Refine
Year of publication
- 2020 (34) (remove)
Document Type
- Doctoral Thesis (34) (remove)
Keywords
- Transformation (2)
- Aesthetics (1)
- Antriebstechnik (1)
- Contemporary Literature (1)
- Discourse Studies (1)
- Elektromobilität (1)
- Energiepolitik (1)
- Energy Policy (1)
- Erzähltechnik (1)
- Gegenwartsliteratur (1)
Institute
- Fakultät Nachhaltigkeit (11)
- Fakultät Wirtschaftswissenschaften (10)
- Fakultät Bildung (9)
- Institut für Management und Organisation (IMO) (4)
- Fakultät Kulturwissenschaften (3)
- Institut für Bildungswissenschaft (IBIWI) (2)
- Institut für Nachhaltige Chemie und Umweltchemie (INUC) (2)
- Institut für Nachhaltigkeitssteuerung (INSUGO) (2)
- Institut für Politikwissenschaft (IPW) (2)
- Institut für Psychologie (IFP) (2)
To improve the properties of thermochemical heat storage materials, salt mixtures were evaluated for their heat storage capacity and cycle stability as part of the innovation incubator project "Thermochemical battery" of the Leuphana university Lüneburg. Based on naturally occurring compound minerals, 16 sulfates, 18 chlorides and 5 chloride multi-mixtures, 18 bromides and 5 intermixtures between sulfates, chlorides and bromides were synthesized either from liquid solution or by dry mixing for TGA/DSC screening before continuing the heat storage evaluation with five different measurement setups at a laboratory scale. The TGA/DSC analysis served as a screening process to reduce the number of testing materials for the upscaled experiments. The evaluation process consisted of a three-cycle dehydration/hydration measurement at Tmax=100°C and Tmax=200°C. In case of the bromide samples a measurement of hydration conditions with Tmax=110°C and a water flow at e=18.68mbar, were added to the procedure to detect the maximum water uptake temperature. Also, a single dehydration to a temperature of Tmax=500°C was implemented to observe melting behavior and to easier calculate the samples’ stages of hydration from the remaining anhydrous mass. Materials which showed high energy storage density and improved cycle stability during this first evaluation were cleared for multi-cycle measurements of 10 to 25 dehydration and hydration cycles at Tmax = 100 to 120°C and the evaluations at m=20 to 100g scale. An estimate for the specific heat capacities at different temperatures of the materials which passed the initial stage was calculated from the TGA/DSC results as well. The laboratory scale measurement setup went through five stages of refining, which led to reducing the intended maximum sample mass from m=100g to m=20g. A switch from supplied liquid water to water vapor as the used reactant was also implemented in exchange for improved dehydration conditions. Introducing a vacuum pump for evaporating the water limited the influence of outside heat sources during hydration and in-situ dehydration was enabled as to not disturb the state the samples were settling in between measurements. Baseline calculation from blanc measurements with glass powder and attempts to calculate the specific heat capacity cp of the tested materials by 6 applying the Joule-Lenz-law to the measurement apparatus was another step of method development. The evaluation process of the laboratory scale tests at the final setting consisted of 1 to 5 cycle measurements of in-situ dehydration and hydrations with applied vacuum for t=30 minutes at p~30mbar. Upscaling the sample mass to m=20g allowed for a close observation of different material behaviors. Agglomeration, melting and dissolving of the m=10mg samples during the TGA/DSC analysis can be deducted from the recorded measurement curves and the state of the sample after measurement. However, at laboratory scale the visible volume changes, observed sample consistency after agglomeration and an automatic removal of molten and dissolved sample mass during the measurement allowed for a better characterization and understanding of the magnitude of the actual changes. This was done for the first time, particularly for mixed salts. Of the original number of 62 samples, 4 mixtures which passed the initial TGA/DSC screening namely {2MgCl2+ KCl}, {2MgCl2+CaCl2}, {5SrBr2+8CaCl2} and {2ZnCl2 + CaCl2} were chosen for further evaluation. The multi-cycle TGA/DSC measurements of {2MgCl2+ KCl}, {2MgCl2+CaCl2} and {5SrBr2+8CaCl2} showed an improved cycle stability for all three materials over the untreated educts. Of the four materials {2ZnCl2 + CaCl2} displayed the strongest deliquescence during hydration in the upscaled experimental setup. {2MgCl2+CaCl2} proved to be the most stable material regarding the heat storage density. The {MgCl2} content of the mixture is likely to partially or completely react to {Mg(OH)Cl} at temperatures of T>110°C, which however does not impede the heat storage density. {5SrBr2+8CaCl2} displayed a low melting point in hydrated state, causing a fast material loss. This makes it an undesirable storage material. A lower heating rate may still help to avoid an early melting. The {2MgCl2+KCl} mixture was the most temperature stable of the mixtures showing no melting or dissolving behavior. A reaction of the {MgCl2} component of the mixture to {Mg(OH)Cl} was not observed within the applied temperature range of T=25 to 200°C.
