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Since the early 2000s, ecosystem services strongly gained significance as a research topic. However, the temporal dimension of ecosystem services has not been taken into consideration, although this should be the basis for a sustainable long-term management of ecosystems and their services. Therefore, the author presents three articles in this thesis that deal with temporal aspects of ecosystem services. In two of them she also present a proposal for a framework for the classification of ecosystem services based on their temporal dynamics. In this dissertation she differentiates between two types of temporal aspects, both of which have in common that change takes place over a certain period of time. The concepts of transformation, transition and regime shift are used to describe changes in social or ecological systems as a whole, for example the transformation towards a more sustainable society. The temporal dynamics, on the other hand, relate to the temporal changes in ecosystem services themselves. The first article focuses on how the literature on ecosystem services incorporates social and ecological change. The second and third articles deal with the temporal dynamics of ecosystem services. While the second article presents a preliminary framework for categorizing the temporal dynamics of ecosystem services, the third article uses this framework to test how the temporal dynamics of ecosystem services are represented in the literature. Based on the insights from the three articles, the author concludes that most of the studies on ecosystem services only focus on one point in time. One reason for this is that most studies are conducted over a maximum of a four-year time span which does not allow to monitor dynamics over longer time spans.
The importance of a social perspective on the relationships between humans and nature has longbeen acknowledged. The field of social-ecological systems research in particular is striving toachieve a holistic understanding of human-nature relationships by balancing social andecological perspectives. Here I sought to develop a social understanding of the Saxon area inCentral Romania, by exploring aspects of human-nature relationships as seen from theperspective of local people. To this end, I employed the concepts of social-ecological systems(SES), ecosystem services (ES) and cultural landscapes to assess perceptions of locals throughempirical case studies.I first conducted a literature review to acquire an overview of a particular type of human-naturerelationship mediated by non-consumptive use and non-use values (“cultural ecosystemservices”). Second, to isolate and address the interaction from the social system to the ecologicalsystem, I investigated the different ways locals perceived the role of landscapes in SouthernTransylvania. I conceptually mapped these landscape preferences by revealing their potentialland use and management implications. Third, to approach the human-nature relationship fromthe ecological system to the social system, I studied the flow of ES to disaggregated humanbeneficiaries. Specifically, I studied which factors, beyond ecosystem processes and functions,influenced nature derived human well-being from the perspective of potential beneficiaries. Iconceptualised the mediating role of a range of contextual factors underpinning the currentdistribution of ES, with regard to the relation between ES and human well-being. Fourth, inorder to explore an example of bidirectional human-nature relationship, I studied the particularcase of human-carnivore coexistence and the suite of mechanisms shaping it.Despite building throughout this thesis a more complex and in-depth understanding of the humandimensions of the studied system, I chose four main cross-cutting themes to explain the human-nature connection in Southern Transylvania. These four themes may serve as pillars of a sociallyminded understanding, as well as potential research and policy foci. First, the values held bylocals are key for understanding the endemic human-nature relationships and should not beoverlooked in future social-ecological assessments or policy interventions. Second, the culturallandscape of Southern Transylvania is both a physical and virtual space of social-ecologicalinteraction fostering human-nature experiences and social-ecological knowledge integration.Third, the identified diversity of the social system in terms of landscape aspirations and ESbeneficiaries is expanding the range of human-nature connections, but at the same time, may infuture be a source of conflict or disconnection if not managed appropriately. Finally, small-scalefarmers, through their interactions with the land and resultant belief system, play a major role inmaintaining the human-nature relationships, but their values and lifestyle are threatened.
Many fewer women than men try the entrepreneurial way in Germany. Any explanation for this phenomenon must be complex, as many factors are relevant for its production. Among other things, it is possible to speculate on sexual/gender discrimination, on more or less voluntary decisions of women or on different starting conditions for potential entrepreneurs. We assume that these options are closely related. This paper will concentrate, though, on the third alternative. Its focus will be set on the “family field,” or more precisely, on the role of family law in hindering women from trying self-employment. The family field in Germany has not evolved in the sense of gender equality along with all other areas of society - e.g., entrepreneurship. No gender equality is possible if the family field is not part of it. This paper analyses causes and consequences for this phenomenon.
