden zusätzlich in Haushalten in urbanen Gebieten statt. Die aufgrund der inventarisierten Produkte zu erwartenden Stoffe wurden im Laufe eines Jahres durch ein speziell abgestimmtes Monitoringprogramm im Abwasser des dörflichen Wohngebietes in Tages- und Stundenmischproben untersucht. Alle Proben wurden nach der Probenahme aufgearbeitet und mittels Flüssigchromatographie gekoppelt mit einem Triple-Quad-Massenspektrometer analysiert. Dabei wurden die Konzentrationen von 14 Wirkstoffen gemessen: 1,2-Benzisothiazol-3(2H)-on (BIT), C12-Benzalkoniumchlorid, Carbendazim, 5-Chlor-2-methyl-2H-isothiazol-3-on (CMIT), Dichloroctylisothiazolinon (DCOIT), N,NDiethyl-meta-toluamid (DEET), Diuron, Icaridin, 2-Octyl-2H-isothiazol-3-on (OIT), Piperonylbutoxid (PBO), Triclosan, Tebuconazol, Terbutryn und Tetramethrin. Vielen Befragten war nicht bewusst, dass sie Biozidprodukte nutzen. Der Begriff "Biozid" war oft nicht bekannt und wurde inhaltlich häufig falsch verstanden. Die Auswertungen der inventarisierten Produkte und der darin enthaltenen bioziden Wirkstoffe zeigten, dass ein Großteil der Wirkstoffe nicht aus Biozidprodukten in das Abwasser gelangt, sondern aus Körperpflegeprodukten und Wasch- und Reinigungsmitteln. Insgesamt 64 % der Anwendungen von bioziden Wirkstoffen in den inventarisierten Produkten wurden nicht unter der Umweltrisikobewertung der Verordnung (EU) 528/2012 über die Bereitstellung auf dem Markt und die Verwendung von Biozidprodukten berücksichtigt, was zu einer erheblichen Unterschätzung der Umweltrisiken führt. Die Ergebnisse der Abwasseruntersuchungen deuten ebenfalls darauf hin, dass biozide Wirkstoffe aus Wasch- und Reinigungsmitteln, Körperpflegeprodukten und Biozidprodukten gleichermaßen in das Abwasser eingetragen werden. Die Messergebnisse können gut mit den Produktinventaren in Verbindung gebracht werden. Einige Wirkstoffe scheinen maßgeblich durch Biozidprodukte eingetragen zu werden. Auch Konservierungsmittel wurden regelmäßig nachgewiesen. Für Triclosan hingegen ist gemäß den Inventaren Zahnpasta vermutlich die Produktgruppe, die in dem untersuchten Wohngebiet maßgeblich für den Eintrag ins Abwasser verantwortlich ist. Diese Arbeit zeigt zum ersten Mal, welche Produkte im Haushalt eine wichtige Quelle für biozide Wirkstoffe im Abwasser sind. Sie müssen mit einbezogen werden, wenn Emissionen an der Quelle reduziert werden sollen. Es sollten Maßnahmen ergriffen werden, die über die Produktzulassung von Biozidprodukten hinausgehen, um die Emissionen so gering wie möglich zu halten. Diese Maßnahmen sollten sich nicht darauf beschränken, die Bevölkerung über Biozidprodukte aufzuklären und zu sensibilisieren. Stattdessen sollten Maßnahmen früher in der Wertschöpfungskette ansetzen, wie zum Beispiel beim Design der Wirkstoffe oder der Formulierung der Produkte, um so Einträge biozider Wirkstoffe in die Umwelt zu verringern.
Despite growing research on sustainability transformations, our understanding of how transformative transdisciplinary research can support local actors who foster change towards sustainability is still somewhat limited. To contribute to this research question, the investigator conducted research in a transdisciplinary case study in Southern Transylvania, where non-governmental organizations (NGO) drive sustainability initiatives to foster desired changes (e.g., supporting small-scale farmers or conserving natural and cultural heritage). Interactions with these local actors and reflections on the research question shaped the research of this dissertation. In paper 1, the author conducted a literature review on amplification processes that describe actions, which local actors can apply to increase the impact of their sustainability initiatives. In paper 2, he conducted a literature review on the application of indigenous and local knowledge (ILK) in sustainability transformations research to understand whether this research engages with the conceptualization of transformations from local actors. The results show that ILK is generally applied to confirm and complement scientific knowledge in contexts of environmental, climate, social-ecological, and species change. In paper 3, the author derived principles that provide guidance for how to integrate sustainability initiatives from local actors in transformative transdisciplinary research. Based on his transdisciplinary research with the NGOs in Southern Transylvania and by using systems and futures thinking as an approach for analysis, he derived three principles that provide guidance for the co-design of sustainability intervention strategies that build on, strengthen, and complement existing initiatives from local actors. In paper 4, the author explored empirically how to identify relevant local actors for collaborations that seek to intervene in specific characteristics of a system (e.g., parameters or design of a system). He applied a leverage points' perspective to analyse the social networks of the NGOs in Southern Transylvania that amplify the impact of their initiatives. This dissertation as a whole contributes insights to three recommendations of how transformative transdisciplinary research can support local actors fostering change towards sustainability: First, by conducting research that studies and supports local actors who increase the impact of their sustainability initiatives via amplification processes (Paper 1 and 4); Second, by engaging specifically with the initiatives, networks, and knowledge from local actors, who foster bottom-up, place-based transformations (Paper 1-4); Third, by identifying and collaborating with local actors that are relevant for strategic systems interventions that build on, strengthen, and complement existing initiatives (Paper 3-4).
Crowdfunding is considered a promising instrument for transforming existing socio-technical regimes by financing radical innovations of such entrepreneurs. However, this potential has not yet been fully explored. Therefore, this dissertation addresses the overarching research question of how sustainable entrepreneurs can exploit the full potential of investment-based crowdfunding to develop from niche operators to actors in the socio-technical regime. Five journal articles and one book chapter are included in this PhD project, which use a wide range of quantitative methodologies. In the framework paper, the findings are conceptually evaluated on a meta-level by applying the multi-level perspective. The key insights can be assigned to four categories, including the financing and marketing function, the target group, and the project presentation. The analysis shows that investment-based crowdfunding is suitable to equally fund and market the business ideas of environmental entrepreneurs, since the quest for entering the mass market is highest for such ventures. In contrast, purely social entrepreneurs tend to conduct crowdfunding projects on a smaller scale and probably aim to stay in the niche. Nevertheless, profit-oriented social entrepreneurs are still encouraged to use investment-based crowdfunding for funding and marketing purposes. The prominent display of environmental effects (e.g. the amount of compensated greenhouse gases) and financial incentives (e.g. high interest rates) has a high impact on the investment decision of individuals on investment-based crowdfunding platforms. The case of fairafric is used as a best practice example to demonstrate how crowdfunding can be a stepping stone for sustainability-oriented niche actors to enter the mass market. The fair-trade and organic chocolate manufacturer has undergone six crowdfunding campaigns which enabled it to grow and build a strong community of supporters. The outcomes of this dissertation clarify how sustainable entrepreneurs can unleash the potential of investment-based crowdfunding for financing and marketing purposes.
Comparable collaborations between farmers and institutions with communal catering have been less in research focus so far. Within the region of Lüneburg, an example for such a regional-organic cooperation is not known yet. Thus,this work represents the starting point to fill the research gap within the field of sustainable food systems in urban living labs as part of the research project GLOCULL (Globally and Locally-sustainable food-water-energy innovation in Urban Living Labs). The work aims at building up such a regional-organic food cooperation between a local farmer and a kindergarten community catering servicebased on scientific insights and practical persons’ knowledge.
In der Wasser- und Abwasseruntersuchung hat der Summenparameter eine heraus-ragende Bedeutung. Sowohl in der gesetzlichen Überwachung als auch der Bemes-sung von Abwasserbehandlungsanlagen werden Belastungen vielfach über die Zu-sammenfassung von Einzelstoffen in Stoffgruppen ausgedrückt. Stoffgruppen lassen sich mit Hilfe von Summenparametern zuverlässig und im Vergleich zu Einzelstoffen mit geringerem Aufwand bestimmen. Im Rahmen dieser Arbeit werden die Verfahrens-grundlagen der Summenparameter und ihre Verwendung in der Wasser- und Abwas-seruntersuchung erläutert. Ein bedeutender wie auch umstrittener Summenparameter ist der AOX - Adsorbier-bare organisch gebundene Halogene (AOX). Bedeutend ist er deshalb, weil er ein ord-nungs- und abgaberechtlich relevanter Abwasserparameter ist. Umstritten ist er unter anderem, weil er ursprünglich für andere Zwecke als die Abwasseruntersuchung ent-wickelt wurde. Seinerzeit war der AOX ein Überwachungsparameter für Trinkwasser. Als Abwasserparameter dient er zur Erfassung einer im Abwasser unerwünschten Stoffgruppe, der besorgnisauslösende Eigenschaften wie Persistenz, Bioakkumulier-barkeit und Toxizität (PBT-Eigenschaften) zugeschrieben wird. Im zweiten Teil der Ar-beit wurden exemplarisch am Parameter AOX die Zusammenhänge zwischen Stoff-parametern und besorgnisauslösenden Eigenschaften bzw. Wirkungen der ausge-wählten parameterausmachenden Substanzen untersucht. Die Untersuchungsergeb-nisse wurden vor allem in Zusammenhang mit der Ermittlung und Verankerung von Mindestanforderungen für das Einleiten von Abwasser bewertet.
In this dissertation, a multi-proxy study, which included palaeoecological, lithological, geochemical and geochronological methods, was carried out to investigate climatic and environmental changes and their interaction during the Quaternary in formerly glaciated and non-glaciated areas. The information obtained will be used to provide a better understanding of the regional stratigraphic framework and to establish broader regional terrestrial correlations within the global marine isotope stage (MIS) framework. This study was conducted on two key drillings, the Garding-2 research drill core in the German North Sea coastal area of Schleswig-Holstein and the GBY#2 archaeological core at the Gesher Benot Ya'aqov (GBY) site, in the Upper Jordan Valley in Israel. The results of this study are presented in three papers. Papers I and II focus on the study of the Garding-2 core, while the multi-proxy study of the GBY#2 core is presented in Paper III. The results of a variety of analyses conducted on the 240 m long Garding-2 sequence show interglacial-glacial cycles that are mainly controlled by variations in temperature. This sequence is composed of mainly fluvial-shallow marine sediments intercalated by muddy-peaty deposits. Based on the palynological and lithological findings, the Pliocene-Pleistocene transition was observed at 182.87 m. It is overlain by Praetiglian and the subsequent sediments of the Waalian and Bavelian Complexes. The boundary of either the second or third Cromerian Interglacial with younger sediments, which still belong to MIS 19, is marked by the last occurrence of Tsuga at 119.50 m and the development of mixed-deciduous forests. The palynologically equivalent sediments of the Bilshausen Interglacial were found below two Elsterian till layers, at 89.00 m-82.00 m. These sediments showed high and increased percentages of Pinus and Picea and scattered occurrences of Abies and Carpinus, which are similar to the features of the beginning of the Bilshausen or Rhume interglacial. An unconformity occurred at 80.29 m, at the bottom of late Holsteinian deposits, characterised by the occurrences of Fagus and Pterocarya, with low percentages of Abies and Carpinus and the absence of Buxus. These deposits are succeeded by sediments of the Fuhne cold period that shows higher percentages of NAP and occurrences of Ericales, Helianthemum and Selaginella selaginoides, which are unconformably overlain by Drenthian till at 73.00 m-71.00 m. A single peaty sample at 69.25 m with Pinus-Picea-Abies assemblage is correlated with the late Eemian Interglacial. This deposit is overlain by Weichselian glaciofluvial sediments. Middle-late Holocene sediments occurred from 20 m upwards, following a hiatus, which was caused by the Early Holocene transgression. A subsequent thin layer of marine Atlantic sediments is unconformably overlain by marine-tidal flat deposits up to 11.00 m. The first occurrence of Fagus (at 15.97 m) and Carpinus (at 15.03 m), which was optically stimulated luminescence (OSL)-dated to 3130 +/- 260 BP (at 16.22 m, Zhang et al., 2014), gives evidence for a Subboreal age for these deposits. Sandy sediments of the early Subatlantic, which were deposited between 11.00 m and the top of the Garding-2 sequence, indicate that local salt marshes, dunes and tidal flat vegetation expanded during this period. Due to regional features and the peculiarities of the local coastal environment, the expansions of Fagus and Carpinus, which are characteristic for the Subboreal-Subatlantic transition at about 2700 BP in northern Germany, are not clearly reflected in the Garding-2 pollen diagram. In the Mediterranean area, a 50 m long core of GBY#2, was drilled at the Acheulian site of Gesher Benot Ya'akov. The GBY#2 core provides a long Early-Middle Pleistocene geological, environmental and climatological record, which also enriches the knowledge of hominin-habitat relationships documented at the margins of the Hula Palaeo-lake. The sediment sequence of GBY#2 is under- and overlain by two basalt flows that are 40Ar/39Ar dated: two samples at the bottom of the core dated to 1195 +/- 67 ka (at 48.30 m) and 1137 +/- 69 ka (at 45.30 m), and another one at the top dated to 659 +/- 85 ka (at 14.90 m). With the additional chronological identification of the Matuyama Brunhes Boundary (MBB) and the correlation with the GBY excavation sites, the sedimentary sequence of GBY#2 provides the climatic history during the late part of the mid-Pleistocene transition (MPT, 1.2 Ma-0.5 Ma). Multi-proxy analyses including those of pollen and non-pollen palynomorphs, macro botanical remains, molluscs, ostracods, fish, amphibians and micromammals provide evidence for lake and lake-margin environments during MIS 20 and MIS 19. During MIS 20, relatively cool semi-moist conditions were followed by a pronounced dry phase. During the subsequent MIS 19, warm and moist interglacial conditions were characterised by Quercus-Pistacia woodlands in this area. The depositional environment changed from an open water lake during MIS 20 to a lake margin environment in MIS 19. This finding is at odds with changing climate conditions from relatively dry to moist. This discrepancy could be explained by the prograding pattern of the lake shore due to the infilling of the basin, which resulted in shallower water. Climatic changes during the Late Tertiary and the Quaternary in the high latitude regions in northwest Europe and during the Early-Middle Pleistocene in the mid latitude regions of the Middle East follow the patterns of global climatic changes, which are mainly controlled by orbital obliquity (+/-41 ka cycle) during the Early Pleistocene and by orbital eccentricity (+/-100 ka cycle) during the MPT (1.2 Ma-0.5 Ma) and the younger periods of the Quaternary. The results of this study also provide reliable evidence for long distance correlation of stratigraphic and climatic events of the Quaternary, which extends knowledge of regional and global impact of climatic fluctuations on the environment.
Rangelands are the most widespread land-use systems in drylands, where they often represent the only sustainable form of land-use due to the limited water availability. The intensity of the land-use of such rangeland ecosystems in drylands depends to a large extent on the climatic variability in time and space. Rangeland systems are seriously threatened by climate change, because climate change will alternate the availability of water in time and space. This dissertation therefore deals with the question which role climatic variability plays for the effects of grazing on vegetation in dry rangelands. The relatively intact steppes in central Mongolia were chosen as a model system. They are characterised by low precipitation and high climatic variability in the south (100mm annual precipitation), and comparatively high precipitation and low climatic variability in the north (250mm). The effects of grazing on vegetation on 15 grazing transects were investigated along the climatic gradient. The central elements were the plant species and their abundances on 10m x 10m areas, for which functional characteristics such as height, affiliation of functional groups or leaf nutrients were recorded. The main hypothesis of this dissertation is that grazing has a greater impact on vegetation communities with increasing rainfall. To test this hypothesis, three studies were carried out. In a first study, the research group found that the vegetation communities in the dry area differ strongly along the climatic gradient, while the plant communities in the wetter area differ more strongly along the grazing gradient. The results of the second study suggested that this difference can be explained by a functional environmental filter that becomes weaker from south to north as the niche spectrum increases. The third study has shown that this is likely a function of the higher availability of resources, which at the same time leads to higher grazing pressure, therewith stressing the vegetation especially in years with droughts. In summary, the author concludes that the climate gradient also represents an environmental filter that filters species for certain characteristics, thus having a significant influence on the vegetation. Climatic variability influences the effect of grazing on vegetation, which is particularly problematic where the grazing intensity is high and the species are less adapted to strong climatic fluctuations. Future scenarios predict increasing productivity and therefore increasing livestock density. This may lead to an increase in floristic and functional diversity across the climate gradient, but also to increasing grazing effects and therefore threads for overgrazing. Increasing climatic variability is likely to intensify this thread, especially in the moister regions, whereas the dry rangelands are likely to be more resilient due to the adaptation of the plants to non-equilibrium dynamics.
Smartphones make intensive use of precious metals and so called conflict minerals in order to reach their high performance in a compact size. In recent times, sustainability challenges related to production, use and disposal of smartphones are increasingly a topic of public debate. Thus, established industry actors and newly emerging firms are driven to engage in more sustainable practices, such as sustainable sourcing of materials, maintenance services or take-back schemes for discarded mobile phones. Many of these latter efforts can be related to the concept of a circular economy (CE). This thesis explores how CE-related value creation architectures (VCAs) in the smartphone industry contribute to slowing and closing resource loops in a CE. In order to analyze these new industry arrangements, transaction cost theory (TCT) is used as a guiding theory for a make-or-buy analysis. Combining TCT with the concept of a CE is a novel research approach that enables the empirical analysis of relationships between focal actors (e.g. manufacturers) and newly emerging loop operators (e.g. recycling firms) in the smartphone industry. Case studies of such VCAs are conducted with case companies drawn from the Innovation Network on Sustainable Smartphones (INaS) at Leuphana Universtity of Lüneburg and analyzed regarding their involved actors, partnerships, circular activities, motivation and perceived barriers. Evidence from the conducted case studies suggests that asset specificity for circular practices increases for higher order CE-loops such as maintenance or reuse, therefore long-term partnerships between focal actors and loop operators or vertical integration of CE practices are beneficial strategies to reach a sophisticated CE. Similarly, circular practices that go beyond recycling require a strong motivation, either through integration in the focal firm´s quality commitment or through business model recognition. It is further suggested that the circular design of products and services could reduce necessary transaction costs and thus overall costs of a circular economy. Four different integration strategies for circular economy practices have been derived from the conducted case studies. These are: 1) vertically integrated loops, 2) cooperative loop-networks, 3) outsourcing to loop operators and 4) independent loop operators. This work thus provides evidence that circular economy activities do not necessarily have to be managed by focal actors in the value chain. Rather, circular practices can also be put forward by specialized loop operators or even independent actors such as repair shops.
The aim of this paper is to determine how a carbon footprint label for grocery products can be designed to facilitate a sustainable consumption behaviour. Therefore, a mixed-method approach was used consisting out of a review of relevant literature and an explorative quantitative survey with n=158 participants. It was found that consumers generally have a positive attitude towards carbon labelling, but they lack understanding of the term, its underlying concepts and the emissions caused by grocery products. In regard to the design criteria of a carbon label, labels with a coloured scale are preferred most by consumers. Also, the mechanisms of consumer behaviour imply that not all parts of the behaviour are visible and controllable for individuals themselves. The concluding concept proposal summarises important criteria of a carbon labelling system that has the goal to educate consumers and facilitate a lower carbon consumption behaviour, such as a simple visual design, the use of a colour scale, a design enabling a comparison, the provision of a link to further information, the public enforcement of the system and overall uniformity.