Panic disorder is a common anxiety disorder, which is associated with high subjective burden as well as a high cost for the health economy. According to the National Treatment Guideline S3, cognitive behavior therapy is recommended as the most effective psychological treatment. However, many people in need do not have access to cognitive behavior therapy. Internet-based interventions have proven to be an effective way to provide access to evidence-based treatment to those affected. For anxiety disorders, such as panic disorder and agoraphobia, a good effectiveness of internet-based interventions has been proven in numerous international studies. However, the internet has changed over the last few years: mobile technologies have considerable potential to further improve the adherence and effectiveness of internet-based interventions. Against this background, the authors developed the hybrid online training "GET.ON Panic". In this training, an app has been integrated into a browser-based online training. The app consists of a mobile diary for self-monitoring as well as a mobile exposure-guide that supports participants in self-exposure exercises in their everyday lives.In an initial exploratory feasibility study, qualitative interview data and quantitative measurements were collected in a pre-post design of 10 participants. Usage, user friendliness, user satisfaction and acceptance of the app were generally considered high. The use of interoceptive exposure exercises and daily summaries of anxiety and mood were the most widely performed and rated the best, while in vivo exposure exercises and the monitoring of acute panic symptoms were found to be difficult.In the efficacy study, 92 participants with mild to moderate panic symptoms were randomized into two parallel groups. After eight weeks, the intervention group showed a significant improvement in the severity of panic symptoms compared to the waiting control group. Using the intention-to-treat approach, a covariance analysis with baseline values as a covariate yielded a mean effect of Cohen's d=0.66 in reducing the panic symptoms in favor of the intervention group. This effect increased to d=0.89 after three months and stayed at d=0.81 at the 6-month measurement point. Response and remission rates were also significantly higher in the intervention group. This positive effect was also shown for secondary outcomes such as depressive symptoms and quality of life. A correlation between app usage and clinical outcomes could not be found. This work was the first to demonstrate that a hybrid online training based on cognitive behavior therapy is effective in reducing panic symptoms as well as panic disorder. In addition, this work contributes to a deeper understanding of the potential of mobile technologies in the field of e-mental health.
