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The world wide population growth and the increasing water scarcity endanger more and more the human society. Water saving measures alone will not be sufficient to solve all associated problems. Therefore, people in arid countries might come back to any kind of water available. In this context the way people regard wastewater must change in terms that it has to be recognized as a water resource. The reuse of wastewater, treated and untreated, for irrigation purposes in agriculture is already established in some semi-arid and arid countries. Countries with absolute water scarcity like Israel might not only be forced to reduce their water consumption, but even to transfer reused water to other sectors. Concerns of authorities and the general public about potential health risks are completely understandable. The health risks of wastewater are mainly originating from pathogens which are negatively correlated with its treatment. Therefore, the quality of a wastewater effluent derived from mechanical-biological treatment can be further improved by additional treatment steps like soil aquifer treatment (SAT). This process is adopted at the Israeli Shafdan facility in the south of Tel Aviv. Conventionally treated wastewater is applied on surface basins from where it percolates into the coastal plain aquifer which supplies approximately one quarter of Israel ́s drinking water. After a certain residence time in the subsurface the water is recovered by wells surrounding the recharge area. Although the pumping regime creates a hydraulic barrier to the pristine groundwater, concerns exist that a contamination of the surrounding drinking water wells could occur. So far, little is known about the removal of organic trace pollutants during the SAT process in general and for the Shafdan site in particular. Consequently, the need arose to study the purification power of the SAT process in terms of the removal of organic trace pollutants. For this purpose reliable wastewater tracers are essential to be able to differentiate between degradation and sorption processes on the one hand and dilution with pristine groundwater on the other hand. Based on their chemical properties, their worldwide usage in a variety of foodstuffs and beverages, and first data about the fate and occurrence of sucralose, artificial sweeteners came into the focus as promising tracer candidates.
Thus, in the present work an analytical method for the simultaneous determination of seven commonly used artificial sweeteners in different water matrices, like surface water and wastewater, was developed (see chapter 2). The method is based on the solid phase extraction (SPE) of the analytes by a styrene-divinylbenzene (SDB) copolymer material, and the analysis by liquid chromatography-electrospray ionization tandem mass-spectrometry (LC-ESI- MS/MS). The sensitivity in negative ionization mode was considerably enhanced by postcolumn addition of the alkaline modifier tris(hydroxymethyl) aminomethane. In potable water, except for aspartame and neohesperidine dihydrochalchone, absolute recoveries >75 % were obtained for all analytes under investigation, but were considerably reduced due to matrix effects in treated wastewater. The widespread distribution of the artificial sweeteners acesulfame, saccharin, cyclamate, and sucralose in the aquatic environment was proven. Concentrations in two German wastewater treatment plant (WWTP) influents ranged up to 190 μg/L for cyclamate, several tens of μg/L for acesulfame and saccharin, and about 1 μg/L for sucralose. For saccharin and cyclamate removal rates >90 % during wastewater treatment were observed, whereas acesulfame and sucralose turned out to be very persistent. As a result of high influent concentrations and low removal rates in WWTPs, acesulfame was the dominant sweetener in German surface waters with concentrations up to 2.7 μg/L. The detection of acesulfame and sucralose in recovery wells in the Shafdan SAT site in Israel in the μg/L range was a promising sign for their possible use as anthropogenic markers. As acesulfame and sucralose showed a pronounced stability in WWTPs and were detected in recovery wells of the SAT site in Israel it became worthwhile to assess their tracer suitability compared to other organic trace pollutants suggested as anthropogenic markers in the past (see chapter 3). Therefore, the prediction power of the two sweeteners was evaluated in comparison with the antiepileptic drug carbamazepine (CBZ), the X-ray contrast medium diatrizoic acid (DTA) and two benzotriazoles (1H-benzotriazole (BTZ) and its 4-methyl analogue (4TTri)). The concentrations of these compounds and their ratios were tracked from WWTPs with different treatment technologies, to recipient waters and further to river bank filtration (RBF) wells. Additionally, acesulfame and sucralose were compared with CBZ during advanced wastewater treatment by SAT in Israel. Only the persistent compounds acesulfame, sucralose, and CBZ showed stable ratios when comparing influent and effluent
concentrations of four German WWTPs with conventional wastewater treatment. However, by the additional application of powdered activated carbon in a fifth WWTP CBZ, BTZ, and 4-TTri were selectively removed resulting in a pronounced shift of the concentration ratios towards the nearly unaffected sweeteners. Results of a seven months monitoring program along the rivers Rhine and Main showed an excellent correlation between CBZ and acesulfame concentrations (r2 = 0.94), and still good values when correlating the concentrations with both benzotriazoles (r2 = 0.66 - 0.82). In RBF wells acesulfame and CBZ were again the compounds with the best concentration correlation (r2 = 0.85).