Companies are invited to contribute to the United Nations' 17 Sustainable Development Goals (SDGs) and sustainability management accounting (SMA) has an important role to play in achieving them. However, if companies are to address the SDGs and linkages beyond organizational boundaries, SMA needs a broader scope than is conventionally assumed. Therefore, the author advances a multi-level framework that addresses context, action-formation, and transformative contributions (CAT) in the following directions: first, an innovative systematic method that allows screening company-related SDGs and assessing corporate contributions to selected SDGs is introduced; second, management control systems are integrated to support managers in guiding employee behavior to make contributions to the SDGs; and, third, self-reinforcing mechanisms of the path-dependence theory are incorporated to serve as a guide to identifying barriers to individuals and groups becoming involved in SMA. This advanced CAT framework contributes to corporate practice and research by providing a multilevel framework that offers concrete management guidance for SMA to address the SDGs. It also facilitates analysis of both enabling and inhibiting factors at the organizational level. The advanced CAT framework has several implications for SMA: it promotes backcasting from the SDGs for benchmarking purposes, integrates different social, environmental, and economic issues, facilitates future-oriented action and transformation planning, addresses different layers such as the company as well as individuals and groups within it and enables to identify barriers hindering individuals and groups from becoming involved in SMA.
"Reallabore" erleben als junges Format transformativer Nachhaltigkeitsforschung gegenwärtig eine beeindruckende Konjunktur. Die Dissertation arbeitet den Reallabor‐Ansatz aus Perspektive der transdisziplinären Forschung methodisch aus. Die Basis hierfür bildet die Erfahrung mit dem Auf‐ und Ausbau von einem der ersten Reallabore in Deutschland: Das langfristig ausgelegte "Quartier Zukunft - Labor Stadt" in Karlsruhe transformiert in Kooperation mit der Zivilgesellschaft ein Quartier modellhaft in einen nachhaltigeren Lebensraum. Es setzt dabei gleichermaßen auf Bildung, Forschung und Praxis. Die vorgelegten Artikel der kumulativen Dissertation bilden verschiedene Stadien der Entwicklung der Reallaborforschung und der methodologischen Reflexion ab. Die ersten beiden Texte entwickeln eine praxisnahe Definition und ordnen Reallabore ein in verwandte Diskurse. Die folgenden beiden Artikel stammen aus der beginnenden Stabilisierung des Reallabordiskurses. Der eine stellt Ziele und Designprinzipien für Reallabore als Rahmen transformativer und transdisziplinärer Forschung dar, der zweite greift aktuelle Diskussionen um Lernprozesse konzeptionell auf. Die letzten zwei Artikel fokussieren auf die Ebene der Projekte im Reallabor am Beispiel der Transformativen Projektseminare, einmal in analytischer Perspektive, einmal in methodisch‐didaktischer. Der Rahmentext abstrahiert die Ergebnisse der zuvor publizierten Artikel entlang dreier Forschungsfragen: Was ist neu am Reallabor‐Ansatz? Welches Potenzial hat ein Reallabor für transdisziplinäre Forschung? Und welche Rolle spielt Lernen im Reallabor? Die methodologische Reflexion führt zu einem Verständnis von Reallaboren als Format zwischen Urban Living Labs und Transition Labs, das sich gegenüber diesen insbesondere durch Langfristigkeit, Bildungsziele und eine klare Trennung zwischen Labor und Experimenten auszeichnet. Aus der kritischen Auseinandersetzung mit Reallaboren wird eine doppelte Bezugnahme auf Transdisziplinarität herausgearbeitet, einerseits als Infrastruktur für transdisziplinäre Projekte, andererseits als in sich transdisziplinäres Unterfangen. Ausgehend von dieser Unterscheidung wird ein Vorschlag gemacht, an welche experimentellen Methodologien jenseits der klassisch‐naturwissenschaftlichen die transdisziplinäre Forschung, die bislang kaum experimentell arbeitet, anknüpfen kann. Das Reallabor unterstützt solche Experimente durch einen Rahmen aus materieller Infrastruktur, durch Kompetenzen der Beteiligten, durch Wissensbestände und soziale Vernetzung. Die Vernetzung über Projektgrenzen hinweg, ein weiteres wesentliches Charakteristikum eines Reallabors, dient dazu, parallele Experimente zu vernetzen und iterative Lernzyklen zu unterstützen. Diese Aspekte werden verbunden zum "Apfelmodell" transdisziplinärer Forschung im Reallabor, in dem das Reallabor als doppeltes Bindeglied fungiert, einerseits zwischen internen und externen Lernzyklen, und andererseits zwischen wissenschaftlichen, bildungsorientierten und praktischen. Durch die Interpretation der Abläufe im Reallabor als Lernprozesse wird ein Anschluss an Bildungsprozesse auf unterschiedlichen Skalen möglich. Neben Lernprozessen im Reallabor als Lernumgebung lässt sich das Reallabor als lernende Institution und als Kristallisationspunkt gesellschaftlicher Lernprozesse verstehen. Das Apfelmodell kann gleichermaßen im Kontext theoretischer Fragen im Transdisziplinaritätsdiskurs herangezogen werden als auch praktischen Zwecken dienen, insbesondere in der Planung von Reallaboren, in der quervernetzten Konzeption von Projekten darin, in der Evaluation und in der Kommunikation.
Polen weist eine kleinteilige Agrarstruktur auf – ein in den Augen der polnischen Agrarpolitik unerwünschtes Phänomen. Entsprechend misst sie der Veränderung der kleinteiligen Agrarstruktur Polens zu größeren Einheiten hin eine hohe Priorität bei. Vor dem Hintergrund vielfältiger sozial-ökologischer Krisenphänomene, die oftmals mit einer intensiven, industriellen und großskaligen Landwirtschaft verbunden sind, stellt sich jedoch die Frage, ob solche Bestrebungen im Hinblick auf Nachhaltigkeit, der sich die polnische Agrarpolitik und die Politik für die Entwicklung ländlicher Räume ebenfalls verpflichtet, zielführend sind. Um dieser Frage nachzugehen, wurde für die vorliegende Dissertation in zwei landwirtschaftlich besonders kleinteilig strukturierten Regionen Polens (Wojewodschaft Lubelskie und Wojewodschaft Podkarpackie) eine empirische Studie unter Betreibern von kleinen landwirtschaftlichen Betrieben durchgeführt. Ziel der Studie war es zu untersuchen, welche Lebenswirklichkeiten und Wirtschaftsweisen sich in kleinen landwirtschaftlichen Betrieben finden und ob diese Lebenswirklichkeiten und Wirtschaftsweisen den vielfältigen landwirtschaftsbezogenen sozial-ökologischen Krisenphänomenen entgegenwirken können. Den theoretischen Hintergrund der Arbeit bilden die Nachhaltigkeitsdebatte, das Konzept der gesellschaftlichen Naturverhältnisse der Sozialen Ökologie sowie wachstumskritische Positionen (insbesondere die Ansätze von Suffizienz und Subsistenz). Die Ergebnisse der empirischen Studie zeigen, dass die Lebenswirklichkeiten und Wirtschaftsweisen von Betreibern von kleinen landwirtschaftlichen Betrieben sehr vielfältig sind. Die befragten Landwirte verfolgen in ihren Betrieben unterschiedliche ökonomische Modelle. Doch trotz dieser unterschiedlichen Modelle, die die befragten Landwirte in ihren Betrieben verfolgen, liegen ihrem Handeln gleichermaßen der Wunsch nach Existenzsicherung und der Wunsch nach Autonomie als wesentliche Motivation zugrunde. Insgesamt zeigen die Ergebnisse der empirischen Studie einige der Herausforderungen für Betreiberinnen und Betreiber von kleinen landwirtschaftlichen Betrieben auf, die aus den gegenwärtigen institutionellen und politisch-wirtschaftlichen Rahmenbedingungen für die Landwirtschaft resultieren. Ebenso zeigen die Ergebnisse, dass die Wirtschaftsweisen, die in den untersuchten kleinen Betrieben vorgefunden wurden, nur bedingt zu einer nachhaltigen Entwicklung ländlicher Räume beitragen können. Die Ergebnisse zeigen insbesondere die Dringlichkeit auf, die gegenwärtigen politisch-wirtschaftlichen Rahmenbedingungen für die Landwirtschaft zu ändern und naturerhaltende Wirtschaftsweisen auch finanziell attraktiv zu machen, wenn diese einen Beitrag zu einer nachhaltigen Entwicklung ländlicher Räume leisten sollen.
Design methods for collaborative knowledge production in inter- and transdisciplinary research
(2022)
This dissertation seeks to better understand how design methods facilitate collaborative knowledge production and integration in inter- and transdisciplinary sustainability research. Through five independent papers, this dissertation contributes to addressing the research question on four levels – conceptual-epistemological, empirical, methodological and practical. By exploring the linkages between design research and inter- and transdisciplinary research, a conceptual basis for the targeted use of design methods in collaborative processes of inter- and transdisciplinary research is laid and their spectrum of methods is expanded. This is followed by the development of a transformative epistemology in and for problem-oriented, collaborative forms of research, such as transdisciplinary sustainability research, called problematic designing. Based on a deeper understanding of integration and collaborative knowledge production, as well as its accompanying challenges, empirical research into applying design prototyping as a method in and for situations of collaborative research was conducted. To this end, the findings provide a fundamental basis for the facilitation of inter- and transdisciplinary research processes when dealing with complex problems. With its inherent openness and iterative approach in addressing the unknowns of complex phenomena, design prototyping contributes to the required form of imagination that enables to anticipate possible futures. Furthermore, by including visual-haptic modes of expression, design prototyping reduces the dominance of language and text in scientific negotiation processes and does justice to the diversity of cognitive modes. Finally, the empirical findings of this dissertation emphasise the importance of the visual-haptic dimension for collaborative knowledge production and the communication of knowledge, and provide insights into the visual structuring of human thought processes. The results on material metaphors, collaborative prototyping and material-metaphorical imagery contribute decisively to the basic knowledge of the epistemological quality of design and the importance of the visual and haptic for thought processes in general. The extension and adaptation of existing analysis methods in this dissertation add to the further development of analysis of visual-haptic data. The results are once again reflected in the synthesis of this framework paper as cross-cutting issues.
The energy sector is regarded as one of the decisive subsystems influencing the future of sustainable development. Consequently, there is a need for a comprehensive transformation of energy generation, conversion and use. The importance of building capacities for energy policy development in developing countries is bound up with the need to formulate global strategies to meet the challenges that humanity face, especially to achieve the targets manifested in the Agenda 2030 and Paris Agreement. The aim of this research is to better understand how to empower marginalised key societal actors, co-produce alternative discourses about energy futures and articulate those discourses to influence policy change within a context of illiberal democracies in Latin America. The research concerns the design, function and effectiveness of scientifically grounded participatory process, which has been justified theoretically and tested empirically. The process presupposes theoretical perspectives relating to theory, method and empirical application. The first draws on theories of sustainability transition and transformation, including transition management. The second draws on ideas taken from the knowledge co-production and transdisciplinary sustainability research. The empirical application, concerns the implementation of a Transdisciplinary Transition Management Arena (TTMA) and its effectiveness, measured by potential for the co-production of knowledge and for stimulating collective action. As result of the process, a conceptual model of the energy system, long-term visions and transformation strategies were developed. The TTMA processes demonstrated that cross-sectoral and inter-institutional, combined efforts, can help actors visualize possible, future alternatives for sustainable energy development and how to realize such alternatives. The structures provided were helpful for the emergence and empowerment of new sustainable-energy-transition coalitions in both Ecuador and Peru. Chapter 1 describes the general context in which this scientific project is developed and presents a synthesis of the processes and its main outcomes. The research results are described in detail in the scientific papers presented in chapters 2, 3 and 4.
It is understood among research and policy makers that addressing unsustainable individual consumption patterns is key for the vision of sustainable development. Education for Sustainable Consumption (ESC) is attributed a pivotal role for this purpose, aiming to improve the capacity of individuals to connect to and act upon knowledge, values and skills in order to respond successfully and purposefully to the demands of sustainable consumption. Yet despite political, scientific, and educational efforts and increasing awareness in the general population, little has been achieved to substantially change behavioral patterns so far. As part of the explanation for this shortcoming, it has been argued that current ESC practices have neglected the personal dimension of sustainable consumption, especially the affective-motivational processes underlying unsustainable consumption patterns. Against this background, this cumulative thesis is guided by the question how personal competencies for sustainable consumption can be defined, observed, and developed within educational settings. Special attention is given to mindfulness practices, describing the practice of cultivating a deliberate, unbiased and openhearted awareness of perceptible experience in the present moment. Drawing upon an explorative, qualitative research methodology, the thesis looks at three different mindfulness-based interventions aiming to stimulate competencies for sustainable consumption, reaching out to a total number of 321 participants (employees and university students). In this thesis, the author suggests to define personal competencies for sustainable consumption as abilities, proficiencies, or skills related to inner states and processes that can be considered necessary or sufficient to engage with sustainable consumption (SC). These include ethics, self-awareness, emotional resilience, selfcare, access to and cultivation of personal resources, access to and cultivation of ethical qualities, and mindsets for sustainability. The thesis holds that the observation of personal competencies benefits from a combination of different methodological and methodical angles. When working with self-reports as empirical data, a pluralistic qualitative methods approach can help overcoming shortcomings that are specifically related to individual methods while increasing the self-reflexivity of the research. Moreover, it is suggested to let learners analyze their own personal statements in groups, applying scientific methods. The products of the group analyses represent data based on an inter-subjectively shared perspective of learners that goes beyond self-estimation of personal competencies. In terms of developing personal competencies for SC, it can be concluded that mindfulness practice alone is not sufficient to build personal competencies for SC. While it can stimulate generic personal competencies, individuals do not necessarily apply these competencies within the domain of their consumption. Nevertheless, mindfulness practice can play an important role in ESC, insofar as it lays the inner foundation to engage with sustainability-related issues. More precisely, it allows learners to experience the relevance of their inner states and processes and the influence they have on actual behaviors, leading to a level of selfawareness that would not be accessible solely through discursive-intellectual means. Furthermore, participants experience mindfulness practice as a way to develop ethical qualities and access psychological resources, entailing stronger emotional resilience and improved well-being. In order to unleash its full potential for stimulating personal competencies for SC, however, the findings of the thesis suggest that mindfulness practice should be (a) complemented with methodically controlled self-inquiry and (b) related to a specific behavioral change. In this vein, self-inquiry-based and self-experience-based learning – two pedagogical approaches developed during the period of research for this thesis – turned out to be promising pedagogies for educational settings striving to stimulate the development of personal competencies for SC.
Food forests present a promising solution to address multiple sustainability challenges adaptable to local contexts. As biodiverse multi-strata agroforestry systems, they can provide several ecological, socio-cultural and economic services. They sequester carbon, limit soil erosion and regulate the micro-climate; they offer the opportunity for education on healthy diets and ecology, and they produce food and can create livelihood opportunities. However, despite their obvious benefits, food forests are still a niche concept. To date, research has focused on their ecological and social services; we lack an understanding of food forests as a comprehensive sustainability solution, including their economic dimension, and knowledge on how to develop them. Addressing these gaps, this qualitative research used a solution- and process-oriented methodology guided by transformational sustainability research. In a comparative case study approach, it created an inventory of 209 food forests, followed by interviews and site visits of 14 sites to understand their characteristics and assess their sustainability (Article 1). More indepth, it analyzed the implementation path of seven food forest for success factors, barriers and coping strategies (Article 2). Based on these insights, two experimental case studies were initiated to develop sustainable food forests with practice partners, one based in Phoenix, Arizona, U.S. and one in Lüneburg, Germany. Two studies analyzed the cases' outputs and processes highlighting success factors and challenges, including the role of a sustainable entrepreneurial ecosystem (Article 3, Phoenix case) and key features of productive partnerships to understand why one case succeeded and the other failed (Article 4). Findings include key features of existing and sustainable food forests as well as success factors on how to develop them; namely acquiring a complementary skill set that includes specialty farming and entrepreneurial know-how, securing sufficient start-up funds and long-term land access as well as overcoming regulatory restrictions. Supporting institutions are especially needed to integrate and professionalize the planning stage and provide know-how on alternative business practices. Key features of productive partnerships include an entrepreneurial attitude, access to support functions, long-term orientation and commitment to food system sustainability.
Thermal energy storage systems have a high potential for a sustainable energy management. Low temperature thermochemical energy stores based on gas-solid reactions represent appealing alternative options to sensible and latent storage technologies, in particular for heating and cooling purposes. They convert heat energy provided from renewable energy and waste heat sources into chemical energy and can effectively contribute to load balancing and CO2 mitigation. At present, several obstacles are associated with the implementation in full-scale reactors. Notably, the mass and heat transfer must be optimized. Limitations in the heat transport and diffusions resistances are mainly related to physical stability issues, adsorption/desorption hysteresis and volume expansion and can impact the reversibility of gas-solid reactions. The aim of this thesis was to examine the energy storage and cooling efficiency of CaCl2, MgCl2, and their physical salt mixtures as adsorbents paired with water, ethanol and methanol as adsorbates for utilization in a closed, low level energy store. Two-component composite adsorbents were engineered using a representative set of different host matrices (activated carbon, binderless zeolite NaX, expanded natural graphite, expanded vermiculite, natural clinoptiolite, and silica gel). The energetic characteristics and sorption behavior of the parent salts and modified thermochemical materials were analyzed employing TGA/DSC, TG-MS, Raman spectroscopy, and XRD. Successive discharging/charging cycles were conducted to determine the cycle stability of the storage materials. The overall performance was strongly dependent on the material combination. Increase in the partial pressure of the adsorbate accelerated the overall adsorbate uptake. From energetic perspectives the CaCl2-H2O system exhibited higher energy storage densities than the CaCl2 and MgCl2 alcoholates studied. The latter were prone to irreversible decomposition. Ethyl chloride formation was observed for MgCl2 at room and elevated temperatures. TG-MS measurements confirmed the evolution of alkyl chloride from MgCl2 ethanolates and methanolates upon heating. However, CaCl2 and its ethanolates and methanolates proved reversible and cyclable in the temperature range between 25°C and 500°C. All composite adsorbents achieved intermediate energy storage densities between the salt and the matrix. The use of carbonaceous matrices had a heat and mass transfer promoting effect on the reaction system CaCl2-H2O. Expanded graphite affected only moderately the adsorption/desorption of methanol onto CaCl2. CaCl2 dispersed inside zeolite 13X showed excellent adsorption kinetics towards ethanol. However, main drawback of the molecular sieve used as supporting structure was the apparent high charging temperature. Despite variations in the reactivity over thermal cycling caused by structural deterioration, composite adsorbents based on CaCl2 have a good potential as thermochemical energy storage materials for heating and cooling applications. Further research is required so that the storage media tested can meet all necessary technical requirements.
