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Einsatz der Planarchromatographie mit wirkungsbezogener Detektion zur Untersuchung von Wässern
(2018)
Unter Wirkungsbezogener Analytik (WBA) wird die Kopplung eines chromatographischen Trennverfahrens mit einem biologischen Testsystem verstanden. Der Vorteil bei dieser Herangehensweise ist, dass die zuvor getrennten Probeninhaltsstoffe anhand ihrer Aktivität mit einem in vitro-Testsystem detektiert werden. Es hat sich gezeigt, dass die Hochleistungsdünnschichtchromatographie (HPTLC) besonders geeignet für die WBA ist. Bislang konnte nicht gezeigt werden, dass die WBA mit HPTLC auch als routinefähige Methode eingesetzt wurde. In dieser Arbeit erfolgte eine Optimierung der Detektion der Endpunkte Biolumineszenzhemmung (Aliivibrio fischeri), antibiotische Wirkung (Bacillus subtilis), Neurotoxizität (Acetylcholinesterase) von der HPTLC-Platte hinsichtlich Routinefähigkeit. Zusätzlich konnte in ersten Versuchen gezeigt werden, dass es möglich ist, direkt gentoxische Verbindungen mittels des umu-Tests auf der HPTLC-Platte nachzuweisen. Für die einzelnen Biotests sind unterschiedliche Inkubationszeiten notwendig. Dies führt aufgrund von Diffusion auf der HPTLC-Platte zu einer Bandenverbreiterung. Es wurden unterschiedliche Methoden und Arbeitsweisen zur Verminderung der Diffusion erprobt und optimiert. Eine Möglichkeit ist die mechanische Eindämmung durch die Einbringung einer Gaze in eine verfestigte Calciumalginatschicht. Optimiert wurde dieses Verfahren am Bacillus subtilis-Hemmtest. Für Enzymtests ist eine vergleichsweise kurze Inkubationszeit notwendig. Daher tritt hier eine geringere Bandenverbreiterung auf, womit eine mechanische Einschränkung der Diffusion nicht geeignet ist. Um die auftretende Bandenverbreiterung möglichst gering zu halten, wurde besonders die Aufbringung des Substrats optimiert. Dies geschah am Beispiel des HPTLC-Acetylcholinesterasehemmtests. Die Ermittlung der unterschiedlichen bandenverbreiternden Einflussfaktoren erfolgte mittels statistisches Versuchsplanung. Anhand der gewonnenen Erkenntnisse konnte die Methode soweit optimiert werden, dass die bei der Detektion von AChE-Inhibitoren auftretende Bandenverbreiterung sehr gering gehalten werden kann. Aufgrund der hohen Empfindlichkeit des Verfahrens lassen sich selbst geringe Spuren von Verunreinigungen in Referenzsubstanzen detektieren. Besonders für den Routineeinsatz der WBA mit der HPTLC ist die Vergleichbarkeit der Ergebnisse erforderlich. Dazu wurde anhand des HPTLC-Leuchtbakterienhemmtests mit Aliivibrio fischeri eine Auswertestrategie erarbeitet. Die Ermittlung der Biolumineszenzhemmung findet analog zum Küvettentest statt und kann ortsaufgelöst als Hemmwert-Chromatogramm dargestellt werden. Die Darstellung der Hemmung in einem Hemmwert-Chromatogramm gleicht die Stauchung der Peaks aufgrund des sigmoiden Verlaufs der Dosis-Wirkungsbeziehung teilweise aus. Durch die nichtlineare Beziehung zwischen Konzentration bzw. Flächenmasse und Wirkung der unbekannten Substanzen ist es für den Vergleich von Proben notwendig, einen Bezugspunkt zu setzen. Bewährt hat sich dafür der EC50-Wert. Da aber in den meisten Fällen die Konzentration unbekannt ist, wird als Bezugspunkt das Auftragevolumen gewählt, welches erforderlich ist um eine Hemmung von 50% auszulösen. Der Kehrwert des berechneten Auftragevolumens für 50% Hemmung stellt das reziproke Iso-Hemmvolumen (RIHV) dar. Dieser RIHV-Wert hat sich für den Probenvergleich in verschiedenen Anwendungen bewährt. Das Prinzip der Auswertung kann vom HPTLC-Leuchtbakterientest mit Anpassung auf den HPTLC-Bacillus subtilis-Hemmtest übertragen werden. Für den Vergleich der Wirkung auf die Acetylcholinesterase-Hemmung wird in Anlehnung zum RIHV, das reziproke Iso-Aktivitätsvolumen (RIAV) herangezogen. Hier wird das Auftragevolumen, welches notwendig ist, eine Aktivität der AChE von 50% zu erreichen, als Kehrwert angegeben. Zur Ermittlung der Messunsicherheit der Chromatographie und der detektierten Wirkung wurden parallel zu den Proben Referenzverbindungen untersucht. Bei der Überwachung einer gesicherten Deponie über einen Zeitraum von 4,5 Jahren konnte gezeigt werden, dass es sich bei der Hochleistungsdünnschichtchromatographie mittels automatisierter Mehrfachentwicklung (HPTLC/AMD) um ein reproduzierbares Chromatographiesystem handelt. Bei der Anwendung des Leuchtbakterien-, Bacillus subtilis- und des Acetylcholinesterase-Hemmtests auf verschiedene Deponie- und Abwasserproben wurden über einen Zeitraum von sieben Monaten Standardabweichungen von 5-9% Hemmung für die testspezifischen Referenzsubstanzen ermittelt. Als Ergebnis der Validierung wurden der HPTLC-Aliivibrio fischeri-, der HPTLC-Bacillus subtilis- und der HPTLC-Acetylcholinesterase- Hemmtest am 24.03.2015 von der deutschen Akkreditierungsstelle (DAkkS) akkreditiert. Zur Ermittlung potenziell gentoxischer Substanzen wurde der umu-Test ausgewählt. Mit dem umu-Test auf der HPTLC-Platte ist es derzeit möglich, die aus der DIN 38415-3 bekannte direkt wirkende gentoxische Substanz 4-Nitroquinolin-N-oxid (4-NQO) auf der HPTLC-Platte nachzuweisen. Für einen erfolgreichen Nachweis von indirekt wirkenden Substanzen, die erst nach der Aktivierung durch Stoffwechselenzyme gentoxisch wirken, war es nicht möglich, das erforderliche Metabolisierungssystem auf der HPTLC-Platte aufrecht zu erhalten. Zur Durchführung der WBA ist für die meisten Wasserproben (z. B. Oberflächenwasser oder Grundwasser) eine Anreicherung erforderlich. Parallel zu den Arbeiten mit den biologischen Testsystemen erfolgte die Optimierung der Anreicherung von organischen Verbindungen aus Wasserproben. Für die Festphasenextraktion (SPE) wurden verschiedene Materialien bei den pH-Werten 2, 7 und 9 mit Substanzen unterschiedlicher Polarität getestet. Die besten Wiederfindungen über den gesamten Polaritätsbereich erzielte die Phase "Agilent Plexa" (Polydivinylbenzol) mit einer angepassten Elutionsabfolge. Bei der Auswahl des Materials und der Anpassung der Elutionsabfolge wurde auch auf einen möglichst geringen Blindwert für den Biolumineszenz-Hemmtest mit Aliivibrio fischeri geachtet. Damit wurde eine für die WBA geeignete Anreicherungsmethode gefunden. Zur Verbesserung der Extraktionsausbeute von polaren Verbindungen mittels Flüssig-Flüssig-Extraktion (LLE) wurde die Mikro-LLE mit dem in allen Verhältnissen mit Wasser mischbaren Extraktionsmittel Acetonitril getestet. Die im Blindwert auftretenden störenden Substanzen konnten durch Ausheizen des zur Phasentrennung erforderlichen Natriumchlorids erheblich reduziert werden. Bei den Untersuchungen zur Wiederholbarkeit mit einer Deponiesickerwasserprobe und der Detektion der Biolumineszenz von Aliivibrio fischeri waren nur geringe Abweichungen der Hemmwerte detektierbar. Aufgrund der zu erwartenden komplexen Zusammensetzung von Proben aus dem Deponiebereich ist eine Gradientenelution für die HPTLC/AMD notwendig. Anhand von Referenzverbindungen und Extrakten aus verschiedenen Deponien wurde die HPTLC/AMD-Trennung für ein Screening optimiert. Mit diesem Screening-Gradient ist es möglich, die wirkenden Probenbestandteile über die gesamte Trennstrecke zu verteilen. Zusätzlich fand noch eine Entwicklung einer isokratischen HPTLC-Trennung für eine schnelle Beurteilung von Proben statt, wobei bei dieser Methode Abstriche bezüglich der Trennleistung gemacht werden mussten. Zudem konnte gezeigt werden, dass der aufwendige Identifizierungsprozess durch spezifische postchromatographische Derivatisierungsreaktionen auf der HPTLC-Platte unterstützt werden kann. Dazu wurde der Bratton-Marshall-Nachweis von primären Aminen optimiert. Durch den Nachweis von austauschbaren Protonen mittels des H/D-Austausches lassen sich die denkbaren Strukturen deutlich einschränken. Für einen nahezu vollständigen H/D-Austausch hat sich die Kopplung von HPTLC und Massenspektrometer (MS) als besonders geeignet gezeigt, da hier nur wenige Milliliter an deuterierten Lösemitteln benötigt werden. Erprobt wurden die optimierten Methoden an verschiedenen Wässern, welche aus Kläranlagen und aus dem Umfeld von Deponien stammen. Durch die Einführung des RIHV- bzw. RIAV-Wertes ist es möglich Wässer von verschiedenen Probennahmestellen, z. B. Deponiesickerwässer, anhand ihrer Wirkung vergleichend zu beurteilen. Auch kann damit die Veränderung des Wirkungsmusters über einen Aufbereitungsprozess beobachtet werden. Die Untersuchungsergebnisse zeigen zudem, dass auch bei der WBA Feldblindproben entscheidend sind, um Proben sicher beurteilen zu können.
Human activities have become a major driver of global change, so that global society and economy are facing consequences such as climate change, increasing scarcity of resources, environmental pollution and degradation as well as disturbances of ecosystem functioning and services.In order to meet these main challenges in an appropriate way, adequate starting points and solutions must be pursued at all levels to shift the current socio-economic pathway from an unsustainable to a safe operating and thus sustainable development within the planetary boundaries. One of the application concepts in industrial contexts is Industrial Symbiosis (IS), which deals with the set-up of advanced circular/cascading systems, in which the energy and material flows are prolonged for multiple material and energetic (re-)utilization within industrial systems in order to increase resource productivity and efficiency, while reducing environmental impacts. The overarching goal of the research project was to identify and develop approaches to enable the evolution of Industrial Symbiosis (IS) in Industrial Parks (IPs). IS is a collaborative cross-sectoral approach to connect the resource supply and demand of various industries in order to optimize the resource use through exchange of materials, energy, water and human resources across different companies, while generating ecological, technical, social and economic benefits. Many Information Communication Technology (ICT) tools have been developed to facilitate IS, but they predominantly focus on the as-is analysis of the IS system, and do not consider the development of a common desired target vision or corresponding possible future scenarios as well as conceivable transformation paths from the actual to the defined (sustainability) target state. This gap shall be addressed in this work, presenting the software requirements engineering results for a holistic IT-supported IS tool covering system analysis, transformation simulation and goal-setting. This study also aims to present the conceptual IT-supported IS tool and its corresponding prototype, developed for the identification of IS opportunities in IPs. This IS tool serves as an IS facilitating platform, providing transparency among market players and proposing potential cooperation partners according to selectable criteria (e.g. geographical radius, material properties, material quality, purchase quantity, delivery period). Therefore a quantitative indicator system was compiled and recurring patterns were identified to utilize this knowledge in the comprehensive IT-supported IS tool. So this IS tool builds the technology-enabled environment for the processes of first screening of IS possibilities and initiation for further complex business-driven negotiations and agreements for long-term IS business relationships.