Um das noch bestehende Reichweitenproblem von Elektrofahrzeugen zu lösen, sind Fahrzeugkonzepte wie Plug-in Hybridfahrzeuge sehr vielversprechend, sofern mit ihm überwiegend im Batteriebetrieb gefahren wird. Sie kombinieren die Vorteile des Verbrennungsmotors und des Elektromotors, sodass das lokale Emissionsproblem in Ballungszentren gelöst werden kann, ohne dass der Kunde dabei auf die Reichweite verzichten muss. Wenn das Fahrzeug allerdings überwiegend für Kurzstrecken genutzt wird, sind alterungsbedingte Veränderungen des Kraftstoffes möglich, da dieser länger im Tank verbleibt als üblich. In dieser Arbeit wird ein Konzept zur sensorischen Bestimmung der Qualität des Kraftstoffes vorgestellt. Hierzu wurde ein Prototyp entwickelt, in dem mithilfe des Real- und Imaginärteils der Permittivität alternde Kraftstoffe erkannt werden können. Dabei konnte durch das frequenzabhängige Permittivitätssignal des Sensors spezifisch zwischen nieder- und hochmolekularen Oxidationsprodukten in Kraftstoffen unterschieden werden. Da das Verbrennungs- und Emissionsverhalten des Motors von der Kraftstoffmischung vorgegeben ist, bietet eine zusätzliche sensorische Erfassung der Kraftstoffzusammensetzung weitere Optimierungspotenziale, um Emissionen zu reduzieren: So ist das Motormanagement im Fahrzeug zumeist auf Referenzkraftstoffe mit gleichbleibender Qualität abgestimmt. Variable Kraftstoffzusammensetzungen, die durch die Erdöllagerstätte und den zusätzlichen Konversionsverfahren zur Herstellung von fortschrittlichen Kraftstoffen vorgegeben sind, werden in dieser Anpassungsstrategie bisher nicht berücksichtigt. Als weitere Aufgabe wird in dieser Arbeit daher ein multisensorischer Ansatz verfolgt, wonach zusätzlich zur Kraftstoffalterung noch die Kraftstoffzusammensetzung erkannt werden kann. Insgesamt bietet die Sensorik das Potenzial zur kontinuierlichen Kraftstoffüberwachung in Plug-in Hybridfahrzeugen, um so einen Beitrag zum sicheren und nachhaltigen Betrieb solcher Fahrzeuge gewährleisten zu können.
Sustainable landscape development is the main goal of decision makers worldwide. Achieving this goal in the long term leads to achieving social, economic and environmental sustainability. Remote sensing has been playing an essential role in monitoring remote areas. This study has employed part of the role of remote sensing in supporting the direction of decision makers towards sustainable landscape development. The study has focused on some of the main elements affecting sustainable environment: land uses, specifically agricultural land uses, water quality, forests, and water hazards such as floods. Three research programs were undertaken to investigate the role of Terrasar-x imagery, as a source of remote sensing data, in monitoring the environment and achieving the previous stated elements. The investigation was intended to investigate the effectiveness of TSX imagery in identifying the cropping pattern of selected study areas by employing a pixel-based supervised maximum likelihood classifier, as published in Paper I, assessment of the efficiency of using TSX imagery in determining land use and the flood risk maps by applying an object-based decision tree classifier as published in Paper II, and determination of the potential of inferential statistics tests such as the two samples Z-test and multivariate analysis, for example Factor Analysis, for identifying the kind of forest canopy, based on the backscattering coefficient of TSX imagery of forest plots, as presented in Paper III. Papers I and II covered two pilot areas in the Lower Saxonian Elbe Valley Biosphere Reserve “das Biosphärenreservat "Niedersächsische Elbtalaue" around Walmsburger Werder and Wehninger Werder. Paper III focused on the Fuhrberger Feld water protection area near Hanover in Germany. The inputs for this research were mainly SAR Imagery and the ground truth data collected from field surveys, in addition to databases, geo-databases and maps. The study presented in Paper I used two filters to decrease speckle noise namely De-Grandi as multi-temporal speckle filter, and Lee as an adaptive filter. A multi-temporal classification method was used to identify the different crops using a pixel-based maximum likelihood classifier. The classification accuracy was assessed based on the external user accuracy for each crop, the external producer accuracy for each crop, the Kappa index and the external total accuracy for the entire classification. Three cropping pattern maps were produced namely the cropping pattern map of Wehninger Werder in 2011 and the cropping pattern maps of Walmsburger Werder in 2010 and in 2011. The study showed that image filtering was essential for enhancing the accuracy of crop classification. The multi-temporal filter De-Grandi enhanced the producer accuracy by about 10% compared to the Lee filter. Furthermore, gathering and utilizing large ground truth data greatly enhanced the accuracy of the classification. The research verified that using sequence images covering the growing season usually improved the classification results. The results exposed the effect of the polarization and demonstrate that the majority of the classifications produced according to the crop calendar had higher total producer accuracy than using all acquisitions. The study demonstrated undertaken in Paper II applied the decision tree object-based classifier in determining the major land uses and the inundation extent areas in 2011 and 2013 using the Lee-filtered imagery. Based on the maps produced for the land uses and inundation areas, the hazard areas due to the floods in 2011 and 2013 were identified. The study illustrated that 95% of the inundated area was classified correctly, that 90% of vegetated lands were accurately determined, and