The importance of a social perspective on the relationships between humans and nature has longbeen acknowledged. The field of social-ecological systems research in particular is striving toachieve a holistic understanding of human-nature relationships by balancing social andecological perspectives. Here I sought to develop a social understanding of the Saxon area inCentral Romania, by exploring aspects of human-nature relationships as seen from theperspective of local people. To this end, I employed the concepts of social-ecological systems(SES), ecosystem services (ES) and cultural landscapes to assess perceptions of locals throughempirical case studies.I first conducted a literature review to acquire an overview of a particular type of human-naturerelationship mediated by non-consumptive use and non-use values (“cultural ecosystemservices”). Second, to isolate and address the interaction from the social system to the ecologicalsystem, I investigated the different ways locals perceived the role of landscapes in SouthernTransylvania. I conceptually mapped these landscape preferences by revealing their potentialland use and management implications. Third, to approach the human-nature relationship fromthe ecological system to the social system, I studied the flow of ES to disaggregated humanbeneficiaries. Specifically, I studied which factors, beyond ecosystem processes and functions,influenced nature derived human well-being from the perspective of potential beneficiaries. Iconceptualised the mediating role of a range of contextual factors underpinning the currentdistribution of ES, with regard to the relation between ES and human well-being. Fourth, inorder to explore an example of bidirectional human-nature relationship, I studied the particularcase of human-carnivore coexistence and the suite of mechanisms shaping it.Despite building throughout this thesis a more complex and in-depth understanding of the humandimensions of the studied system, I chose four main cross-cutting themes to explain the human-nature connection in Southern Transylvania. These four themes may serve as pillars of a sociallyminded understanding, as well as potential research and policy foci. First, the values held bylocals are key for understanding the endemic human-nature relationships and should not beoverlooked in future social-ecological assessments or policy interventions. Second, the culturallandscape of Southern Transylvania is both a physical and virtual space of social-ecologicalinteraction fostering human-nature experiences and social-ecological knowledge integration.Third, the identified diversity of the social system in terms of landscape aspirations and ESbeneficiaries is expanding the range of human-nature connections, but at the same time, may infuture be a source of conflict or disconnection if not managed appropriately. Finally, small-scalefarmers, through their interactions with the land and resultant belief system, play a major role inmaintaining the human-nature relationships, but their values and lifestyle are threatened.
This PhD thesis examines the connections between sustainability knowledge management (SKM) and sustainability management tools in small and medium-sized enterprises (SMEs). While previous literature has established that knowledge is essential for the application of sustainability management tools, the effects of such tools on knowledge management are under-researched in the sustainability context. Drawing on multiple academic papers and utilizing various research methods, including a systematic literature review, several quantitative surveys and a multiple case study approach, the thesis systematically examines how such tools can facilitate the identification, acquisition, conversion, application and retention of sustainability knowledge, and potentially lead to the improvement of SKM effectiveness in SMEs. Furthermore, it examines how support functions for sustainability management tools and SKM correspond with each other. The findings reveal that sustainability management tools facilitate the SKM processes (identification, acquisition, conversion, application and retention), and align with the support factors (e.g. top management support, shared vision, employee qualifications) to advance SKM in SMEs. Particularly, such tools permit the institutionalization of sustainability knowledge into the daily routines and practices in SMEs. Additionally, tools create a support structure for SKM, embedding and preserving sustainability knowledge in documents, policies, procedures and norms for an enterprise´s collective knowledge for sustainability management. The thesis concludes with complementing areas of future research and offers practical implications for SME management.