Das Ziel der vorliegenden Dissertation ist es, die Auswirkungen des Klimawandels auf die Entwicklung des Vorlandes als Ergebnis der sich ändernden hydraulidschen Bedingungen zu untersuchen. Die Untersuchung beschäftigt sich mit der Entwicklung des Vorlandes, da dieses Gebiet stark abhängig von Wasserstandsänderungen ist. Diese werden möglicherweise durch Klimawandel verstärkt und können folglich die zahlreichen Funktionen des Vorlandes beinträchtigen. Diese Problematik erfordert die Durchführung einer Untersuchung, die zunächst die durch die Variationen der Wasserstände betroffenen physikalischen Prozesse im Fluss und in den Flussauen analysiert und anschließend eine Methodologie für die Analyse der zukünftigen Entwicklung des Vorlandes herleitet. Beispielhaft wurde ein Bereich an der unteren Mittelelbe in Niedersachsen, Norddeutschland für die Untersuchung ausgewählt. Zu diesem Zweck befasst sich die Untersuchung im ersten Teil mit der aktuellen Diskussion über den Klimawandel und mit den bestehenden Schwierigkeiten, zu einer belastbaren zukünftigen Prognose des Ausmaßes der klimatischen Veränderungen zu gelangen. Anschließend konzentriert sich die Untersuchung auf die Interaktionen zwischen Abflüssen, Vegetation und Sedimenten, die die Flussmorphodynamik bedingen. Ein weiterer Schwerpunkt dieser Arbeit ist die Untersuchung der mathematischen Modelle, die eine Analyse des zukünftigen Verhaltens des Vorlandes ermöglichen. Mithilfe dieser Untersuchung werden die Vorteile der eindimensionalen Modellierung für die Prognose der Entwicklung dieses Gebiets deutlich. Die Untersuchung im ersten Teil der Dissertation führt zur Erkenntnis, dass sich das Verhalten des Vorlandes aus der Interaktion zwischen Fluss- und Flussauenmorphologie und der Auenvegetation ergibt. Diese Interaktionen bestimmen letztlich die zukünftigen Wasserstände und somit die hydraulischen Bedingungen für diese Zone. Für die Analyse des zukünftigen Verhaltens des Vorlandes unter Einfluss des Klimawandels wird eine Methodologie vorgeschlagen, die als Dynamische Interaktion von Modellen bezeichnet wird. Der Einfluss des Klimawandels wird durch die Variation von Abflüssen im Flussmodell, im Sedimenttransport- und Bodenwasserbewegungsmodell sowie bei der Analyse von Veränderungen der Vegetation berücksichtigt. Dazu werden die durch regionale Klimamodelle prognostizierten zukünftigen Niederschläge in die Berechnung der zukünftigen Abflüsse durch eine in dieser Dissertation entwickelten Modifikation des stochastischen Modells AutoRegressive-Moving-Average (ARMA) eingeschlossen. Die ausgearbeiteten Entwicklungsprognosen der verschiedenen Modelle werden miteinander verknüpft, um zukünftige Wasserstände und Überflutungen und damit die neuen hydraulischen Bedingungen für das Vorland zu prognostizieren. Im zweiten Teil dieser Dissertation wird die vorgeschlagene Methodologie der Dynamischen Interaktion von Modellen in einem Fallbeispiel angewandt. Dafür wurden zwei Messstationen an der Elbe zwischen Elbe-km 511 und 515 installiert, die auch im Rahmen des Projekts KLIMZUG-NORD verwendet wurden. Diese Messstationen ermöglichten innerhalb von 2 Jahren die Erhebung von mehr als 300.000 Felddaten. Diese Informationen erlauben es, die Entwicklung des Vorlandes (2021-2050) in einer regulierten Flussstrecke der Elbe (Mittelelbe) zu prognostizieren. Dazu werden zunächst die bedeutenden Charakteristika des Untersuchungsgebiets dargestellt und nachfolgend Material und Methoden erläutert, die für die Analyse der Entwicklung des Vorlandes im Untersuchungsgebiet erforderlich sind. Die Flussmorphologie wird für den Zeitraum 2001-2100 modelliert, da eine Tendenz bei möglichen Variationen in einem kurzen Zeitraum nur schwer wahrgenommen werden kann. Die jeweiligen Modelle werden u.a. mithilfe erhobener Felddaten, Daten aus der Literatur, Klimadaten aus den Stationen des Deutschen Wetterdiensts (DWD), projizierten Daten des regionalen Klimamodells REMO, Daten des hydrologischen ATLAS von Deutschland, Abflussdaten des Pegels Neu Darchau (Elbe-km 536,4), Geschiebe-Schwebstoffdaten des Wasser- und Schifffahrtsamts (WSA) und der Bundesanstalt für Gewässerkunde (BfG), Wassertemperaturdaten der Arbeitsgemeinschaft für die Reinhaltung der Elbe (ARGE-ELBE) und das Digitale Geländemodell (DGM) kalibriert. Die durch das stochastische Modell ARMA/Variation erhaltenen Berechnungen der zukünftigen Abflüsse, die die Prognose der regionalen Klimamodelle berücksichtigen, werden mit den durch die BfG-Modelle erhaltenen Ergebnissen verglichen, um die Problematik der Vielfalt von klimatischen Prognosen anzugehen. Schließlich werden in dieser Dissertation die Anwendung und Bedeutung der vorgeschlagenen Methodologie für die Analyse der Entwicklung des Vorlandes anderer Flüsse und Regionen außerhalb Mitteleuropas behandelt.
In der vorliegenden Arbeit wurde ein ICP-QMS mit integrierter Reaktions- /Kollisionszelle erfolgreich eingesetzt, um die Elemente Vanadium, Chrom, Mangan, Eisen, Nickel, Kobalt, Kupfer, Zink, Arsen, Molybdän, Cadmium, Blei und Uran direkt in verdünntem Meerwasser zu bestimmen. Die Bestimmung von Elementspuren in Meerwasser wurde realisiert, indem alle zur Verfügung stehenden Möglichkeiten zur Minimierung von Interferenzen bei der Bestimmung von Elementen mit ICP-QMS angewendet wurden.
Diese Arbeit stellt eine Pionierarbeit zum Thema Keyline Design als ganzheitliches Gestaltungskonzept für landwirtschaftliche Betriebe im deutschsprachigen Raum dar und ist aus der Zusammenarbeit mit Akteuren der Gemeinschaft Schloss Tempelhof in Süddeutschland entstanden. Keyline Design hat zum Ziel, durch systematische Planung von landwirtschaftlicher Flächennutzung und Tiefenlockerung in einem topographieabhängigen Kultivierungsmuster, die Bodenfruchtbarkeit zu steigern sowie Wasserfluss auf Landschaften kontrolliert zu nutzen und gleichmäßig zu verteilen. Vor dem Hintergrund von Bodendegradation durch landwirtschaftliche Praktiken und sich verändernde klimatische Bedingungen, stellen divers gestaltete Landschaften eine wichtige Anpassungsstrategie zum Schutz gegen Extremwetterereignisse dar. Keyline Design hat bisher innerhalb dieses Diskurses in Zentral- und Nordeuropa wenig Beachtung erfahren. Für die transdisziplinäre Zusammenarbeit wurde innerhalb dieser Arbeit eine Vorgehensweise zur Erstellung eines Keyline Entwicklungsszenarios entwickelt: Mithilfe eines transdisziplinären Arbeitstreffens und einem online Fragebogen wurden die Ziele und Entwicklungswünsche der 140 Personen umfassenden Gemeinschaft Schloss Tempelhof erfasst und auf Basis eines Keyline Kultivierungsmusters ein Entwicklungsszenario für die landwirtschaftliche Flächennutzung erstellt. Keyline Design wurde als Planungskonzept für die topographieabhängige Integration von Agroforstsystemen, wie Pufferzonen, Waldweiden und Alley Cropping, sowie für die Platzierung von Wasserkörpern genutzt. Die Ergebnisse des Entwicklungsszenarios zeigen, dass das erarbeitete Kultivierungsmuster von der Topographie abhängig ist, die Ausgestaltung des Szenarios jedoch vor allem vom Kontext der Akteure.
This study aims to answer four main research questions regarding the roles, strategies, barriers, and representation of the media and environmental nongovernmental organisations (ENGOs) in environmental communication in Malaysia. From a theoretical lens, this study has incorporated the essential concepts of media, ENGOs, and environmental communication from both Western and Asian, particularly Malaysian perspectives as primary points of reference. For the purpose of this study, a total of 13 interviewees from Media A and Media B and 11 interviewees from ENGO A and ENGO B were chosen for the qualitative interview while 2,050 environmental articles were collected as samples from Media A´s and Media B´s newspapers along with ENGO A´s and ENGO B´s newsletters from the period 2012 to 2014 for the quantitative content analysis. Specifically, the findings from interview confirmed that both the Malaysian media and ENGOs have shared quite similar roles in environmental communication, particularly in environmental legitimacy (creating trust, credibility, and relationships with the public), in democracy (acting as a watchdog and mobilising the public sphere), and in constructing public mind about environmental problems. Pictures undoubtedly were one of the most vital tools in social construction, especially for presenting the reality of the environmental problems to the public. This was in harmony with the results of the quantitative content analysis, where more than 60% of pictures were found on environmental articles in media newspapers and ENGOs newsletters. Malaysian media and ENGOs have shared two common strategies in environmental communication, namely campaigning and collaboration with other stakeholders, while the ENGOs have two extra strategies: advocacy and lobbying strategies. Malaysian media and ENGOs also have collaborated with each other and the level of collaboration between them was at the coordination (medium) level. Both social actors especially the media were also relied heavily on their sources for environmental articles and the result of quantitative content analysis showed that the government was the main source for media newspapers, whereas other ENGOs and laypersons were the main sources for ENGOs´ newsletters. There are also colossal barriers faced by both Malaysian media and ENGOs throughout the process of environmental communication and some of the barriers faced by both media and ENGOs include the problem with limited knowledge of the environment, while some other barriers, like media laws and ownership, were only faced by the media; other barriers such as funding problems were specifically faced by the ENGOs. In terms of representation of environmental information, the Malaysian media make more presentations on environmental problems, especially on topics like floods, wildlife and water crises in their newspapers, while ENGOs have given more attention to environmental effort topics such as conservation and sustainable living in their newsletters. Surprisingly, not only the media but also the ENGOs used the same (news) values like timeliness, proximity, and impact as criteria for the selection of environmental issues for their publications. Other factors such as the background of the organisation and the interest of journalists or editors also influence the selection of environmental issues. It is hoped that the proposed theoretical framework of this study can serve as a crucial guideline for the development of environmental communication studies, especially among the media and ENGOs not only in Malaysia but also in other (Southeast) Asian regions that share a similar background.
Environmental governance beyond borders: Governing telecoupled systems towards sustainability
(2023)
This doctoral dissertation analyses the environmental governance of long-distance social-ecological interactions in telecoupled systems in two issue domains: global commodity chains and infrastructure projects as part of China’s Belt and Road Initiative (BRI). Although both domains involve different governance actors, institutions and processes, they both concern the question of how the involved actors develop governance structures and institutional responses to telecoupling. This dissertation aims to contribute to a deeper understanding of how to govern environmental problems that are associated with global flows. Since many multilateral environmental governance initiatives have not yet produced the desired solutions to global problems, particular attention is directed at unilateral state-led governance approaches. This dissertation addresses the questions of (1) how to achieve a spatial fit between the scale of telecoupled systems and the scale of governance institutions, (2) how governance actors exercise agency in governing telecoupled systems, and (3) how state actors can govern the domestic and foreign environmental effects of telecoupled flows. The results show that creating a spatial fit in the governance of global commodity flows is challenging because boundary and resolution mismatches can emerge. Boundary mismatches denote situations where social-ecological problems transcend established jurisdictional boundaries, whereas resolution mismatches refer to governance institutions that have too coarse a spatial resolution to allow them to address the specific aspects of social-ecological problems effectively. No single governance institution is likely to avoid all mismatches, which highlights the need to align multiple governance approaches to effectively govern telecoupled systems.