Key Words: Gender studies, Family Law, Entrepreneurship, chance equality, social sustainability
To improve the properties of thermochemical heat storage materials, salt mixtures were evaluated for their heat storage capacity and cycle stability as part of the innovation incubator project "Thermochemical battery" of the Leuphana university Lüneburg. Based on naturally occurring compound minerals, 16 sulfates, 18 chlorides and 5 chloride multi-mixtures, 18 bromides and 5 intermixtures between sulfates, chlorides and bromides were synthesized either from liquid solution or by dry mixing for TGA/DSC screening before continuing the heat storage evaluation with five different measurement setups at a laboratory scale. The TGA/DSC analysis served as a screening process to reduce the number of testing materials for the upscaled experiments. The evaluation process consisted of a three-cycle dehydration/hydration measurement at Tmax=100°C and Tmax=200°C. In case of the bromide samples a measurement of hydration conditions with Tmax=110°C and a water flow at e=18.68mbar, were added to the procedure to detect the maximum water uptake temperature. Also, a single dehydration to a temperature of Tmax=500°C was implemented to observe melting behavior and to easier calculate the samples’ stages of hydration from the remaining anhydrous mass. Materials which showed high energy storage density and improved cycle stability during this first evaluation were cleared for multi-cycle measurements of 10 to 25 dehydration and hydration cycles at Tmax = 100 to 120°C and the evaluations at m=20 to 100g scale. An estimate for the specific heat capacities at different temperatures of the materials which passed the initial stage was calculated from the TGA/DSC results as well. The laboratory scale measurement setup went through five stages of refining, which led to reducing the intended maximum sample mass from m=100g to m=20g. A switch from supplied liquid water to water vapor as the used reactant was also implemented in exchange for improved dehydration conditions. Introducing a vacuum pump for evaporating the water limited the influence of outside heat sources during hydration and in-situ dehydration was enabled as to not disturb the state the samples were settling in between measurements. Baseline calculation from blanc measurements with glass powder and attempts to calculate the specific heat capacity cp of the tested materials by 6 applying the Joule-Lenz-law to the measurement apparatus was another step of method development. The evaluation process of the laboratory scale tests at the final setting consisted of 1 to 5 cycle measurements of in-situ dehydration and hydrations with applied vacuum for t=30 minutes at p~30mbar. Upscaling the sample mass to m=20g allowed for a close observation of different material behaviors. Agglomeration, melting and dissolving of the m=10mg samples during the TGA/DSC analysis can be deducted from the recorded measurement curves and the state of the sample after measurement. However, at laboratory scale the visible volume changes, observed sample consistency after agglomeration and an automatic removal of molten and dissolved sample mass during the measurement allowed for a better characterization and understanding of the magnitude of the actual changes. This was done for the first time, particularly for mixed salts. Of the original number of 62 samples, 4 mixtures which passed the initial TGA/DSC screening namely {2MgCl2+ KCl}, {2MgCl2+CaCl2}, {5SrBr2+8CaCl2} and {2ZnCl2 + CaCl2} were chosen for further evaluation. The multi-cycle TGA/DSC measurements of {2MgCl2+ KCl}, {2MgCl2+CaCl2} and {5SrBr2+8CaCl2} showed an improved cycle stability for all three materials over the untreated educts. Of the four materials {2ZnCl2 + CaCl2} displayed the strongest deliquescence during hydration in the upscaled experimental setup. {2MgCl2+CaCl2} proved to be the most stable material regarding the heat storage density. The {MgCl2} content of the mixture is likely to partially or completely react to {Mg(OH)Cl} at temperatures of T>110°C, which however does not impede the heat storage density. {5SrBr2+8CaCl2} displayed a low melting point in hydrated state, causing a fast material loss. This makes it an undesirable storage material. A lower heating rate may still help to avoid an early melting. The {2MgCl2+KCl} mixture was the most temperature stable of the mixtures showing no melting or dissolving behavior. A reaction of the {MgCl2} component of the mixture to {Mg(OH)Cl} was not observed within the applied temperature range of T=25 to 200°C.