around 80% of the forest and the residential areas were correctly recognized. The research undertaken in Paper III statistically analyzed the backscattering coefficient of the Lee-filtered TSX in some forest plots by the Factor Analysis and two sample Z-test. The study showed that Factor analysis tools succeeded in differentiating between the coniferous forest and the deciduous forest and mixed forest, but failed to discriminate between the deciduous and the mixed forest. On one hand, only one factor was extracted for each sample plot of the coniferous forest with approximately equal loadings during the whole acquisition period from March 2008 to January 2009. On the other hand, two factors were extracted for each deciduous or mixed forest sample plot, where one factor had high loadings during the leaf-on period from May to October, and the other one had high loadings during the leaf-off period from November to April. Furthermore, the research revealed that the two sample Z-test enabled not only differentiation between the deciduous and the mixed forest against the coniferous forest, but also discrimination between deciduous forest and the mixed forest. Statistically significant differences were observed between the mean backscatter values of the HH-polarized acquisitions for the deciduous forest and the mixed forest during the leaf-off period, but no statistically significant difference was found during the leaf-on period. Moreover, plot samples for the deciduous forest had slightly higher mean backscattering coefficients than those for the mixed forest during the leaf-off period.
It is understood among research and policy makers that addressing unsustainable individual consumption patterns is key for the vision of sustainable development. Education for Sustainable Consumption (ESC) is attributed a pivotal role for this purpose, aiming to improve the capacity of individuals to connect to and act upon knowledge, values and skills in order to respond successfully and purposefully to the demands of sustainable consumption. Yet despite political, scientific, and educational efforts and increasing awareness in the general population, little has been achieved to substantially change behavioral patterns so far. As part of the explanation for this shortcoming, it has been argued that current ESC practices have neglected the personal dimension of sustainable consumption, especially the affective-motivational processes underlying unsustainable consumption patterns. Against this background, this cumulative thesis is guided by the question how personal competencies for sustainable consumption can be defined, observed, and developed within educational settings. Special attention is given to mindfulness practices, describing the practice of cultivating a deliberate, unbiased and openhearted awareness of perceptible experience in the present moment. Drawing upon an explorative, qualitative research methodology, the thesis looks at three different mindfulness-based interventions aiming to stimulate competencies for sustainable consumption, reaching out to a total number of 321 participants (employees and university students). In this thesis, the author suggests to define personal competencies for sustainable consumption as abilities, proficiencies, or skills related to inner states and processes that can be considered necessary or sufficient to engage with sustainable consumption (SC). These include ethics, self-awareness, emotional resilience, selfcare, access to and cultivation of personal resources, access to and cultivation of ethical qualities, and mindsets for sustainability. The thesis holds that the observation of personal competencies benefits from a combination of different methodological and methodical angles. When working with self-reports as empirical data, a pluralistic qualitative methods approach can help overcoming shortcomings that are specifically related to individual methods while increasing the self-reflexivity of the research. Moreover, it is suggested to let learners analyze their own personal statements in groups, applying scientific methods. The products of the group analyses represent data based on an inter-subjectively shared perspective of learners that goes beyond self-estimation of personal competencies. In terms of developing personal competencies for SC, it can be concluded that mindfulness practice alone is not sufficient to build personal competencies for SC. While it can stimulate generic personal competencies, individuals do not necessarily apply these competencies within the domain of their consumption. Nevertheless, mindfulness practice can play an important role in ESC, insofar as it lays the inner foundation to engage with sustainability-related issues. More precisely, it allows learners to experience the relevance of their inner states and processes and the influence they have on actual behaviors, leading to a level of selfawareness that would not be accessible solely through discursive-intellectual means. Furthermore, participants experience mindfulness practice as a way to develop ethical qualities and access psychological resources, entailing stronger emotional resilience and improved well-being. In order to unleash its full potential for stimulating personal competencies for SC, however, the findings of the thesis suggest that mindfulness practice should be (a) complemented with methodically controlled self-inquiry and (b) related to a specific behavioral change. In this vein, self-inquiry-based and self-experience-based learning – two pedagogical approaches developed during the period of research for this thesis – turned out to be promising pedagogies for educational settings striving to stimulate the development of personal competencies for SC.