The fact that digitalization comes along with a lot of negative effects onto the environment is slightly known in the case of energy consumption by hardware, especially regarding mobile devices, having a limited battery life. However, awareness of environmental issues of software, being the driver of hardware, is mainly missing, even if the research field addressing corresponding issues is growing. Thus, the doctoral thesis at hand addresses the question How to draw (a) developers and (b) usersattention to environmental issues of software? By presenting (a) a calculation method of the carbon footprint of software projects and (b) a concept for an eco-label for software products, evaluated by a user survey, the doctoral thesis provides two strategies how to draw the attention to environmental issues of software. Summarizing, this thesis can act as a basis for further research in bridging from science to society in the context of environmental issues of software. Its findings can be seen as starting points for practical implementations of methods and tools supporting a more environmentally friendly way of developing software and informing about environmental issues of software usage. In order to get the implementation of the research results of the thesis going, it highlights practical implications for diverse groups of stakeholders - researchers, certifiers, public administration and professional purchasers, and environmental associations - that have been identified as being important for the practical implementation of the presented concepts and, thus, represent the target group of the doctoral thesis.
Neben dem Klimawandel und der Verstädterung zählt der Verlust biologischer und kultureller Vielfalt mit unberechenbaren Konsequenzen für die Bereitstellung von Ökosystemdienstleistungen zu den größten Herausforderungen der Zukunft, auch in UNESCO-Biosphärenreservaten, die Modellregionen für nachhaltige Entwicklung sind. Deshalb wurden durch die vorliegende Studie erstmalig Ökosystemdienstleistungen im UNESCO-Biosphärenreservat Schaalsee erfasst und bewertet. Dort sind insgesamt 39 Ökosystemdienstleistungen nachzuweisen, wobei räumliche Unterschiede hinsichtlich der Zonierung zu beobachten sind: Je strenger der Schutzstatus, desto geringer ist die Anzahl an nutzbaren Ökosystemdienstleistungen. Mittels Q-Methode wurden fünf unterschiedliche Werteperspektiven auf die bereitgestellten Ökosystemdienstleistungen identifiziert: 1) Übereinstimmung mit der Biosphärenreservats-Idee, 2) Regionalität mit dem Streitpunkt Kultur, die als a) entbehrlicher Luxus oder b) elementarer Lebensinhalt wahrgenommen wird, 3) Landwirtschaft und Nostalgie sowie 4) Vorsorge durch natürliche Regulierungsleistungen. Alle Perspektiven stimmen darin überein, dass die Vielfalt der Natur und sauberes Trinkwasser sowie die meisten regulierenden Ökosystemdienstleistungen von großer Wichtigkeit sind. Die Ergebnisse der Erfassung können als Grundlage zur weiteren Untersuchung der Ökosystemdienstleistungen im UNESCO Biosphärenreservat Schaalsee verwendet werden.
The global coffee market is connected to many sustainability issues like the persisting poverty of coffee farmers, and degrading ecosystems. Many interventions, from state-led regulation to industry-led certification processes, exist, that try to change global value chains to shift societies back on more sustainable trajectories. To this date, it is still under debate if these interventions are an effective means to change global value chains. With climate change and persisting issues of social justice as strong accelerators, calls are increasingly made for a radical transformation of global production and consumption patterns. Many frameworks try to inform research and real-world policies for a transformation of global value chains. In this dissertation, the author uses the framework of the practical, political and personal sphere proposed by O'Brien and Sygna (2013) highlighting that the interactions between these three spheres bare the greatest potential for a transformation towards sustainability. However, in this dissertation, the author argues that it is exactly at the nexus between the three spheres of transformation where barriers towards a fundamental shift of systems occur. He, therefore, uses three perspectives to bring empirical nuance to the problems that arise on the interplay between the different spheres of transformation. (1) The scientific perspective: using a systematic review of alternative trade arrangements; (2) the producer perspective: facilitating a participatory network analysis of social-ecological challenges of Ugandan coffee farmers and their adaptive management practices; (3) the consumer perspective: through the use of a German consumer survey and a structural equation model to investigate into the Knowledge-Doing-Gap end-consumers are facing. Through the results from the scientific perspective, the author is able to show that most of the research is investigating the certified market and that the effectiveness of labels rarely exceeding the practical sphere. His empirical research on the producer perspective highlights that Ugandan coffee farmers facilitate a variety of on-farm crop management (practical sphere) but their support structures rarely exceed informal exchange with neighboring communities (political sphere). Exchange with governmental actors and global traders is happening but has been assessed as not sufficient to cope with the social-ecological challenges the producers are facing. Through the results of the consumer perspective, the author is able to highlight that even though end-consumers have pro-sustainable attitudes (personal sphere) they are facing situational constraints (political sphere) that create a gap between their attitudes and the respective behavior. Using these empirical insights about drivers and barriers for a transformation he proposes that frameworks, aiming to inform research and policies, need to include two aspects: (1) the notion of a forced transformation; and (2) the translational capacity of the frameworks to create meaningful interdisciplinary discourses in different contexts. The author, therefore, propose two approaches:(1) a fourth sphere, called the "planetary force" to include the notion of a forced transformation that is already happening in different contexts, highlighted by the producer perspective in this dissertation; and (2) the consequent use of methods that create interdisciplinary exchange and rigorous testing.
The principle of this thesis was to study the environmental fate of three highly used psychotropic drugs and this achieved through: 1) examining the biodegradability of TMI, DMI and CPTX, 2) studying the behaviour of TMP, DMI and CPTX in photodegradation tests using Xe and UV lamps with studying the effect of different environmental conditions on their UV-photodegradation behaviour, 3) monitoring the primary elimination of TMP, DMI and CPTX during photodegradation and biodegradation tests using HPLC, and measuring their degree of mineralization by means of dissolved organic carbon analyser (DOC), 4) elucidating the structures of the transformation products (TPs) which formed during the degradation of TMI, DMI and CPTX by using LC-MS/MS analysis, 5) analysing the biodegradability of their TPs by laboratory tests and in-silico assessments in order to determine the fate and persistence of these TPs in the aquatic environment, 6) conducting in-silico toxicity predictions for the selected psychotropic drugs and their TPs in human (carcinogenicity, genotoxicity and mutagenicity) and in eco-system (toxicity to microorganisms and toxicity in rainbow trouts). As an overall conclusion, the present work demonstrates that a combination of laboratory simulation tests, LC-MS/MS analysis and in-silico tools result in valuable new information regarding environmental fate of three important psychotropic drugs and their TPs. This dissertation also highlights that different environmental conditions such as temperature, initial drug concentration and pH can differently affect the degradation behaviour of pharmaceuticals even when they are highly structurally related. Therefore, one cannot conclude from one pharmaceutical to another but each one needs to be investigated individually and this present a great challenge for risk assessment kinetics of chemicals in the aquatic environment. The results presented here showed that the investigated pharmaceuticals and their TPs can negatively affect the environment which may be harmful to the ecosystem as they might have been present for decades in the aquatic environment without any knowledge of their environmental fate or connected risk. Therefore, further work needs to be done including analysis of environmental samples (e.g., surface waters), as well as laboratory toxicity tests to further expand knowledge on their exact environmental impact.
This cumulative dissertation investigates food policy councils (FPCs) as potential levers for sustainability transformation. The four research papers included here on this recent phenomenon in Germany present new insights regarding the process of FPCs' emergence (Emergence paper), the legal conditions which affect their establishment (Legal paper), the different roles of FPCs in policy-making processes (Roles paper) and FPCs' potential to democratise the food system (Food democracy paper). Drawing on and contextualizing the results of the four individual studies, the framework paper uses the leverage points concept originally developed by Meadows (1999) and adopted by Abson et al. (2016) as a lens to discuss FPCs’ potential as levers for sustainability transformation. This conceptual background includes three so-called realms of leverage, which are considered to be of particular importance in transformational, solution-oriented sustainability science: first, the change, stability and learning in institutions (re-structure), second, the interactions between people and nature (re-connect) and third, the ways in which knowledge is produced and used (re-think). Framing the findings of the four research papers in terms of these three realms, the framework paper shows that FPCs could serve as cross realm levers, i.e. as interventions that simultaneously address knowledge production, institutional reform and human-nature interactions.
Global environmental changes and the subsequent biodiversity loss has raised concerns over the consequences for the functioning of ecosystems and human well-being. This thesis provides new mechanistic insights into the role of tree diversity in regulating forest productivity and forests’ responses to climate change. The thesis also addresses the overlooked functional role of ecological continuity in mediating ecosystem processes in the context of multiple global environmental changes. The findings of the thesis emphasize the need to retain the functional integrity of forest ecosystem by preserving biodiversity and acknowledging the ecological memory forests.
Increasingly, researchers are expected to work in collaborative interdisciplinary teams to tackle more complex and interrelated problems. However, the prospect of collaborating with others, from different disciplines, exerts countervailing forces on researchers. There is the lure of transcending the limitations of one's own knowledge, methods and conventions, belonging to diverse intellectual communities and tackling, together, ambitious research topics. On the other hand, there is the risk that collaborating across disciplinary boundaries will be taxing, confounding at times, with no guarantee of success. This thesis is about collaborative interdisciplinary research from the perspective of a formative accompanying researcher. The author accompanied an interdisciplinary research team in the field of sustainability over three years for the duration of a collaborative project. Formative accompanying research (FAR) is an approach to "research into research" that learns about, with and for a collaborative interdisciplinary team. The author found - through immersion in the literature, her own daily experiences of collaborating, and her observations – that interdisciplinary collaboration is very difficult. It requires a basic understanding and appreciation of other disciplines and methods, as well as the skills to integrate research inquiries and findings across diverse epistemologies. It also requires awareness that collaborative interdisciplinary research is more than an intellectual task of knowledge creation. Other factors matter, such as interpersonal relationships, power differentials, different research tempos and a sense of belonging. And these factors have an impact on processes and outcomes of collaborative knowledge creation. Knowing this implies a willingness to keep learning and to tolerate discomfort so as to cultivate deeper levels of collaborative capacity. The author discovered that in these deeper levels lie skills for staying with inevitable tensions, for talking and listening to generate new understanding together, and for applying a researcher's frank curiosity to oneself too. A formative accompanying researcher, who is part of the team she is researching, has to navigate delicate terrain. In this thesis, the author develops a FAR methodology that takes seriously the questions of positionality and relationality, and reflects on the experiences of putting these into practice. A FAR practice involves remaining in dynamic movement between observing and participating, between exercising curiosity and care, and between the researchers' own sense of impartiality and investment in relation to the issues at hand. There is merit in furthering the methodology and practice of FAR on its own terms. This includes attending to the skills required by a formative accompanying researcher to remain oriented within the concentric circles of research, relationship and loyalty that make up a collaborative team. There is also the question of how FAR, and other forms of research into research, can help to advance collaborative interdisciplinary research. The author argues for creating the conditions in research teams that would enable treating collaboration as a capacity to develop, and that would facilitate team members' receptivity to learning with FAR. Furthermore, she explores dilemmas of intervening as a formative accompanying researcher and of sustaining dynamic positionality over the long-term.