Abstract. The ecological literature suggests that biodiversity reduces the variance of ecosystem services. Thus, conservative biodiversity management has an insurance value to risk-averse users of ecosystem services. We analyze a conceptual ecological-economic model in which such management measures generate a private benefit and, via ecosystem processes at higher hierarchical levels, a positive externality on other ecosystem users. We find that ecosystem management and environmental policy depend on the extent of uncertainty and risk-aversion as follows: (i) Individual effort to improve ecosystem quality unambiguously increases. The free-rider problem may decrease or increase, depending on the characteristics of the ecosystem and its management; in particular, (ii) the size of the externality may decrease or increase, depending on how individual and aggregate management effort influence biodiversity; and (iii) the welfare loss due to free-riding may decrease or increase, depending on how biodiversity influences ecosystem service provision.
In 1999 David Elstein delivered a lecture series examining the evolvement of UK broadcasting policy from 1949 to 1999. His sharp analysis is a valuable contribution to the post-war devel-opment of the British broadcasting system and unfolds many topical issues in current media policy debates.
An empirical analysis of various waves of the ALLBUS social survey shows that union density fell substantially in western Germany from 1980 to 2004 and in eastern Germany from 1992 to 2004. Such a negative trend can be observed for men and women and for different groups of the workforce. Regression estimates indicate that the probability of union membership is related to a number of personal and occupational variables such as age, public sector employment and being a blue collar worker (significant in western Germany only). A decomposition analysis shows that differences in union density over time and between eastern and western Germany to a large degree cannot be explained by differences in the characteristics of employees. Contrary to wide-spread perceptions, changes in the composition of the workforce seem to have played a minor role in the fall in union density in western and eastern Germany.
The Macro Polity Revisited
(2021)
This dissertation includes six articles tied together by the overarching question of how changes in public opinion, economics and public policy co-evolve in mature democracies, with a focus on redistributive (in seven European democracies) and secessionist preferences (in Catalonia and Scotland). The theoretical inspiration derives from three sources: 1. the Macro Polity model by Erikson, MacKuen/Stimson, 2. the Thermostatic Responsiveness model by Soroka and Wlezien, and 3. the literature on representation gap models by Gilens, Elsaesser and others. The Macro Polity and Thermostatic Responsiveness models come with an optimistic undertone, emphasizing that public policies adapt to public opinion, producing the policy-opinion congruence that defines responsive government. The Representation Gap model, by contrast, is more pessimistic in highlighting that the preferences of low-income groups are generally worse represented in public policies than the preferences of middle-income and especially high-income groups. While there is evidence in favor of these models for the majoritarian political systems in the US, Canada and the UK, less is known about the validity of these models in proportional democracies of continental Europe. The contributions in this dissertation address this research gap by integrating the three models and combining nearly 500 surveys to study the evolution of European public opinion at the national and subnational level.
This thesis analyses how European merger control law is applied to the energy sector and to which extent its application may facilitate the liberalisation of the electricity, natural gas and petroleum industries so that only these concentrations will be cleared that honour the principles of the liberalisation directives. After having discussed the complex micro- and macro-economic considerations which accompany any concentration of business activities, this thesis discusses the merger control regime of the European Community (EC) so as to establish whether the merger control under either Art. 66 Treaty Establishing the European Coal and Steal Community (ECSCT), the case law under Art. 101 and 102 Treaty on the functioning of the European Union (TFEU) and (Art. 81 and Art. 82 Treaty Establishing the European Economic Community (ECT), as it was introduced by the Commission and reviewed by the CJEU, the original Merger Regulation (MR1989) or the amended Merger Regulation of 1997 (MR1997) or the amended Merger Regulation of 2004 (MR2004) facilitate the liberalisation of European electricity and gas markets. Said liberalisation was introduced by the Internal Electricity Market Directive (IEMD), the Hydrocarbons Licensing Directive and the Internal Gas Market Directive (IGMD). The paper focuses on the contestable idea that regulatory amendments - especially the introduction of third party access by means of the directives - only form a first necessary condition for attaining economic alterations whereas pro-active conduct of the marketers is the second and decisive one in order to increase the competitive performance of the European energy supply industries. The analysis is supported by a second argument which relates closely to the ambivalent nature of concentrations: A concentration may be used to increase the process of market opening and the expansion into new markets by pooling of scarce resources. It may also be used as a retro -active means so as to create national champions, increase barriers to market entry of new competitors, enable cross-subsidisation so as to expand dominant positions on heretofore competitive up- and downstream markets.