Fire plays an important role in the earth system by influencing ecosystems and climate, but climate in turn also influences fire. The system became more complex when humans started using fire as a tool. Understanding the interaction between humans, fire and climate is the major aim of paleofire research. Understanding changes in these three aspects in the past will help predicting future climate, fire and human interactions. The use of lake sediment cores as natural archives for reconstructing past fire activity by counting charcoal particles is well established. This present dissertation is dedicated to the evaluation and application of specific organic molecular markers for biomass burning: levoglucosan, mannosan and galactosan were used as proxies for reconstructing past fire activity in lake sediments thorough the entire Holocene. First, a new analytical method was developed using high-performance anion exchange chromatography combined with mass spectrometry to separate and detect these three monosaccharide anhydrides in lake sediments. The suitability of this analytical method was proven by comparing the levoglucosan, mannosan and galactosan results in selected lake sediment samples from Lake Kirkpatrick, New Zealand and by correlating the results with macroscopic charcoal. Furthermore, the method was successfully applied to a lake sediment core from Lake Petén Itzá, Guatemala to reconstruct regional Holocene fire history. The analyses of levoglucosan were combined with fecal sterols to reconstruct late Holocene human fire interactions at Lake Trasimeno, Italy, demonstrating low fire activity during the Roman period. This combination of studies proves that these molecular markers are valid fire proxies in sediments from multiple locations around the globe. Comparison of levoglucosan, mannosan and galactosan concentrations with macroscopic charcoal trends in Lake Kirkpatrick and Lake Petén Itzá, suggests that the molecular markers represent more regional fire history and low temperature fires in contrast to macroscopic charcoal, which is a local fire proxy. In addition, vegetation changes (Lake Kirkpatrick and Lake Petén Itzá) and charcoal morphotypes (Lake Petén Itzá) were compared to the levoglucosan/mannosan and levoglucosan/(mannosan+galactosan) ratios suggesting that these ratios may be a suitable tool to track burned fuel. Biodegradation tests demonstrate the potential degradation of levoglucosan, mannosan and galactosan if dissolved in water, but findings in ancient sediment samples suggest that particle-bound levoglucosan, mannosan and galactosan can be buried in sediments over millennial time scales. Although uncertainties still exist, the results of this research suggests that organic molecular markers are a suitable regional fire proxy and isomer ratios may help understand changes in burned vegetation.
Agricultural production of smallholder farmers in Myanmar is facing soil fertility degradation and in consequence, crop yields decline due to the imbalances of nutrient supply. In most cases, all above ground biomass is removed from the fields after harvesting the crops and during land preparation for the next crop. Higher temperatures also stimulate the higher mineralisation rates and released mineral nutrients are lost from fallow lands before sowing the next crops. Regarding the addition of mineral fertilizers, except for cash crops, farmers are reluctant to apply fertilizers for the crops that are sown for household’s self-sufficiency. In the Dry Zone, irrigated agriculture is available in recent years and farmers could overcome water scarcity through irrigation. With the availability of irrigation water, farmers could prolong the cropping period, nevertheless crop yields are decreasing year by year. In recent decades, research findings are indicating the benefits of biochar application for soil fertility improvement and food security. Smallholder farmers can produce biochar from agricultural by-products such as pigeon pea stems, cotton stems and rice husks by using biochar stoves. Large-scale production is possible by producing both biochar and thermal energy simultaneously, such as getting rice husk biochar and producing thermal energy by burning rice husks. By those means, environmental pollution due to the smokes from stubble burnings and the health hazards from smokes arise from kitchens can also be reduced. Present research was conducted to test the effects of the application of biochars produced from different crop residues together with NPK fertilizers on crop yields and soil properties in the rice-chickpea-cotton cropping system of the Central Dry Zone area of Myanmar during 2012 and 2013 cropping seasons at Shwe Daung Farm, Mandalay Division, Myanmar. Effects of biochar applications in combination with NPK fertilizers were compared with NPK fertilizer (without biochar) application and the control (without biochar and NPK fertilizers). Biochars used in the experiments were produced from three kinds of locally available raw materials (rice husk, rice straw and, pigeon pea stem) at temperature above 550°C by using a kiln made from a 200-Liter diesel barrel. Field experiments were conducted on sandy loam soil in the Central Dry Zone of Myanmar. After harvesting rice in 2012, chickpea was sown without application of both organic and inorganic fertilizers. After harvesting chickpea in 2013, cotton was sown on the same experimental plots. Treatments were rice husk biochar (Rh) 20 Mg ha-1 + NPK fertilizers; rice straw biochar (Rs) 20 Mg ha-1 + NPK fertilizers; pigeon pea stem biochar (Ps) 20 Mg ha-1 + NPK fertilizers; rice husk biochar and farmyard manure mixture (Rh biochar + FYM) 10 Mg ha-1 + NPK fertilizers; NPK fertilizers (without biochar); and the control (without fertilizer and biochar). Biochar weights represented fresh biochar weights. Equal rate of NPK fertilizers were applied in all treatments. However, fertilizer rates were different with respect to the crops. In rice experiment, 100:50:50 kg ha-1 rate of Urea (N): Triple Super Phosphate (P): Muriate of potash (K) was applied. In cotton experiment, 100:30:117 kg ha-1 rate of Urea (N): Triple Super Phosphate (P): Muriate of potash (K) was applied. Crop