The research described in this dissertation focuses on developing a process to remove oligomers and suppress their formation by intercepting the aging procedure's precursors using adsorbents when biodiesel and its blends are used as fuel. So far, there has been no attempt to cause the stabilization of biodiesel and its blends using adsorbents from open literature. This investigation is one of the first studies on the use of adsorbents to mitigate biodiesel and diesel fuel's stability behavior–biodiesel blends and the removal of oligomers or suppressing the formation of high molecular mass species in aging oil. This study's primary aim has been achieved by several experimental measurements that provided results on adsorbents' effecton fuel oxidative stability, especially ester-based fuel like biodiesel and its blends. The chemical composition and some critical rheological analyses of the samples have been measured to understand their role in the oxidation of the sample by comparing the presence and absence of the adsorbents during the aging process. Furthermore, it aims to use adsorbents to suppress oligomers' formation and remove them in aging oil due to the influence of biodiesel and its blends. The research project also seeks to stabilize fuel, especially ester-based fuel like biodiesel, and its blends using the adsorbents. The adsorbents' application will enhance biodiesel's oxidative stability and its blends during long-term storage or application, focusing on its use in plug-in hybrid vehicles, emergency power plants,and generators. The combustion engine only starts in plug-in hybrid vehicles if the battery cannot supply energy on longer journeys. As a result, the fuel remains longer in plug-in hybrid vehicles. Fuels that are exposed to heat and oxygen over anextendedperiod can form aging products. These aging products lead to the formation of deposits, especially in the case of diesel fuels mixed with biodiesel content,and can, therefore, endanger the operational safety of the vehicle in critical components such as injectors or filter units.
Vor dem Hintergrund der steigenden Relevanz unternehmerischer Nachhaltigkeit beschäftigt sich die Wissenschaft verstärkt mit der Frage, welche Kompetenzen Entscheider benötigen, um Nachhaltigkeitsstrategien in Unternehmen erfolgreich umsetzen zu können. Denn entgegen der weit verbreiteten Meinung, dass bei der Umsetzung von Nachhaltigkeitsstrategien nur Win-win-Situationen auftreten, stoßen Manager bei der Integration ökologischer und sozialer Ziele ins Ziel-System der Unternehmen auf widersprüchliche ökonomische Rationalitäten (zwischen Effizienz und einzelnen/mehreren Dimensionen von Nachhaltigkeit) und inhärente Konflikte nachhaltiger Entwicklung (zwischen den Dimensionen sozial, ökologisch und ökonomisch). In der Folge entstehen vielfältige dilemmatische Entscheidungssituationen. Um Nachhaltigkeit langfristig in Unternehmen etablieren zu können, müssen die Dilemmata wahrgenommen und bewältigt werden. Voraussetzung hierfür sind vielfältige persönliche Kompetenzen bei den Entscheidern. Die vorliegende Arbeit untersucht die auftretenden dilemmatischen Entscheidungssituationen und den Umgang mit diesen. Darüber hinaus bestimmt sie die für die Dilemma-Bewältigung relevanten Kompetenzen sowie die zur Umsetzung von CS-Strategien erforderlichen Rahmenbedingungen im Unternehmen. Im Ergebnis wird ein Framework zu Dilemmata, den notwendigen Kompetenzen und den Rahmenbedingungen erarbeitet. Basierend darauf werden entsprechende Handlungsempfehlungen gegeben. Der erarbeitete CS-Dilemmata-Kompetenz-Atlas stellt praxisrelevantes Wissen für Unternehmen und Berater zur erfolgreicheren Umsetzung von Nachhaltigkeitsstrategien zur Verfügung.
In der vorliegenden Arbeit geht es um eine Bildpraxis, die an die Fotografie gekoppelt ist. Die Forschungsarbeit von Vera Brandner baut auf der These auf, dass die Fotografie aufgrund ihrer ´Undiszipliniertheit´ speziell in inter- und transdisziplinären sowie interkulturellen Forschungsfeldern dem gemeinsamen Lernen und Forschen dienen kann, da sie für viele Menschen - egal woher sie kommen, welchen lebensweltlichen oder disziplinären Hintergrund sie mitbringen - leicht zugänglich und nutzbar ist. Auf diesen Zusammenhang beruht der methodologische Rahmen Generative Bildarbeit, den Vera Brandner in ihrer Doktorarbeit konzipiert, empirisch erprobt und konsolidiert hat. Verschiedene Aspekte fotografisch-visueller Methoden werden mit postkolonialer, fotokritischer und emanzipatorischer Theorienbildung verschränkt. Konzeptuelle und praktische Basisarbeit für die Entwicklung Generativer Bildarbeit wurde in der Arbeit des Vereins ipsum1 zwischen 2003 und 2010 in Angola, Pakistan, Afghanistan, Israel, Palästina und Österreich geleistet. Es handelt sich dabei um eine Systematisierung der verschiedenen Blickakte, Interaktions- und Reflexionsformen, die im fotografischen Geflecht möglich sind, um diese für das dialogische Arbeiten mit Menschen verschiedener Erkenntniskulturen nutzbar zu machen. Die Fotografie wird als Praxisform in Situationen eingesetzt, in denen die beteiligten Akteur_innen einander aufgrund ihrer unterschiedlichen Herkunft, Sozialisierung und Spezialisierung fremd sind, durch geteilte Problemstellungen jedoch miteinander in Verbindung stehen. Es geht bei Generativer Bildarbeit um ein Arbeiten an den Grenzen des Eigenen und des Anderen, wobei diese Problemstellungen zugänglich, beforschbar und transformierbar gemacht werden. Die Fotografie wird zum Übungs- und Forschungsfeld für das Umgehen mit Kultureller Differenz. In diesem Übungsfeld entwickeln die Teilnehmer_innen Gestaltungs- und Reflexionsformen, um mit bestehenden Widersprüchen und Unsicherheiten ihrem jeweiligen Kontext entsprechend umzugehen.
In zahlreichen, sowohl wissenschaftlichen als auch politischen Veröffentlichungen, wird die "Energiewende" als Transformationsprojekt eingeordnet. Zweifelsohne birgt eine Umstellung auf ein erneuerbares Energiesystem transformative Potenziale. Die Bedeutungsbestimmung von "Energiewende" oder auch Transformation bleibt in Politik und Forschung aber häufig unklar. Um dem zu begegnen, wird in der vorliegenden Studie die Bedeutung von "Energiewende", wie sie im Bundestag verhandelt wird, untersucht. Darauf aufbauend wird analysiert, ob und inwiefern die „Energiewende“ einem Anspruch als Transformationsprojekt gerecht werden kann, bzw. wie sich die Wirkrichtung der mit "Energiewende" verbundenen Politiken im Spannungsfeld beharrend – reformistisch – transformativ verorten lässt. Die besondere gesellschaftliche Bedeutung der Bundestags-Debatten um "Energiewende" leitet sich diskurstheoretisch unter anderem aus der ihnen zukommenden "Schaufensterfunktion" ab, wonach die Debatten strategisch auf eine außerparlamentarische Öffentlichkeit ausgerichtet sind. Hinzu kommt, dass sich der hier stattfindende Diskurs, bspw. in Gesetzen, unmittelbar materialisiert. Als Startpunkt der Untersuchung wird der Beginn der rot-grünen Regierungszeit gewählt (1998), da diese – u.a. wegen der Verabschiedung des Erneuerbaren-Energien-Gesetzes (EEG) und dem politischen Beschluss zum Atomausstieg – in besonderer Weise mit der "Energiewende" in Verbindung gebracht wird. Als Endpunkt dient die letzte vollständige Wahlperiode zum Zeitpunkt der Untersuchung. Die Diskursanalyse bezieht sich demnach auf die Bundestagsdebatten zur "Energiewende" zwischen der 14. und 18. Legislaturperiode (1998-2017). Das methodische Innovationspotenzial der Arbeit liegt insbesondere in der Verbindung aus einem Verfahren quantitativer, computerbasierter Diskursanalyse mit einer qualitativen Analyse. Als Ergebnis der Verknüpfung von Transformations- und Diskurstheorie wird ein methodisch komplexes Forschungsdesign präsentiert, das sich neben der Analyse des "Energiewende"-Diskurses auf weitere Bereiche der politischen Transformationsforschung übertragen lässt.
Das Ausrichten der Abwasserentsorgung erfolgt in engen kommunalpolitischen und rechtlich-ökologischen Grenzen. Dabei werden weder die Rahmenbedingungen analysiert oder hinterfragt noch werden anhand akzeptierter Ziele langfristige Konzepte zur Ausgestaltung der Abwasserentsorgung entwickelt. Die Diskussion um die Wahrnehmung von Aufgaben durch die öffentliche Hand oder durch private Träger ist vielmehr durch die Kontroverse zwischen Effizienz und hoheitlicher Aufgabenerfüllung geprägt. Die gegenwärtige Problemhandhabung wird den komplexen Zusammenhängen, die mit der Abwasserentsorgung verbunden sind, nicht gerecht. Die schlechte Finanzsituation der Kommunen sollte genutzt werden, um zu neuen Formen der Aufgabenerfüllung zu gelangen.
Neben den Folgen der industriellen Landwirtschaft lassen sich weltweit degradierte Böden, massives Artensterben und ein zunehmender anthropogener Klimawandel verzeichnen. Um diesen Trend zu brechen, muss Landwirtschaft neu gedacht und transformiert werden. Dafür bedarf es innovativer und vor allem nachhaltiger Landnutzungskonzepte. Einen Beitrag zu einem solchen zukunftsfähigen Landnutzungskonzept können Waldgärten leisten. Dabei handelt es sich um mehrschichtige Systeme, welche multifunktional die natürliche Struktur von Wäldern und Waldrändern imitieren. Auf diese Weise können verschiedene Funktionen erfüllt werden, wie beispielsweise die Produktion von vielfältigen Lebensmitteln. Bisher ist das Konzept des Waldgartens in Deutschland noch nicht weit verbreitet. Es wurde bisher wenig wissenschaftliche Forschung auf dem Gebiet betrieben, und in Deutschland existieren bisher nur wenige Waldgärten. In anderen Ländern bestehen hingegen schon länger erste Erfahrungen oder auch schon lange Traditionen mit Waldgärten. Im Folgenden wird die Fallstudie Hof an den Teichen vorgestellt, zusammengefasst, welche Vorarbeiten bereits stattgefunden haben, und das Forschungsziel und die Forschungsfragen hergeleitet.
Das Bildungskonzept Bildung für nachhaltige Entwicklung (BNE) gilt als Schlüsselfaktor für eine nachhaltige Entwicklung. Die Stärkung der Kompetenzen von Multiplikatoren und somit Lehrkräften als Gestalter formaler Bildung ist ein Ziel auf dem Weg zu einer qualitativ hochwertigen Bildung. Es gilt, im Verlauf der Lehrkräftebildung Möglichkeiten zu schaffen, die Entwicklung relevanter Kompetenzen gezielt zu unterstützen, um effektivere Ergebnisse im Bereich BNE zu erreichen. Für den universitären Teil der Lehrkräftebildung geht dies einher mit einer entsprechenden Gestaltung von Lernumgebungen, durch die angehende Lehrkräfte relevante Kompetenzen zu Beginn ihres individuellen Bildungsweges entwickeln können. Darüber hinaus sollen durch entsprechende Fort- und Weiterbildungsformate auch bereits im Schuldienst tätige Lehrkräfte erreicht werden. Das als transdisziplinäres Format angelegte Entwicklungsteam Sachunterricht, bestehend aus Sachunterrichtslehrkräften, Vertretern außerschulischer Bildungsorte und Forschenden der Universität, bildet den Ausgangspunkt dieser Arbeit. Die vorliegende Arbeit fokussiert die Untersuchung von Möglichkeiten der Professionalisierung von (angehenden) Lehrkräften zu BNE im Kontext des Entwicklungsteams. Dazu wurde zunächst theoretisch-konzeptionell der Frage nachgegangen, welche Kompetenzen relevant für die Integration von BNE in Schule und Unterricht sind und wie Lehr-Lernsettings gestaltet werden sollten, um die Entwicklung entsprechender Kompetenzen zu unterstützen. Im Rahmen zweier empirischer Studien wurde anschließend einerseits die Kompetenzentwicklung seitens der Studierenden analysiert, die an einem durch das Entwicklungsteam begleiteten Seminar teilnahmen. Andererseits liegt der Fokus auf dem spezifischen Format des transdisziplinären Entwicklungsteams und es wurde untersucht, inwiefern wechselseitiges Lernen zwischen den Entwicklungsteammitgliedern initiiert werden und dies in einer Veränderung der pädagogischen Praxis resultieren kann. Aufgrund seiner hohen Anschlussfähigkeit an den bildungswissenschaftlichen Diskurs wurde das Modell der BNE-spezifischen professionellen Handlungskompetenz den konzeptionellen Überlegungen und den darauf aufbauenden empirischen Untersuchungen zugrunde gelegt. Die Gestaltung eines Lehr-Lern-Settings für angehende Lehrkräfte mit dem Ziel der Förderung entsprechender Kompetenzen wurde anhand des Konzepts der offenen Lernumgebung vorgenommen. Die Ergebnisse zeigen zum einen, dass das in enger Zusammenarbeit mit dem Entwicklungsteam als offene Lernumgebung durchgeführte Seminar die Professionalisierung der Studierenden unterstützt und der Aufbau von (BNE-spezifischer) professioneller Handlungskompetenz durch kollaboratives Gestalten in Kooperation mit der Praxis ermöglicht wird. Zum anderen zeigt sich, dass die transdisziplinäre Zusammenarbeit ein wechselseitiges von- und miteinander Lernen zu BNE im Entwicklungsteam Sachunterricht fördert und Professionalisierungsprozesse sowohl seitens der Lehrkräfte als auch des außerschulischen Akteurs zumindest in einigen Bereichen angestoßen wurden.
Die heutige industrielle Landwirtschaft birgt vielfältige Probleme wie die Degradierung der Böden, den Verlust von Biodiversität, Nitrate im Grundwasser sowie die hohe Abhängigkeit von fossilen Energieträgern. Einen möglichen Lösungsansatz bietet das Konzept der regenerativen Landwirtschaft, welches weltweit zunehmend Beachtung findet. Deren Ziel ist es, Agrarökosysteme und insbesondere die Böden kontinuierlich zu verbessern, indem durch bestimmte landwirtschaftliche Methoden und ganzheitliches Management unter anderem gestörte Nährstoff-, Wasser- und Kohlenstoff- Kreisläufe wieder geschlossen werden. Die Verwendung von Pflanzenkohle als Bodenhilfsstoff könnte ein mögliches Werkzeug der regenerativen Landwirtschaft sein, da Forschungen gezeigt haben, dass Pflanzenkohle durch ihre spezifischen Eigenschaften in der Lage ist, die physikalischen und chemischen Eigenschaften des Bodens langfristig zu beeinflussen und dadurch zum Bodenaufbau beizutragen. Es handelt sich jedoch um eine vergleichsweise neue Methode, die in Deutschland bislang wenig praktiziert wird, und es gibt einige Kritik an der Produktion und Verwendung von Pflanzenkohle. Das Ziel der Arbeit ist es daher herauszufinden, ob und auf welche Weise die Verwendung von Pflanzenkohle im Ackerbau ein Bestandteil einer regenerativen Landwirtschaft in Deutschland sein kann. Hierfür wurden auf Grundlage der vorhandenen Literatur einige Thesen aufgestellt. Für die empirische Erhebung von Praxiswissen wurden leitfadengestützte Experteninterviews mit je einem Vertreter der Anbauweisen biologisch-dynamisch, organisch-biologisch und der Permakultur geführt. Die Ergebnisse wurden ergänzt durch ein Interview mit einer Expertin aus dem Bereich der Pflanzenkohleproduktion, um technische Details zu konkretisieren. Im Ergebnis wird unter anderem deutlich, dass der Pflanzenkohleeinsatz für jede Fläche gründlich überlegt werden muss. Allgemein sollte Pflanzenkohle nur in kleinen, dezentralen landwirtschaftlichen Systemen eingesetzt werden und Teil einer Abfall-Management-Strategie sein. Es müssen sowohl das Ziel der Anwendung, als auch die Eigenschaften der eingesetzten Kohle bekannt sein und ein Einsatz sollte nur in einem System erfolgen, welches bereits regenerativ bewirtschaftet wird.
This dissertation evaluated the efficacy of three different internet-based interventions that can be regarded as indirect interventions to reduce depression since they primarily targeted risk factors for depression. For this purpose three registered randomized controlled trials were conducted. In addition to assessing the efficacy of the interventions regarding the primary outcomes, the efficacy to reduce depression and further secondary outcomes was studied. In Study I (N=200) the efficacy of an internet-based stress management intervention (iSMI), which was adapted and tailored to career starting teachers, was compared to a waitlist control group (WLG). The participants of the intervention group (IG) reported significant reductions on the primary outcome perceived stress at post-intervention (T2) and three month follow-up (3-MFU). Furthermore, it was shown that the intervention indirectly also reduced depression at T2 and 3-MFU. The effects were sustained at an extended 6-MFU. Besides efficacy, the feasibility to complement the iSMI with a newly developed internet-based classroom management training was shown. Moreover, mediation analyses corroborated the role of problem- and emotion-focused coping skills in the intervention's effect on stress and the indirect effect of the intervention on depression through stress. Study II (N=262) demonstrated the efficacy of an internet- and app-based gratitude intervention on the reduction of primary assessed repetitive negative thoughts at T2 and 3-MFU, as compared to a WLG. The participants of the IG also reported significantly reduced depressive symptoms at T2, and 3-MFU, with significant clinically meaningful effects. The effects were sustained at an extended 6-MFU. Besides efficacy, mediation analyses showed that repetitive negative thinking mediated the gratitude intervention's effect on depression. Finally, Study III N(=351) showed that an internet-based intervention, tackling worries at the beginning of the COVID-19 pandemic, was effective as compared to an active mental health advice group. At T2, two weeks after randomization, the IG reported significantly reduced levels on the primary outcome worry as compared to controls. Participants of the IG also reported significantly reduced levels of depression at T2, with significant clinically meaningful reductions. The extended follow-ups in the IG indicated that the improvements from baseline were sustained until the 2-MFU and the 6-MFU. In a mediation analysis, worry was shown to mediate the intervention's effect on depression. Across all three studies a reliable deterioration of depression was occasionally observed. In summary, the studies in this dissertation demonstrated the efficacy of various indirect interventions focusing on rather common psychological problems to indirectly reduce depressive symptoms. The extent to which depression severity could be reduced is comparable to reductions found within participants with comparable baseline depression severity, in internet-based interventions directly addressing depressive symptoms. Indirect interventions are suggested to increase the uptake of interventions that reduce depressive symptoms, since they might be perceived as less stigmatizing and might broaden the range of interventions to choose from.