Whereas the extant literature discusses what Sustainability-Oriented Innovations (SOIs) are and why firms develop them, little is known about how they are developed. To enable firms to innovate for sustainability, it is essential to know more about the processes underlying SOI development, which are considered as very difficult, with many firms failing. Drawing on several academic papers and relying on qualitative research methods, the thesis uses the Fireworks model to examine how innovation processes unfold at established small and medium-sized enterprises (SMEs). The main contribution of the thesis is to advance the Fireworks model to the context of SOIs unfolding at SMEs. The findings reveal that SOIs unfold in an emergent, somewhat chaotic way, that duration and outcome are uncertain, that the overall journey is composed of multiple intertwined innovation paths, of which several will likely lead to setbacks. To manage this complex process, the thesis suggests to set four management foci: (1) to create a dedicated organizational unit for exploration, (2) to create conditions allowing intelligent learning for efficient exploration, (3) to carry out in-depth investigation of the related technological innovation systems, and (4) to plan carefully the re-integration of the innovation into the core business for commercialization.
The Ili Delta in Kazakhstan is an important ecosystem that offers crucial wetland habitats for several bird species. However, the Ili River, the Ili Delta and the Balkhash Lake are suffering from water shortage due to climate change and human activities. The desertification of the Aral Sea, an obvious point of comparison to the Balkhash region, also involved the degradation of wetland habitats and the related loss of many bird species relying on these habitats. Therefore, water shortage at the Ili Delta may also be the reason for the loss of wetland habitats and bird species. In this study, bird species numbers, species abundances as well as bird diversity at different habitats in the Ili Delta were examined. There are many habitat types provided by the Ili Delta, for example reed bed vegetation, Tugay forest, bare soil floodplains along rivers and steppe. The results of this study showed that the central delta region with habitats of submerged reed vegetation showed the highest number of bird species and the greatest diversity. Threatened bird species at the Ili Delta were also observed only in these wetland habitats. Steppe habitats showed the lowest numbers of bird species and the lowest bird diversity. In general, all habitats at the Ili Delta are important for the ecosystem and essential for the bird species that depend on them for their survival. With expansion of arid steppe habitats due to water shortage, however, previous wetland habitats may be lost. Moreover, bird species that depend on these wetland habitats may also be lost. Therefore, protective measures for the Balkhash region in general and the wetland habitats at the Ili Delta and its distinct avifauna in particular are urgently needed.
This thesis deals with the influence of sustainability communication on the purchase decision of sustainable tourism products involving German specialist tour operators. Sustainability communication is a challenge, because sustainable tourism is an abstract and vague concept which consumers find it difficult to grasp and about which they are sceptical. The service characteristics of tourism products complicate the decision making stage, which is a high-involvement situation of uncertainty to which sustainable product attributes add complexity. As an introduction, an interdisciplinary theory discussion reveals knowledge gaps in terms of the value-belief-norm theory and the elaboration likelihood model (ELM). The first article, which is the first systematic literature review on the topic, reveals that there is a limited theoretical understanding of sustainability communication, a lack of practical understanding of how to design sustainability messages, and an inadequate set of methodologies for its research. It identifies knowledge gaps concerning: the holistic approach to sustainability communication; its role in the attitude-behaviour gap; an interdisciplinary theoretical understanding focusing on belief-based social psychological theories and theories of persuasion; qualitative methods; and experimental design. The second article investigates the role of sustainability communication in the attitude-behaviour gap, employing the value-belief-norm theory to explain how information is processed by special interest customers. Interview findings show that ineffective sustainability communication is the reason for the gap and that customers unintentionally booked sustainably. The study identifies eight groups of beliefs which explain the processing of sustainability attributes. Sustainability information is effective when it is value-congruent, that is, when customers perceive they can make a difference, they begin to ascribe a responsibility to themselves. The third article investigates how to design an effective sustainability message in tour operator advertising. Drawing on the ELM, the study shows that appeal type does not significantly influence persuasion but the topic presented is important. Cultural sustainability is the sustainability topic that is most persuasive for cultural tourists, while consumer prior knowledge and issue-involvement with the topic promote successful information processing.