growth data, yield component data and yield data of each treatment were recorded. Soil samples from topsoil (0-0.2 m) were taken before starting the experiments, after harvesting rice and cotton, respectively, and analysed. A biogeochemical model, denitrification decomposition (DNDC) model, was used to estimate soil organic carbon storage and greenhouse gas emissions during crop growing seasons and to quantify the long-term impact of biochar applications on rice, chickpea and cotton yields.The results from soil analyses indicated that although initial soil pH was at 8.0 and pH values of biochars ranged between 8.0 and 10.0 soil pH after two years of biochar application did not increase. pH values were below 8.0. That value was lower than initial soil pH. That could be due to the effect of the change of cropping system from upland to lowland rice cultivation and the effects of biochar additions to the alkaline sandy loamy soil of the experimental site. Although total exchangeable cation value was not significantly different among the treatments, compositions of major cations were significantly different among the treatments. Exchangeable potassium increased in Rs biochar + NPK applied soils. Exchangeable sodium increased in control, and conventional NPK fertilizer applied soils. Reduction of soil bulk density from 1.8 g cm-3 to 1.6-1.7 g cm-3 occurred in biochar treatments compared to control and conventional NPK fertilizer application treatments. Positive changes of total carbon and total nitrogen of soils were found in biochar treatments compared to control and conventional NPK fertilizer application. Application of pigeon pea stem biochar + NPK fertilizers showed the highest crop growth and the highest yield in rice. The highest chickpea yield was obtained from the plot that applied rice husk biochar + NPK fertilizers. Cotton crop growth and yield was the highest in rice husk biochar and farmyard manure mixture + NPK fertilizer application. The lowest crop growth and yield was obtained from the control in cotton. The results of this study suggested that biochars from different biomass materials had different effects on soil properties and crop yields under different growing conditions and cultivated crops. Although the applied biochars had a high pH, soil pH did not increase after biochar applications. The growth and yield of tested crops were higher than that of the control and conventional NPK fertilizer application. Rice husk biochar and farmyard manure mixture + NPK fertilizer application can be assumed as a suitable soil amendment application under upland crop cultivation. Pigeon pea stems biochar + NPK fertilizers should be applied in rice cultivation. Rice husk biochar + NPK fertilizers and rice husk biochar-farmyard manure mixture + NPK fertilizers showed as the appropriate biochar soil amendments for the study area compared to rice straw biochar + NPK fertilizers and pigeon pea stem biochar + NPK fertilizers. Application of these biochars increased total exchangeable cations, reduced bulk density, increased organic carbon, regulated soil pH and, can easily be accessed by smallholder farmers by promising crop yields for sustainable agricultural production. Rice straw biochar + NPK fertilizers and pigeon pea stem biochar + NPK fertilizers also showed positive influences on soil fertility and crop growth. However, extensive application of those biochars might require large-scale productions and distributions. To obtain the detail information regarding the impact of biochar application on the agro-ecosystem and surrounding atmosphere, further research activities may need to carry out under different agricultural production conditions. When model fitness was tested, it was found that DNDC model was fit for the simulation of crop yields and soil organic carbon under the conditions of the experimental site. Simulation of soil organic carbon dynamics and crop yields for 30 years and 50 years after the addition of biochars in combination with NPK fertilizers showed that such applications could maintain the crop yields at the same level up to 50 years. That could maintain soil organic carbon at a level higher than conventional NPK fertilizer application. Regarding the simulation of GHGs emissions, the model simulated nitrous oxide emission close to actual emissions of agricultural soils of Myanmar. Simulated CH4 emissions from control and conventional NPK fertilizer application variant were consistent with the well-known emissions of Myanmar rice fields. To confirm the accuracy of simulated CH4 emissions from biochar applied soils, it may need field investigations and validations of model results. Simulated effects of rice husk-, rice straw- and pigeon pea stem fresh biomass applications and that of rice husk-, rice straw- and pigeon pea stem biochar applications on rice, chickpea, cotton yields and soil organic carbon (SOC) were compared. Objective of this simulation was to compare the effects of fresh biomass-applications and the application of biochars produced from the same biomass on crop yields and SOC by using DNDC model. The results showed that simulated rice yields of rice husk biochar and rice straw biochar applications were 33% and 31%, respectively, higher than that of pigeon pea green manure applications. However, simulated rice yield from pigeon pea stem biochar application was 4% higher than that of iv pigeon pea stem green manure application. Simulated chickpea yield from pigeon pea green manure treatment was the highest among all of biochar and biomass applications. Simulated cotton yields obtained from fresh biomass applications were lower than that of biochar applications. In estimating the future yields, all crop yields from rice husk and rice straw biomass applications were lower than that of rice husk and rice straw biochar applications in the initial year of simulation. However, in the following years, the yields remained at the same level up to the end of simulated years. In pigeon pea stem green manure application, crop yields were higher than the other treatments since the initial year up to the end of simulated years. Simulated SOC was lower in fresh biomass applications compared to biochar applications.