Mikroalgen können bei den internationalen Bemühungen zur Begrenzung der CO2-Emissionen einen wichtigen Beitrag leisten. In der Photosynthese der Mikroalgen wird das CO2 aus der Atmosphäre in Biomasse fixiert. Im Gegensatz zu Landpflanzen können Mikroalgen zudem exponentiell wachsen, haben geringere Anforderungen an die Wasserqualität und konkurrieren nicht mit Agrarflächen, die begrenzt und für die Nahrungsmittelsicherheit der Weltbevölkerung erforderlich sind. Die produzierte Mikroalgenbiomasse kann als regenerative Ressource zu Biokraftstoffen wie Biogas und Biodiesel umgewandelt und somit als Energieträger genutzt werden. Zudem können Mikroalgen auch bei der biotechnologischen Produktion kommerziell relevanter Wertstoffe wie Pigmenten und Omega-3-Fettsäuren für die Nahrungsmittelindustrie Anwendung finden. Mit dem Ziel der Steigerung dieser Wertstoffe stand die Untersuchung des Einflusses der Kultivierungsparameter Licht und Temperatur auf das Wachstum und die Zusammensetzung der Mikroalgenbiomasse im Mittelpunkt dieser Dissertation. Insbesondere der Einfluss unterschiedlicher Lichtspektren auf das Wachstum und die Wertstoffproduktion in Mikroalgen wurde detailliert untersucht. Zusätzlich wurde überprüft, ob sich die gewonnenen Erkenntnisse auch auf Landpflanzen übertragen lassen. Im Rahmen dieser Promotion wurde erstmals systematisch der Einfluss unterschiedlicher Temperaturen und Lichtspektren im zeitlichen Verlauf der Kultivierung auf Mikroalgen untersucht. Hierbei konnten distinkte Spektralbereiche sowie Temperaturen ermittelt werden, die für eine maximale Produktion von Biomasse und Pigmenten sowie einem maximalen Desaturierungsgrad der Fettsäuren erforderlich sind. Die in dieser Arbeit gewonnenen Erkenntnisse tragen zu einem besseren Verständnis der Biochemie von photosynthetischen Organismen bei.
Einsatz der Planarchromatographie mit wirkungsbezogener Detektion zur Untersuchung von Wässern
(2018)
Unter Wirkungsbezogener Analytik (WBA) wird die Kopplung eines chromatographischen Trennverfahrens mit einem biologischen Testsystem verstanden. Der Vorteil bei dieser Herangehensweise ist, dass die zuvor getrennten Probeninhaltsstoffe anhand ihrer Aktivität mit einem in vitro-Testsystem detektiert werden. Es hat sich gezeigt, dass die Hochleistungsdünnschichtchromatographie (HPTLC) besonders geeignet für die WBA ist. Bislang konnte nicht gezeigt werden, dass die WBA mit HPTLC auch als routinefähige Methode eingesetzt wurde. In dieser Arbeit erfolgte eine Optimierung der Detektion der Endpunkte Biolumineszenzhemmung (Aliivibrio fischeri), antibiotische Wirkung (Bacillus subtilis), Neurotoxizität (Acetylcholinesterase) von der HPTLC-Platte hinsichtlich Routinefähigkeit. Zusätzlich konnte in ersten Versuchen gezeigt werden, dass es möglich ist, direkt gentoxische Verbindungen mittels des umu-Tests auf der HPTLC-Platte nachzuweisen. Für die einzelnen Biotests sind unterschiedliche Inkubationszeiten notwendig. Dies führt aufgrund von Diffusion auf der HPTLC-Platte zu einer Bandenverbreiterung. Es wurden unterschiedliche Methoden und Arbeitsweisen zur Verminderung der Diffusion erprobt und optimiert. Eine Möglichkeit ist die mechanische Eindämmung durch die Einbringung einer Gaze in eine verfestigte Calciumalginatschicht. Optimiert wurde dieses Verfahren am Bacillus subtilis-Hemmtest. Für Enzymtests ist eine vergleichsweise kurze Inkubationszeit notwendig. Daher tritt hier eine geringere Bandenverbreiterung auf, womit eine mechanische Einschränkung der Diffusion nicht geeignet ist. Um die auftretende Bandenverbreiterung möglichst gering zu halten, wurde besonders die Aufbringung des Substrats optimiert. Dies geschah am Beispiel des HPTLC-Acetylcholinesterasehemmtests. Die Ermittlung der unterschiedlichen bandenverbreiternden Einflussfaktoren erfolgte mittels statistisches Versuchsplanung. Anhand der gewonnenen Erkenntnisse konnte die Methode soweit optimiert werden, dass die bei der Detektion von AChE-Inhibitoren auftretende Bandenverbreiterung sehr gering gehalten werden kann. Aufgrund der hohen Empfindlichkeit des Verfahrens lassen sich selbst geringe Spuren von Verunreinigungen in Referenzsubstanzen detektieren. Besonders für den Routineeinsatz der WBA mit der HPTLC ist die Vergleichbarkeit der Ergebnisse erforderlich. Dazu wurde anhand des HPTLC-Leuchtbakterienhemmtests mit Aliivibrio fischeri eine Auswertestrategie erarbeitet. Die Ermittlung der Biolumineszenzhemmung findet analog zum Küvettentest statt und kann ortsaufgelöst als Hemmwert-Chromatogramm dargestellt werden. Die Darstellung der Hemmung in einem Hemmwert-Chromatogramm gleicht die Stauchung der Peaks aufgrund des sigmoiden Verlaufs der Dosis-Wirkungsbeziehung teilweise aus. Durch die nichtlineare Beziehung zwischen Konzentration bzw. Flächenmasse und Wirkung der unbekannten Substanzen ist es für den Vergleich von Proben notwendig, einen Bezugspunkt zu setzen. Bewährt hat sich dafür der EC50-Wert. Da aber in den meisten Fällen die Konzentration unbekannt ist, wird als Bezugspunkt das Auftragevolumen gewählt, welches erforderlich ist um eine Hemmung von 50% auszulösen. Der Kehrwert des berechneten Auftragevolumens für 50% Hemmung stellt das reziproke Iso-Hemmvolumen (RIHV) dar. Dieser RIHV-Wert hat sich für den Probenvergleich in verschiedenen Anwendungen bewährt. Das Prinzip der Auswertung kann vom HPTLC-Leuchtbakterientest mit Anpassung auf den HPTLC-Bacillus subtilis-Hemmtest übertragen werden. Für den Vergleich der Wirkung auf die Acetylcholinesterase-Hemmung wird in Anlehnung zum RIHV, das reziproke Iso-Aktivitätsvolumen (RIAV) herangezogen. Hier wird das Auftragevolumen, welches notwendig ist, eine Aktivität der AChE von 50% zu erreichen, als Kehrwert angegeben. Zur Ermittlung der Messunsicherheit der Chromatographie und der detektierten Wirkung wurden parallel zu den Proben Referenzverbindungen untersucht. Bei der Überwachung einer gesicherten Deponie über einen Zeitraum von 4,5 Jahren konnte gezeigt werden, dass es sich bei der Hochleistungsdünnschichtchromatographie mittels automatisierter Mehrfachentwicklung (HPTLC/AMD) um ein reproduzierbares Chromatographiesystem handelt. Bei der Anwendung des Leuchtbakterien-, Bacillus subtilis- und des Acetylcholinesterase-Hemmtests auf verschiedene Deponie- und Abwasserproben wurden über einen Zeitraum von sieben Monaten Standardabweichungen von 5-9% Hemmung für die testspezifischen Referenzsubstanzen ermittelt. Als Ergebnis der Validierung wurden der HPTLC-Aliivibrio fischeri-, der HPTLC-Bacillus subtilis- und der HPTLC-Acetylcholinesterase- Hemmtest am 24.03.2015 von der deutschen Akkreditierungsstelle (DAkkS) akkreditiert. Zur Ermittlung potenziell gentoxischer Substanzen wurde der umu-Test ausgewählt. Mit dem umu-Test auf der HPTLC-Platte ist es derzeit möglich, die aus der DIN 38415-3 bekannte direkt wirkende gentoxische Substanz 4-Nitroquinolin-N-oxid (4-NQO) auf der HPTLC-Platte nachzuweisen. Für einen erfolgreichen Nachweis von indirekt wirkenden Substanzen, die erst nach der Aktivierung durch Stoffwechselenzyme gentoxisch wirken, war es nicht möglich, das erforderliche Metabolisierungssystem auf der HPTLC-Platte aufrecht zu erhalten. Zur Durchführung der WBA ist für die meisten Wasserproben (z. B. Oberflächenwasser oder Grundwasser) eine Anreicherung erforderlich. Parallel zu den Arbeiten mit den biologischen Testsystemen erfolgte die Optimierung der Anreicherung von organischen Verbindungen aus Wasserproben. Für die Festphasenextraktion (SPE) wurden verschiedene Materialien bei den pH-Werten 2, 7 und 9 mit Substanzen unterschiedlicher Polarität getestet. Die besten Wiederfindungen über den gesamten Polaritätsbereich erzielte die Phase "Agilent Plexa" (Polydivinylbenzol) mit einer angepassten Elutionsabfolge. Bei der Auswahl des Materials und der Anpassung der Elutionsabfolge wurde auch auf einen möglichst geringen Blindwert für den Biolumineszenz-Hemmtest mit Aliivibrio fischeri geachtet. Damit wurde eine für die WBA geeignete Anreicherungsmethode gefunden. Zur Verbesserung der Extraktionsausbeute von polaren Verbindungen mittels Flüssig-Flüssig-Extraktion (LLE) wurde die Mikro-LLE mit dem in allen Verhältnissen mit Wasser mischbaren Extraktionsmittel Acetonitril getestet. Die im Blindwert auftretenden störenden Substanzen konnten durch Ausheizen des zur Phasentrennung erforderlichen Natriumchlorids erheblich reduziert werden. Bei den Untersuchungen zur Wiederholbarkeit mit einer Deponiesickerwasserprobe und der Detektion der Biolumineszenz von Aliivibrio fischeri waren nur geringe Abweichungen der Hemmwerte detektierbar. Aufgrund der zu erwartenden komplexen Zusammensetzung von Proben aus dem Deponiebereich ist eine Gradientenelution für die HPTLC/AMD notwendig. Anhand von Referenzverbindungen und Extrakten aus verschiedenen Deponien wurde die HPTLC/AMD-Trennung für ein Screening optimiert. Mit diesem Screening-Gradient ist es möglich, die wirkenden Probenbestandteile über die gesamte Trennstrecke zu verteilen. Zusätzlich fand noch eine Entwicklung einer isokratischen HPTLC-Trennung für eine schnelle Beurteilung von Proben statt, wobei bei dieser Methode Abstriche bezüglich der Trennleistung gemacht werden mussten. Zudem konnte gezeigt werden, dass der aufwendige Identifizierungsprozess durch spezifische postchromatographische Derivatisierungsreaktionen auf der HPTLC-Platte unterstützt werden kann. Dazu wurde der Bratton-Marshall-Nachweis von primären Aminen optimiert. Durch den Nachweis von austauschbaren Protonen mittels des H/D-Austausches lassen sich die denkbaren Strukturen deutlich einschränken. Für einen nahezu vollständigen H/D-Austausch hat sich die Kopplung von HPTLC und Massenspektrometer (MS) als besonders geeignet gezeigt, da hier nur wenige Milliliter an deuterierten Lösemitteln benötigt werden. Erprobt wurden die optimierten Methoden an verschiedenen Wässern, welche aus Kläranlagen und aus dem Umfeld von Deponien stammen. Durch die Einführung des RIHV- bzw. RIAV-Wertes ist es möglich Wässer von verschiedenen Probennahmestellen, z. B. Deponiesickerwässer, anhand ihrer Wirkung vergleichend zu beurteilen. Auch kann damit die Veränderung des Wirkungsmusters über einen Aufbereitungsprozess beobachtet werden. Die Untersuchungsergebnisse zeigen zudem, dass auch bei der WBA Feldblindproben entscheidend sind, um Proben sicher beurteilen zu können.
Human activities have become a major driver of global change, so that global society and economy are facing consequences such as climate change, increasing scarcity of resources, environmental pollution and degradation as well as disturbances of ecosystem functioning and services.In order to meet these main challenges in an appropriate way, adequate starting points and solutions must be pursued at all levels to shift the current socio-economic pathway from an unsustainable to a safe operating and thus sustainable development within the planetary boundaries. One of the application concepts in industrial contexts is Industrial Symbiosis (IS), which deals with the set-up of advanced circular/cascading systems, in which the energy and material flows are prolonged for multiple material and energetic (re-)utilization within industrial systems in order to increase resource productivity and efficiency, while reducing environmental impacts. The overarching goal of the research project was to identify and develop approaches to enable the evolution of Industrial Symbiosis (IS) in Industrial Parks (IPs). IS is a collaborative cross-sectoral approach to connect the resource supply and demand of various industries in order to optimize the resource use through exchange of materials, energy, water and human resources across different companies, while generating ecological, technical, social and economic benefits. Many Information Communication Technology (ICT) tools have been developed to facilitate IS, but they predominantly focus on the as-is analysis of the IS system, and do not consider the development of a common desired target vision or corresponding possible future scenarios as well as conceivable transformation paths from the actual to the defined (sustainability) target state. This gap shall be addressed in this work, presenting the software requirements engineering results for a holistic IT-supported IS tool covering system analysis, transformation simulation and goal-setting. This study also aims to present the conceptual IT-supported IS tool and its corresponding prototype, developed for the identification of IS opportunities in IPs. This IS tool serves as an IS facilitating platform, providing transparency among market players and proposing potential cooperation partners according to selectable criteria (e.g. geographical radius, material properties, material quality, purchase quantity, delivery period). Therefore a quantitative indicator system was compiled and recurring patterns were identified to utilize this knowledge in the comprehensive IT-supported IS tool. So this IS tool builds the technology-enabled environment for the processes of first screening of IS possibilities and initiation for further complex business-driven negotiations and agreements for long-term IS business relationships.
Das Ziel der vorliegenden Dissertation ist es, die Auswirkungen des Klimawandels auf die Entwicklung des Vorlandes als Ergebnis der sich ändernden hydraulidschen Bedingungen zu untersuchen. Die Untersuchung beschäftigt sich mit der Entwicklung des Vorlandes, da dieses Gebiet stark abhängig von Wasserstandsänderungen ist. Diese werden möglicherweise durch Klimawandel verstärkt und können folglich die zahlreichen Funktionen des Vorlandes beinträchtigen. Diese Problematik erfordert die Durchführung einer Untersuchung, die zunächst die durch die Variationen der Wasserstände betroffenen physikalischen Prozesse im Fluss und in den Flussauen analysiert und anschließend eine Methodologie für die Analyse der zukünftigen Entwicklung des Vorlandes herleitet. Beispielhaft wurde ein Bereich an der unteren Mittelelbe in Niedersachsen, Norddeutschland für die Untersuchung ausgewählt. Zu diesem Zweck befasst sich die Untersuchung im ersten Teil mit der aktuellen Diskussion über den Klimawandel und mit den bestehenden Schwierigkeiten, zu einer belastbaren zukünftigen Prognose des Ausmaßes der klimatischen Veränderungen zu gelangen. Anschließend konzentriert sich die Untersuchung auf die Interaktionen zwischen Abflüssen, Vegetation und Sedimenten, die die Flussmorphodynamik bedingen. Ein weiterer Schwerpunkt dieser Arbeit ist die Untersuchung der mathematischen Modelle, die eine Analyse des zukünftigen Verhaltens des Vorlandes ermöglichen. Mithilfe dieser Untersuchung werden die Vorteile der eindimensionalen Modellierung für die Prognose der Entwicklung dieses Gebiets deutlich. Die Untersuchung im ersten Teil der Dissertation führt zur Erkenntnis, dass sich das Verhalten des Vorlandes aus der Interaktion zwischen Fluss- und Flussauenmorphologie und der Auenvegetation ergibt. Diese Interaktionen bestimmen letztlich die zukünftigen Wasserstände und somit die hydraulischen Bedingungen für diese Zone. Für die Analyse des zukünftigen Verhaltens des Vorlandes unter Einfluss des Klimawandels wird eine Methodologie vorgeschlagen, die als Dynamische Interaktion von Modellen bezeichnet wird. Der Einfluss des Klimawandels wird durch die Variation von Abflüssen im Flussmodell, im Sedimenttransport- und Bodenwasserbewegungsmodell sowie bei der Analyse von Veränderungen der Vegetation berücksichtigt. Dazu werden die durch regionale Klimamodelle prognostizierten zukünftigen Niederschläge in die Berechnung der zukünftigen Abflüsse durch eine in dieser Dissertation entwickelten Modifikation des stochastischen Modells AutoRegressive-Moving-Average (ARMA) eingeschlossen. Die ausgearbeiteten Entwicklungsprognosen der verschiedenen Modelle werden miteinander verknüpft, um zukünftige Wasserstände und Überflutungen und damit die neuen hydraulischen Bedingungen für das Vorland zu prognostizieren. Im zweiten Teil dieser Dissertation wird die vorgeschlagene Methodologie der Dynamischen Interaktion von Modellen in einem Fallbeispiel angewandt. Dafür wurden zwei Messstationen an der Elbe zwischen Elbe-km 511 und 515 installiert, die auch im Rahmen des Projekts KLIMZUG-NORD verwendet wurden. Diese Messstationen ermöglichten innerhalb von 2 Jahren die Erhebung von mehr als 300.000 Felddaten. Diese Informationen erlauben es, die Entwicklung des Vorlandes (2021-2050) in einer regulierten Flussstrecke der Elbe (Mittelelbe) zu prognostizieren. Dazu werden zunächst die bedeutenden Charakteristika des Untersuchungsgebiets dargestellt und nachfolgend Material und Methoden erläutert, die für die Analyse der Entwicklung des Vorlandes im Untersuchungsgebiet erforderlich sind. Die Flussmorphologie wird für den Zeitraum 2001-2100 modelliert, da eine Tendenz bei möglichen Variationen in einem kurzen Zeitraum nur schwer wahrgenommen werden kann. Die jeweiligen Modelle werden u.a. mithilfe erhobener Felddaten, Daten aus der Literatur, Klimadaten aus den Stationen des Deutschen Wetterdiensts (DWD), projizierten Daten des regionalen Klimamodells REMO, Daten des hydrologischen ATLAS von Deutschland, Abflussdaten des Pegels Neu Darchau (Elbe-km 536,4), Geschiebe-Schwebstoffdaten des Wasser- und Schifffahrtsamts (WSA) und der Bundesanstalt für Gewässerkunde (BfG), Wassertemperaturdaten der Arbeitsgemeinschaft für die Reinhaltung der Elbe (ARGE-ELBE) und das Digitale Geländemodell (DGM) kalibriert. Die durch das stochastische Modell ARMA/Variation erhaltenen Berechnungen der zukünftigen Abflüsse, die die Prognose der regionalen Klimamodelle berücksichtigen, werden mit den durch die BfG-Modelle erhaltenen Ergebnissen verglichen, um die Problematik der Vielfalt von klimatischen Prognosen anzugehen. Schließlich werden in dieser Dissertation die Anwendung und Bedeutung der vorgeschlagenen Methodologie für die Analyse der Entwicklung des Vorlandes anderer Flüsse und Regionen außerhalb Mitteleuropas behandelt.
In der vorliegenden Arbeit wurde ein ICP-QMS mit integrierter Reaktions- /Kollisionszelle erfolgreich eingesetzt, um die Elemente Vanadium, Chrom, Mangan, Eisen, Nickel, Kobalt, Kupfer, Zink, Arsen, Molybdän, Cadmium, Blei und Uran direkt in verdünntem Meerwasser zu bestimmen. Die Bestimmung von Elementspuren in Meerwasser wurde realisiert, indem alle zur Verfügung stehenden Möglichkeiten zur Minimierung von Interferenzen bei der Bestimmung von Elementen mit ICP-QMS angewendet wurden.