Fostering sustainable urban mobility at neighborhood-based mobility stations with cargo bikes
(2019)
Agrobiodiversität besitzt vielfältigen ökologischen, ökonomischen und sozio-kulturellen Wert. Sie ist eine grundlegende Voraussetzung für zukünftige Nutzungen und steht gleichzeitig in einem besonderen Verhältnis zu menschlichem Handeln. Zwar basiert Agrobiodiversität auf Natur, sie ist jedoch wesentlich durch landwirtschaftliche Tätigkeiten gestaltet worden und kann ohne weitere Nutzung durch den Menschen nicht erhalten und erneuert werden. Die vorliegende Dissertation analysiert die Gestaltung gesellschaftlicher Naturverhältnisse in der ländlichen Entwicklung am Beispiel der nachhaltigen Nutzung von Agrobiodiversität. Schutz und Nutzung von Agrobiodiversität wird hierfür in einem ersten Schritt als sozial-ökologisches Phänomen konzipiert. Daran schließen sich Analysen auf agrarpolitischer und landwirtschaftlich praktischer Ebene an. Anhand einer Analyse der der Gemeinsamen Agrarpolitik der Europäischen Union (GAP) und im speziellen der Politik zur ländlichen Entwicklung wird deutlich, dass eine programmatische Orientierung an Wettbewerbsfähigkeit und einer nachhaltigen Entwicklung besteht und das Paradigma einer multifunktionalen Landwirtschaft integrierende Ansätze bietet. Diese Ansätze werden jedoch weiterhin vor dem Hintergrund einer unhinterfragten Logik realisiert, die davon ausgeht, dass naturerhaltendes Wirtschaften nicht wettbewerbsfähig sein kann. Die GAP löst somit die hierarchische Trennung zwischen Schutz und Nutzung von Agrobiodiversität nicht auf. Trotz der Wirkmächtigkeit der GAP kann mittels der Fallstudie "Arche-Region Flusslandschaft Elbe" an einem konkreten Beispiel aus der landwirtschaftlichen Praxis dargestellt werden, wie nachhaltige Agrobiodiversitätsnutzung umgesetzt wird. Aus den Ergebnissen der Fallstudie werden abschließend Schlussfolgerungen für eine Weiterentwicklung der Politik zur ländlichen Entwicklung und EU-Agrarpolitik im Allgemeinen abgeleitet.
Climate change and atmospheric deposition of nitrogen affect biodiversity patterns and functions of forest ecosystems worldwide. Many studies have quantified tree growth responses to single global change drivers, but less is known about the interaction effects of these drivers at the plant and ecosystem level. In the present study, the authors conducted a full-factorial greenhouse experiment to analyse single and combined effects of nitrogen fertilization (N treatment) and drought (D treatment) on 16 morphological and chemical response variables of one-year-old Fagus sylvatica seedlings originating from eight different seed families from the Cantabrian Mountains (NW Spain). Drought exerted the strongest effect on response variables, reflected by decreasing biomass production. However, D and N treatments interacted for some of the response variables, indicating that N fertilization has the potential to strengthen the negative effects of drought (with both antagonistic and amplifying interactions). For example, combined effects of N and D treatments caused a sevenfold increase of necrotic leaf biomass. The authors hypothesize that increasing drought sensitivity was mainly attributable to a significant reduction of the root biomass in combined N and D treatments, limiting the plants' capability to satisfy their water demands. Significant seed family effects and interactions of seed family with N and D treatments across response variables suggest a high within-population genetic variability. In conclusion, the findings indicated a high drought sensitivity of Cantabrian beech populations, but also interaction effects of N and D on growth responses of beech seedlings.
This thesis aims at contributing to the better understanding of the roles of international and domestic institutional and governance patterns for corporate sustainability practices. By combining governance and new institutionalism approaches it bridges the gap between the close look at specific corporate sustainability (CS) policies and the broader view on institutional frameworks. The qualitative comparative approach aims to provide deeper insights on the implementation of different governance schemes by transnational corporations ((TNC). Finally, the conclusions might allow for the development of a) recommendations for the balancing of TNCs' CS management between global and domestic requirements, and b) policy recommendations in the field of CS governance. The overarching research question is as follows: What role do national governance patterns play in comparison to global governance practices in shaping the corporate sustainability (CS) management of transnational corporations (TNCs)? In order to further operationalize this research objective, it is structured into three subquestions: (1) What are relevant institutional factors and global governance patterns for corporate sustainability/ Corporate Social Responsibility (CSR)? (2) What are relevant institutional factors and national governance patterns for corporate sustainability/CSR in Germany, the US, and India? (3) How do these national and global governance patterns influence TNCs' CS management? The first two questions aim at tracing the institutional framework and governance patterns at both national and international levels by identifying norms, stakeholder expectations, prevalent modes of governance and actors involved in governance processes. On this basis, the third question targets TNCs' reaction to internationally varying governance patterns. Here, it is of main interest how relevant governance instruments are perceived by business actors and to which extent their sustainability management at the companies' headquarters and subsidiaries reflect global and national institutional and governance patterns. In order to answer these questions, literature research and a structured qualitative analysis have been conducted. The concepts of CS and CSR build the basis to analyze how TNCs and their subsidiaries manage their social and ecological corporate responsibilities. Against this conceptual background, the research question is approached empirically by the means of an international comparison. Three institutionally highly diverse countries were chosen: Germany, India and the US. India, an emerging market economy, was included to increase the diversity of the sample and to close the research gap indicated above. In order to identify the differences in governance for CS in these three countries, document analyses and 42 guideline-based interviews with experts from governments, NGOs, trade unions and trade associations were carried out. At the same time, global governance instruments for corporate sustainability – which are already relatively well researched - were identified by analyzing the relevant secondary literature. In a second step, in order to explore how TNCs strategically deal with the multitude of different governance approaches at their headquarters and subsidiaries, three case studies of Germany-headquartered transnational corporations in the chemical and engineering industries (Siemens, BASF and Bayer) have been conducted.
A central aspect of sustainability governance is collaboration, which has been lauded for its benefits but also criticized for its challenges. The potential benefits of collaboration have apparently been recognized also in the context of EU agriculture. Yet, there has been a lack of holistic consideration of how collaboration can be systematically integrated and promoted in the governance of EU agriculture. Sustainable agriculture cannot only be encouraged through changes in the overall governance system but also through the support of existing and emerging small-scale collaborative initiatives for sustainable agriculture. Indeed, there has been substantial research on the conditions that influence success of similar collaborative initiatives. However, the knowledge resulting from this research remains rather scattered and does not allow for the identification of overall patterns. Additionally, little of this research specifically focuses on sustainable agriculture. What is more, the promotion of collaboration for sustainable agriculture is further complicated by the lack of clarity of the meaning of sustainable agriculture, which is an inherently ambiguous and contested concept. This cumulative dissertation aims to address these gaps by contributing to a better understanding of how collaboration can be facilitated and designed as a means to govern for and advance sustainable agriculture. For this purpose, the dissertation addresses three sub-aims: 1) Advancing the understanding of the concept of sustainable agriculture; 2) scrutinizing the current governance system regarding its potential to facilitate or hamper collaboration; 3) assessing conceptually and empirically how actor collaboration can be facilitated as a means to govern for sustainable agriculture, both from a top-down and a bottom-up perspective. In doing so, this dissertation focuses on EU agriculture and applies a mix of methods, ranging from qualitative to quantitative dominant. The findings of this dissertation highlight that collaboration has been underappreciated and even hampered as an approach to governing for sustainable agriculture. In contrast, this dissertation argues that collaboration offers one promising way to promoting and realizing agriculture and emphasizes the need to integrate different approaches to collaboration and to sustainable agriculture.
Companies increasingly use social and environmental accounting and reporting (SEAR) to measure, manage, and report their influence on ecological and social issues, i.e., climate change and human rights violations. Nowadays, there are many different tools, frameworks, and standards for SEAR that companies can use. Beyond the content presented in the tool itself, e.g., social and/or ecological information, these tools differ, among others, by the language used and the type of data collected (e.g., qualitative, quantitative, or monetary data). This dissertation aims to expand previous literature by clarifying the effects of SEAR on corporate decision-making and its influencing factors. Additionally, antecedents for implementation and use of SEAR in regard to supporting sustainability decision-making are discussed. For this purpose, the given dissertation investigates public sustainability reports by companies with different environmental orientation, conducts two survey-based case studies on the effects of different types of SEAR and one qualitative case study on the antecedents of institutionalizing management accounting change through SEAR. The results lead to seven criteria that practitioners and researchers should recognize for supporting successful SEAR regarding a company's environmental orientation, the role of employees and leadership as well as the specific SEAR tool itself.
This dissertation addresses the question of how sustainability curricula can be implemented and established in higher education institutions. Universities – as hubs for knowledge generation, innovation, and education – provide a central leverage point for sustainably developing society at large. Therefore, the institutionalization of sustainability curricula is not only socially demanded, but also stipulated in numerous political statements from the international community (e.g., those of the UN and UNESCO) and operationalized via Sustainable Development Goal No. 4: "Quality Education". Previous findings on how such implementation can be successful and what factors support or inhibit the process have come primarily through case studies of individual higher education institutions. These studies have been largely descriptive rather than analytical and leave open questions about the generalizability of their findings. The present dissertation addresses this research gap. Through a meta-study (i.e., an analytical comparison of existing case studies), generalizable findings on the implementation processes of sustainability curricula are explored. In the first step, a case universe was collected in order to provide a database for deeper analyses. In two further analysis steps that built on the case universe from Step 1, certain factors that promote or inhibit the implementation of sustainability curricula (Step 2) and specific implementation patterns (Step 3) were examined. The presented findings add a complementary empirical perspective to the discourse on the establishment of education for sustainable development (ESD) at higher education institutions. First, the case studies that specifically address the implementation processes of sustainability curricula are reviewed and analyzed here for the first time as part of a research landscape. This research landscape reveals where research on such implementation processes has been or is being conducted. On this basis, both researchers and funders can reflect on the status quo and plan further research or funding endeavors. Second, this dissertation offers the opportunity to compare a multitude of individual case studies and thus to develop new and generalizable insights into the implementation of sustainability curricula. The empirical analysis uses 133 case studies to identify key factors that promote or inhibit the implementation of sustainability curricula and to add a complementary perspective to the discourse, which has thus far been dominated by theoretical considerations and individual case studies. The analysis thereby offers a new perspective on generalizable influencing factors that appear to be important across different contexts. Thus far, specific patterns of implementation processes have been infrequently studied, and with few datasets. This dissertation analyzes the complex interplay between over 100 variables and provides one of the first research attempts at better understanding the processes that lead to the deep-rooted and comprehensive implementation of sustainability curricula. Internal and external practitioners of higher education institutions can find examples and evidence that can be useful in planning the next steps of their sustainability curriculum implementation. This dissertation offers generalizable empirical findings on how universities can succeed in recognizing their own responsibility to that end and in realizing this transformation through the implementation of ESD.
One of the Colombian strategies to diversify and decarbonize the energy sector is encouraging the use of non-conventional renewable resources (NCRR). This thesis measures the environmental rebound effect (ERE) when increasing the shares of wind power into the Colombian power grid in the residential (household) sector. For doing so, a process-based Life Cycle Assessment (P-LCA), an environmental extended input output (EEIO) model and re-spending models (almost ideal demand system AIDS) were applied. Direct rebound effect was measured thought the elasticity price of the electricity demand; furthermore, the environmental savings for increasing the shares of wind power into the grid were calculated via P-LCA. For doing so, a P-LCA for a wind farm in Colombia was performed, whereas the information for other energy resources (Hydro, Coal, Gas, Solar and Thermal) where collected from Ecoinvent 3.4 database. To calculate the environmental indirect rebound effect the monetary savings obtained for the environmental efficiency were calculated. For doing so, an AIDS was applied to obtain the marginal budget shares (MBS). Combining the MBS obtained with the EEIO model the monetary savings were translated into environmental indicators. The ERE is presented for ten impact categories (climate change (CC), acidification (A), ecotoxicity (E), marine eutrophication (MEUT), terrestrial eutrophication (TEUT), carcinogenic effects (CE), non-carcinogenic effects (NCE), ozone layer depletion (OD), photochemical ozone creation (POC), and respiratory effects, inorganics (RES)). Moreover, a sensitive analysis was conducted to measure the variability of the ERE to different values of the direct rebound effect and different percentages of price efficiency. The results show that the inclusion of the environmental rebound effect has generally a non-negligible impact on the overall environmental indicators across all studied years. Such impacts ranging across impact categories from 5% (eutrophication) and 6,109% (photochemical oxidant creation) for the combined model, whereas for the single model the values fall on the ranges of 1% (eutrophication) and 9,277% (photochemical oxidant creation). Further, a sensitivity analysis of the elasticity price of the electricity and the price of the electricity reveals that the ERE varies in different ways, specifically, changes in these parameters could vary the impacts, respectively, by up to about <1% and 38%. Backfire effects are present for 8 of the 10 environmental impacts studied in different magnitudes across the years, depending meanly of the savings available to re-invest.
