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Despite the great progress that has been made in the prophylaxis of oral diseases over the past decades, dental caries and periodontal diseases remain major challenges in the field of dentistry. Biofilm formation on dental hard tissues is strongly associated with the etiology of these oral diseases. Therefore, the process of bioadhesion and biofilm formation on tooth surfaces is of particular interest for dental research. The first stage of bioadhesion on dental surfaces is the formation of the pellicle layer. This mainly acellular film, composed largely of adsorbed proteins, glycoproteins, and lipids, is distinguished from the microbial biofilm (plaque). As the interface between teeth and the oral environment, the pellicle plays a key role in the maintenance of oral health and is of great physiological and pathophysiological importance. On the one hand, the pellicle shows protective properties for the underlying dental hard tissues. On the other hand, it also serves as the basis for dental plaque and therefore, for the development of oral diseases such as caries and periodontitis. Hydrophobic interactions, which are governed by lipophilic substances, are of high relevance for bacterial adherence. Therefore, pellicle lipids, which are a significant constituent of this biological structure, are an interesting target for dental research, as they could modulate oral surfaces, influence microbial interactions, and potentially impede bacterial adherence. Compared to the extensive work on the pellicle´s ultrastructure and protein/amino acid composition, little attention has been given to its lipid profile. Knowledge of the lipid composition of the pellicle may provide insight into several oral pathological states, including caries, dental erosion, and periodontal disease processes and could contribute to novel approaches in preventive dentistry. The principle aim of this thesis was the comprehensive characterization of the fatty acid (FA) profile of the in situ formed pellicle layer. This includes the influence of pellicle maturation on the FA profile as well as intra- and interindividual differences. Furthermore, investigations on the effect of rinses with edible oils on the pellicle´s FA composition were a focus of this work. For these purposes, an analytical method based on a combination of innovative specimen generation and convenient sample preparation with sensitive mass spectrometric analysis was successfully developed and comprehensively validated within this thesis. Pellicle samples were formed in situ on bovine enamel slabs mounted on individual upper jaw splints. After a comprehensive sample preparation, gas chromatography coupled with electron impact ionization mass spectrometry (GC-EI/MS) was used in order to characterize qualitatively and quantitatively a wide range of FA (C12-C24). The individual FA profiles of pellicle and saliva samples collected from ten research participants were investigated. The relative FA profiles of the pellicle samples gained from the different subjects were very similar, whereas the amount of FAs showed significant interindividual variability. Compared to the pellicle´s characteristic FA profile, higher proportions of unsaturated FAs were detected in the saliva samples, highlighting that FAs available in saliva are not adsorbed equivalently to the pellicle layer. This, in turn, shows that pellicle formation is a highly selective process that does not correlate directly with salivary composition. Additionally, pellicle samples collected after 3, 30, 60, 120, and 240 min of intraoral exposure were analyzed. It could be shown that pellicle maturation has only a minor impact on the FA composition. However, the FA content increased substantially with increasing oral exposure time. Modifying the pellicle´s lipid composition by using edible oils as a mouthwash could alter the physicochemical characteristics of the pellicle and strengthen its protective properties by delaying bacterial adhesion. Therefore, the impact of rinses with safflower oil on the pellicle´s FA composition was determined. The application of rinses with safflower oil resulted in an accumulation of its specific FAs in the pellicle, thus representing a possibility for modifying the pellicle´s lipid profile. The present work is the first to apply a validated method that combines in situ pellicle formation, sample preparation, and the comprehensive determination of FAs via a sensitive analytical method. The results provide valuable information regarding the pellicle´s FA composition which closes an existing knowledge gap in pellicle research. A broader knowledge of the lipid composition of the pellicle contributes to the understanding of oral bioadhesion processes and may help facilitate novel approaches in preventive dentistry.