Diese Arbeit stellt eine Pionierarbeit zum Thema Keyline Design als ganzheitliches Gestaltungskonzept für landwirtschaftliche Betriebe im deutschsprachigen Raum dar und ist aus der Zusammenarbeit mit Akteuren der Gemeinschaft Schloss Tempelhof in Süddeutschland entstanden. Keyline Design hat zum Ziel, durch systematische Planung von landwirtschaftlicher Flächennutzung und Tiefenlockerung in einem topographieabhängigen Kultivierungsmuster, die Bodenfruchtbarkeit zu steigern sowie Wasserfluss auf Landschaften kontrolliert zu nutzen und gleichmäßig zu verteilen. Vor dem Hintergrund von Bodendegradation durch landwirtschaftliche Praktiken und sich verändernde klimatische Bedingungen, stellen divers gestaltete Landschaften eine wichtige Anpassungsstrategie zum Schutz gegen Extremwetterereignisse dar. Keyline Design hat bisher innerhalb dieses Diskurses in Zentral- und Nordeuropa wenig Beachtung erfahren. Für die transdisziplinäre Zusammenarbeit wurde innerhalb dieser Arbeit eine Vorgehensweise zur Erstellung eines Keyline Entwicklungsszenarios entwickelt: Mithilfe eines transdisziplinären Arbeitstreffens und einem online Fragebogen wurden die Ziele und Entwicklungswünsche der 140 Personen umfassenden Gemeinschaft Schloss Tempelhof erfasst und auf Basis eines Keyline Kultivierungsmusters ein Entwicklungsszenario für die landwirtschaftliche Flächennutzung erstellt. Keyline Design wurde als Planungskonzept für die topographieabhängige Integration von Agroforstsystemen, wie Pufferzonen, Waldweiden und Alley Cropping, sowie für die Platzierung von Wasserkörpern genutzt. Die Ergebnisse des Entwicklungsszenarios zeigen, dass das erarbeitete Kultivierungsmuster von der Topographie abhängig ist, die Ausgestaltung des Szenarios jedoch vor allem vom Kontext der Akteure.
This study aims to answer four main research questions regarding the roles, strategies, barriers, and representation of the media and environmental nongovernmental organisations (ENGOs) in environmental communication in Malaysia. From a theoretical lens, this study has incorporated the essential concepts of media, ENGOs, and environmental communication from both Western and Asian, particularly Malaysian perspectives as primary points of reference. For the purpose of this study, a total of 13 interviewees from Media A and Media B and 11 interviewees from ENGO A and ENGO B were chosen for the qualitative interview while 2,050 environmental articles were collected as samples from Media A´s and Media B´s newspapers along with ENGO A´s and ENGO B´s newsletters from the period 2012 to 2014 for the quantitative content analysis. Specifically, the findings from interview confirmed that both the Malaysian media and ENGOs have shared quite similar roles in environmental communication, particularly in environmental legitimacy (creating trust, credibility, and relationships with the public), in democracy (acting as a watchdog and mobilising the public sphere), and in constructing public mind about environmental problems. Pictures undoubtedly were one of the most vital tools in social construction, especially for presenting the reality of the environmental problems to the public. This was in harmony with the results of the quantitative content analysis, where more than 60% of pictures were found on environmental articles in media newspapers and ENGOs newsletters. Malaysian media and ENGOs have shared two common strategies in environmental communication, namely campaigning and collaboration with other stakeholders, while the ENGOs have two extra strategies: advocacy and lobbying strategies. Malaysian media and ENGOs also have collaborated with each other and the level of collaboration between them was at the coordination (medium) level. Both social actors especially the media were also relied heavily on their sources for environmental articles and the result of quantitative content analysis showed that the government was the main source for media newspapers, whereas other ENGOs and laypersons were the main sources for ENGOs´ newsletters. There are also colossal barriers faced by both Malaysian media and ENGOs throughout the process of environmental communication and some of the barriers faced by both media and ENGOs include the problem with limited knowledge of the environment, while some other barriers, like media laws and ownership, were only faced by the media; other barriers such as funding problems were specifically faced by the ENGOs. In terms of representation of environmental information, the Malaysian media make more presentations on environmental problems, especially on topics like floods, wildlife and water crises in their newspapers, while ENGOs have given more attention to environmental effort topics such as conservation and sustainable living in their newsletters. Surprisingly, not only the media but also the ENGOs used the same (news) values like timeliness, proximity, and impact as criteria for the selection of environmental issues for their publications. Other factors such as the background of the organisation and the interest of journalists or editors also influence the selection of environmental issues. It is hoped that the proposed theoretical framework of this study can serve as a crucial guideline for the development of environmental communication studies, especially among the media and ENGOs not only in Malaysia but also in other (Southeast) Asian regions that share a similar background.
Environmental governance beyond borders: Governing telecoupled systems towards sustainability
(2023)
This doctoral dissertation analyses the environmental governance of long-distance social-ecological interactions in telecoupled systems in two issue domains: global commodity chains and infrastructure projects as part of China’s Belt and Road Initiative (BRI). Although both domains involve different governance actors, institutions and processes, they both concern the question of how the involved actors develop governance structures and institutional responses to telecoupling. This dissertation aims to contribute to a deeper understanding of how to govern environmental problems that are associated with global flows. Since many multilateral environmental governance initiatives have not yet produced the desired solutions to global problems, particular attention is directed at unilateral state-led governance approaches. This dissertation addresses the questions of (1) how to achieve a spatial fit between the scale of telecoupled systems and the scale of governance institutions, (2) how governance actors exercise agency in governing telecoupled systems, and (3) how state actors can govern the domestic and foreign environmental effects of telecoupled flows. The results show that creating a spatial fit in the governance of global commodity flows is challenging because boundary and resolution mismatches can emerge. Boundary mismatches denote situations where social-ecological problems transcend established jurisdictional boundaries, whereas resolution mismatches refer to governance institutions that have too coarse a spatial resolution to allow them to address the specific aspects of social-ecological problems effectively. No single governance institution is likely to avoid all mismatches, which highlights the need to align multiple governance approaches to effectively govern telecoupled systems.
The fact that digitalization comes along with a lot of negative effects onto the environment is slightly known in the case of energy consumption by hardware, especially regarding mobile devices, having a limited battery life. However, awareness of environmental issues of software, being the driver of hardware, is mainly missing, even if the research field addressing corresponding issues is growing. Thus, the doctoral thesis at hand addresses the question How to draw (a) developers and (b) usersattention to environmental issues of software? By presenting (a) a calculation method of the carbon footprint of software projects and (b) a concept for an eco-label for software products, evaluated by a user survey, the doctoral thesis provides two strategies how to draw the attention to environmental issues of software. Summarizing, this thesis can act as a basis for further research in bridging from science to society in the context of environmental issues of software. Its findings can be seen as starting points for practical implementations of methods and tools supporting a more environmentally friendly way of developing software and informing about environmental issues of software usage. In order to get the implementation of the research results of the thesis going, it highlights practical implications for diverse groups of stakeholders - researchers, certifiers, public administration and professional purchasers, and environmental associations - that have been identified as being important for the practical implementation of the presented concepts and, thus, represent the target group of the doctoral thesis.
Neben dem Klimawandel und der Verstädterung zählt der Verlust biologischer und kultureller Vielfalt mit unberechenbaren Konsequenzen für die Bereitstellung von Ökosystemdienstleistungen zu den größten Herausforderungen der Zukunft, auch in UNESCO-Biosphärenreservaten, die Modellregionen für nachhaltige Entwicklung sind. Deshalb wurden durch die vorliegende Studie erstmalig Ökosystemdienstleistungen im UNESCO-Biosphärenreservat Schaalsee erfasst und bewertet. Dort sind insgesamt 39 Ökosystemdienstleistungen nachzuweisen, wobei räumliche Unterschiede hinsichtlich der Zonierung zu beobachten sind: Je strenger der Schutzstatus, desto geringer ist die Anzahl an nutzbaren Ökosystemdienstleistungen. Mittels Q-Methode wurden fünf unterschiedliche Werteperspektiven auf die bereitgestellten Ökosystemdienstleistungen identifiziert: 1) Übereinstimmung mit der Biosphärenreservats-Idee, 2) Regionalität mit dem Streitpunkt Kultur, die als a) entbehrlicher Luxus oder b) elementarer Lebensinhalt wahrgenommen wird, 3) Landwirtschaft und Nostalgie sowie 4) Vorsorge durch natürliche Regulierungsleistungen. Alle Perspektiven stimmen darin überein, dass die Vielfalt der Natur und sauberes Trinkwasser sowie die meisten regulierenden Ökosystemdienstleistungen von großer Wichtigkeit sind. Die Ergebnisse der Erfassung können als Grundlage zur weiteren Untersuchung der Ökosystemdienstleistungen im UNESCO Biosphärenreservat Schaalsee verwendet werden.
The global coffee market is connected to many sustainability issues like the persisting poverty of coffee farmers, and degrading ecosystems. Many interventions, from state-led regulation to industry-led certification processes, exist, that try to change global value chains to shift societies back on more sustainable trajectories. To this date, it is still under debate if these interventions are an effective means to change global value chains. With climate change and persisting issues of social justice as strong accelerators, calls are increasingly made for a radical transformation of global production and consumption patterns. Many frameworks try to inform research and real-world policies for a transformation of global value chains. In this dissertation, the author uses the framework of the practical, political and personal sphere proposed by O'Brien and Sygna (2013) highlighting that the interactions between these three spheres bare the greatest potential for a transformation towards sustainability. However, in this dissertation, the author argues that it is exactly at the nexus between the three spheres of transformation where barriers towards a fundamental shift of systems occur. He, therefore, uses three perspectives to bring empirical nuance to the problems that arise on the interplay between the different spheres of transformation. (1) The scientific perspective: using a systematic review of alternative trade arrangements; (2) the producer perspective: facilitating a participatory network analysis of social-ecological challenges of Ugandan coffee farmers and their adaptive management practices; (3) the consumer perspective: through the use of a German consumer survey and a structural equation model to investigate into the Knowledge-Doing-Gap end-consumers are facing. Through the results from the scientific perspective, the author is able to show that most of the research is investigating the certified market and that the effectiveness of labels rarely exceeding the practical sphere. His empirical research on the producer perspective highlights that Ugandan coffee farmers facilitate a variety of on-farm crop management (practical sphere) but their support structures rarely exceed informal exchange with neighboring communities (political sphere). Exchange with governmental actors and global traders is happening but has been assessed as not sufficient to cope with the social-ecological challenges the producers are facing. Through the results of the consumer perspective, the author is able to highlight that even though end-consumers have pro-sustainable attitudes (personal sphere) they are facing situational constraints (political sphere) that create a gap between their attitudes and the respective behavior. Using these empirical insights about drivers and barriers for a transformation he proposes that frameworks, aiming to inform research and policies, need to include two aspects: (1) the notion of a forced transformation; and (2) the translational capacity of the frameworks to create meaningful interdisciplinary discourses in different contexts. The author, therefore, propose two approaches:(1) a fourth sphere, called the "planetary force" to include the notion of a forced transformation that is already happening in different contexts, highlighted by the producer perspective in this dissertation; and (2) the consequent use of methods that create interdisciplinary exchange and rigorous testing.
The principle of this thesis was to study the environmental fate of three highly used psychotropic drugs and this achieved through: 1) examining the biodegradability of TMI, DMI and CPTX, 2) studying the behaviour of TMP, DMI and CPTX in photodegradation tests using Xe and UV lamps with studying the effect of different environmental conditions on their UV-photodegradation behaviour, 3) monitoring the primary elimination of TMP, DMI and CPTX during photodegradation and biodegradation tests using HPLC, and measuring their degree of mineralization by means of dissolved organic carbon analyser (DOC), 4) elucidating the structures of the transformation products (TPs) which formed during the degradation of TMI, DMI and CPTX by using LC-MS/MS analysis, 5) analysing the biodegradability of their TPs by laboratory tests and in-silico assessments in order to determine the fate and persistence of these TPs in the aquatic environment, 6) conducting in-silico toxicity predictions for the selected psychotropic drugs and their TPs in human (carcinogenicity, genotoxicity and mutagenicity) and in eco-system (toxicity to microorganisms and toxicity in rainbow trouts). As an overall conclusion, the present work demonstrates that a combination of laboratory simulation tests, LC-MS/MS analysis and in-silico tools result in valuable new information regarding environmental fate of three important psychotropic drugs and their TPs. This dissertation also highlights that different environmental conditions such as temperature, initial drug concentration and pH can differently affect the degradation behaviour of pharmaceuticals even when they are highly structurally related. Therefore, one cannot conclude from one pharmaceutical to another but each one needs to be investigated individually and this present a great challenge for risk assessment kinetics of chemicals in the aquatic environment. The results presented here showed that the investigated pharmaceuticals and their TPs can negatively affect the environment which may be harmful to the ecosystem as they might have been present for decades in the aquatic environment without any knowledge of their environmental fate or connected risk. Therefore, further work needs to be done including analysis of environmental samples (e.g., surface waters), as well as laboratory toxicity tests to further expand knowledge on their exact environmental impact.
This cumulative dissertation investigates food policy councils (FPCs) as potential levers for sustainability transformation. The four research papers included here on this recent phenomenon in Germany present new insights regarding the process of FPCs' emergence (Emergence paper), the legal conditions which affect their establishment (Legal paper), the different roles of FPCs in policy-making processes (Roles paper) and FPCs' potential to democratise the food system (Food democracy paper). Drawing on and contextualizing the results of the four individual studies, the framework paper uses the leverage points concept originally developed by Meadows (1999) and adopted by Abson et al. (2016) as a lens to discuss FPCs’ potential as levers for sustainability transformation. This conceptual background includes three so-called realms of leverage, which are considered to be of particular importance in transformational, solution-oriented sustainability science: first, the change, stability and learning in institutions (re-structure), second, the interactions between people and nature (re-connect) and third, the ways in which knowledge is produced and used (re-think). Framing the findings of the four research papers in terms of these three realms, the framework paper shows that FPCs could serve as cross realm levers, i.e. as interventions that simultaneously address knowledge production, institutional reform and human-nature interactions.
Global environmental changes and the subsequent biodiversity loss has raised concerns over the consequences for the functioning of ecosystems and human well-being. This thesis provides new mechanistic insights into the role of tree diversity in regulating forest productivity and forests’ responses to climate change. The thesis also addresses the overlooked functional role of ecological continuity in mediating ecosystem processes in the context of multiple global environmental changes. The findings of the thesis emphasize the need to retain the functional integrity of forest ecosystem by preserving biodiversity and acknowledging the ecological memory forests.
Increasingly, researchers are expected to work in collaborative interdisciplinary teams to tackle more complex and interrelated problems. However, the prospect of collaborating with others, from different disciplines, exerts countervailing forces on researchers. There is the lure of transcending the limitations of one's own knowledge, methods and conventions, belonging to diverse intellectual communities and tackling, together, ambitious research topics. On the other hand, there is the risk that collaborating across disciplinary boundaries will be taxing, confounding at times, with no guarantee of success. This thesis is about collaborative interdisciplinary research from the perspective of a formative accompanying researcher. The author accompanied an interdisciplinary research team in the field of sustainability over three years for the duration of a collaborative project. Formative accompanying research (FAR) is an approach to "research into research" that learns about, with and for a collaborative interdisciplinary team. The author found - through immersion in the literature, her own daily experiences of collaborating, and her observations – that interdisciplinary collaboration is very difficult. It requires a basic understanding and appreciation of other disciplines and methods, as well as the skills to integrate research inquiries and findings across diverse epistemologies. It also requires awareness that collaborative interdisciplinary research is more than an intellectual task of knowledge creation. Other factors matter, such as interpersonal relationships, power differentials, different research tempos and a sense of belonging. And these factors have an impact on processes and outcomes of collaborative knowledge creation. Knowing this implies a willingness to keep learning and to tolerate discomfort so as to cultivate deeper levels of collaborative capacity. The author discovered that in these deeper levels lie skills for staying with inevitable tensions, for talking and listening to generate new understanding together, and for applying a researcher's frank curiosity to oneself too. A formative accompanying researcher, who is part of the team she is researching, has to navigate delicate terrain. In this thesis, the author develops a FAR methodology that takes seriously the questions of positionality and relationality, and reflects on the experiences of putting these into practice. A FAR practice involves remaining in dynamic movement between observing and participating, between exercising curiosity and care, and between the researchers' own sense of impartiality and investment in relation to the issues at hand. There is merit in furthering the methodology and practice of FAR on its own terms. This includes attending to the skills required by a formative accompanying researcher to remain oriented within the concentric circles of research, relationship and loyalty that make up a collaborative team. There is also the question of how FAR, and other forms of research into research, can help to advance collaborative interdisciplinary research. The author argues for creating the conditions in research teams that would enable treating collaboration as a capacity to develop, and that would facilitate team members' receptivity to learning with FAR. Furthermore, she explores dilemmas of intervening as a formative accompanying researcher and of sustaining dynamic positionality over the long-term.
Fostering sustainable urban mobility at neighborhood-based mobility stations with cargo bikes
(2019)
Agrobiodiversität besitzt vielfältigen ökologischen, ökonomischen und sozio-kulturellen Wert. Sie ist eine grundlegende Voraussetzung für zukünftige Nutzungen und steht gleichzeitig in einem besonderen Verhältnis zu menschlichem Handeln. Zwar basiert Agrobiodiversität auf Natur, sie ist jedoch wesentlich durch landwirtschaftliche Tätigkeiten gestaltet worden und kann ohne weitere Nutzung durch den Menschen nicht erhalten und erneuert werden. Die vorliegende Dissertation analysiert die Gestaltung gesellschaftlicher Naturverhältnisse in der ländlichen Entwicklung am Beispiel der nachhaltigen Nutzung von Agrobiodiversität. Schutz und Nutzung von Agrobiodiversität wird hierfür in einem ersten Schritt als sozial-ökologisches Phänomen konzipiert. Daran schließen sich Analysen auf agrarpolitischer und landwirtschaftlich praktischer Ebene an. Anhand einer Analyse der der Gemeinsamen Agrarpolitik der Europäischen Union (GAP) und im speziellen der Politik zur ländlichen Entwicklung wird deutlich, dass eine programmatische Orientierung an Wettbewerbsfähigkeit und einer nachhaltigen Entwicklung besteht und das Paradigma einer multifunktionalen Landwirtschaft integrierende Ansätze bietet. Diese Ansätze werden jedoch weiterhin vor dem Hintergrund einer unhinterfragten Logik realisiert, die davon ausgeht, dass naturerhaltendes Wirtschaften nicht wettbewerbsfähig sein kann. Die GAP löst somit die hierarchische Trennung zwischen Schutz und Nutzung von Agrobiodiversität nicht auf. Trotz der Wirkmächtigkeit der GAP kann mittels der Fallstudie "Arche-Region Flusslandschaft Elbe" an einem konkreten Beispiel aus der landwirtschaftlichen Praxis dargestellt werden, wie nachhaltige Agrobiodiversitätsnutzung umgesetzt wird. Aus den Ergebnissen der Fallstudie werden abschließend Schlussfolgerungen für eine Weiterentwicklung der Politik zur ländlichen Entwicklung und EU-Agrarpolitik im Allgemeinen abgeleitet.