The overall aim of this thesis is to develop empirical probabilistic frameworks that help to quantify the impacts of temporal and spatial scale dependencies and model uncertainties of climate projections regarding precipitation-dependent parameters. The thesis is structured in four articles. Article one is the first study that analyzed climate projections from the spatially highly resolved regional climate model (RCM) ensemble EURO-CORDEX. Additionally, the significance and the robustness of the projected changes are analyzed, and improvements related to the higher horizontal resolution of the new data set are discussed. A major finding is, that RCM simulations provide higher daily precipitation intensities, which are missing in the global climate model (GCM) simulations, and that they show a significantly different climate change of daily precipitation intensities with a smoother shift from low towards high intensities. The second article elaborates on impacts of temporal and spatial aggregation on extreme precipitation intensities. By combining radar data with cloud observations, the different temporal and spatial scaling behavior of stratiform and convective type precipitation events can be analyzed for the first time. The separation between convective and stratiform type events also allows to quantify the contribution of convective events to the extremes. Further, it is shown that temporal averaging has similar effects on the precipitation distribution as spatial averaging. Associated pairs of temporal and spatial resolutions that show comparable intensity distributions are identified. Using precipitation data from radar observations, a gauge station network and a spatially highly resolved regional climate model, the third paper optimizes the process that finds associated temporal and spatial scales (see second article). This information is used to develop a method that adjusts point measurements to the temporal and spatial scale of a previously defined model grid. The study shows that this procedure can be used to improve bias-adjustment methods in areas with a low gauge station density. It is known that the EURO-CORDEX ensemble overestimates precipitation and shows a common cold bias in the Alpine region. The fourth article evaluates how these biases are changing the temperature distribution and the temperature dependency of precipitation-frequencies. These biases are a source of uncertainty that is not captured by the robustness tests performed in the first article. A probabilistic-decomposition-framework is developed to quantify the impact of these biases on precipitation-frequency changes and to investigate causes for the ensemble spread.
Excessive fertilizer use leads to nutrient imbalances and losses of these to the environment through leaching, runoff and gaseous emissions. Nutrient use efficiency (NUE) in agriculture is often low and improving it could increase the sustainability of agricultural systems. The main aims of this thesis were to gain a better understanding of plant-soil-microbe interactions in order to improve agricultural NUEs. The studies included experimentally tested how crops respond to addition of high carbon amendments, fertilizer application rates and timing, and crop rotations. Furthermore, methods for measurement of roots were compared and a protocol for measurement of roots was developed. The first experiment simulated an agricultural field using mesocosms. In this setting, the researchers tested the effect of 4 previous crops (precrops), which either had or did not have a symbiosis with arbuscular mycorrhizal fungi (AMF)/rhizobia, on the focal crop (winter barley). They also tested the addition of high carbon amendments (wheat straw/sawdust) for immobilization of residual soil nitrogen (N) at harvest of the previous crop. Overall, the findings were that non-AMF precrops had a positive effect on winter barley yield compared to AMF precrops. Wheat straw reduced N leaching, whereas sawdust addition had a negative effect on the yield of winter barley. The second experiment tested the effect of different fertilizer (N/phosphorus (P)) application timings on plant traits grown in rhizoboxes. Overall, delaying N application had a more detrimental effect on plant biomass than delaying P application. The root system increased its root length initially due to N-deficiency, but was quickly thus N-limited that root length was relatively lower than the control group. Because of the many root related measurements in the second experiment, a step-by-step method for measuring root traits under controlled and field conditions was developed and included in this thesis. This method paper describes precisely how root traits of interest can be measured, and helps with deciding which approach should be taken depending on the experimental design. Additionally, the authors compared the bias and accuracy of several popular root measurement methods. Overall, these results highlight the importance of crop choice in crop rotations and the plasticity of root systems in relation to nutrient application. The results show high carbon amendments could reduce nitrate leaching after the harvest of crops, especially those with high risk of nitrate leaching, although they had only small impacts on yield.
Both sustainability and transdisciplinary research can change academic research, especially with regard to its relevance for, and relationship with, its environments. Transdisciplinary sustainability research (TSR), thus, offers the opportunity to change non-sustainable development paths of sciences themselves. In order to fully exploit this possibility, this PhD project addresses the question of how TSR, in the first place, does conceptualize and, in the second place, could conceptualize knowledge, research, and science. Firstly, this PhD project analyzes, from a discourse studies perspective, the term problem in TSR, against the background of discourses on sustainable development. Secondly, it explores the historical-analytical and transformative concept of the problematic. The results, firstly, show the consequences of a problem-solving focus for TSR, and secondly, differentiate it from a transformative direction of problematic designing, as a more appropriate view on the dimensions of transformation and their qualities of change that matter for TSR. This PhD project aims to contribute to a self-understanding of, and a philosophical communication about, TSR, as a research form in the sustainability sciences.
Auf Grund der stetig wachsenden Menge an Daten gewinnt die automatische Datenanalyse durch Algorithmen zunehmend an Bedeutung. Im Speziellen trägt die Analyse von Texten ohne manuelles Zutun zu einer erheblichen Erleichterung der Extraktion von relevanten Informationen bei. Sprachliche Informationen können neben der Zuordnung zu Kategorien auf Regeln und Muster untersucht werden. Diese Art der Untersuchung fällt in den Bereich des Text Minings, und in der vorliegenden Arbeit geht es darum, eine qualitative Inhaltsanalyse zum Thema Nachhaltigkeit nachzuempfinden. Es soll geprüft werden, in wie weit automatisierte Verfahren in der Lage sind, Ergebnisse einer bereits bestehenden Untersuchung zu erzielen. In der Durchführung werden mit der Open Source-Software RapidMiner vier Prozesse erstellt, die darauf abzielen, Zeitungsartikel auf ihren Inhalt zu analysieren. Unter anderem werden eine Assoziationsanalyse und eine Klassifikation realisiert, deren Ziel es ist, den Kontext und die Verwendung des Begriffes der Nachhaltigkeit in den Medien zu untersuchen. Die vorliegende Studie will prüfen, ob automatisierten Methoden im Vergleich zu manuellen Verfahren hinreichende Ergebnisse liefern können, sodass die hiesigen Resultate an denen der zu Grunde gelegten Studie von Fischer und Haucke gemessen werden sollen. Die Ergebnisse zeigen, dass die Realisierung einer Inhaltsanalyse mit RapidMiner möglich ist und zu erheblichen Zeiteinsparungen gegenüber konventionellen Verfahren führt. Sie zeigen jedoch auch, dass sich die Minderung des Aufwandes in der Ergebnisqualität widerspiegelt und somit der alleinige Einsatz von Text Mining Verfahren zur Analyse von spezifischen Kontexten noch nicht ausreichend ist.
To respond to the challenges of the Anthropocene, scholars from various disciplines increasingly emphasize that a mere outer transformation is insufficient and that we also need an inner transformation that addresses deep leverage points. Yet, the open questions are how the inner and outer dimensions relate to each other and how inner transformation might lead to outer transformation. How we attempt to answer these questions is determined by our dominant paradigm. Paradigms define how we understand and shape the world, and thus, they define how we conceptualize challenges, such as inner and outer transformation. Various authors argue that the dominant paradigm, which is characterized by reductionism, empiricism, dualism, and determinism, might be a root cause for insufficiently addressing sustainability challenges. As an alternative, many argue for a relational paradigm, which understands complex phenomena in terms of constitutive processes and relations. A relational paradigm might offer possibilities to reconceptualize inner and outer transformation in the Anthropocene and might shed new light on how to integrate both in sustainability science. Yet, it is still being determined how a relational paradigm can contribute to the understanding of inner and outer transformations towards sustainability in the Anthropocene. Therefore, this dissertation's overarching scope is to contribute to systems change towards a more social-ecological future by generating insights into and exploring possibilities of a relational paradigm for inner and outer transformation in the Anthropocene. This thesis is divided into three sub-questions. The first research question aims to increase the theoretical understanding of a relational paradigm. The second research question aims to develop a transformative educational case study grounded in a relational, justice-oriented approach. The third research question aims to analyze how a relational paradigm might contribute to policies and practices for sustainable lifestyles. The results indicate that inner and outer transformation in the Anthropocene can be reconceptualized as paradigm-ing relationality in the Ecocene. "Paradigm-ing" as an active verb, reconceptualizes inner and outer transformation into ontologies, epistemologies, ethics, and socialecological realities that are ongoing, nonhierarchical, nonlinear, dynamic, co-creative processes of intra-action. The Ecocene decenters the human and attends to what we might be able to intra-actand become-with. These insights can offer unexplored perspectives to address sustainability challenges and increase our capacities to respond in novel ways.
Existing institutions no longer appear to be sufficiently capable to deal with the complexity and uncertainty associated with the wicked problem of sustainability. Achieving the required sustainability transformation will thus require purposeful reform of existing institutional frameworks. However, existing research on the governance of sustainability of sustainability transformations has strongly focused on innovation and the more "creative" aspects of these processes, blinding our view to the fact that they go hand with the failure, decline or dismantling of institutions that are no longer considered functional or desirable. This doctoral dissertation thus seeks to better understand how institutional failure and decline can contribute productively to sustainability transformations and how such dynamics in institutional arrangements can serve to restructure existing institutional systems. A systematic review of the conceptual literature served to provide a concise synthesis of the research on "failure" and "decline" in the institutional literature, providing important first insights into their potentially productive functions. This was followed up by an archetype analysis of the productive functions of failure and decline, drawing on a wide range of literatures. This research identified five archetypical pathways: (1) crises triggering institutional adaptations toward sustainability, (2) systematic learning from failure and breakdown, (3) the purposeful destabilisation of unsustainable institutions, (4) making a virtue of inevitable decline, and (5) active and reflective decision making in the face of decline instead of leaving it to chance. Empirical case studies looking at the German energy transition and efforts to phase out coal in the Powering Past Coal Alliance served to provide more insights on (a) how to effectively harness "windows of opportunity" for change, and (b) the governance mechanisms used by governments to actively remove institutions. Results indicate that the lock-in of existing technologies, regulations and practices can throw up important obstacles for sustainability transformations. The intentional or unintentional destabilisation of the status quo may thus be required to enable healthy renewal within a system. This process required active and reflective management to avoid the irreversible loss of desirable institutional elements. Instruments such as "sunset clauses" and "experimental legislation" may serve as important tools to learn through "trial and error", whilst limiting the possible damage done by failure. Focusing on the subject of scale, this analysis finds that the level at which failure occurs is likely to determine the degree of change that can be achieved. Failures at the policy-level are most likely to merely lead to changes to the tools and instruments used by policy makers. This research thus suggests that failures on the polity- and political level may be required to achieve transformative changes to existing power structures, belief-systems and paradigms. Finally, this research briefly touches on the role of actor and agency in the governance of sustainabilitytransformations through failure and decline. It finds that actors may play an important role in causing a system or one of its elements to fail and in shaping the way events are come to be perceived.