The timber shortage led to large scale afforestations on previously agriculturally used land in Central Europe during the 19th and 20th century. Widespread afforestation programs created recent forest ecosystems (i.e. young forest systems in terms of their development history). Despite the positive effect of increasing the forest area of Central Europe, the ecological effects of these land-use changes on forest ecosystems remain poorly understood. In order to increase the understanding of ecosystem processes in forests, an assessment of conceivable shifts in ecosystem functions caused by former land-use changes and forest management is required. By analysing aboveground growth rates of European beech (Fagus sylvatica L.) in response to environmental change drivers, such as climate extremes and nitrogen (N) deposition, the presented thesis aims to assess the role of land-use and management legacies in modulating present responses to drivers of environmental change. To this end, annual radial growth rates of individual trees were measured in mature beech stands. The investigated stands differed either in their land-use history (i.e. ancient forest sites versus recent forests) or their forest management history (i.e. managed forest sites versus short-term and long-term unmanaged forest sites). Measurements of radial growth rates were complemented by analyses of the fine root systems, soil chemical properties and crown projection areas to gain insights into the mechanisms underlying alterations in tree growth. Within the projects of the presented thesis, shifts in the climate-growth relationships driven by land-use and management legacies were analysed. In addition, land-use legacy mediated differences in the climate-nitrogen-growth relationships were assessed. The key findings are: (I) Soil legacy driven alterations in the fine root systems cause a higher sensitivity of radial increment rates to water deficits in summer for trees growing on recent forest sites than for trees growing on ancient forest sites. (II) Management legacies (in terms of tree release) enhance the sensitivity of beech’s radial growth to water deficits in spring through changes in crown sizes. (III) Interacting effects of spring water deficits and co-occurring high deposition of reactive N compounds lead to stronger radial growth declines in trees growing in ancient forests. This is likely caused by resource allocation processes towards seed production, which is, in turn, mirrored by decreasing radial growth rates. In this context, high N deposition likely boosts mass fructification in beech trees. Overall, it has been demonstrated that the ecological continuity plays a crucial role in modulating both climate sensitivity and the growth response to interacting effects of water deficits and nitrogen deposition in beech trees. The presented thesis identified a trade-off between the climate sensitivity and maximised growth rates within beech trees, depending on forest history. The results show that the growth of beech in ancient, unmanaged beech forests is less sensitive to water deficits than in recent and managed beech forests. Additionally, interacting effects of spring water deficits and N deposition likely increase the reproductive effort of beech trees, particularly in ancient forests. Thus, the results of this thesis once again underpin the uniqueness of ancient, unmanaged beech forests, whose importance for the conservation of biodiversity has been widely acknowledged. In summary, the presented thesis highlights the need to consider the "ecological memory" of forest ecosystems when predicting responses to current and future environmental changes.
This paper examines whether the attacks on the World Trade Center and the Pentagon on September 11th, 2001 have influenced the job prospects of Arabs in the German labor market. Using a large, representative database of the German working population, the attacks are treated as a natural experiment that may have caused an exogenous shift in attitudes toward persons who are perceived to be Arabs. Evidence from regression-adjusted difference-in-differences-estimates indicates that 9/11 did not cause a severe decline in job prospects. This result is robust over a wide range of control groups and several definitions of the sample and the observation period. Several explanations for this result, which is in line with prior evidence from Sweden, are offered.
Personally meaningful tourist experiences foster subjective mental wellbeing. Modern, human-centred technologies such as gamified technology have been recognised as a promising means to support tourists in their co-creation of meaningful tourist experiences. However, a deeper understanding and conceptualisation of tourists' engagement with gamified technologies in the tourist experience has remained absent so far. This study draws on positive psychology as the guiding theoretical lens to conceptualise and explore tourists' underlying motives for engaging with gamified technology, as well as the gratifications thereof for the tourist experience. In doing so, this thesis identifies how tourists generate meaning through interacting with gamified technology in the tourist experience, thereby fostering the co-creation of meaningful tourist experiences and contributing to subjective mental wellbeing. Being among the first studies to link the concepts of positive psychology, gamified technology, and tourist experiences, the results of this thesis provide rich findings on the underlying motives for tourists to engage with gamified technology during vacation, as well as the gratifications of gamified technology for the creation of meaning in the tourist experience. Using the theoretical lens of positive psychology and achievement motivation theory as the main theoretical underpinning, this study is positioned at the intersection of social psychology, human-computer interaction, and tourism as the field of application. Conceptually, this thesis provides an in-depth understanding of tourists’ engagement with gamified technology, including the socio-psychological motivators for engagement and the outcomes thereof for the tourist experience.