The dissertation contains four journal articles which are embedded within a framework manuscript that interconnects the individual articles and provides relevant background information. The dissertation's overall objective is to provide a multilayered and critical in-depth engagement with the timely phenomenon of integrated reporting (IR), a new reporting concept that is envisaged to revolutionize firms' present reporting infrastructure. While extant corporate reports (e.g., annual financial- and CSR report) often are criticized for being disconnected and to suffer from a lack of coherence, IR intends to provide all information that is material to a firm's short-, medium- und long-term value creation within one single, succinct document. To contribute to a set of previously defined relevant research gaps in literature, the dissertation makes use of a combined empirical-quantitative and explorative-qualitative research design. The first article entitled investigates a set of different IR-, corporate governance and financial accounting-specific factors that are expected to determine European and South African firms' materiality disclosure quality. To this purpose, an original, hand-collected materiality disclosure score was developed. The second article explores IR perceptions of SME managers that have not embarked on IR, but are potential candidates to do so in future. Based on a review of extant literature, the article develops a theoretical framework to subsequently discuss motives for and barriers to IR adoption. The critical discussion contributes to the academic debate on incentives for and barriers to voluntary IR adoption. The third article investigates whether voluntary IR adoption among European firms is associated with lower cost of public debt. While earlier studies suggest that IR leads to lower information asymmetries, increases analyst forecasts, and decreases cost of equity, corresponding evidence for the debt market is largely missing. Subsequent analyses test as to whether such an association is even more pronounced by a firm's environmental, social and governance (ESG) performance or its belonging to an environmentally sensitive industry. The fourth article uses an experimental design to investigate nonprofessional investors' reactions to an IR assurance. To this purpose, two separate experiments with two different groups of nonprofessional investors were carried out: one with Masters students and one with managers of large corporations. Results help to answer the question as to whether an IR assurance as well as its determinants, namely the assurance provider and the assurance level, affect nonprofessional investors' financial decision-making. In the second step, subsequent in-depth interviews reveal an IR assurance-critical attitude among managers, who draw upon their practical experience with assurance engagements.
In this dissertation, advanced nonlinear control strategies and nonlinear minimum-variance observation are combined, in order to improve the estimation and/or tracking quality within control and fault detection tasks, for several types of systems from the fields of electromobility and conventional drivetrain technology that have some potential for sustainability or performance improvements. The application-specific innovations in terms of nonlinear Kalman filter methods are: (1) Improved state of charge estimation for Lithium-ion battery cells, powered by a novel self-adaptive EKF that uses a high-order polynomial curve fit as a decomposition of the uncertain nonlinear output equation with intentionally redundant bases, and with a reduced number of polynomial parameters that are adapted online by the EKF itself. (2) Online estimation of the time delay between two periodic signals of roughly the same shape that have pronounced uncorrelated noise, based on a fractional-order approximation of the transcendent transfer function of the time delay which is used as a model in a novel kind of EKF. (3) Using two (E)KFs (one for the linear subsystem and one for the nonlinear subsystem of a new kind of multi-stage piezo-hydraulic actuator) in a cascaded loop structure in order to reduce the computation load of the estimation, by appropriate 'interfacing' between the two observers (using one shared system model equation, among other aspects). - The innovations in terms of nonlinear control methods are powered by observation, as well: (1) Sliding mode velocity control of a DC drive that is subject to nonlinear friction and unknown load torques, enhanced by an equivalent control law, and with a new intelligent switching gain adaptation scheme (for reduced control chattering and, thus, less energy consumption and actuator wear), which is powered by Taylor-linearized model predictive control, which in turn requires observer-based disturbance compensation (by a KF with a double-integrator disturbance model) for model-matching purposes in order to function correctly. (2) Direct speed control of permanent-magnet three-phase synchronous motors that have a high power-to-volume ratio, based on sliding mode control in a rotating d,q coordinate system, with a new equivalent control method that exploits both system inputs and with a secondary sliding surface to ensure compliance with the current-trajectory of maximum efficiency for the required torque, and which works without measurement of the rotor angle (thanks to a new kind of EKF that estimates all states in the stationary α,β coordinate system, as well as the disturbance/load torque and its derivative). In all instances, improvements (compared to methods existing in the literature) in terms of control and estimation performance have been achieved and confirmed using simulation studies or real experiments.