Wind energy is expected to become the largest source of electricity generation in Europe's future energy mix. As a consequence, future electricity generation will be exposed to an increasing degree to weather and climate. With planning and operational lifetimes of wind energy infrastructure reaching climate time scales, adaptation to changing climate conditions is of relevance to support secure and sustainable energy supply. Premise for success of wind energy projects is the ability to service financial obligations over the project lifetime. Though, revenues(viaelectricity generation) are exposed to changing climate conditions affecting the wind resource, operating conditions or hazardous events interfering with the wind energy infrastructure. For the first time, a procedure is presented to assess such climate change impacts specifically for wind energy financing. At first, a generalised financing chain for wind energy is prepared to (qualitatively) trace the exposure of individual cost elements to physical climate change. In this regard, the revenue through wind power production is identified as the essential component within wind energy financing being exposed to changing climate conditions. This implies the wind resource to be of crucial interest for an assessment of climate change impacts on the financing of wind energy. Therefore, secondly, a novel high-resolution experimental modelling framework with the non-hydrostatic extension of the regional climate model REMO is set up to generate physically consistent climate and climate change information of the wind resource across wind turbine operating altitudes. With this setup, enhanced simulated intra-annual and inter-annual variability across the lower planetary boundary layer is achieved, being beneficial for wind energy applications, compared to state-of-the-art regional climate model configurations. In addition, surrogate climate change experiments with this setup disclose vertical wind speed changes in the lower planetary boundary layer to be indirectly affected by temperature changes through thermodynamically-induced atmospheric stability alterations. Moreover, air density changes are identified to occasionally exceed the net impact of wind energy density changes originating from changes in wind speed. This supports the consideration of air density information (in addition to wind speed) for wind energy yiel assumptions. Thirdly, the generated climate and climate change information of the wind resource are transferred to a simplified but fully-fledged financial model to assess the financial risk of wind energy project financing with respect to changing climate conditions. Sensitivity experiments for an imaginary offshore wind farm located in the German Bight reveal the long-term profitability of wind energy project financing not to be substantially affected by changing wind resource conditions, but incidents with insufficient servicing of financial obligations experience changes exceeding -10% to 14%. The integration of wind energy-specific climate and climate change information into existing financial risk assessment procedures would illustrate a valuable contribution to enable climate change adaptation for wind energy.
Smartphones make intensive use of precious metals and so called conflict minerals in order to reach their high performance in a compact size. In recent times, sustainability challenges related to production, use and disposal of smartphones are increasingly a topic of public debate. Thus, established industry actors and newly emerging firms are driven to engage in more sustainable practices, such as sustainable sourcing of materials, maintenance services or take-back schemes for discarded mobile phones. Many of these latter efforts can be related to the concept of a circular economy (CE). This thesis explores how CE-related value creation architectures (VCAs) in the smartphone industry contribute to slowing and closing resource loops in a CE. In order to analyze these new industry arrangements, transaction cost theory (TCT) is used as a guiding theory for a make-or-buy analysis. Combining TCT with the concept of a CE is a novel research approach that enables the empirical analysis of relationships between focal actors (e.g. manufacturers) and newly emerging loop operators (e.g. recycling firms) in the smartphone industry. Case studies of such VCAs are conducted with case companies drawn from the Innovation Network on Sustainable Smartphones (INaS) at Leuphana Universtity of Lüneburg and analyzed regarding their involved actors, partnerships, circular activities, motivation and perceived barriers. Evidence from the conducted case studies suggests that asset specificity for circular practices increases for higher order CE-loops such as maintenance or reuse, therefore long-term partnerships between focal actors and loop operators or vertical integration of CE practices are beneficial strategies to reach a sophisticated CE. Similarly, circular practices that go beyond recycling require a strong motivation, either through integration in the focal firm´s quality commitment or through business model recognition. It is further suggested that the circular design of products and services could reduce necessary transaction costs and thus overall costs of a circular economy. Four different integration strategies for circular economy practices have been derived from the conducted case studies. These are: 1) vertically integrated loops, 2) cooperative loop-networks, 3) outsourcing to loop operators and 4) independent loop operators. This work thus provides evidence that circular economy activities do not necessarily have to be managed by focal actors in the value chain. Rather, circular practices can also be put forward by specialized loop operators or even independent actors such as repair shops.