Increasing objections have been formulated towards broadening the security category. Securitisation is used to bring attention to urgent and existential threats that cannot be resolved through ordinary political decisions. During the time of the state of emergency between 2015 and 2017, France strengthened its security forces and introduced generalised surveillance measures to curb the terrorist threat. The purpose of this Bachelor thesis is to problematise the securitisation of terrorism in the French case. To do so, the Just Securitisation Theory by Rita Floyd is used to examine the following research question: Was it just to securitise terrorism in France between 2015 and 2017? Through critical discourse analysis of 54 presidential speech acts and secondary text analysis, this study aims to scrutinise securitising moves and security practices of the French government. The presented results indicate that the justness of securitisation is highly questionable. The analysis shows that the governments set excessive goals of eliminating terrorism and that security measures were misappropriated to fight organised crime instead of terrorism.
Despite the great progress that has been made in the prophylaxis of oral diseases over the past decades, dental caries and periodontal diseases remain major challenges in the field of dentistry. Biofilm formation on dental hard tissues is strongly associated with the etiology of these oral diseases. Therefore, the process of bioadhesion and biofilm formation on tooth surfaces is of particular interest for dental research. The first stage of bioadhesion on dental surfaces is the formation of the pellicle layer. This mainly acellular film, composed largely of adsorbed proteins, glycoproteins, and lipids, is distinguished from the microbial biofilm (plaque). As the interface between teeth and the oral environment, the pellicle plays a key role in the maintenance of oral health and is of great physiological and pathophysiological importance. On the one hand, the pellicle shows protective properties for the underlying dental hard tissues. On the other hand, it also serves as the basis for dental plaque and therefore, for the development of oral diseases such as caries and periodontitis. Hydrophobic interactions, which are governed by lipophilic substances, are of high relevance for bacterial adherence. Therefore, pellicle lipids, which are a significant constituent of this biological structure, are an interesting target for dental research, as they could modulate oral surfaces, influence microbial interactions, and potentially impede bacterial adherence. Compared to the extensive work on the pellicle´s ultrastructure and protein/amino acid composition, little attention has been given to its lipid profile. Knowledge of the lipid composition of the pellicle may provide insight into several oral pathological states, including caries, dental erosion, and periodontal disease processes and could contribute to novel approaches in preventive dentistry. The principle aim of this thesis was the comprehensive characterization of the fatty acid (FA) profile of the in situ formed pellicle layer. This includes the influence of pellicle maturation on the FA profile as well as intra- and interindividual differences. Furthermore, investigations on the effect of rinses with edible oils on the pellicle´s FA composition were a focus of this work. For these purposes, an analytical method based on a combination of innovative specimen generation and convenient sample preparation with sensitive mass spectrometric analysis was successfully developed and comprehensively validated within this thesis. Pellicle samples were formed in situ on bovine enamel slabs mounted on individual upper jaw splints. After a comprehensive sample preparation, gas chromatography coupled with electron impact ionization mass spectrometry (GC-EI/MS) was used in order to characterize qualitatively and quantitatively a wide range of FA (C12-C24). The individual FA profiles of pellicle and saliva samples collected from ten research participants were investigated. The relative FA profiles of the pellicle samples gained from the different subjects were very similar, whereas the amount of FAs showed significant interindividual variability. Compared to the pellicle´s characteristic FA profile, higher proportions of unsaturated FAs were detected in the saliva samples, highlighting that FAs available in saliva are not adsorbed equivalently to the pellicle layer. This, in turn, shows that pellicle formation is a highly selective process that does not correlate directly with salivary composition. Additionally, pellicle samples collected after 3, 30, 60, 120, and 240 min of intraoral exposure were analyzed. It could be shown that pellicle maturation has only a minor impact on the FA composition. However, the FA content increased substantially with increasing oral exposure time. Modifying the pellicle´s lipid composition by using edible oils as a mouthwash could alter the physicochemical characteristics of the pellicle and strengthen its protective properties by delaying bacterial adhesion. Therefore, the impact of rinses with safflower oil on the pellicle´s FA composition was determined. The application of rinses with safflower oil resulted in an accumulation of its specific FAs in the pellicle, thus representing a possibility for modifying the pellicle´s lipid profile. The present work is the first to apply a validated method that combines in situ pellicle formation, sample preparation, and the comprehensive determination of FAs via a sensitive analytical method. The results provide valuable information regarding the pellicle´s FA composition which closes an existing knowledge gap in pellicle research. A broader knowledge of the lipid composition of the pellicle contributes to the understanding of oral bioadhesion processes and may help facilitate novel approaches in preventive dentistry.