Die Energiewende steht im Zentrum aktueller gesellschaftlicher Debatten. Die Frage ist: Wie kann die gegenwärtige Klimakrise aufgehalten und gleichzeitig der Energiebedarf gedeckt werden? Einigkeit besteht darüber, dass eine Strategie zur Energiewende die Umstellung auf erneuerbare Energieträger beinhalten muss. Das Problem ist: Zentrale Begriffe wie "erneuerbare Energieträger " sind uneindeutig und deshalb besonders für naturwissenschaftliche Laien missverständlich. Ihnen wird dadurch die gesellschaftliche Teilhabe an der Debatte erschwert. Wie kann der naturwissenschaftliche Unterricht dazu beitragen, die oben benannten Missverständnisse aufzuklären? Er muss die Schüler dabei unterstützen, die naturwissenschaftlichen Schlüsselprinzipien der verschiedenen Energieträger und darauf aufbauend die Energiewende angemessen zu verstehen. Zu diesem Zweck muss der Unterricht entsprechend strukturiert werden. Welche Leitlinien sowohl die Lehrkräfte der Naturwissenschaften als auch die Entwickler der Unterrichtsmaterialien dabei beachten sollten: Das klärt die vorliegende Studie. Hierfür wird das Modell der didaktischen Rekonstruktion als Forschungsrahmen genutzt. Ausgehend von einem gemäßigt konstruktivistischen Lehr-Lernverständnis werden drei Unterfragen beantwortet: (1) Welche vorunterrichtlichen Vorstellungen bringen Schüler in den Unterricht mit? (2) Welche Vorstellungen haben Wissenschaftler? (3) Welche Unterschiede ergeben sich im Vergleich der Vorstellungen? Für die Beantwortung dieser Fragen wurden in der Erhebung problemzentrierte, leitfadengestützte Interviews mit 27 Achtklässlern geführt und Auszüge aus zwei wissenschaftlichen Gutachten ausgewählt. Mit einer qualitativen Inhaltsanalyse konnten in der Auswertung Inhaltsaspekte identifiziert werden, die Potenzial für die unterrichtliche Vermittlung haben. Mit dem so reduzierten Datenmaterial wurde eine systematische Metaphernanalyse durchgeführt. Damit wurden erfahrungsbasierte Muster hinter den Vorstellungen rekonstruiert. Aus dem systematischen Vergleich der Ergebnisse lassen sich Lernchancen und Lernhindernisse für das Verstehen von naturwissenschaftlichen Hintergründen der Energiewende ableiten. Diese werden in Form von Leitlinien für den naturwissenschaftlichen Unterricht zusammengefasst. Diese Leitlinien können von Lehrpersonen und Entwicklern von Lehrmaterialien genutzt werden, um ein fachlich angemessenes Verstehen der naturwissenschaftlichen Schlüsselprinzipien der Energieträger und der Energiewende zu fördern.