Ensuring food security and halting biodiversity loss are two of the most pressing global sustainability challenges. Attempts to identify pathways have been dominated with a biophysical-technical focus that provides technical solutions to the integration of food security and biodiversity conservation. The social-political dimension, however, including equity, governance, and empowerment received little to no attention. By focusing on the poorly investigated social-political dimension, this dissertation aimed to identify governance properties that facilitate and impede the integration of food security and biodiversity conservation through an empirical case study conducted in a multi-level governance setting of southwestern Ethiopia. To address the overarching goal of this dissertation, first the author examined how the existing widely discussed food security approaches and agricultural land use framework, land sparing versus land sharing unfold in the local context of southwestern Ethiopia. The finding in this dissertation indicated that the existing global framing of food security approaches as well as frameworks around agricultural land use has limited applicability in on-the-ground realities mainly because landscapes are complex systems that consist of stakeholders with multiple and (often) conflicting interests. This was evident from the finding that local land use preference was not a matter of "either/or", but instead involved mixed features exhibiting properties of both land sparing and land sharing. Moreover, in addition to the biophysical factors embedded in the existing food security approaches and land use frameworks, stakeholders preference involved social factors such as the compatibility of land use strategy with local values and traditions, which are mainly unaccounted in the existing global frameworks. Findings in this dissertation revealed that the existing reductionist analytical framings to the issues of food security and biodiversity conservation seldom address the complexity inherent within and between food security and biodiversity conservation sectors. Second, this dissertation identified governance structural and process related challenges that influence individual as well as integrated achievements of food security and biodiversity conservation goals. The result of the study showed that the governance of food security and biodiversity conservation was characterized by a strongly hierarchical system with mainly linear vertical linkages, lacking horizontal linkages between stakeholders that would transcend administrative boundaries. Furthermore, with regard to the governance process, three key and interdependent categories of governance process challenges namely, institutional misfit, the problem of interplay, and policy incoherence influenced the achievement of individual and integrated goals of food security and were identified. Given the interdependence of these governance challenges, coupled with the complexity inherent in the food security and biodiversity conservation, attempts to achieve the dual goals thus needs an integrative, flexible and adaptive governance system Third, to understand how food security and biodiversity conservation unfold in the future, the author explored future development trajectories for southwestern Ethiopia. Iterative scenario planning process produced four plausible future scenarios that distinctly differed with regard to dominating land use strategies and crops grown, actor constellations and governance mechanisms, and outcomes for food security and biodiversity conservation. Three out of the four scenarios focused on increasing economic gains through intensive and commercial agricultural production. In contrast, one scenario involved features that are widely considered as beneficial to food security and biodiversity conservation, such as agroecological production, diversification practices, and increased social-ecological resilience. In smallholder landscapes such as the one studied here, such a pathway that promises benefits for both food security and biodiversity conservation may need to be given greater emphasis. In order to ensure the integration of food security and biodiversity conservation, recognizing their interdependence and addressing the challenges in a way that fits with the local dynamics is essential. In addition, addressing the food security-biodiversity nexus requires a holistic analytical lens. Moreover, this dissertation indicated that there is a clear need to pay attention to the governance structure that accommodates the diversity of perspectives, enable participation and strong coordination across geographical boundaries, policy domains and governance levels. Finally, this dissertation revealed opportunities to integrate food security and biodiversity through the pro-active management of social-ecological interactions that produce a win-win outcome. The win-win outcome could be achieved in a system that involve properties such as diversification and modern agroecological techniques, smallholders empowerment, emphasize adaptive governance of social-ecological systems, value local knowledge, culture and traditions, and ensure smallholders participation.
A solid knowledge about nature is essential to understand the consequences of biodiversity loss, the limitation of natural resources and the need for a sustainable development. Inspired by these challenges, the researcher investigated in her dissertation seed predation, an important ecosystem function, as part of citizen science project. As seed predation has only rarely been investigated along urban-rural gradients and to integrate the question if the background (urban vs. rural) of primary school children affects their environmental knowledge, she selected study sites in and around Lüneburg and Hamburg, in Northern Germany. In her ecological experiments, it was found that slugs are important seed predators that independently of urbanization predated about 30% of all seeds in the anthropogenically used landscapes investigated. Also, for the first time, primary school children could be integrated in a citizen science approach into this research and it could be shown that even seven year old children can record data as reliable as a scientist. Finally, the researcher investigated the native species knowledge from the children taking part as citizen scientists in her research, considering possible differences due to their urban or rural background. Contrary to her expectation, the urban or rural background had no significant effect on the species knowledge. However, the work provides a good foundation to transfer the approach of introducing a basic foundation of a taxonomical species concept in primary school to foster further understanding on biodiversity and ecosystem functions.
Over the past two decades, transitions research has witnessed rapid development. However, there is still a notable gap in our understanding of sustainability transitions in conflict settings and the role of international organizations in these transitions. Little is known about the dynamics of power, limiting and facilitating factors, and the role of (international) actors in sustainability transitions in conflict settings. This dissertation seeks to make contributions to these discussions by examining energy transitions in Afghanistan, a conflict-affected country, between 2001 and 2021. It specifically focuses on the involvement of international development organizations, shedding light on their role in energy access, institutional change, and imagining Afghanistan's future energy system development. After security, access to affordable energy is frequently reported to be Afghanistan's most pressing need. Following the fall of the first Taliban regime in 2001, billions of dollars and dozens of international development organizations poured into Afghanistan to support the reconstruction of the country including its energy sector. Between 2001 and 2021, the government of Afghanistan and the international development organizations worked on various aspects of energy system development despite on-going insurgency and threats against infrastructural projects. In 2021, the Taliban regained power, resulting in the suspension of operations for most development organizations, with only a few humanitarian agencies remaining active. Within this context, this thesis explores topics such as the country's energy potential and policy, the role of international development organizations in the energy sector, and visions for a future energy system in Afghanistan. The research conducted for this thesis employed a qualitative case study approach, utilizing semi-structured interviews and document analysis.
Aufgrund ihrer Struktur sind insbesondere urbane Strukturen von Klimafolgen wie z.B. Hitze, Stürme oder Starkregen betroffen. Der Raum- und Umweltplanung kommt dabei hinsichtlich der sozial-ökologischen Naturverhältnisse eine wichtige Rolle zu, sofern sie die Aufgaben der Krisenbewältigung annehmen und verantwortungsvoll wahrnehmen will. Auch die Hansestadt Lüneburg steht zukünftig vor einigen Herausforderungen. Durch den allgemeinen Trend der Urbanisierung und als Teil der Metropolregion Hamburg gilt Lüneburg als beliebter Wohnraum. Die vorliegende Arbeit lenkt den Blick auf die Klimafolgenanpassung bei Starkregen in der Stadtplanung allgemein und auf die Hansestadt Lüneburg. Zunächst werden die der Ausarbeitung zugrundegelegten Begriffe sowie die Bedeutung von Starkregenereignissen in der Stadtplanung definiert und näher erläutert. Darauf folgt die Darstellung der zur Beantwortung der Forschungsfrage verwendeten Methoden. Anschließend werden in der empirischen Forschung das bisherige Auftreten von Starkregen analysiert, bestehende Adaptionsstrategien norddeutscher Städte und Regionen aufgezeigt, ein Zukunftsausblick auf Grundlage wissenschaftlicher Prognosen gegeben und konkrete, auf die Hansestadt Lüneburg bezogene Analysen und Szenarien erstellt, bevor ein Resümee der empirischen Forschung gezogen werden kann. Abschließend wird das methodische Vorgehen reflektiert, die Ergebnisse diskutiert und ein kurzer Ausblick auf zukünftige Herausforderungen gegeben.
Um das noch bestehende Reichweitenproblem von Elektrofahrzeugen zu lösen, sind Fahrzeugkonzepte wie Plug-in Hybridfahrzeuge sehr vielversprechend, sofern mit ihm überwiegend im Batteriebetrieb gefahren wird. Sie kombinieren die Vorteile des Verbrennungsmotors und des Elektromotors, sodass das lokale Emissionsproblem in Ballungszentren gelöst werden kann, ohne dass der Kunde dabei auf die Reichweite verzichten muss. Wenn das Fahrzeug allerdings überwiegend für Kurzstrecken genutzt wird, sind alterungsbedingte Veränderungen des Kraftstoffes möglich, da dieser länger im Tank verbleibt als üblich. In dieser Arbeit wird ein Konzept zur sensorischen Bestimmung der Qualität des Kraftstoffes vorgestellt. Hierzu wurde ein Prototyp entwickelt, in dem mithilfe des Real- und Imaginärteils der Permittivität alternde Kraftstoffe erkannt werden können. Dabei konnte durch das frequenzabhängige Permittivitätssignal des Sensors spezifisch zwischen nieder- und hochmolekularen Oxidationsprodukten in Kraftstoffen unterschieden werden. Da das Verbrennungs- und Emissionsverhalten des Motors von der Kraftstoffmischung vorgegeben ist, bietet eine zusätzliche sensorische Erfassung der Kraftstoffzusammensetzung weitere Optimierungspotenziale, um Emissionen zu reduzieren: So ist das Motormanagement im Fahrzeug zumeist auf Referenzkraftstoffe mit gleichbleibender Qualität abgestimmt. Variable Kraftstoffzusammensetzungen, die durch die Erdöllagerstätte und den zusätzlichen Konversionsverfahren zur Herstellung von fortschrittlichen Kraftstoffen vorgegeben sind, werden in dieser Anpassungsstrategie bisher nicht berücksichtigt. Als weitere Aufgabe wird in dieser Arbeit daher ein multisensorischer Ansatz verfolgt, wonach zusätzlich zur Kraftstoffalterung noch die Kraftstoffzusammensetzung erkannt werden kann. Insgesamt bietet die Sensorik das Potenzial zur kontinuierlichen Kraftstoffüberwachung in Plug-in Hybridfahrzeugen, um so einen Beitrag zum sicheren und nachhaltigen Betrieb solcher Fahrzeuge gewährleisten zu können.
Seit den frühen 1990er Jahren wird transdisziplinäre Nachhaltigkeitsforschung in Form von problemorientierten Forschungs- und Lernprojekten konzeptioniert und praktisch umgesetzt, an denen außeruniversitäre Akteuren beteiligt sind. Diese Forschungsarbeit verfolgt drei Ziele: Erstens, die Konzeptualisierung der Begriffe Kultur, Multi-, Inter- und Transkulturalität in der Literatur zur transdisziplinären Nachhaltigkeitsforschung zu untersuchen. Zweitens, die Konzeptionierung und Umsetzung von transdisziplinären Forschungs- und Lernprojekten in Hinblick auf kulturelles Differenzieren zu analysieren. Drittens, konzeptionelle Beiträge zur Gestaltung von transdisziplinären Forschungs- und Lernprojekten zu entwickeln. Methodisch wird auf Literaturanalysen und eine qualitative Untersuchung zweier transdisziplinärer Lernforschungsprojekte zurückgegriffen. Unter dem Begriff Forschungs- und Lernprojekt werden in dieser Forschungsarbeit sowohl Forschungsprojekte als auch Lehr-Lernforschungsprojekte gefasst. Zentrale Ergebnisse der Forschungsarbeit sind die Folgenden: Erstens wird der Kulturbegriff in der transdisziplinären Nachhaltigkeitsforschung zwar vielfältig verwendet, als Forschungsthema, Hintergrund von Beteiligten, Kooperationsweise, Projektkontext, in Hinblick auf Interkulturalität oder als Wissenskultur, allerdings kaum ausdifferenziert und konkretisiert. Zweitens besteht auf der Ebene der Konzeptionierung von transdisziplinären Forschungs- und Lernprojekten: 1) ein starkes Übergewicht von Integration und Konsens gegenüber einer Auseinandersetzung mit Differenz, 2) eine implizite Vorauswahl von Beteiligten durch bestimmte Begrifflichkeiten und methodologische Ansätze und 3) eine Reproduktion von Machtverhältnissen durch (dichotome) Symmetrie- und Ausgleichsvorstellungen. Drittens zeigt sich auf der Ebene der Umsetzung von Lernforschungsprojekten: 1) eine starke Prozessorientierung der Projekte, 2) ein Spannungsfeld zwischen einer Öffnung und Steuerung in Hinblick auf den Projektverlauf und 3) vielfältige Differenzaushandlungen in Interaktionen (wie Zeitlichkeit, Verantwortung, Erfahrung, Relevanz). Die Ergebnisse zeigen, dass politische Implikationen der Forschung und zentrale Ungleichheitskategorien der Kultur- und Sozialwissenschaften (u.a. race, class, gender, body) kaum thematisiert werden. Vorschläge zur Gestaltung transdisziplinärer Forschungs- und Lernprojekte werden in Hinblick auf ein Verständnis von Forschungsdesigns als Prozesse, einem Erkunden von Differenzierungen und Forscherpositionen und der Bedeutung eines Verlernens entwickelt.