This study aims to answer four main research questions regarding the roles, strategies, barriers, and representation of the media and environmental nongovernmental organisations (ENGOs) in environmental communication in Malaysia. From a theoretical lens, this study has incorporated the essential concepts of media, ENGOs, and environmental communication from both Western and Asian, particularly Malaysian perspectives as primary points of reference. For the purpose of this study, a total of 13 interviewees from Media A and Media B and 11 interviewees from ENGO A and ENGO B were chosen for the qualitative interview while 2,050 environmental articles were collected as samples from Media A´s and Media B´s newspapers along with ENGO A´s and ENGO B´s newsletters from the period 2012 to 2014 for the quantitative content analysis. Specifically, the findings from interview confirmed that both the Malaysian media and ENGOs have shared quite similar roles in environmental communication, particularly in environmental legitimacy (creating trust, credibility, and relationships with the public), in democracy (acting as a watchdog and mobilising the public sphere), and in constructing public mind about environmental problems. Pictures undoubtedly were one of the most vital tools in social construction, especially for presenting the reality of the environmental problems to the public. This was in harmony with the results of the quantitative content analysis, where more than 60% of pictures were found on environmental articles in media newspapers and ENGOs newsletters. Malaysian media and ENGOs have shared two common strategies in environmental communication, namely campaigning and collaboration with other stakeholders, while the ENGOs have two extra strategies: advocacy and lobbying strategies. Malaysian media and ENGOs also have collaborated with each other and the level of collaboration between them was at the coordination (medium) level. Both social actors especially the media were also relied heavily on their sources for environmental articles and the result of quantitative content analysis showed that the government was the main source for media newspapers, whereas other ENGOs and laypersons were the main sources for ENGOs´ newsletters. There are also colossal barriers faced by both Malaysian media and ENGOs throughout the process of environmental communication and some of the barriers faced by both media and ENGOs include the problem with limited knowledge of the environment, while some other barriers, like media laws and ownership, were only faced by the media; other barriers such as funding problems were specifically faced by the ENGOs. In terms of representation of environmental information, the Malaysian media make more presentations on environmental problems, especially on topics like floods, wildlife and water crises in their newspapers, while ENGOs have given more attention to environmental effort topics such as conservation and sustainable living in their newsletters. Surprisingly, not only the media but also the ENGOs used the same (news) values like timeliness, proximity, and impact as criteria for the selection of environmental issues for their publications. Other factors such as the background of the organisation and the interest of journalists or editors also influence the selection of environmental issues. It is hoped that the proposed theoretical framework of this study can serve as a crucial guideline for the development of environmental communication studies, especially among the media and ENGOs not only in Malaysia but also in other (Southeast) Asian regions that share a similar background.