Climate change and atmospheric deposition of nitrogen affect biodiversity patterns and functions of forest ecosystems worldwide. Many studies have quantified tree growth responses to single global change drivers, but less is known about the interaction effects of these drivers at the plant and ecosystem level. In the present study, the authors conducted a full-factorial greenhouse experiment to analyse single and combined effects of nitrogen fertilization (N treatment) and drought (D treatment) on 16 morphological and chemical response variables of one-year-old Fagus sylvatica seedlings originating from eight different seed families from the Cantabrian Mountains (NW Spain). Drought exerted the strongest effect on response variables, reflected by decreasing biomass production. However, D and N treatments interacted for some of the response variables, indicating that N fertilization has the potential to strengthen the negative effects of drought (with both antagonistic and amplifying interactions). For example, combined effects of N and D treatments caused a sevenfold increase of necrotic leaf biomass. The authors hypothesize that increasing drought sensitivity was mainly attributable to a significant reduction of the root biomass in combined N and D treatments, limiting the plants' capability to satisfy their water demands. Significant seed family effects and interactions of seed family with N and D treatments across response variables suggest a high within-population genetic variability. In conclusion, the findings indicated a high drought sensitivity of Cantabrian beech populations, but also interaction effects of N and D on growth responses of beech seedlings.
This thesis aims at contributing to the better understanding of the roles of international and domestic institutional and governance patterns for corporate sustainability practices. By combining governance and new institutionalism approaches it bridges the gap between the close look at specific corporate sustainability (CS) policies and the broader view on institutional frameworks. The qualitative comparative approach aims to provide deeper insights on the implementation of different governance schemes by transnational corporations ((TNC). Finally, the conclusions might allow for the development of a) recommendations for the balancing of TNCs' CS management between global and domestic requirements, and b) policy recommendations in the field of CS governance. The overarching research question is as follows: What role do national governance patterns play in comparison to global governance practices in shaping the corporate sustainability (CS) management of transnational corporations (TNCs)? In order to further operationalize this research objective, it is structured into three subquestions: (1) What are relevant institutional factors and global governance patterns for corporate sustainability/ Corporate Social Responsibility (CSR)? (2) What are relevant institutional factors and national governance patterns for corporate sustainability/CSR in Germany, the US, and India? (3) How do these national and global governance patterns influence TNCs' CS management? The first two questions aim at tracing the institutional framework and governance patterns at both national and international levels by identifying norms, stakeholder expectations, prevalent modes of governance and actors involved in governance processes. On this basis, the third question targets TNCs' reaction to internationally varying governance patterns. Here, it is of main interest how relevant governance instruments are perceived by business actors and to which extent their sustainability management at the companies' headquarters and subsidiaries reflect global and national institutional and governance patterns. In order to answer these questions, literature research and a structured qualitative analysis have been conducted. The concepts of CS and CSR build the basis to analyze how TNCs and their subsidiaries manage their social and ecological corporate responsibilities. Against this conceptual background, the research question is approached empirically by the means of an international comparison. Three institutionally highly diverse countries were chosen: Germany, India and the US. India, an emerging market economy, was included to increase the diversity of the sample and to close the research gap indicated above. In order to identify the differences in governance for CS in these three countries, document analyses and 42 guideline-based interviews with experts from governments, NGOs, trade unions and trade associations were carried out. At the same time, global governance instruments for corporate sustainability – which are already relatively well researched - were identified by analyzing the relevant secondary literature. In a second step, in order to explore how TNCs strategically deal with the multitude of different governance approaches at their headquarters and subsidiaries, three case studies of Germany-headquartered transnational corporations in the chemical and engineering industries (Siemens, BASF and Bayer) have been conducted.
A central aspect of sustainability governance is collaboration, which has been lauded for its benefits but also criticized for its challenges. The potential benefits of collaboration have apparently been recognized also in the context of EU agriculture. Yet, there has been a lack of holistic consideration of how collaboration can be systematically integrated and promoted in the governance of EU agriculture. Sustainable agriculture cannot only be encouraged through changes in the overall governance system but also through the support of existing and emerging small-scale collaborative initiatives for sustainable agriculture. Indeed, there has been substantial research on the conditions that influence success of similar collaborative initiatives. However, the knowledge resulting from this research remains rather scattered and does not allow for the identification of overall patterns. Additionally, little of this research specifically focuses on sustainable agriculture. What is more, the promotion of collaboration for sustainable agriculture is further complicated by the lack of clarity of the meaning of sustainable agriculture, which is an inherently ambiguous and contested concept. This cumulative dissertation aims to address these gaps by contributing to a better understanding of how collaboration can be facilitated and designed as a means to govern for and advance sustainable agriculture. For this purpose, the dissertation addresses three sub-aims: 1) Advancing the understanding of the concept of sustainable agriculture; 2) scrutinizing the current governance system regarding its potential to facilitate or hamper collaboration; 3) assessing conceptually and empirically how actor collaboration can be facilitated as a means to govern for sustainable agriculture, both from a top-down and a bottom-up perspective. In doing so, this dissertation focuses on EU agriculture and applies a mix of methods, ranging from qualitative to quantitative dominant. The findings of this dissertation highlight that collaboration has been underappreciated and even hampered as an approach to governing for sustainable agriculture. In contrast, this dissertation argues that collaboration offers one promising way to promoting and realizing agriculture and emphasizes the need to integrate different approaches to collaboration and to sustainable agriculture.
Companies increasingly use social and environmental accounting and reporting (SEAR) to measure, manage, and report their influence on ecological and social issues, i.e., climate change and human rights violations. Nowadays, there are many different tools, frameworks, and standards for SEAR that companies can use. Beyond the content presented in the tool itself, e.g., social and/or ecological information, these tools differ, among others, by the language used and the type of data collected (e.g., qualitative, quantitative, or monetary data). This dissertation aims to expand previous literature by clarifying the effects of SEAR on corporate decision-making and its influencing factors. Additionally, antecedents for implementation and use of SEAR in regard to supporting sustainability decision-making are discussed. For this purpose, the given dissertation investigates public sustainability reports by companies with different environmental orientation, conducts two survey-based case studies on the effects of different types of SEAR and one qualitative case study on the antecedents of institutionalizing management accounting change through SEAR. The results lead to seven criteria that practitioners and researchers should recognize for supporting successful SEAR regarding a company's environmental orientation, the role of employees and leadership as well as the specific SEAR tool itself.
This dissertation addresses the question of how sustainability curricula can be implemented and established in higher education institutions. Universities – as hubs for knowledge generation, innovation, and education – provide a central leverage point for sustainably developing society at large. Therefore, the institutionalization of sustainability curricula is not only socially demanded, but also stipulated in numerous political statements from the international community (e.g., those of the UN and UNESCO) and operationalized via Sustainable Development Goal No. 4: "Quality Education". Previous findings on how such implementation can be successful and what factors support or inhibit the process have come primarily through case studies of individual higher education institutions. These studies have been largely descriptive rather than analytical and leave open questions about the generalizability of their findings. The present dissertation addresses this research gap. Through a meta-study (i.e., an analytical comparison of existing case studies), generalizable findings on the implementation processes of sustainability curricula are explored. In the first step, a case universe was collected in order to provide a database for deeper analyses. In two further analysis steps that built on the case universe from Step 1, certain factors that promote or inhibit the implementation of sustainability curricula (Step 2) and specific implementation patterns (Step 3) were examined. The presented findings add a complementary empirical perspective to the discourse on the establishment of education for sustainable development (ESD) at higher education institutions. First, the case studies that specifically address the implementation processes of sustainability curricula are reviewed and analyzed here for the first time as part of a research landscape. This research landscape reveals where research on such implementation processes has been or is being conducted. On this basis, both researchers and funders can reflect on the status quo and plan further research or funding endeavors. Second, this dissertation offers the opportunity to compare a multitude of individual case studies and thus to develop new and generalizable insights into the implementation of sustainability curricula. The empirical analysis uses 133 case studies to identify key factors that promote or inhibit the implementation of sustainability curricula and to add a complementary perspective to the discourse, which has thus far been dominated by theoretical considerations and individual case studies. The analysis thereby offers a new perspective on generalizable influencing factors that appear to be important across different contexts. Thus far, specific patterns of implementation processes have been infrequently studied, and with few datasets. This dissertation analyzes the complex interplay between over 100 variables and provides one of the first research attempts at better understanding the processes that lead to the deep-rooted and comprehensive implementation of sustainability curricula. Internal and external practitioners of higher education institutions can find examples and evidence that can be useful in planning the next steps of their sustainability curriculum implementation. This dissertation offers generalizable empirical findings on how universities can succeed in recognizing their own responsibility to that end and in realizing this transformation through the implementation of ESD.
One of the Colombian strategies to diversify and decarbonize the energy sector is encouraging the use of non-conventional renewable resources (NCRR). This thesis measures the environmental rebound effect (ERE) when increasing the shares of wind power into the Colombian power grid in the residential (household) sector. For doing so, a process-based Life Cycle Assessment (P-LCA), an environmental extended input output (EEIO) model and re-spending models (almost ideal demand system AIDS) were applied. Direct rebound effect was measured thought the elasticity price of the electricity demand; furthermore, the environmental savings for increasing the shares of wind power into the grid were calculated via P-LCA. For doing so, a P-LCA for a wind farm in Colombia was performed, whereas the information for other energy resources (Hydro, Coal, Gas, Solar and Thermal) where collected from Ecoinvent 3.4 database. To calculate the environmental indirect rebound effect the monetary savings obtained for the environmental efficiency were calculated. For doing so, an AIDS was applied to obtain the marginal budget shares (MBS). Combining the MBS obtained with the EEIO model the monetary savings were translated into environmental indicators. The ERE is presented for ten impact categories (climate change (CC), acidification (A), ecotoxicity (E), marine eutrophication (MEUT), terrestrial eutrophication (TEUT), carcinogenic effects (CE), non-carcinogenic effects (NCE), ozone layer depletion (OD), photochemical ozone creation (POC), and respiratory effects, inorganics (RES)). Moreover, a sensitive analysis was conducted to measure the variability of the ERE to different values of the direct rebound effect and different percentages of price efficiency. The results show that the inclusion of the environmental rebound effect has generally a non-negligible impact on the overall environmental indicators across all studied years. Such impacts ranging across impact categories from 5% (eutrophication) and 6,109% (photochemical oxidant creation) for the combined model, whereas for the single model the values fall on the ranges of 1% (eutrophication) and 9,277% (photochemical oxidant creation). Further, a sensitivity analysis of the elasticity price of the electricity and the price of the electricity reveals that the ERE varies in different ways, specifically, changes in these parameters could vary the impacts, respectively, by up to about <1% and 38%. Backfire effects are present for 8 of the 10 environmental impacts studied in different magnitudes across the years, depending meanly of the savings available to re-invest.
The overall aim of this thesis is to develop empirical probabilistic frameworks that help to quantify the impacts of temporal and spatial scale dependencies and model uncertainties of climate projections regarding precipitation-dependent parameters. The thesis is structured in four articles. Article one is the first study that analyzed climate projections from the spatially highly resolved regional climate model (RCM) ensemble EURO-CORDEX. Additionally, the significance and the robustness of the projected changes are analyzed, and improvements related to the higher horizontal resolution of the new data set are discussed. A major finding is, that RCM simulations provide higher daily precipitation intensities, which are missing in the global climate model (GCM) simulations, and that they show a significantly different climate change of daily precipitation intensities with a smoother shift from low towards high intensities. The second article elaborates on impacts of temporal and spatial aggregation on extreme precipitation intensities. By combining radar data with cloud observations, the different temporal and spatial scaling behavior of stratiform and convective type precipitation events can be analyzed for the first time. The separation between convective and stratiform type events also allows to quantify the contribution of convective events to the extremes. Further, it is shown that temporal averaging has similar effects on the precipitation distribution as spatial averaging. Associated pairs of temporal and spatial resolutions that show comparable intensity distributions are identified. Using precipitation data from radar observations, a gauge station network and a spatially highly resolved regional climate model, the third paper optimizes the process that finds associated temporal and spatial scales (see second article). This information is used to develop a method that adjusts point measurements to the temporal and spatial scale of a previously defined model grid. The study shows that this procedure can be used to improve bias-adjustment methods in areas with a low gauge station density. It is known that the EURO-CORDEX ensemble overestimates precipitation and shows a common cold bias in the Alpine region. The fourth article evaluates how these biases are changing the temperature distribution and the temperature dependency of precipitation-frequencies. These biases are a source of uncertainty that is not captured by the robustness tests performed in the first article. A probabilistic-decomposition-framework is developed to quantify the impact of these biases on precipitation-frequency changes and to investigate causes for the ensemble spread.
Excessive fertilizer use leads to nutrient imbalances and losses of these to the environment through leaching, runoff and gaseous emissions. Nutrient use efficiency (NUE) in agriculture is often low and improving it could increase the sustainability of agricultural systems. The main aims of this thesis were to gain a better understanding of plant-soil-microbe interactions in order to improve agricultural NUEs. The studies included experimentally tested how crops respond to addition of high carbon amendments, fertilizer application rates and timing, and crop rotations. Furthermore, methods for measurement of roots were compared and a protocol for measurement of roots was developed. The first experiment simulated an agricultural field using mesocosms. In this setting, the researchers tested the effect of 4 previous crops (precrops), which either had or did not have a symbiosis with arbuscular mycorrhizal fungi (AMF)/rhizobia, on the focal crop (winter barley). They also tested the addition of high carbon amendments (wheat straw/sawdust) for immobilization of residual soil nitrogen (N) at harvest of the previous crop. Overall, the findings were that non-AMF precrops had a positive effect on winter barley yield compared to AMF precrops. Wheat straw reduced N leaching, whereas sawdust addition had a negative effect on the yield of winter barley. The second experiment tested the effect of different fertilizer (N/phosphorus (P)) application timings on plant traits grown in rhizoboxes. Overall, delaying N application had a more detrimental effect on plant biomass than delaying P application. The root system increased its root length initially due to N-deficiency, but was quickly thus N-limited that root length was relatively lower than the control group. Because of the many root related measurements in the second experiment, a step-by-step method for measuring root traits under controlled and field conditions was developed and included in this thesis. This method paper describes precisely how root traits of interest can be measured, and helps with deciding which approach should be taken depending on the experimental design. Additionally, the authors compared the bias and accuracy of several popular root measurement methods. Overall, these results highlight the importance of crop choice in crop rotations and the plasticity of root systems in relation to nutrient application. The results show high carbon amendments could reduce nitrate leaching after the harvest of crops, especially those with high risk of nitrate leaching, although they had only small impacts on yield.
Both sustainability and transdisciplinary research can change academic research, especially with regard to its relevance for, and relationship with, its environments. Transdisciplinary sustainability research (TSR), thus, offers the opportunity to change non-sustainable development paths of sciences themselves. In order to fully exploit this possibility, this PhD project addresses the question of how TSR, in the first place, does conceptualize and, in the second place, could conceptualize knowledge, research, and science. Firstly, this PhD project analyzes, from a discourse studies perspective, the term problem in TSR, against the background of discourses on sustainable development. Secondly, it explores the historical-analytical and transformative concept of the problematic. The results, firstly, show the consequences of a problem-solving focus for TSR, and secondly, differentiate it from a transformative direction of problematic designing, as a more appropriate view on the dimensions of transformation and their qualities of change that matter for TSR. This PhD project aims to contribute to a self-understanding of, and a philosophical communication about, TSR, as a research form in the sustainability sciences.
Auf Grund der stetig wachsenden Menge an Daten gewinnt die automatische Datenanalyse durch Algorithmen zunehmend an Bedeutung. Im Speziellen trägt die Analyse von Texten ohne manuelles Zutun zu einer erheblichen Erleichterung der Extraktion von relevanten Informationen bei. Sprachliche Informationen können neben der Zuordnung zu Kategorien auf Regeln und Muster untersucht werden. Diese Art der Untersuchung fällt in den Bereich des Text Minings, und in der vorliegenden Arbeit geht es darum, eine qualitative Inhaltsanalyse zum Thema Nachhaltigkeit nachzuempfinden. Es soll geprüft werden, in wie weit automatisierte Verfahren in der Lage sind, Ergebnisse einer bereits bestehenden Untersuchung zu erzielen. In der Durchführung werden mit der Open Source-Software RapidMiner vier Prozesse erstellt, die darauf abzielen, Zeitungsartikel auf ihren Inhalt zu analysieren. Unter anderem werden eine Assoziationsanalyse und eine Klassifikation realisiert, deren Ziel es ist, den Kontext und die Verwendung des Begriffes der Nachhaltigkeit in den Medien zu untersuchen. Die vorliegende Studie will prüfen, ob automatisierten Methoden im Vergleich zu manuellen Verfahren hinreichende Ergebnisse liefern können, sodass die hiesigen Resultate an denen der zu Grunde gelegten Studie von Fischer und Haucke gemessen werden sollen. Die Ergebnisse zeigen, dass die Realisierung einer Inhaltsanalyse mit RapidMiner möglich ist und zu erheblichen Zeiteinsparungen gegenüber konventionellen Verfahren führt. Sie zeigen jedoch auch, dass sich die Minderung des Aufwandes in der Ergebnisqualität widerspiegelt und somit der alleinige Einsatz von Text Mining Verfahren zur Analyse von spezifischen Kontexten noch nicht ausreichend ist.
To respond to the challenges of the Anthropocene, scholars from various disciplines increasingly emphasize that a mere outer transformation is insufficient and that we also need an inner transformation that addresses deep leverage points. Yet, the open questions are how the inner and outer dimensions relate to each other and how inner transformation might lead to outer transformation. How we attempt to answer these questions is determined by our dominant paradigm. Paradigms define how we understand and shape the world, and thus, they define how we conceptualize challenges, such as inner and outer transformation. Various authors argue that the dominant paradigm, which is characterized by reductionism, empiricism, dualism, and determinism, might be a root cause for insufficiently addressing sustainability challenges. As an alternative, many argue for a relational paradigm, which understands complex phenomena in terms of constitutive processes and relations. A relational paradigm might offer possibilities to reconceptualize inner and outer transformation in the Anthropocene and might shed new light on how to integrate both in sustainability science. Yet, it is still being determined how a relational paradigm can contribute to the understanding of inner and outer transformations towards sustainability in the Anthropocene. Therefore, this dissertation's overarching scope is to contribute to systems change towards a more social-ecological future by generating insights into and exploring possibilities of a relational paradigm for inner and outer transformation in the Anthropocene. This thesis is divided into three sub-questions. The first research question aims to increase the theoretical understanding of a relational paradigm. The second research question aims to develop a transformative educational case study grounded in a relational, justice-oriented approach. The third research question aims to analyze how a relational paradigm might contribute to policies and practices for sustainable lifestyles. The results indicate that inner and outer transformation in the Anthropocene can be reconceptualized as paradigm-ing relationality in the Ecocene. "Paradigm-ing" as an active verb, reconceptualizes inner and outer transformation into ontologies, epistemologies, ethics, and socialecological realities that are ongoing, nonhierarchical, nonlinear, dynamic, co-creative processes of intra-action. The Ecocene decenters the human and attends to what we might be able to intra-actand become-with. These insights can offer unexplored perspectives to address sustainability challenges and increase our capacities to respond in novel ways.