Diese Dissertation verfolgt einerseits das Ziel der umfassenden Sichtung der technischen, psychologischen, philosophischen und neurobiologischen Grundlagen der Künstlichen Intelligenz und damit die Etablierung einer epistemischen und ontologischen Eingrenzung der Technologie und andererseits das Ziel der moralphilosophischen Beurteilung und Risikobewertung. Die zentrale Hypothese unterstellt der Technologie, die überhaupt nur durch die rasanten Fortschritte der Natur- und Ingenieurwissenschaften und damit durch die Aufklärung ermöglicht wurde, eine Unterwanderung der zentralen Prinzipien und Werte der Aufklärung. Zu befürchten ist eine selbstverschuldete Unmündigkeit des Menschen durch die Künstliche Intelligenz. Wesentlich in der Argumentation ist das Aufgeben von menschlicher Autonomie zugunsten einer Technologie, die selbst nicht autonom sein kann, die Verlagerung von Verantwortlichkeiten in einen neu entstandenen rechtsfreien Raum, der Verlust der menschlichen Individualität und letztlich die Preisgabe der Menschenwürde durch den Übergang in ein "Reich ohne Notwendigkeit", aus dem es kein Entkommen gibt. Eine Ethik der Künstlichen Intelligenz muss, so die normative Schlussfolgerung, die Wahrung der menschlichen Autonomie, Verantwortlichkeit, Individualität und Würde in den Vordergrund stellen, sodass ein individueller und kollektiver Rückfall des Menschen in die Unmündigkeit verhindert wird.
Contemporary society is shaped by the idea that time is, above all, a scarce economic resource that must be used efficiently. Increasingly, however, scientific findings suggest that such a way of perceiving of time seems a major cause of the current global climate and sustainability crisis. Considerably less research work has been carried out in relation to the role of individual time-related needs regarding unsustainable consumption behaviour, although consumer research has been addressing needs-oriented approaches to sustainable consumption for a long time. Environmental and Sustainability Education (ESE) is considered an essential strategy to achieve the global sustainability goals of Agenda 2030. Internationally, as well as on a national level, ESE is increasingly mainstreamed in educational curricula and practice. Given the relation between time, needs and sustainability, it appears valuable to inquire into this field from the perspective of ESE. The core research interest of this cumulative dissertation is therefore the question of how the connection between time, our needs and sustainability can be conveyed through pedagogical approaches. The inquiry used an exploratory, qualitative research design to address this question. In a first step, the concept of sustainability-related time use competence was developed. This then served as a guiding concept for the understanding of time used in this work and as the overall objective for the educational intervention developed and piloted as part of the research. Next, a content analysis of German curricula was conducted with the aim of determining whether and to what extent these address the relation between time and sustainability. The results show curricula contain only a few starting points that encourage a connection between time and sustainability in school lessons. The study further indicates that an understanding of time as a scarce resource to be used efficiently has prevailed in school contexts so far. The next step involved developing and piloting a time use competence curriculum in cooperation with three partner schools, using an Action Research Approach. This intervention followed the pedagogical approach of Self-Inquiry Based Learning (SIBL) seeking to sensitise learners to the relation between individual needs and consumer behaviour. During implementation, which lasted one semester, students logged their time, were encouraged to reflect on their personal needs, and subsequently implement individual change projects related to time use. This was embedded in continuous reflective individual and group exercises. The results strengthen the hypothesis that there is a relation between time use and sustainability. Furthermore, the pedagogical approach of SIBL has proven suitable to enable students to reflect on their time use and to raise their awareness of the role of individual needs. Participants reported that changes in time use did indeed increase their personal well-being. A third empirical study was carried out, inquiring into students' time use during the period of COVID-19-induced school closures, using a Grounded Theory Approach. Since the pandemic disrupted young peoples' routines drastically, the research focused on which kinds of learning experiences students made during this time and which insights can be derived for ESE. The results of the semi-structured interviews with 69 participants show first that a variety of learning experiences are revealed, such as learning one's own learning and everyday rhythms or creatively adapting consumption habits to the new situation of "lockdown". Overall, a key finding of this work is that students are currently unable to adequately realise their time-related needs. In view of the findings from research on time and sustainability, one recommendation is therefore that everyday school life could give students more space to organise their time according to their needs. Furthermore, it would be advisable to give the topic of time in connection with sustainability more space in curricula and in teacher training. The experiences during the pandemic have shown that schools and all actors involved including students and teachers, are so far insufficiently prepared to handle crises. Here, the approach to time use competence piloted in this work can offer valuable stimulations for ESE research and practice. This is especially true since it is compatible with existing approaches to key competencies for sustainability by seeking to complement them with a stronger focus on individual, needs-oriented time shaping.
This dissertation examines how smallholder farming livelihoods may be more effectively leveraged to address food security. It is based on empirical research in three woredas (districts) in the Jimma Zone of southwestern Ethiopia. Findings in the chapters that follow draw on quantitative and qualitative data. In this research, the author focuses on local actors to investigate how they can be better supported in their roles as agents who have the ability to improve their livelihoods and achieve food security. This general aim is operationalized through three research questions: (i) How do livelihood strategies influence food security?; (ii) What livelihood challenges are common and how do households cope with these?; and (iii) How do social institutions, in which livelihoods are embedded, influence people's abilities to undertake livelihoods and be food secure? Using quantitative data from a survey of randomly selected households, the author applied a number of multivariate statistical analysis to determine types of livelihood strategies and to establish how these strategies are associated with capital assets and food security. Here she views livelihood strategies as a portfolio of livelihood activities that households undertake to make a living. The predominant livelihood in the study area was diversified smallholder farming involving mainly the production of crops. Based on their analyses, the authors found five types of livelihood strategies to be present along a gradient of crop diversity. Food security generally decreased with less crops being part of the livelihood strategy. The livelihood strategies were associated with households' capital assets. The status of food (in)security of each household during the lean season was measured using the Household Food Insecurity Access Scale (HFIAS). A generalized linear model established that the type of livelihood strategy a household undertook significantly influenced their food security. Other significant variables were educational attainment and gender of household head. The findings contribute evidence to the benefits of diversified livelihoods for food security. Smallholder farming in southwest Ethiopia is beset with process-related and outcome-related challenges. Here, a process-related challenge pertains to the lack of different types of capital assets that people need to be able to undertake their livelihoods, while an outcome-related challenge pertains to lack of food. The most frequently mentioned process-related challenges were associated with the natural capital either as lack in necessary ecosystem services or high levels of ecosystem disservices. Farming households typically faced the combined challenges of decreasing soil fertility, land scarcity, die-off of oxen due to diseases, and wild animal pests. Lack of cash was also common. The findings indicate that when households liquidate a physical asset in order to gain cash, the common outcome is an erosion of their capital asset base. On the other hand, when households drew on their social capital, they tended to maintain their capital asset base. Human capital, for example, in the form of available labor was also important for coping. Protecting and enhancing natural capital is needed to strengthen the basis of livelihoods in the study area, and maintaining social and human capitals is important to enable farming households to cope with challenges without eroding their capital asset base. Smallholder farming in southwest Ethiopia is embedded in a social context that creates differentiated challenges and opportunities. Gender is an axis of social differentiation on which many of the differences are based. The currently ruling Ethiopian political coalition has put important policy reforms in place to empower women. Local residents reported notable changes related to gender in the last ten years. To make sense of the changes, the authors adapted the leverage points concept. Using this concept, the authors classified the reported changes as belonging to the domains of visible gaps, social structures, and attitudes. Importantly, changes within these domains interacted. The most prominent driver of the changes observed was the government's emphasis on empowering women and government-organized interventions including gender sensitization trainings. The changes toward more egalitarian relationships at the household level were perceived by local residents to lead to better implementation of livelihoods, and better ability to be food secure. The study offers the insight that while changing deep, underlying drivers (e. g. attitudes) of systemic inequalities is critical, other leverage points such as formal institutional change and closing of certain visible gaps can facilitate deeper changes (e. g. attitudes) through interaction between different leverage points. This can inform gender transformative approaches. While positive gender-related changes have been observed, highly unequal gender norms still persist that lead to women as well as poor men being disadvantaged. Social norms which provide the basis for collective understanding of acceptable attitudes and behaviors are entrenched in people's ways of being and doing and can therefore significantly lag behind formal institutional changes. Norms influenced practices around access and control of capital assets, decision-making, and allocation of activities with important implications for who gets to participate, how, and who gets to benefit. To more effectively leverage smallholder farming for a food secure future, this dissertation closes with four key insights namely: (1) Diversified livelihoods combining food and cash crops result in better food security; (2) Enhancing natural and social capital is a requisite for viable smallholder farming; (3) Social and gender equality are strategically important in improving livelihoods and food security; and (4) Institutions particularly social norms are key to achieving gender and social equality.
The Sustainable Development Goals (SDGs) recognize the importance of the inextricable link between social and ecological systems and human quality of life (QoL) and biodiversity. Therefore, understanding the feedback and interactions between biodiversity, nature’s contributions to people (NCP), and QoL plays a central role in advancing toward sustainability. In this context, the social-ecological systems (SES) approach has advanced on the subject, particularly in recent decades; however, much remains to be done to comprehensively understand these relationships and interactions, especially at local decision-making scales. In this thesis, through the lenses of the SES approach, the researcher investigates connections between biodiversity, NCP, and QoL in a tropical dry forest (TDF) on the Western coast of Mexico. This place is one of the best-known Neotropical TDF and has been the focus of SES research in the past 20 years, making it an excellent case study for exploring these connections. First, to approach the need for dialogue among different global and local scales and between global and local frameworks, the thesis identifies five key components of the SES dynamics-(1) ecological supply, (2) co-production of NCP, (3) management, (4) demand, and (5) benefits - and three local decision-making scales of analysis: individual plot, smallholder, and land tenure or governance units. A literature review was performed on the social-ecological indicators for the last 11 years in the Chamela-Cuixmala region to operationalize this framework. Second, this thesis uses social-ecological information to identify social-ecological systems units (SESU) spatially explicitly. A methodology was provided to spatially identify the components of social-ecological systems that environmental conditions and management practices have shaped at three previously stated relevant decision-making scales: plots owned by individuals, plot owners, and governance units. To do so, the research group identified and characterized: (1) ecological clusters (EC), (2) social-management clusters (SC), and (3) SESU in a TDF in western Mexico. The findings suggested that decision-makers (ejidatarios, i.e., type of ownership (related to agrarian reform), that in most cases the land allocated is small-smallholders) are bounded by the topographical characteristics and the public policies that determine communal (or private) governance and the number of resources available to them. Finally, the thesis examines the self-perceived QoL across the different SESU, finding 48 QoL items, which were grouped into six categories: 1) social capital, 2) economic capital, 3) agency, 4) nature, 5) peasant non-work activities, and 6) government and services; and two additional dimensions referred to obstacles and enablers of QoL. The researchers found that the more land cover transformation, the more enablers, and obstacles of QoL are identified; emphasis was put on economic capital to achieve QoL. As management is intensified and governance fosters individualism across SES, the higher the Current Welfare Index, and the lower the self-perceived material and non-material satisfaction.
Sustainability transitions research proposes fundamental changes of societal systems' organisation to overcome persistent societal challenges, such as climate change or biodiversity loss, and allowing systems to become more sustainable. This thesis adresses an underlying tension in sustainability transitions research: between transitions as an open-ended process of fundamental change and the normative direction of this change: sustainability. In doing so, three themes are in the focus of the research: individual agency, normativity and transdisciplinary collaboration. Thereby, the thesis aims to strengthen process-oriented and potentially transformative approaches to sustainability transition research, in contrast to primarily descriptive-analitical approaches. Transition management as a recent and salient example of transdisciplinary transition research is chosen to provide research framework and application context. Based on conceptual-theoretic, empirical case study and reflexive work, three main results are contributed: First, a psychologically enriched understanding of individual and sustainability related agency in conceptual and empirical understandings of transition management is developed. This builds on two perspectives: a psychologically enriched capability approach as well as the analysis of social effects (social learning, empowerment and social capital development) of transition management to capture sustainability oriented agency increases. As second main result, normative considerations, namely sustainability, are included into transition management on conceptual and empirical levels. Therein, substantive, procedural and intentional aspects of sustainability are combined: Substantive aspects are covered by proposing capabilities, behavioral freedoms to live a valuable life, as normative yardsticks to measure developments. Procedural aspects include a detailed understanding of facilitating a learning journey towards making sustainability meaningful in the local transition management cases and setting up experiments for its realiziation. Intentional aspects are addressed by linking social effects of transition management to awareness, motivations and feelings of responsibility towards sustainability. As a third main result, the transdisciplinary collaboration in transition management of creating an arena as an interactive learning space is conceptualized and explored, as well as the roles of the researchers therein. Key issues of this learning space, the community arena, are drawn out and ideal-type roles and activities of researchers in addressing these issues are proposed and empirically analysed. As synthesis of thesis results, ten principles of sustainability transition management are proposed.