Despite warnings from scientists and from society starting in the 1970s, we have long overshot our planetary boundaries – eroding biodiversity, changing our landscapes, and polluting our soil and atmosphere. Yes, efforts to change the unsustainable trajectories of our Earth system have increased through, for example, the Millennium Goals, the Sustainable Development Goals, or the Aichi Targets, but to no avail. The interventions to increase sustainability are conflicting on local, national and global levels, and often prioritise quick-fixes and short-term solutions instead of tackling the root causes of the “sustainability gap”. We, hence, need to find “places to intervene in complex systems that bring about transformative change” (Meadows 1999) – a premise and concept that Donella Meadows calls “leverage points”. Based on her seminal work, a team from the Leuphana University has identified three “realms of leverage” in which changes may lead to system transformation (Abson et al. 2017). One of these realms is the reconnection of humans to nature. In this habilitation, I focus on this realm of leverage and aim to (1) enhance the understanding of the influence of landscape change on human-nature relations through empirical, place-based research and comparisons across landscapes in different countries and continents; (2) identify and clarify the new concepts of relational values and leverage points; and (3) highlight empirical evidence on leverage points to foster human-nature relations for sustainability transformation, building mainly on empirical work done in six landscapes in Transylvania, Romania and Lower Saxony, Germany, but also including case studies from Ethiopia and India, systematic literature reviews and conceptual pieces. This thesis showed that cultural landscapes are changing with astonishingly comparable trajectories toward unsustainable futures. Our earth’s current environmental and climate crisis will continue to erode the fundaments of sustainability, hence, re-connecting humans to nature is of outstanding significance for transformative change. Identifying leverage points and implementing an intervention to strengthen human–nature relations will be a great challenge in the coming years. One possible leverage point can be strengthening experiential and emotional dimensions, as they specifically shape the connections people have with cultural landscapes. Further, this thesis highlighted the importance of the interlinkages between shallow and deep leverage points. Our results show that structurally complex landscapes and structurally rich social relations mediated by nature are interlinked and strengthening one, may strengthen the other. Moreover, strengthening sense of place and a sense of agency may enable self- and re-organization of cultural landscapes by opening the possibility to renegotiate people’s values for values and the goals of the social-ecological system, which, in turn, may enhance the structural diversity of landscapes and small-scale agriculture. Our results presented in this thesis also lay the ground for the hypothesis that degrading landscapes might also degrade social relations, which, in turn, can lead to contrasts and conflicts between actors and social groups. Although much work is still necessary to foster transformative change, this thesis offers innovative approaches. This thesis created and popularised the “Leverage points perspective”, including “chains of leverage”, as well as producing novel insights on human-nature relations – such as the distinction of human-nature connectedness and relational values, classifying relational value groups and empirically assessing dimensions of human-nature connectedness and relational values concerning landscape change and landscape features. These novel contributions can have wide-ranging impacts on the scientific discussions and societal implementation of interventions for sustainability.
Leverage points to foster human-nature relations for sustainability transformation
Fostering socio-economic development throughout all Member States is a fundamental goal of the European Union. With one third of its budget, the EU tries to support regional development in lessdeveloped regions and improve the life of its citizens. To reach its goal, a shift can be observed from a single sided focus on factor mobility and thus transportation and other infrastructure facilities to a higher diversity in approaches, including culture, the arts and creativity. Here, creative industries and innovation are keywords within Structural Funds, the main instrument of EU regional policies. However, very little is known on how cultural operators in the form of artists, opera houses etc. contribute to regional development by implementing Structural Funds projects. The framework conditions set on EU level are very open, allowing the sector to contribute in their own way to socioeconomic development. To improve the understanding of how cultural operators access Structural Funds this dissertation was guided by the question: What kind of strategies do cultural operators use to access Structural Funds in Poland? Or on a more abstract level: What are the formal and informal norms within the application process for cultural operators, and in which way do they impact the application strategies of cultural operators in Poland? By working on those questions, this dissertation is providing an insight into how cultural operators on the ground approach Structural Funds. The case study on cultural operators in Poland serves as a concrete example and gives a clearer picture of access strategies, barriers and facilitators within this process. Because research is scarce on this subject, a choice for an in-depth case study analysis within one country was taken. With a theoretical framework of sociological Neo Institutionalism, especially a model developed by Victor Nee and Paul Ingram (1998), the research focusses on different levels of interaction and the role of formal and informal norms. The model was modified to support the analysis of actors’ strategies, and explain the application process of cultural operators. Here, the focus was on the micro level (cultural operators) and its interaction with the meso level (national). The model was enriched at the end of the research with elements of Bourdieu’s theory of practise, namely his concepts of fields and capital. Poland was selected as case study country due to its unique position as the biggest new Member State with its long cultural tradition at the heart of Europe and a very positive formal framework for cultural projects within Structural Funds. The focus was on the years 2004-2007 and thus covered mainly the first funding period for Poland. As empirical evidence, 27 expert interviews were carried out with cultural operators and their environment in Poland. They were analysed on a qualitative basis, using Atlas.ti, and co-occurrence network views. The author conducted all interviews within a period of two months, and most of the interviews were conducted in English. Important steps within the analysis were the emergence of a project idea, the ‘melting’ of this idea into a project application, different challenges linked to the application process and information gathering as a crucial factor within this process. In the end, the findings were validated by three EU experts from the Commission and the European Parliament. Conclusions: Findings show that the application strategy is driven by a set of formal and informal norms. Among them one can find elements linked to financing and co-financing, access and distribution of information and capacity building in the form of knowledge gathering and experience. The informal channels proved to be especially valuable. Further, the organisation resources have a significant impact when applying for Structural Funds. This is not limited to sufficient financial means but also related to existing networks and knowledge of whom to ask for information and support. Here, reference can be made e.g. to Bourdieu’s concept of capitals. Based on those findings, a typology of three different actors’ groups with different challenges and project profiles was developed. It can be shown that their positions and strategies are influenced, not only by formal rules and norms, but also to a high level, by informal norms and structures. As a result, projects were generally implemented by rather big and well-established organisations. Most of them focussed on the conservation of cultural heritage or the construction of new, ‘classical’ cultural infrastructure such as museums and opera houses. However, innovation and creativity are thought to grow especially in smaller, often younger and ‘different’ settings. As the EU is interested in those elements to find a region-tailored solution to socio-economic development needs, a nearly exclusive focus on rather traditional flagship projects implemented by well-established organisations appears insufficient: In other words, there is a discrepancy between proclaimed possibilities and attempts within political statements and Structural Funds rules on one side and the picture on the ground on the other side. Thus, if the fostering of socio-economic development through innovation and new approaches is to emerge, attempts need to be taken to increasingly support cultural operators with less favourable given capital. The thesis presented enhances knowledge within these processes and therefore contributes to the improvement of the situation. Because only if conditions are analysed and known, processes on national and EU level can change and alternatives be considered. As a conclusion for the micro level, a strong networking and gathering of know-how independently from formal structures seems the most promising short-term approach. From a long-term perspective, a formalisation of networks and stronger lobbying, especially on national level but also on EU level will be needed if framework conditions are to change in favour of a more diversified and flexible approach.
Tropical forests worldwide support high biodiversity and contribute to the sustenance of local people’s livelihoods. However, the conservation and sustainability of these forests are threatened by land-use changes and a rapidly increasing human population. This dissertation, therefore, aimed to characterize biodiversity patterns in the moist Afromontane forests of southwestern Ethiopia and to examine how biodiversity patterns are affected by land-use and land-use changes (mediated by coffee management intensity, landscape attributes and housing development) in a context of a rapidly growing rural population. To achieve this goal, the author takes an interdisciplinary approach where, first, she examined the effects of coffee management intensity on diversity patterns of woody plants and birds, spanning a gradient of site-level disturbance from nearly undisturbed forest interior to highly managed shade coffee forests. Results showed that specialized species of woody plants (forest specialists) and birds (forest specialists, insectivores and frugivores) were affected by coffee management intensity. The richness of forest specialist trees and the richness and/or abundance of insectivores, frugivores and forest specialist birds decrease with increasing levels of disturbance. Second, the author investigated the effects of landscape context on woody plants, birds and mammals. Community composition and specialist species of woody plants and birds were sensitive to landscape context, where woody plants responded positively to gradients of edge-interior and birds to gradients of edge-interior and forest cover. Further results showed that a diverse mammal community, with 26 species, occurs at the forest edge of shade coffee forests and that the leopard, an apex predator in the region depended on large areas of natural forest. A closer examination of leopard activity patterns revealed a shift in the diel activity as a response to human disturbance inside the forest, further highlighting the importance of natural undisturbed forests for leopards in the