Existing institutions no longer appear to be sufficiently capable to deal with the complexity and uncertainty associated with the wicked problem of sustainability. Achieving the required sustainability transformation will thus require purposeful reform of existing institutional frameworks. However, existing research on the governance of sustainability of sustainability transformations has strongly focused on innovation and the more "creative" aspects of these processes, blinding our view to the fact that they go hand with the failure, decline or dismantling of institutions that are no longer considered functional or desirable. This doctoral dissertation thus seeks to better understand how institutional failure and decline can contribute productively to sustainability transformations and how such dynamics in institutional arrangements can serve to restructure existing institutional systems. A systematic review of the conceptual literature served to provide a concise synthesis of the research on "failure" and "decline" in the institutional literature, providing important first insights into their potentially productive functions. This was followed up by an archetype analysis of the productive functions of failure and decline, drawing on a wide range of literatures. This research identified five archetypical pathways: (1) crises triggering institutional adaptations toward sustainability, (2) systematic learning from failure and breakdown, (3) the purposeful destabilisation of unsustainable institutions, (4) making a virtue of inevitable decline, and (5) active and reflective decision making in the face of decline instead of leaving it to chance. Empirical case studies looking at the German energy transition and efforts to phase out coal in the Powering Past Coal Alliance served to provide more insights on (a) how to effectively harness "windows of opportunity" for change, and (b) the governance mechanisms used by governments to actively remove institutions. Results indicate that the lock-in of existing technologies, regulations and practices can throw up important obstacles for sustainability transformations. The intentional or unintentional destabilisation of the status quo may thus be required to enable healthy renewal within a system. This process required active and reflective management to avoid the irreversible loss of desirable institutional elements. Instruments such as "sunset clauses" and "experimental legislation" may serve as important tools to learn through "trial and error", whilst limiting the possible damage done by failure. Focusing on the subject of scale, this analysis finds that the level at which failure occurs is likely to determine the degree of change that can be achieved. Failures at the policy-level are most likely to merely lead to changes to the tools and instruments used by policy makers. This research thus suggests that failures on the polity- and political level may be required to achieve transformative changes to existing power structures, belief-systems and paradigms. Finally, this research briefly touches on the role of actor and agency in the governance of sustainabilitytransformations through failure and decline. It finds that actors may play an important role in causing a system or one of its elements to fail and in shaping the way events are come to be perceived.
Ensuring food security and halting biodiversity loss are two of the most pressing global sustainability challenges. Attempts to identify pathways have been dominated with a biophysical-technical focus that provides technical solutions to the integration of food security and biodiversity conservation. The social-political dimension, however, including equity, governance, and empowerment received little to no attention. By focusing on the poorly investigated social-political dimension, this dissertation aimed to identify governance properties that facilitate and impede the integration of food security and biodiversity conservation through an empirical case study conducted in a multi-level governance setting of southwestern Ethiopia. To address the overarching goal of this dissertation, first the author examined how the existing widely discussed food security approaches and agricultural land use framework, land sparing versus land sharing unfold in the local context of southwestern Ethiopia. The finding in this dissertation indicated that the existing global framing of food security approaches as well as frameworks around agricultural land use has limited applicability in on-the-ground realities mainly because landscapes are complex systems that consist of stakeholders with multiple and (often) conflicting interests. This was evident from the finding that local land use preference was not a matter of "either/or", but instead involved mixed features exhibiting properties of both land sparing and land sharing. Moreover, in addition to the biophysical factors embedded in the existing food security approaches and land use frameworks, stakeholders preference involved social factors such as the compatibility of land use strategy with local values and traditions, which are mainly unaccounted in the existing global frameworks. Findings in this dissertation revealed that the existing reductionist analytical framings to the issues of food security and biodiversity conservation seldom address the complexity inherent within and between food security and biodiversity conservation sectors. Second, this dissertation identified governance structural and process related challenges that influence individual as well as integrated achievements of food security and biodiversity conservation goals. The result of the study showed that the governance of food security and biodiversity conservation was characterized by a strongly hierarchical system with mainly linear vertical linkages, lacking horizontal linkages between stakeholders that would transcend administrative boundaries. Furthermore, with regard to the governance process, three key and interdependent categories of governance process challenges namely, institutional misfit, the problem of interplay, and policy incoherence influenced the achievement of individual and integrated goals of food security and were identified. Given the interdependence of these governance challenges, coupled with the complexity inherent in the food security and biodiversity conservation, attempts to achieve the dual goals thus needs an integrative, flexible and adaptive governance system Third, to understand how food security and biodiversity conservation unfold in the future, the author explored future development trajectories for southwestern Ethiopia. Iterative scenario planning process produced four plausible future scenarios that distinctly differed with regard to dominating land use strategies and crops grown, actor constellations and governance mechanisms, and outcomes for food security and biodiversity conservation. Three out of the four scenarios focused on increasing economic gains through intensive and commercial agricultural production. In contrast, one scenario involved features that are widely considered as beneficial to food security and biodiversity conservation, such as agroecological production, diversification practices, and increased social-ecological resilience. In smallholder landscapes such as the one studied here, such a pathway that promises benefits for both food security and biodiversity conservation may need to be given greater emphasis. In order to ensure the integration of food security and biodiversity conservation, recognizing their interdependence and addressing the challenges in a way that fits with the local dynamics is essential. In addition, addressing the food security-biodiversity nexus requires a holistic analytical lens. Moreover, this dissertation indicated that there is a clear need to pay attention to the governance structure that accommodates the diversity of perspectives, enable participation and strong coordination across geographical boundaries, policy domains and governance levels. Finally, this dissertation revealed opportunities to integrate food security and biodiversity through the pro-active management of social-ecological interactions that produce a win-win outcome. The win-win outcome could be achieved in a system that involve properties such as diversification and modern agroecological techniques, smallholders empowerment, emphasize adaptive governance of social-ecological systems, value local knowledge, culture and traditions, and ensure smallholders participation.
A solid knowledge about nature is essential to understand the consequences of biodiversity loss, the limitation of natural resources and the need for a sustainable development. Inspired by these challenges, the researcher investigated in her dissertation seed predation, an important ecosystem function, as part of citizen science project. As seed predation has only rarely been investigated along urban-rural gradients and to integrate the question if the background (urban vs. rural) of primary school children affects their environmental knowledge, she selected study sites in and around Lüneburg and Hamburg, in Northern Germany. In her ecological experiments, it was found that slugs are important seed predators that independently of urbanization predated about 30% of all seeds in the anthropogenically used landscapes investigated. Also, for the first time, primary school children could be integrated in a citizen science approach into this research and it could be shown that even seven year old children can record data as reliable as a scientist. Finally, the researcher investigated the native species knowledge from the children taking part as citizen scientists in her research, considering possible differences due to their urban or rural background. Contrary to her expectation, the urban or rural background had no significant effect on the species knowledge. However, the work provides a good foundation to transfer the approach of introducing a basic foundation of a taxonomical species concept in primary school to foster further understanding on biodiversity and ecosystem functions.
Over the past two decades, transitions research has witnessed rapid development. However, there is still a notable gap in our understanding of sustainability transitions in conflict settings and the role of international organizations in these transitions. Little is known about the dynamics of power, limiting and facilitating factors, and the role of (international) actors in sustainability transitions in conflict settings. This dissertation seeks to make contributions to these discussions by examining energy transitions in Afghanistan, a conflict-affected country, between 2001 and 2021. It specifically focuses on the involvement of international development organizations, shedding light on their role in energy access, institutional change, and imagining Afghanistan's future energy system development. After security, access to affordable energy is frequently reported to be Afghanistan's most pressing need. Following the fall of the first Taliban regime in 2001, billions of dollars and dozens of international development organizations poured into Afghanistan to support the reconstruction of the country including its energy sector. Between 2001 and 2021, the government of Afghanistan and the international development organizations worked on various aspects of energy system development despite on-going insurgency and threats against infrastructural projects. In 2021, the Taliban regained power, resulting in the suspension of operations for most development organizations, with only a few humanitarian agencies remaining active. Within this context, this thesis explores topics such as the country's energy potential and policy, the role of international development organizations in the energy sector, and visions for a future energy system in Afghanistan. The research conducted for this thesis employed a qualitative case study approach, utilizing semi-structured interviews and document analysis.
Aufgrund ihrer Struktur sind insbesondere urbane Strukturen von Klimafolgen wie z.B. Hitze, Stürme oder Starkregen betroffen. Der Raum- und Umweltplanung kommt dabei hinsichtlich der sozial-ökologischen Naturverhältnisse eine wichtige Rolle zu, sofern sie die Aufgaben der Krisenbewältigung annehmen und verantwortungsvoll wahrnehmen will. Auch die Hansestadt Lüneburg steht zukünftig vor einigen Herausforderungen. Durch den allgemeinen Trend der Urbanisierung und als Teil der Metropolregion Hamburg gilt Lüneburg als beliebter Wohnraum. Die vorliegende Arbeit lenkt den Blick auf die Klimafolgenanpassung bei Starkregen in der Stadtplanung allgemein und auf die Hansestadt Lüneburg. Zunächst werden die der Ausarbeitung zugrundegelegten Begriffe sowie die Bedeutung von Starkregenereignissen in der Stadtplanung definiert und näher erläutert. Darauf folgt die Darstellung der zur Beantwortung der Forschungsfrage verwendeten Methoden. Anschließend werden in der empirischen Forschung das bisherige Auftreten von Starkregen analysiert, bestehende Adaptionsstrategien norddeutscher Städte und Regionen aufgezeigt, ein Zukunftsausblick auf Grundlage wissenschaftlicher Prognosen gegeben und konkrete, auf die Hansestadt Lüneburg bezogene Analysen und Szenarien erstellt, bevor ein Resümee der empirischen Forschung gezogen werden kann. Abschließend wird das methodische Vorgehen reflektiert, die Ergebnisse diskutiert und ein kurzer Ausblick auf zukünftige Herausforderungen gegeben.
Um das noch bestehende Reichweitenproblem von Elektrofahrzeugen zu lösen, sind Fahrzeugkonzepte wie Plug-in Hybridfahrzeuge sehr vielversprechend, sofern mit ihm überwiegend im Batteriebetrieb gefahren wird. Sie kombinieren die Vorteile des Verbrennungsmotors und des Elektromotors, sodass das lokale Emissionsproblem in Ballungszentren gelöst werden kann, ohne dass der Kunde dabei auf die Reichweite verzichten muss. Wenn das Fahrzeug allerdings überwiegend für Kurzstrecken genutzt wird, sind alterungsbedingte Veränderungen des Kraftstoffes möglich, da dieser länger im Tank verbleibt als üblich. In dieser Arbeit wird ein Konzept zur sensorischen Bestimmung der Qualität des Kraftstoffes vorgestellt. Hierzu wurde ein Prototyp entwickelt, in dem mithilfe des Real- und Imaginärteils der Permittivität alternde Kraftstoffe erkannt werden können. Dabei konnte durch das frequenzabhängige Permittivitätssignal des Sensors spezifisch zwischen nieder- und hochmolekularen Oxidationsprodukten in Kraftstoffen unterschieden werden. Da das Verbrennungs- und Emissionsverhalten des Motors von der Kraftstoffmischung vorgegeben ist, bietet eine zusätzliche sensorische Erfassung der Kraftstoffzusammensetzung weitere Optimierungspotenziale, um Emissionen zu reduzieren: So ist das Motormanagement im Fahrzeug zumeist auf Referenzkraftstoffe mit gleichbleibender Qualität abgestimmt. Variable Kraftstoffzusammensetzungen, die durch die Erdöllagerstätte und den zusätzlichen Konversionsverfahren zur Herstellung von fortschrittlichen Kraftstoffen vorgegeben sind, werden in dieser Anpassungsstrategie bisher nicht berücksichtigt. Als weitere Aufgabe wird in dieser Arbeit daher ein multisensorischer Ansatz verfolgt, wonach zusätzlich zur Kraftstoffalterung noch die Kraftstoffzusammensetzung erkannt werden kann. Insgesamt bietet die Sensorik das Potenzial zur kontinuierlichen Kraftstoffüberwachung in Plug-in Hybridfahrzeugen, um so einen Beitrag zum sicheren und nachhaltigen Betrieb solcher Fahrzeuge gewährleisten zu können.
Seit den frühen 1990er Jahren wird transdisziplinäre Nachhaltigkeitsforschung in Form von problemorientierten Forschungs- und Lernprojekten konzeptioniert und praktisch umgesetzt, an denen außeruniversitäre Akteuren beteiligt sind. Diese Forschungsarbeit verfolgt drei Ziele: Erstens, die Konzeptualisierung der Begriffe Kultur, Multi-, Inter- und Transkulturalität in der Literatur zur transdisziplinären Nachhaltigkeitsforschung zu untersuchen. Zweitens, die Konzeptionierung und Umsetzung von transdisziplinären Forschungs- und Lernprojekten in Hinblick auf kulturelles Differenzieren zu analysieren. Drittens, konzeptionelle Beiträge zur Gestaltung von transdisziplinären Forschungs- und Lernprojekten zu entwickeln. Methodisch wird auf Literaturanalysen und eine qualitative Untersuchung zweier transdisziplinärer Lernforschungsprojekte zurückgegriffen. Unter dem Begriff Forschungs- und Lernprojekt werden in dieser Forschungsarbeit sowohl Forschungsprojekte als auch Lehr-Lernforschungsprojekte gefasst. Zentrale Ergebnisse der Forschungsarbeit sind die Folgenden: Erstens wird der Kulturbegriff in der transdisziplinären Nachhaltigkeitsforschung zwar vielfältig verwendet, als Forschungsthema, Hintergrund von Beteiligten, Kooperationsweise, Projektkontext, in Hinblick auf Interkulturalität oder als Wissenskultur, allerdings kaum ausdifferenziert und konkretisiert. Zweitens besteht auf der Ebene der Konzeptionierung von transdisziplinären Forschungs- und Lernprojekten: 1) ein starkes Übergewicht von Integration und Konsens gegenüber einer Auseinandersetzung mit Differenz, 2) eine implizite Vorauswahl von Beteiligten durch bestimmte Begrifflichkeiten und methodologische Ansätze und 3) eine Reproduktion von Machtverhältnissen durch (dichotome) Symmetrie- und Ausgleichsvorstellungen. Drittens zeigt sich auf der Ebene der Umsetzung von Lernforschungsprojekten: 1) eine starke Prozessorientierung der Projekte, 2) ein Spannungsfeld zwischen einer Öffnung und Steuerung in Hinblick auf den Projektverlauf und 3) vielfältige Differenzaushandlungen in Interaktionen (wie Zeitlichkeit, Verantwortung, Erfahrung, Relevanz). Die Ergebnisse zeigen, dass politische Implikationen der Forschung und zentrale Ungleichheitskategorien der Kultur- und Sozialwissenschaften (u.a. race, class, gender, body) kaum thematisiert werden. Vorschläge zur Gestaltung transdisziplinärer Forschungs- und Lernprojekte werden in Hinblick auf ein Verständnis von Forschungsdesigns als Prozesse, einem Erkunden von Differenzierungen und Forscherpositionen und der Bedeutung eines Verlernens entwickelt.
Diese Dissertation verfolgt einerseits das Ziel der umfassenden Sichtung der technischen, psychologischen, philosophischen und neurobiologischen Grundlagen der Künstlichen Intelligenz und damit die Etablierung einer epistemischen und ontologischen Eingrenzung der Technologie und andererseits das Ziel der moralphilosophischen Beurteilung und Risikobewertung. Die zentrale Hypothese unterstellt der Technologie, die überhaupt nur durch die rasanten Fortschritte der Natur- und Ingenieurwissenschaften und damit durch die Aufklärung ermöglicht wurde, eine Unterwanderung der zentralen Prinzipien und Werte der Aufklärung. Zu befürchten ist eine selbstverschuldete Unmündigkeit des Menschen durch die Künstliche Intelligenz. Wesentlich in der Argumentation ist das Aufgeben von menschlicher Autonomie zugunsten einer Technologie, die selbst nicht autonom sein kann, die Verlagerung von Verantwortlichkeiten in einen neu entstandenen rechtsfreien Raum, der Verlust der menschlichen Individualität und letztlich die Preisgabe der Menschenwürde durch den Übergang in ein "Reich ohne Notwendigkeit", aus dem es kein Entkommen gibt. Eine Ethik der Künstlichen Intelligenz muss, so die normative Schlussfolgerung, die Wahrung der menschlichen Autonomie, Verantwortlichkeit, Individualität und Würde in den Vordergrund stellen, sodass ein individueller und kollektiver Rückfall des Menschen in die Unmündigkeit verhindert wird.
Contemporary society is shaped by the idea that time is, above all, a scarce economic resource that must be used efficiently. Increasingly, however, scientific findings suggest that such a way of perceiving of time seems a major cause of the current global climate and sustainability crisis. Considerably less research work has been carried out in relation to the role of individual time-related needs regarding unsustainable consumption behaviour, although consumer research has been addressing needs-oriented approaches to sustainable consumption for a long time. Environmental and Sustainability Education (ESE) is considered an essential strategy to achieve the global sustainability goals of Agenda 2030. Internationally, as well as on a national level, ESE is increasingly mainstreamed in educational curricula and practice. Given the relation between time, needs and sustainability, it appears valuable to inquire into this field from the perspective of ESE. The core research interest of this cumulative dissertation is therefore the question of how the connection between time, our needs and sustainability can be conveyed through pedagogical approaches. The inquiry used an exploratory, qualitative research design to address this question. In a first step, the concept of sustainability-related time use competence was developed. This then served as a guiding concept for the understanding of time used in this work and as the overall objective for the educational intervention developed and piloted as part of the research. Next, a content analysis of German curricula was conducted with the aim of determining whether and to what extent these address the relation between time and sustainability. The results show curricula contain only a few starting points that encourage a connection between time and sustainability in school lessons. The study further indicates that an understanding of time as a scarce resource to be used efficiently has prevailed in school contexts so far. The next step involved developing and piloting a time use competence curriculum in cooperation with three partner schools, using an Action Research Approach. This intervention followed the pedagogical approach of Self-Inquiry Based Learning (SIBL) seeking to sensitise learners to the relation between individual needs and consumer behaviour. During implementation, which lasted one semester, students logged their time, were encouraged to reflect on their personal needs, and subsequently implement individual change projects related to time use. This was embedded in continuous reflective individual and group exercises. The results strengthen the hypothesis that there is a relation between time use and sustainability. Furthermore, the pedagogical approach of SIBL has proven suitable to enable students to reflect on their time use and to raise their awareness of the role of individual needs. Participants reported that changes in time use did indeed increase their personal well-being. A third empirical study was carried out, inquiring into students' time use during the period of COVID-19-induced school closures, using a Grounded Theory Approach. Since the pandemic disrupted young peoples' routines drastically, the research focused on which kinds of learning experiences students made during this time and which insights can be derived for ESE. The results of the semi-structured interviews with 69 participants show first that a variety of learning experiences are revealed, such as learning one's own learning and everyday rhythms or creatively adapting consumption habits to the new situation of "lockdown". Overall, a key finding of this work is that students are currently unable to adequately realise their time-related needs. In view of the findings from research on time and sustainability, one recommendation is therefore that everyday school life could give students more space to organise their time according to their needs. Furthermore, it would be advisable to give the topic of time in connection with sustainability more space in curricula and in teacher training. The experiences during the pandemic have shown that schools and all actors involved including students and teachers, are so far insufficiently prepared to handle crises. Here, the approach to time use competence piloted in this work can offer valuable stimulations for ESE research and practice. This is especially true since it is compatible with existing approaches to key competencies for sustainability by seeking to complement them with a stronger focus on individual, needs-oriented time shaping.
