333.7 Natürliche Ressourcen, Energie und Umwelt
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Fire plays an important role in the earth system by influencing ecosystems and climate, but climate in turn also influences fire. The system became more complex when humans started using fire as a tool. Understanding the interaction between humans, fire and climate is the major aim of paleofire research. Understanding changes in these three aspects in the past will help predicting future climate, fire and human interactions. The use of lake sediment cores as natural archives for reconstructing past fire activity by counting charcoal particles is well established. This present dissertation is dedicated to the evaluation and application of specific organic molecular markers for biomass burning: levoglucosan, mannosan and galactosan were used as proxies for reconstructing past fire activity in lake sediments thorough the entire Holocene. First, a new analytical method was developed using high-performance anion exchange chromatography combined with mass spectrometry to separate and detect these three monosaccharide anhydrides in lake sediments. The suitability of this analytical method was proven by comparing the levoglucosan, mannosan and galactosan results in selected lake sediment samples from Lake Kirkpatrick, New Zealand and by correlating the results with macroscopic charcoal. Furthermore, the method was successfully applied to a lake sediment core from Lake Petén Itzá, Guatemala to reconstruct regional Holocene fire history. The analyses of levoglucosan were combined with fecal sterols to reconstruct late Holocene human fire interactions at Lake Trasimeno, Italy, demonstrating low fire activity during the Roman period. This combination of studies proves that these molecular markers are valid fire proxies in sediments from multiple locations around the globe. Comparison of levoglucosan, mannosan and galactosan concentrations with macroscopic charcoal trends in Lake Kirkpatrick and Lake Petén Itzá, suggests that the molecular markers represent more regional fire history and low temperature fires in contrast to macroscopic charcoal, which is a local fire proxy. In addition, vegetation changes (Lake Kirkpatrick and Lake Petén Itzá) and charcoal morphotypes (Lake Petén Itzá) were compared to the levoglucosan/mannosan and levoglucosan/(mannosan+galactosan) ratios suggesting that these ratios may be a suitable tool to track burned fuel. Biodegradation tests demonstrate the potential degradation of levoglucosan, mannosan and galactosan if dissolved in water, but findings in ancient sediment samples suggest that particle-bound levoglucosan, mannosan and galactosan can be buried in sediments over millennial time scales. Although uncertainties still exist, the results of this research suggests that organic molecular markers are a suitable regional fire proxy and isomer ratios may help understand changes in burned vegetation.
The importance of a social perspective on the relationships between humans and nature has longbeen acknowledged. The field of social-ecological systems research in particular is striving toachieve a holistic understanding of human-nature relationships by balancing social andecological perspectives. Here I sought to develop a social understanding of the Saxon area inCentral Romania, by exploring aspects of human-nature relationships as seen from theperspective of local people. To this end, I employed the concepts of social-ecological systems(SES), ecosystem services (ES) and cultural landscapes to assess perceptions of locals throughempirical case studies.I first conducted a literature review to acquire an overview of a particular type of human-naturerelationship mediated by non-consumptive use and non-use values (“cultural ecosystemservices”). Second, to isolate and address the interaction from the social system to the ecologicalsystem, I investigated the different ways locals perceived the role of landscapes in SouthernTransylvania. I conceptually mapped these landscape preferences by revealing their potentialland use and management implications. Third, to approach the human-nature relationship fromthe ecological system to the social system, I studied the flow of ES to disaggregated humanbeneficiaries. Specifically, I studied which factors, beyond ecosystem processes and functions,influenced nature derived human well-being from the perspective of potential beneficiaries. Iconceptualised the mediating role of a range of contextual factors underpinning the currentdistribution of ES, with regard to the relation between ES and human well-being. Fourth, inorder to explore an example of bidirectional human-nature relationship, I studied the particularcase of human-carnivore coexistence and the suite of mechanisms shaping it.Despite building throughout this thesis a more complex and in-depth understanding of the humandimensions of the studied system, I chose four main cross-cutting themes to explain the human-nature connection in Southern Transylvania. These four themes may serve as pillars of a sociallyminded understanding, as well as potential research and policy foci. First, the values held bylocals are key for understanding the endemic human-nature relationships and should not beoverlooked in future social-ecological assessments or policy interventions. Second, the culturallandscape of Southern Transylvania is both a physical and virtual space of social-ecologicalinteraction fostering human-nature experiences and social-ecological knowledge integration.Third, the identified diversity of the social system in terms of landscape aspirations and ESbeneficiaries is expanding the range of human-nature connections, but at the same time, may infuture be a source of conflict or disconnection if not managed appropriately. Finally, small-scalefarmers, through their interactions with the land and resultant belief system, play a major role inmaintaining the human-nature relationships, but their values and lifestyle are threatened.
This PhD thesis examines the connections between sustainability knowledge management (SKM) and sustainability management tools in small and medium-sized enterprises (SMEs). While previous literature has established that knowledge is essential for the application of sustainability management tools, the effects of such tools on knowledge management are under-researched in the sustainability context. Drawing on multiple academic papers and utilizing various research methods, including a systematic literature review, several quantitative surveys and a multiple case study approach, the thesis systematically examines how such tools can facilitate the identification, acquisition, conversion, application and retention of sustainability knowledge, and potentially lead to the improvement of SKM effectiveness in SMEs. Furthermore, it examines how support functions for sustainability management tools and SKM correspond with each other. The findings reveal that sustainability management tools facilitate the SKM processes (identification, acquisition, conversion, application and retention), and align with the support factors (e.g. top management support, shared vision, employee qualifications) to advance SKM in SMEs. Particularly, such tools permit the institutionalization of sustainability knowledge into the daily routines and practices in SMEs. Additionally, tools create a support structure for SKM, embedding and preserving sustainability knowledge in documents, policies, procedures and norms for an enterprise´s collective knowledge for sustainability management. The thesis concludes with complementing areas of future research and offers practical implications for SME management.
Ökologische Nachhaltigkeit in Beherbergungsbetrieben in regionalen Naturparks in der Deutschschweiz
(2014)
In der vorliegenden Arbeit wurde ein ICP-QMS mit integrierter Reaktions- /Kollisionszelle erfolgreich eingesetzt, um die Elemente Vanadium, Chrom, Mangan, Eisen, Nickel, Kobalt, Kupfer, Zink, Arsen, Molybdän, Cadmium, Blei und Uran direkt in verdünntem Meerwasser zu bestimmen. Die Bestimmung von Elementspuren in Meerwasser wurde realisiert, indem alle zur Verfügung stehenden Möglichkeiten zur Minimierung von Interferenzen bei der Bestimmung von Elementen mit ICP-QMS angewendet wurden.