region. Together, these findings demonstrate the value of low managed shade coffee forests for biodiversity, and importantly, emphasize the irreplaceable value of undisturbed natural forests for biodiversity. Third, the researcher investigated the effects of prospective rural population growth (mediated by housing development) on the forest mammal community. Here, population growth was projected to negatively influence several mammal species, including the leopard. Housing development that encroached the forest entailed worse outcomes for biodiversity than a combination of prioritized development in already developed areas and coffee forest protection. Fourth, to understand the motivations behind high human fertility rates in the region, she examined the determinants of women fertility preferences, including their perceptions on social and biophysical stressors affecting local livelihoods such as food insecurity and environmental degradation. Fertility preferences were influenced by underlying social norms and mindsets, a perceived utilitarian value of children and male dominance within the household, and were only marginally affected by perceptions of social and biophysical stressors. The findings suggest the need for new deliberative and culturally sensitive approaches that engage with pervasive social norms to slow down population growth. Overall, this dissertation demonstrates the key value of moist Afromontane forests in southwestern Ethiopia for biodiversity conservation. It indicates the need to promote coffee management practices that reduce forest degradation and highlights that high priority should be given to the conservation of undisturbed natural forests. It also suggests the need to integrate conservation goals with housing development in landscape planning. A promising approach to achieve the above conservation priorities would be the creation of a Biosphere Reserve and to promote the ecological connectivity between the larger forest remnants in the region. Finally, this dissertation demonstrates the importance of placed-based holistic approaches in conservation that consider both proximate and distal drivers of forest biodiversity decline.
Transformative learning is increasingly set to become an essential component in sustainability transformation. Despite, little has been done to systematically explore the contribution to sustainability transformation. This learning theory developed decades ago independently of sustainability discourses; however, it provides an analytical framework for understanding the learning processes, outcomes and conditions in individual and social learning towards sustainability transformation. Against this background, the following research question arises: To which extent can transformative learning lead to sustainability transformation? This doctoral work aims to explore transformative learning processes, outcomes, and conditions occurring and advancing towards sustainability transformation of the textile-fashion industry in Mexico. Taking an exploratory approach, the methods employed were literature reviews to untangle concepts and to construct theoretical pillars to support the empirical research design and data analysis. For data collection, snowball-sampling techniques were used to explore the practice field of the textile-fashion industry in Mexico. Qualitative interviews were employed to gather data about the learning experiences of actors. Qualitative and quantitative methods were required to perform the respective data analysis, the qualitative codification of interviewees' responses. Analysis of social media content was also utilised to understand the communication and business practices of projects involved in the transformation of the textile-fashion sector. As a result, this work comprises three articles, one a systematic literature review and two empirical research articles, investigating the transformative learning processes of entrepreneurs in the development of sustainability niches. As for the findings of this doctoral work, the use of transformative learning in sustainability transformation requires a careful study of the theory and its conceptual elements. Regarding the case study, transformative learning is inherent in forming and developing sustainability niches as entrepreneurs venture into them: It is individual prior learning, expectations and actions that initiate the path of sustainability transformation while disorienting dilemmas, critical reflection, and discourse accelerate them. Through these stages, it is when individual learning turns into social learning. On the other hand, based on the multi-level perspective, the interplay between the niche, regime and landscape levels generates a space for sustainability transformation and transformative learning.
Wood-pastures have been present in Europe for thousands of years. This form of grazed landscape, combining herbaceous vegetation with trees and shrubs, has often co-evolved with its human users into complex social-ecological systems (SES). Wood-pastures are associated with high cultural and biodiversity values and are an example of the sustainable use of resources. However, due to their often relatively labour-intensive management and low productivity, large areas of wood-pastures have been lost over the last century. The loss of these areas means not only the loss of biodiversity on both local and landscape scales, but also the loss of traditional farming and cultural heritage in some regions. Across the European Union, wood-pastures are facing different problems and are embedded in different social systems and ecological environments. Yet they are all affected by global change and common European policies. To understand the challenges for wood-pastures in a changing world, a holistic approach combining different disciplines is needed. This dissertation therefore is analyzing wood-pastures across Europe as a Social-ecological System, combining ecology and social science with the aim to identify the barriers and drivers for wood-pastures persistence into the future.