Durch die Neufassung des § 68f Abs.1 Satz 1 StGB tritt die Führungsaufsicht bei vollverbüßter Strafe von zwei Jahren oder bei schwerwiegenden Taten gemäß § 181b StGB nach einem Jahr kraft Gesetzes ein. Diese Reform im Jahr 2007 hat zu einem enormen Anstieg von Führungsaufsichten nach vollverbüßter Jugendstrafe geführt. Die Regelungen und Aufgaben der Verantwortlichen der Führungsaufsicht nach Jugendstrafe sind vielfältig und anders als beispielsweise bei der Führungsaufsicht nach einer Maßregel der Besserung und Sicherung (gem. §§ 63f). Für die Arbeit mit straffälligen Jugendlichen und Heranwachsenden unter Führungsaufsicht nach vollverbüßter Jugendstrafe gibt es für die Justizsozialarbeitenden keine explizite Handreichung. Im Vordergrund der Arbeit liegt die Frage: Welche Faktoren können, aus Sicht der beteiligten Akteure, die Legalbewährung jugendlicher und heranwachsender Vollverbüßer unter Führungsaufsicht begünstigen? Die Praxisforschung wird anhand von 15 Interviews mit den Verantwortlichen der Führungsaufsicht dargestellt und nimmt Bezug auf das in der Praxis erprobte Modellprojekt RESI und das Lebenslagenkonzept.
Thermal energy storage systems have a high potential for a sustainable energy management. Low temperature thermochemical energy stores based on gas-solid reactions represent appealing alternative options to sensible and latent storage technologies, in particular for heating and cooling purposes. They convert heat energy provided from renewable energy and waste heat sources into chemical energy and can effectively contribute to load balancing and CO2 mitigation. At present, several obstacles are associated with the implementation in full-scale reactors. Notably, the mass and heat transfer must be optimized. Limitations in the heat transport and diffusions resistances are mainly related to physical stability issues, adsorption/desorption hysteresis and volume expansion and can impact the reversibility of gas-solid reactions. The aim of this thesis was to examine the energy storage and cooling efficiency of CaCl2, MgCl2, and their physical salt mixtures as adsorbents paired with water, ethanol and methanol as adsorbates for utilization in a closed, low level energy store. Two-component composite adsorbents were engineered using a representative set of different host matrices (activated carbon, binderless zeolite NaX, expanded natural graphite, expanded vermiculite, natural clinoptiolite, and silica gel). The energetic characteristics and sorption behavior of the parent salts and modified thermochemical materials were analyzed employing TGA/DSC, TG-MS, Raman spectroscopy, and XRD. Successive discharging/charging cycles were conducted to determine the cycle stability of the storage materials. The overall performance was strongly dependent on the material combination. Increase in the partial pressure of the adsorbate accelerated the overall adsorbate uptake. From energetic perspectives the CaCl2-H2O system exhibited higher energy storage densities than the CaCl2 and MgCl2 alcoholates studied. The latter were prone to irreversible decomposition. Ethyl chloride formation was observed for MgCl2 at room and elevated temperatures. TG-MS measurements confirmed the evolution of alkyl chloride from MgCl2 ethanolates and methanolates upon heating. However, CaCl2 and its ethanolates and methanolates proved reversible and cyclable in the temperature range between 25°C and 500°C. All composite adsorbents achieved intermediate energy storage densities between the salt and the matrix. The use of carbonaceous matrices had a heat and mass transfer promoting effect on the reaction system CaCl2-H2O. Expanded graphite affected only moderately the adsorption/desorption of methanol onto CaCl2. CaCl2 dispersed inside zeolite 13X showed excellent adsorption kinetics towards ethanol. However, main drawback of the molecular sieve used as supporting structure was the apparent high charging temperature. Despite variations in the reactivity over thermal cycling caused by structural deterioration, composite adsorbents based on CaCl2 have a good potential as thermochemical energy storage materials for heating and cooling applications. Further research is required so that the storage media tested can meet all necessary technical requirements.