After being administrated to humans or animals, pharmaceuticals may be metabolized by a variety of mechanisms and pathways within the body. Once these compounds and/or their metabolites are excreted, they may undergo degradation in the aquatic environment. Unfortunately, a rapid and complete mineralization cannot always be guaranteed, whereas relatively stable transformation products (TPs) may be formed. The largest part of older studies focused on investigation of the elimination kinetics of parent compounds without considering the amount and chemical structure of individual TPs. Only recently, there is an increasing trend to deliver such information. Nevertheless, since drugs are defined as significant environmental pollutants, it is not only important to elucidate their TPs, but also necessary to investigate whether these formed compounds preserve the same mode of action as the parent compound or are even more toxic. Thus, two main objectives of this thesis can be formulated. Firstly, to highlight the concern originated by metabolites and transformation products of pharmaceuticals that contaminate the environment. Hereby, the already-published knowledge on TPs within a certain selection of drugs is assessed to exemplify the number and quality of the existing information on their TPs. Secondly, to particularly investigate the fate of the antibiotic ciprofloxacin (CIP). This is done by (a) evaluating the suitability and sustainability of the photolytic decomposition as an advanced water treatment technique, (b) monitoring the course of genotoxicity of the irradiated mixtures using a battery of genotoxicity and cytoxicity in vitro assays, and (c) considering the potential genotoxicity for CIP´s individual TPs by the employment of in silico approaches using quantitative structure activity relationships (QSAR) models. This thesis based on the results and conclusions of five articles, which can be found in the appendix. A systematic literature review was conducted on the current state of knowledge on pharmaceuticals and its derivatives in the environment. Two groups, namely antibiotics and anticancer drugs, were considered more closely with respect to the availability of chemical structures for their TPs. Furthermore, the photodegradation of CIP as well as a preliminary toxicity assessment of its identified TPs were investigated in three research papers. An extensive review with a table at its core shows the existing data on 158 TPs, which already have an assigned registry number in chemical abstracts service (CAS-RN), was presented. In total, 294 TPs, identified with chemical structures in the literature, were found for 15 compounds out of the 21 that were selected as target compounds. Eleven TPs, created from CIP, were identified by high-performance liquid chromatography/high-resolution multiple-stage mass spectrometry. It was detected that the transformation of CIP mainly occurred through substitution of fluorine, defluorination, hydroxylation of the quinolone core and the breakdown of the piperazine ring. Some of the identified TPs of CIP were predicted as genotoxic by QSAR analysis, while the experimental testing for a few genotoxic and cytotoxic endpoints showed that the potential of the resultant mixtures could be primarily dependent on the concentration of residual CIP. In contrast, irradiation mixtures were neither mutagenic in the Ames Test nor genotoxic in the in vitro Micronucleus Test. It is possible that the effect of the TPs was masked by antagonistic mixture interactions and/or they were not formed at effectively concentrations. Nevertheless, all of the identified TPs of CIP still retained the core quinolone moiety, which is responsible for the biological activity. Thus, a more comprehensive assessment, encompassing more genotoxic endpoints, chemical analysis characterization and exposure analyses, needs to be conducted. Information available on TPs demonstrates that already slight changes in treatment conditions and processes result in the formation of different TPs. Nevertheless, most of the transformation products could neither be identified nor fully assessed regarding their toxicity. This, in turn, presents a major challenge for the identification and assessment of TPs. Hence, from a practical and sustainability point of view, limiting the input of pharmaceuticals into effluents as well as improving their (bio)degradability and elimination behavior, instead of only relying on advanced effluent treatments, is urgently needed. Solutions that focus on this
The ethical apparatus: The material-discursive shaping of ethics, autonomy, and the driverless car
(2023)