This dissertation examines how smallholder farming livelihoods may be more effectively leveraged to address food security. It is based on empirical research in three woredas (districts) in the Jimma Zone of southwestern Ethiopia. Findings in the chapters that follow draw on quantitative and qualitative data. In this research, the author focuses on local actors to investigate how they can be better supported in their roles as agents who have the ability to improve their livelihoods and achieve food security. This general aim is operationalized through three research questions: (i) How do livelihood strategies influence food security?; (ii) What livelihood challenges are common and how do households cope with these?; and (iii) How do social institutions, in which livelihoods are embedded, influence people's abilities to undertake livelihoods and be food secure? Using quantitative data from a survey of randomly selected households, the author applied a number of multivariate statistical analysis to determine types of livelihood strategies and to establish how these strategies are associated with capital assets and food security. Here she views livelihood strategies as a portfolio of livelihood activities that households undertake to make a living. The predominant livelihood in the study area was diversified smallholder farming involving mainly the production of crops. Based on their analyses, the authors found five types of livelihood strategies to be present along a gradient of crop diversity. Food security generally decreased with less crops being part of the livelihood strategy. The livelihood strategies were associated with households' capital assets. The status of food (in)security of each household during the lean season was measured using the Household Food Insecurity Access Scale (HFIAS). A generalized linear model established that the type of livelihood strategy a household undertook significantly influenced their food security. Other significant variables were educational attainment and gender of household head. The findings contribute evidence to the benefits of diversified livelihoods for food security. Smallholder farming in southwest Ethiopia is beset with process-related and outcome-related challenges. Here, a process-related challenge pertains to the lack of different types of capital assets that people need to be able to undertake their livelihoods, while an outcome-related challenge pertains to lack of food. The most frequently mentioned process-related challenges were associated with the natural capital either as lack in necessary ecosystem services or high levels of ecosystem disservices. Farming households typically faced the combined challenges of decreasing soil fertility, land scarcity, die-off of oxen due to diseases, and wild animal pests. Lack of cash was also common. The findings indicate that when households liquidate a physical asset in order to gain cash, the common outcome is an erosion of their capital asset base. On the other hand, when households drew on their social capital, they tended to maintain their capital asset base. Human capital, for example, in the form of available labor was also important for coping. Protecting and enhancing natural capital is needed to strengthen the basis of livelihoods in the study area, and maintaining social and human capitals is important to enable farming households to cope with challenges without eroding their capital asset base. Smallholder farming in southwest Ethiopia is embedded in a social context that creates differentiated challenges and opportunities. Gender is an axis of social differentiation on which many of the differences are based. The currently ruling Ethiopian political coalition has put important policy reforms in place to empower women. Local residents reported notable changes related to gender in the last ten years. To make sense of the changes, the authors adapted the leverage points concept. Using this concept, the authors classified the reported changes as belonging to the domains of visible gaps, social structures, and attitudes. Importantly, changes within these domains interacted. The most prominent driver of the changes observed was the government's emphasis on empowering women and government-organized interventions including gender sensitization trainings. The changes toward more egalitarian relationships at the household level were perceived by local residents to lead to better implementation of livelihoods, and better ability to be food secure. The study offers the insight that while changing deep, underlying drivers (e. g. attitudes) of systemic inequalities is critical, other leverage points such as formal institutional change and closing of certain visible gaps can facilitate deeper changes (e. g. attitudes) through interaction between different leverage points. This can inform gender transformative approaches. While positive gender-related changes have been observed, highly unequal gender norms still persist that lead to women as well as poor men being disadvantaged. Social norms which provide the basis for collective understanding of acceptable attitudes and behaviors are entrenched in people's ways of being and doing and can therefore significantly lag behind formal institutional changes. Norms influenced practices around access and control of capital assets, decision-making, and allocation of activities with important implications for who gets to participate, how, and who gets to benefit. To more effectively leverage smallholder farming for a food secure future, this dissertation closes with four key insights namely: (1) Diversified livelihoods combining food and cash crops result in better food security; (2) Enhancing natural and social capital is a requisite for viable smallholder farming; (3) Social and gender equality are strategically important in improving livelihoods and food security; and (4) Institutions particularly social norms are key to achieving gender and social equality.
The Sustainable Development Goals (SDGs) recognize the importance of the inextricable link between social and ecological systems and human quality of life (QoL) and biodiversity. Therefore, understanding the feedback and interactions between biodiversity, nature’s contributions to people (NCP), and QoL plays a central role in advancing toward sustainability. In this context, the social-ecological systems (SES) approach has advanced on the subject, particularly in recent decades; however, much remains to be done to comprehensively understand these relationships and interactions, especially at local decision-making scales. In this thesis, through the lenses of the SES approach, the researcher investigates connections between biodiversity, NCP, and QoL in a tropical dry forest (TDF) on the Western coast of Mexico. This place is one of the best-known Neotropical TDF and has been the focus of SES research in the past 20 years, making it an excellent case study for exploring these connections. First, to approach the need for dialogue among different global and local scales and between global and local frameworks, the thesis identifies five key components of the SES dynamics-(1) ecological supply, (2) co-production of NCP, (3) management, (4) demand, and (5) benefits - and three local decision-making scales of analysis: individual plot, smallholder, and land tenure or governance units. A literature review was performed on the social-ecological indicators for the last 11 years in the Chamela-Cuixmala region to operationalize this framework. Second, this thesis uses social-ecological information to identify social-ecological systems units (SESU) spatially explicitly. A methodology was provided to spatially identify the components of social-ecological systems that environmental conditions and management practices have shaped at three previously stated relevant decision-making scales: plots owned by individuals, plot owners, and governance units. To do so, the research group identified and characterized: (1) ecological clusters (EC), (2) social-management clusters (SC), and (3) SESU in a TDF in western Mexico. The findings suggested that decision-makers (ejidatarios, i.e., type of ownership (related to agrarian reform), that in most cases the land allocated is small-smallholders) are bounded by the topographical characteristics and the public policies that determine communal (or private) governance and the number of resources available to them. Finally, the thesis examines the self-perceived QoL across the different SESU, finding 48 QoL items, which were grouped into six categories: 1) social capital, 2) economic capital, 3) agency, 4) nature, 5) peasant non-work activities, and 6) government and services; and two additional dimensions referred to obstacles and enablers of QoL. The researchers found that the more land cover transformation, the more enablers, and obstacles of QoL are identified; emphasis was put on economic capital to achieve QoL. As management is intensified and governance fosters individualism across SES, the higher the Current Welfare Index, and the lower the self-perceived material and non-material satisfaction.
Sustainability transitions research proposes fundamental changes of societal systems' organisation to overcome persistent societal challenges, such as climate change or biodiversity loss, and allowing systems to become more sustainable. This thesis adresses an underlying tension in sustainability transitions research: between transitions as an open-ended process of fundamental change and the normative direction of this change: sustainability. In doing so, three themes are in the focus of the research: individual agency, normativity and transdisciplinary collaboration. Thereby, the thesis aims to strengthen process-oriented and potentially transformative approaches to sustainability transition research, in contrast to primarily descriptive-analitical approaches. Transition management as a recent and salient example of transdisciplinary transition research is chosen to provide research framework and application context. Based on conceptual-theoretic, empirical case study and reflexive work, three main results are contributed: First, a psychologically enriched understanding of individual and sustainability related agency in conceptual and empirical understandings of transition management is developed. This builds on two perspectives: a psychologically enriched capability approach as well as the analysis of social effects (social learning, empowerment and social capital development) of transition management to capture sustainability oriented agency increases. As second main result, normative considerations, namely sustainability, are included into transition management on conceptual and empirical levels. Therein, substantive, procedural and intentional aspects of sustainability are combined: Substantive aspects are covered by proposing capabilities, behavioral freedoms to live a valuable life, as normative yardsticks to measure developments. Procedural aspects include a detailed understanding of facilitating a learning journey towards making sustainability meaningful in the local transition management cases and setting up experiments for its realiziation. Intentional aspects are addressed by linking social effects of transition management to awareness, motivations and feelings of responsibility towards sustainability. As a third main result, the transdisciplinary collaboration in transition management of creating an arena as an interactive learning space is conceptualized and explored, as well as the roles of the researchers therein. Key issues of this learning space, the community arena, are drawn out and ideal-type roles and activities of researchers in addressing these issues are proposed and empirically analysed. As synthesis of thesis results, ten principles of sustainability transition management are proposed.
As modern society progresses, waste treatment becomes a pressing issue. Not only are global waste amounts increasing, but there is also an unmet demand for sustainable materials (e.g. bioplastics). By identifying and developing processes, which efficiently treat waste while simultaneously generating sustainable materials, potentially both these issues might be alleviated. Following this line of thought, this dissertation focuses on procedures for treatment of the organic fraction of waste. Organic waste is a suitable starting material for microbial fermentation, where carbohydrates are converted to smaller molecules, such as ethanol, acetic acid, and lactic acid. Being the monomer of the thermoplastic poly-lactic acid, lactic acid is of particular interest with regard to bioplastics production and was selected as target compound for this dissertation. Organic waste acted as substrate for non-sterile batch and continuous fermentations. Fermentations were initiated with inoculum of Streptococcus sp. or with indigenous consortium alone. During batch mode, concentration, yield, and productivity reached maximum values of 50 g L−1, 63%, and 2.93 g L−1 h −1. During continuous operation at a dilution rate of 0.44 d−1, concentration and yield were increased to 69 g L−1 and 86%, respectively, while productivity was lowered to 1.27 g L−1 h −1 . To fully exploit the nutrients present in organic waste, phosphate recovery was analyzed using seashells as adsorbent. Furthermore, the pattern of the indigenous consortium was monitored. Evidently, a very efficient Enterococcus strain tended to dominate the indigenous consortium during fermentation. The isolation and cultivation of this consortium gave a very potent inoculum. In comparison to the non-inoculated fermentation of a different organic waste batch, addition of this inoculum lead to an improved fermentation performance. Lactic acid yield, concentration, and molar selectivity could be increased from 38% to 51%, 49 g L−1 to 65 g L−1, and 46% to 86%, respectively. Eventually, fermentation process data was used to perform techno-economic analysis proposing a waste treatment plant with different catchment area sizes ranging from 50,000 to 1,000,000 people. Economically profitable scenarios for both batch and continuous operation could be identified for a community with as few as 100,000 inhabitants. With the experimental data, as well as techno-economic calculations presented in this dissertation, a profound contribution to sustainable waste treatment and material production was made.
The emergence of sustainability as a guiding principle for tourism development came along with needs to introduce instruments that can monitor the actual impacts of tourism. Sustainability assessments in tourism (SAT) have gained popularity in recent years with a range of measurement schemes being introduced for national and subnational tourism destinations. With the help of sustainability indicators these schemes intend to guide decision-makers in making better evidence-informed decisions and to improve the overall sustainability performance of tourism. With this dissertation, the author aims to contribute to a deeper understanding of the implementation and performance of sustainability assessments, by linking transformative needs of tourism with necessary assessment approaches that can serve as effective instruments for a shift towards a more sustainable tourism development. Thus, the research is part of recent efforts to establish profound and effective measurement approaches for sustainable tourism. The author employs a mixed-methods approach combining qualitative, quantitative, set-theoretic, and review methods, with the aim of maximising the validity of results. First, he explores the general progress and current state of research on sustainability assessments in tourism, with the intention to identify patterns, key elements and research gaps within assessment approaches This is followed by subsequent detailed analyses that examine specific environmental and socio-economic sustainability issues with the aim of providing conceptual, methodological and empirical solutions for assessing them in detail. The dissertation highlights that concrete assessment tools are needed for evidence-informed decision-making and the establishment of effective actions in destination management. The findings indicate that assessments will be more successful in terms of serving as tools for decision-making, if they tackle main drivers of change and encourage management or policymakers to take decisions that affect multiple sustainability issues. It also reviews different concepts and accounting principles and rises awareness of a cautious selection of methods and measurement approaches, as this may affect overall results. The thesis empirically evaluates and applies different measurement approaches in specific destinations, with the help of quantitative and qualitative data collection methodologies. In general, my thesis provides further clarification about key environmental and socio-economic measurement methodologies, which supports ongoing debates about sustainability impacts of tourism. Thus, the research contributes to knowledge, frameworks, methodologies and practical application for tourism governance and tourism sustainability science.
Ein wesentlicher Beitrag zur rationalen Verwendung unserer Energieresourcen kann durch die konsequente Nutzung diskontinuierlich anfallender Wärmeenergie erbracht werden, was aufgrund der zeitlichen Verschiebung von Wärmeangeboten und Wärmebedarf auf direktem Wege oft nicht möglich ist. Dies gilt sowohl für die Nutzung anfallender Abwärme aus Kühlprozessen als auch den ökonomiaschen Einsatz von Solarenergie. Dazu ist erforderlich, mit Hilfe eines effizienten Energiespreichers den überschüssigen Energieanfall zu verlagern.
The emission of anthropogenic trace substances into the aquatic environment continuously poses challenges to water suppliers. The contamination of raw waters with organic trace substances requires complex water treatment processes to secure drinking water quality. The routine monitoring of these raw waters as well as the behavior and fate of organic trace substances during different treatment processes is of great interest to recognize and counter potential dangers at an early stage. Non-target screening using liquid chromatography coupled to high-resolution mass spectrometry (LC-HRMS) allows the detection of thousands of compounds within a single run and covers known as well as unknown substances. Compared to the established analytical techniques, this is a decisive advantage for the monitoring of raw and process waters during water treatment. While the analytical technique LC-HRMS has undergone significant developments in recent years, the algorithms for data processing reveal clear weaknesses. This dissertation therefore deals with reliable processing strategies for LC-HRMS data. The first part of this work seeks to highlight the problematics of false positive and false negative findings. Based on repeated measurements, various strategies of data processing were assessed with regard to the repeatability of the results. To ensure that real peaks were barely or not removed by the filtering procedure, samples were spiked with isotope-labeled standards. The results emphasize that the processing of sample triplicates results in sufficient repeatability and that the signal fluctuation across the triplicates emerged as a powerful filtering criteria. The number of false positives and false negatives could be significantly reduced by the developed strategies which consequently improve the validity of the data. The second part of this thesis addresses the development of processing strategies particularly aimed at assessing water treatment processes. The detected signals were tracked across the treatment process and classified based on their fold changes. A more reliable signal classification was achieved by implementing a recursive integration approach. Special integration algorithms allow a reliable signal classification even though the signal to be compared was below the intensity threshold. Different combinations of replicates of process influents and effluents were processed for evaluating the repeatability. The good repeatability was indicated by the results of both the plausibility checks and the ozonation process (ozonation of pretreated river water) and thus points to high reliability. The applicability of the developed strategies to real world applications is demonstrated in the last part of this work. Besides the prioritization of the generated results, the main focus was the identification of recognized compounds. The developed strategies clearly improve the validity of the underlying data. The combination of LC-HRMS analysis with reliable processing strategies opens up multiple possibilities for a more comprehensive monitoring of water resources and for the assessment of water treatment processes. The processing strategies and validation concepts may be easily transferred to other research fields.
Misophonia in the workplace
(2021)
This paper uses the UN’s Sustainable Development Goals’ inclusion of human well-being and disability rights as a base to examine the work experiences of individuals with the syndrome misophonia who have been employed in white-collar office jobs in the Global North, and how these experiences fit into the current discourse on making offices more inclusive and sustainable. It reports on common workplace triggers, coping mechanisms, and the condition’s perceived effects on misophonics, as well as the perceived barriers and carriers to making workplaces more accommodating to those with the condition. A mixed-methods approach was used to address these points. First, a survey was distributed virtually and 203 responses from misophonics who work(ed) in white-collar office jobs in the study region were collected. Next, ten of these survey takers participated in semi-structured, one-on-one interviews, which were then analyzed using qualitative text analysis. The results showed that many misophonics frequently encounter intense triggers (such as mouth sounds) at the office and that self-perceived levels of productivity, well-being, and workplace sociability can be adversely affected. Though opinions on bans of certain behaviors and items and on certain terminology were diverse, there was consensus on desiring more flexible policies, understanding from others, and quiet or private working spaces, including working from home. Lack of misophonia awareness within the general populace, human resources (HR), upper management, and to some degree, the medical community was identified as a persistent barrier to misophonic employees disclosing or asking for reasonable accommodations even when they felt their misophonia was severe, negatively affected them, and there were provisions that could support them. These experiences were similar to those of other invisible conditions and pointed to the need for workplaces striving to be more sustainable and inclusive to adapt their policies and office design decisions.
In der transdisziplinären Nachhaltigkeitsforschung sollen mit partizipativen Forschungsansätzen Lösungen für einen gesellschaftlichen Wandel hin zur Nachhaltigkeit generiert werden. Allerdings fehlen bisher Begründungen und Belege für die Erwartungen, die mit der Partizipation verbunden werden, und auch die mangelnden gesellschaftlichen Veränderungen durch die transdisziplinäre Nachhaltigkeitsforschung wurden kritisiert. Gleichzeitig legen Forschungen aus dem Feld der governmentality studies nahe, dass partizipative Prozesse auch ein gewisses Risiko bergen, Herrschaftszustände aufrechtzuerhalten. Um einen Wandel hin zur Nachhaltigkeit zu befördern, sollen in dieser Arbeit daher mit der Regierungskonzeption von Michel Foucault die Ausgestaltung der Partizipation in der transdisziplinären Nachhaltigkeitsforschung untersucht werden und insbesondere inwieweit diese stabilisierend für die gesellschaftlichen Verhältnisse wirken kann. Dementsprechend wird die transdisziplinäre Nachhaltigkeitsforschung auf Übereinstimmungen und Unterschiede zur neoliberalen Gouvernementalität untersucht und die Implikationen des Ergebnisses vor dem Hintergrund eines an den Brundtland Berichts angelehnten Nachhaltigkeitsverständnisses diskutiert. Die Untersuchung zeigt starke Parallelen zwischen der transdisziplinären Nachhaltigkeitsforschung und einer neoliberalen Regierungsweise. Auch wenn diese Regierungsweise durchaus Vorteile mit sich bringt, gibt es doch Anzeichen, dass sie, und damit auch die transdisziplinäre Nachhaltigkeitsforschung, dazu neigt, soziale Ungleichheit zu verstärken und strukturelle Gründe für Armut und die Zerstörung der natürlichen Lebensgrundlage zu vernachlässigen. Dies würde den Hauptmotiven des Nachhaltigkeitsverständnisses entgegenwirken.
Im Kontext der Problematik von Fehlinformationen in der populärwissenschaftlichen Literatur widmet sich diese Arbeit in einer Fallstudie drei häufig verkauften Büchern Peter Wohllebens. Untersucht wird, wie nah diese Werke sich am aktuellen Stand der Forschung orientieren und wie gut die getätigten Aussagen nachvollziehbar sind. Für die Untersuchung wurde der Inhalt der Bücher codiert und die resultierenden 8899 Codiereinheiten quantitativ und qualitativ-vergleichend analysiert. Ergänzt wurde dies durch die qualitativ-vergleichende Analyse von drei Schwerpunktthemen. Aus den Ergebnissen wird geschlussfolgert, dass Wohllebens Nähe zum wissenschaftlichen Diskurs unter Einschränkungen ausreichend und die Nachvollziehbarkeit seiner Aussagen mangelhaft ist. Basierend auf diesen Erkenntnissen werden mögliche Maßnahmen und Handlungsfelder für eine Erhöhung der wissenschaftlichen Qualität populärwissenschaftlicher Werke diskutiert. Es werden weitere potentielle Forschungsmöglichkeiten für ein besseres Verständnis der Situation in den Populärwissenschaften identifiziert und vorgeschlagen.