As modern society progresses, waste treatment becomes a pressing issue. Not only are global waste amounts increasing, but there is also an unmet demand for sustainable materials (e.g. bioplastics). By identifying and developing processes, which efficiently treat waste while simultaneously generating sustainable materials, potentially both these issues might be alleviated. Following this line of thought, this dissertation focuses on procedures for treatment of the organic fraction of waste. Organic waste is a suitable starting material for microbial fermentation, where carbohydrates are converted to smaller molecules, such as ethanol, acetic acid, and lactic acid. Being the monomer of the thermoplastic poly-lactic acid, lactic acid is of particular interest with regard to bioplastics production and was selected as target compound for this dissertation. Organic waste acted as substrate for non-sterile batch and continuous fermentations. Fermentations were initiated with inoculum of Streptococcus sp. or with indigenous consortium alone. During batch mode, concentration, yield, and productivity reached maximum values of 50 g L−1, 63%, and 2.93 g L−1 h −1. During continuous operation at a dilution rate of 0.44 d−1, concentration and yield were increased to 69 g L−1 and 86%, respectively, while productivity was lowered to 1.27 g L−1 h −1 . To fully exploit the nutrients present in organic waste, phosphate recovery was analyzed using seashells as adsorbent. Furthermore, the pattern of the indigenous consortium was monitored. Evidently, a very efficient Enterococcus strain tended to dominate the indigenous consortium during fermentation. The isolation and cultivation of this consortium gave a very potent inoculum. In comparison to the non-inoculated fermentation of a different organic waste batch, addition of this inoculum lead to an improved fermentation performance. Lactic acid yield, concentration, and molar selectivity could be increased from 38% to 51%, 49 g L−1 to 65 g L−1, and 46% to 86%, respectively. Eventually, fermentation process data was used to perform techno-economic analysis proposing a waste treatment plant with different catchment area sizes ranging from 50,000 to 1,000,000 people. Economically profitable scenarios for both batch and continuous operation could be identified for a community with as few as 100,000 inhabitants. With the experimental data, as well as techno-economic calculations presented in this dissertation, a profound contribution to sustainable waste treatment and material production was made.
The emergence of sustainability as a guiding principle for tourism development came along with needs to introduce instruments that can monitor the actual impacts of tourism. Sustainability assessments in tourism (SAT) have gained popularity in recent years with a range of measurement schemes being introduced for national and subnational tourism destinations. With the help of sustainability indicators these schemes intend to guide decision-makers in making better evidence-informed decisions and to improve the overall sustainability performance of tourism. With this dissertation, the author aims to contribute to a deeper understanding of the implementation and performance of sustainability assessments, by linking transformative needs of tourism with necessary assessment approaches that can serve as effective instruments for a shift towards a more sustainable tourism development. Thus, the research is part of recent efforts to establish profound and effective measurement approaches for sustainable tourism. The author employs a mixed-methods approach combining qualitative, quantitative, set-theoretic, and review methods, with the aim of maximising the validity of results. First, he explores the general progress and current state of research on sustainability assessments in tourism, with the intention to identify patterns, key elements and research gaps within assessment approaches This is followed by subsequent detailed analyses that examine specific environmental and socio-economic sustainability issues with the aim of providing conceptual, methodological and empirical solutions for assessing them in detail. The dissertation highlights that concrete assessment tools are needed for evidence-informed decision-making and the establishment of effective actions in destination management. The findings indicate that assessments will be more successful in terms of serving as tools for decision-making, if they tackle main drivers of change and encourage management or policymakers to take decisions that affect multiple sustainability issues. It also reviews different concepts and accounting principles and rises awareness of a cautious selection of methods and measurement approaches, as this may affect overall results. The thesis empirically evaluates and applies different measurement approaches in specific destinations, with the help of quantitative and qualitative data collection methodologies. In general, my thesis provides further clarification about key environmental and socio-economic measurement methodologies, which supports ongoing debates about sustainability impacts of tourism. Thus, the research contributes to knowledge, frameworks, methodologies and practical application for tourism governance and tourism sustainability science.
Ein wesentlicher Beitrag zur rationalen Verwendung unserer Energieresourcen kann durch die konsequente Nutzung diskontinuierlich anfallender Wärmeenergie erbracht werden, was aufgrund der zeitlichen Verschiebung von Wärmeangeboten und Wärmebedarf auf direktem Wege oft nicht möglich ist. Dies gilt sowohl für die Nutzung anfallender Abwärme aus Kühlprozessen als auch den ökonomiaschen Einsatz von Solarenergie. Dazu ist erforderlich, mit Hilfe eines effizienten Energiespreichers den überschüssigen Energieanfall zu verlagern.
The emission of anthropogenic trace substances into the aquatic environment continuously poses challenges to water suppliers. The contamination of raw waters with organic trace substances requires complex water treatment processes to secure drinking water quality. The routine monitoring of these raw waters as well as the behavior and fate of organic trace substances during different treatment processes is of great interest to recognize and counter potential dangers at an early stage. Non-target screening using liquid chromatography coupled to high-resolution mass spectrometry (LC-HRMS) allows the detection of thousands of compounds within a single run and covers known as well as unknown substances. Compared to the established analytical techniques, this is a decisive advantage for the monitoring of raw and process waters during water treatment. While the analytical technique LC-HRMS has undergone significant developments in recent years, the algorithms for data processing reveal clear weaknesses. This dissertation therefore deals with reliable processing strategies for LC-HRMS data. The first part of this work seeks to highlight the problematics of false positive and false negative findings. Based on repeated measurements, various strategies of data processing were assessed with regard to the repeatability of the results. To ensure that real peaks were barely or not removed by the filtering procedure, samples were spiked with isotope-labeled standards. The results emphasize that the processing of sample triplicates results in sufficient repeatability and that the signal fluctuation across the triplicates emerged as a powerful filtering criteria. The number of false positives and false negatives could be significantly reduced by the developed strategies which consequently improve the validity of the data. The second part of this thesis addresses the development of processing strategies particularly aimed at assessing water treatment processes. The detected signals were tracked across the treatment process and classified based on their fold changes. A more reliable signal classification was achieved by implementing a recursive integration approach. Special integration algorithms allow a reliable signal classification even though the signal to be compared was below the intensity threshold. Different combinations of replicates of process influents and effluents were processed for evaluating the repeatability. The good repeatability was indicated by the results of both the plausibility checks and the ozonation process (ozonation of pretreated river water) and thus points to high reliability. The applicability of the developed strategies to real world applications is demonstrated in the last part of this work. Besides the prioritization of the generated results, the main focus was the identification of recognized compounds. The developed strategies clearly improve the validity of the underlying data. The combination of LC-HRMS analysis with reliable processing strategies opens up multiple possibilities for a more comprehensive monitoring of water resources and for the assessment of water treatment processes. The processing strategies and validation concepts may be easily transferred to other research fields.
Misophonia in the workplace
(2021)
This paper uses the UN’s Sustainable Development Goals’ inclusion of human well-being and disability rights as a base to examine the work experiences of individuals with the syndrome misophonia who have been employed in white-collar office jobs in the Global North, and how these experiences fit into the current discourse on making offices more inclusive and sustainable. It reports on common workplace triggers, coping mechanisms, and the condition’s perceived effects on misophonics, as well as the perceived barriers and carriers to making workplaces more accommodating to those with the condition. A mixed-methods approach was used to address these points. First, a survey was distributed virtually and 203 responses from misophonics who work(ed) in white-collar office jobs in the study region were collected. Next, ten of these survey takers participated in semi-structured, one-on-one interviews, which were then analyzed using qualitative text analysis. The results showed that many misophonics frequently encounter intense triggers (such as mouth sounds) at the office and that self-perceived levels of productivity, well-being, and workplace sociability can be adversely affected. Though opinions on bans of certain behaviors and items and on certain terminology were diverse, there was consensus on desiring more flexible policies, understanding from others, and quiet or private working spaces, including working from home. Lack of misophonia awareness within the general populace, human resources (HR), upper management, and to some degree, the medical community was identified as a persistent barrier to misophonic employees disclosing or asking for reasonable accommodations even when they felt their misophonia was severe, negatively affected them, and there were provisions that could support them. These experiences were similar to those of other invisible conditions and pointed to the need for workplaces striving to be more sustainable and inclusive to adapt their policies and office design decisions.
In der transdisziplinären Nachhaltigkeitsforschung sollen mit partizipativen Forschungsansätzen Lösungen für einen gesellschaftlichen Wandel hin zur Nachhaltigkeit generiert werden. Allerdings fehlen bisher Begründungen und Belege für die Erwartungen, die mit der Partizipation verbunden werden, und auch die mangelnden gesellschaftlichen Veränderungen durch die transdisziplinäre Nachhaltigkeitsforschung wurden kritisiert. Gleichzeitig legen Forschungen aus dem Feld der governmentality studies nahe, dass partizipative Prozesse auch ein gewisses Risiko bergen, Herrschaftszustände aufrechtzuerhalten. Um einen Wandel hin zur Nachhaltigkeit zu befördern, sollen in dieser Arbeit daher mit der Regierungskonzeption von Michel Foucault die Ausgestaltung der Partizipation in der transdisziplinären Nachhaltigkeitsforschung untersucht werden und insbesondere inwieweit diese stabilisierend für die gesellschaftlichen Verhältnisse wirken kann. Dementsprechend wird die transdisziplinäre Nachhaltigkeitsforschung auf Übereinstimmungen und Unterschiede zur neoliberalen Gouvernementalität untersucht und die Implikationen des Ergebnisses vor dem Hintergrund eines an den Brundtland Berichts angelehnten Nachhaltigkeitsverständnisses diskutiert. Die Untersuchung zeigt starke Parallelen zwischen der transdisziplinären Nachhaltigkeitsforschung und einer neoliberalen Regierungsweise. Auch wenn diese Regierungsweise durchaus Vorteile mit sich bringt, gibt es doch Anzeichen, dass sie, und damit auch die transdisziplinäre Nachhaltigkeitsforschung, dazu neigt, soziale Ungleichheit zu verstärken und strukturelle Gründe für Armut und die Zerstörung der natürlichen Lebensgrundlage zu vernachlässigen. Dies würde den Hauptmotiven des Nachhaltigkeitsverständnisses entgegenwirken.
Im Kontext der Problematik von Fehlinformationen in der populärwissenschaftlichen Literatur widmet sich diese Arbeit in einer Fallstudie drei häufig verkauften Büchern Peter Wohllebens. Untersucht wird, wie nah diese Werke sich am aktuellen Stand der Forschung orientieren und wie gut die getätigten Aussagen nachvollziehbar sind. Für die Untersuchung wurde der Inhalt der Bücher codiert und die resultierenden 8899 Codiereinheiten quantitativ und qualitativ-vergleichend analysiert. Ergänzt wurde dies durch die qualitativ-vergleichende Analyse von drei Schwerpunktthemen. Aus den Ergebnissen wird geschlussfolgert, dass Wohllebens Nähe zum wissenschaftlichen Diskurs unter Einschränkungen ausreichend und die Nachvollziehbarkeit seiner Aussagen mangelhaft ist. Basierend auf diesen Erkenntnissen werden mögliche Maßnahmen und Handlungsfelder für eine Erhöhung der wissenschaftlichen Qualität populärwissenschaftlicher Werke diskutiert. Es werden weitere potentielle Forschungsmöglichkeiten für ein besseres Verständnis der Situation in den Populärwissenschaften identifiziert und vorgeschlagen.