This research argues that the emergent driverless car, as a kind of autonomous vehicle, is a Foucault-ian "ethical apparatus", working as an epistemic device to materially embody and enable discursive power by generating notions of "autonomy" and "ethical decision-making". The ethical implications of AI, algorithmic, and autonomous technologies are topics of current regulatory and academic concern. This concern relates to the lack of meaningful oversight of black boxes inside AI systems, liabilities for manufacturers, and inadequate frameworks to hold AI-based socio-technical systems to account. One recent artefact, the driverless car, has taken on these concerns quite literally in the shaping of a niche discourse of the "ethics of autonomous driving". Ambitions to produce a fully autonomous vehicle based on AI technologies are constrained by speculative concerns that its decision-making in unexpected accident situations cannot be assumed to protect humans. "The ethics of autonomous driving" evaluates proposals to build "ethical machines" by examining the relationship between structures of human values and moral decision-making, and how they comport to computational architectures for decision-making. This is the first case this work takes up, chiefly organised around an analysis of a thought experiment, the Trolley Problem, and the online game, Moral Machine, that crowdsourced values to suggest approaches to an "ethics of autonomous driving". Rather than evaluate the feasibility or appropriateness of these two approaches, this work attends to the more critical issue that ethics is being proposed in terms of technologies turning on the logics of risk, speculation, and probabilistic correlations that are fundamental to how machine learning makes decisions. The concern in this work is less a normative framework or approach for a better or more appropriate ethics of autonomous driving. Rather, this work argues that what we understand as "the ethical" is being transformed when architected by, through, and for Artificial Intelligence / autonomous technologies to become their own regulators. Hence the production of autonomous driving necessitates computational infrastructures that are creating a world legible to and for the navigation of a driverless car. The author argues that this is fostering computational governance that has implications for human bodies and social relations, chiefly that conventional approaches to regulation and accountability attend to human values and decision-making rather than computational ones. A second case that this research examines is that of driverless car crashes, to examine how "autonomous" driving requires substantial embodied human knowledge and micro-work. Taken together, these two cases make an argument for how myriad practices of knowledge-production are translating the human world into something legible to the navigational needs of the car, producing changes in the human world through the actions of the car on that basis, and advancing notions of "autonomy". This work concludes with arguments for a critical reconceptualisation of ethics and ethical decision-making in AI / autonomous systems.
Entrepreneurs and entrepreneurial firms are a frequent research topic in psychological research. However, the focus of this research has largely been on the entrepreneur as a person and on the entrepreneurs’ strategy for the business. By contrast, the entrepreneur as a leader and the entrepreneurial firm as a work environment for employees have received little attention. Therefore, this dissertation aims to integrate theoretic thoughts from organizational behavior research into entrepreneurship research. Specifically, I will focus on novelty creation within entrepreneurial firms and organizational phenomena which provide a context for employees in novelty creating activities. This dissertation adds to the literature as it provides insight in the effects of work environment facets on employees’ engagement in novelty creating activities in entrepreneurial businesses. In three empirical chapters, I will focus first on the effects of entrepreneurial orientation on efficiency of employee work in innovation projects. Second, I will look at a facet of organizational culture, the error management culture, and its effects on individual learning of employees. Last, I will focus on occupational roles of employees within small businesses and effects of these roles on responses to a questionnaire and on work in innovation projects. In all three empirical chapters I test my hypotheses in a sample of N = 40 entrepreneurial businesses and employees within these businesses. For my chapter on occupational roles this sample is complemented by two additional samples of college students. In sum, results indicate that the entrepreneurial business in all three chapters exerts significant influences on employee work. Furthermore, I show that employee participation in novel activities is positive for entrepreneurial businesses (Chapter 2: Correlation between employees’ and entrepreneurs’ evaluation of innovation project effectiveness: r = .44; p < .01; Chapter 3: Correlation between organizational level leaning and organizational growth in sales: r = .35; p < .01). Therefore, I suggest that research on the entrepreneurial firm as a context for work may contribute to our knowledge on success factors in entrepreneurship, and may therefore be a relevant direction of future research. Especially, it may be fruitful to investigate aspects of work in which entrepreneurial firms may differ from other, less entrepreneurial organizations.