Human activities have become a major driver of global change, so that global society and economy are facing consequences such as climate change, increasing scarcity of resources, environmental pollution and degradation as well as disturbances of ecosystem functioning and services.In order to meet these main challenges in an appropriate way, adequate starting points and solutions must be pursued at all levels to shift the current socio-economic pathway from an unsustainable to a safe operating and thus sustainable development within the planetary boundaries. One of the application concepts in industrial contexts is Industrial Symbiosis (IS), which deals with the set-up of advanced circular/cascading systems, in which the energy and material flows are prolonged for multiple material and energetic (re-)utilization within industrial systems in order to increase resource productivity and efficiency, while reducing environmental impacts. The overarching goal of the research project was to identify and develop approaches to enable the evolution of Industrial Symbiosis (IS) in Industrial Parks (IPs). IS is a collaborative cross-sectoral approach to connect the resource supply and demand of various industries in order to optimize the resource use through exchange of materials, energy, water and human resources across different companies, while generating ecological, technical, social and economic benefits. Many Information Communication Technology (ICT) tools have been developed to facilitate IS, but they predominantly focus on the as-is analysis of the IS system, and do not consider the development of a common desired target vision or corresponding possible future scenarios as well as conceivable transformation paths from the actual to the defined (sustainability) target state. This gap shall be addressed in this work, presenting the software requirements engineering results for a holistic IT-supported IS tool covering system analysis, transformation simulation and goal-setting. This study also aims to present the conceptual IT-supported IS tool and its corresponding prototype, developed for the identification of IS opportunities in IPs. This IS tool serves as an IS facilitating platform, providing transparency among market players and proposing potential cooperation partners according to selectable criteria (e.g. geographical radius, material properties, material quality, purchase quantity, delivery period). Therefore a quantitative indicator system was compiled and recurring patterns were identified to utilize this knowledge in the comprehensive IT-supported IS tool. So this IS tool builds the technology-enabled environment for the processes of first screening of IS possibilities and initiation for further complex business-driven negotiations and agreements for long-term IS business relationships.
Determinants of Emotional Experiences in Traffic Situations and Their Impact on Driving Behaviour
(2013)
Emotions play a prominent role in explaining maladaptive driving and resulting motor vehicle accidents (MVAs). Above all, traffic psychologists have focussed their attention on anger and anxiety, including the origins and influence of these emotions on driving behaviours. This dissertation contributes to the field with three manuscripts that build upon each other. Those manuscripts have three separate objectives. The first identifies the broad range of emotions in traffic that should be analysed. Second, the impact of specific emotions on driving behaviour is focussed. Finally, the research investigates how situational and personal factors can influence emotional experiences and influence driving behaviour. The first article tackles the bandwidth of emotions in traffic. In two consecutive online studies (study one: = 100; study two: n = 187), different emotional experiences were assessed using the Geneva Emotion Wheel (and an advanced version). The stimulus material consisted of written traffic situations structured around specific factors (in these studies, predominantly goal congruence, goal relevance and blame). It could be shown that the properties of the situation can elicit emotions such as anger, anxiety and happiness, but also pride, guilt and shame. The second article saw a transfer of those situational factor structures from online-presented text to simulated driving. At this time, the focus of interest was the driving behaviour influenced by the elicited emotions. The simulator study (n = 79) revealed that anger, contempt and anxiety led to similar declines in driving performance profiles. Performance declines included driving at higher speeds, more frequent speeding and worse lateral control. The third article examined to what extent anger and personal characteristics could negatively influence driving behaviour. Two studies were conducted (study one: n = 74; study two; n = 80). The results indicated that specific characteristics of the person (male, little driving experience, high driving motivation, high trait-driving anger) could influence driving behaviour in negative ways, both directly and indirectly, via triggered anger emotions. It can be concluded from these results that the range of emotions in traffic encompasses much more than just anger and anxiety. Furthermore, the second and third articles show that within simulated environments, minimal but effective emotional intensities can be triggered, and those emotions (especially anger and anxiety) create similar performance patterns. Personal characteristics should be considered when explaining the elicitations of emotion and subsequent driving behaviour. The papers of this dissertation echo the call for new comprehensive models to explain the relationships among emotions and traffic behaviours.