Water is an essential natural resource, yet we are experiencing a global water crisis. This crisis is first and foremost a crisis of governance rather than of actual physical resources. Capacities of single, unitary states are severely challenged by the complex, multi-scalar, and dynamic structure of contemporary problems in water resource management. New modes of governance stress the potential of public participation and scalar restructuring for effective and legitimate environmental decision-making. However, a lack evidence on the actual implementation and instrumental value of novel governance modes stands in stark contrast to the strong beliefs and assumptions that often see these being propagated as ´panaceas´ or ´universal remedies´. With this doctoral dissertation I aim to contribute to a deeper understanding of the implementation and performance of public participation and scalar restructuring in environmental governance, and particularly to engage in systematic research into the contextual factors that shape the performance of such governance innovations. Based on the conceptual approaches of participatory, multi-level governance and scale, I advance a conceptual framework specifying mechanisms and important contextual factors describing the potential of participation and rescaling to impact on the efficacy of environmental decision-making. Applying this framework, I employ a mixed-methods approach combining qualitative, quantitative, set-theoretic, and review methods, with the aim of maximising the validity of results. Drawing on the institutional frame of the European Water Framework Directive (WFD), I first assess the extent and conditions under which participation and rescaling are actually implemented in the European water resource management regime. Subsequent analyses examine whether these governance shifts, where implemented, actually lead to environmentally effective and legitimate political decisions, and foster social outcomes. Results indicate that actual changes in governance structures remain modest, whereas previous institutional structures and experiences prove rather durable. Hence, despite recent shifts distributing authority towards alternative actors and scales, the state has persisted in its role as central authority in the European water resource management regime. To the extent that they were implemented, public participation and rescaling were generally positively related with the environmental effectiveness and legitimacy of political outcomes. The analysis provides a context-sensitive understanding, by unravelling the supposedly linear relationship between governance inputs and outputs to develop a more nuanced picture of the governance process rather as a composition of multiple, interdependent causal mechanisms that, depending on their actual configuration, lead to various outcomes. In this way, particularly the tension between legitimacy and effectiveness of political outcomes is disentangled, with both being seen as the result of distinct but interrelated properties of the governance system and its contextual circumstances. The thesis furthermore provides insights of practical and policy relevance, highlighting the need and potential to take a context-sensitive perspective in policy design and decision-making. The framework paper and the Ph.D. thesis thus together enhance academic understanding of environmental governance and its potential contributions to sustainability transitions.
Among all attenuation processes, biodegradation plays one of the most important role and is one of the most desirable processes in the environment. To assess biodegradation, a variety of biodegradation test procedures have been developed by several international organizations. OECD guidelines for ready biodegradability testing represent one of the most prominent group of internationally used screening biodegradation tests (series 301A-F). These tests are usually very simple in their designs and allow for the fast and cheap screening of biodegradability. However, because of their stringency, the test conditions are not close to simulating environmental conditions and may lead to unrealistic results. To overcome these limitations, OECD introduced simulation tests which are designed to investigate the behavior of chemicals in specified environmentally relevant compartments. Despite the fact that simulation tests give more insight into the fate of chemicals in the environment, they are not applied frequently as they are often tedious, time consuming and expensive. Consequently, there is a need to provide a new biodegradation testing method that would combine complex testing environment as in simulation tests, easiness in handling and good data repeatability as in screening biodegradation tests. Another challenge is an adaption of the existing biodegradation testing methods to new types of samples, i.e. mixtures of transformation products (TPs). The research on the presence of pharmaceuticals in the environment gained momentum in the 1990s; since then, it has been growing. Their presence in the environment is a wellestablished fact. A wide range of pharmaceuticals is continuously detected in many environmental compartments such as surface waters, soils, sediments, or ground waters. After pharmaceuticals reach the natural aquatic environment they may undergo a number of processes such as: photolysis (under direct sunlight), hydrolysis, oxidation and reduction reactions, sorption, biodegradation (by bacteria of fungi), and bioaccumulation. These processes, may cause their elimination from aquatic environment, if reaction is complete, or creation of new compounds i.e., transformation products (TPs). What is more, processes, like chlorination and advanced oxidation processes (AOPs), such as H2O2/UV, O3/UV, TiO2/UV, Fenton, and photo-Fenton, or UV treatment which might be applied in water or wastewater treatment, may also lead to the TPs introduction into aquatic environment. The research on the TPs brings many new challenges. From one side, there is a constant need for the the development of a sensitive and reliable analytical separation, detection, and structure elucidation methods. Additionally, there is a need for the preparation of appropriate assays for the investigation of properties of new compounds, especially those answering the question if TPs pose a higher risk to the aquatic ecosystems than their parent compounds. Among numerous groups of pharmaceuticals, two are of great importance: antibiotics since they might promote emergence and maintenance of antimicrobial resistance in the aquatic environment; and cytostatic drugs. Cytostatic drugs can exert carcinogenic, mutagenic and/or teratogenic effects in animals and humans. The challenges of biodegradation testing presented in this thesis, encompasses these different areas of interest and was divided into three objectives: 1) Identification of the knowledge gaps and data distribution of the two groups of pharmaceuticals antibiotics and cytostatic drugs (article I); 2) Increasing the knowledge on biodegradation of cytostatic drugs and their TPs (articles II, III, and IV) and 3) Establishment of a biodegradation test with closer to simulation tests conditions, that could be affordable and to support better understanding on processes in water sediment interface construction - screening water-sediment test. Further validation of the test with an insight into sorption and desorption processes (articles V and VI).
The dissertation project focuses on empirically investigating consumers' attitudes, motivations and purchasing decisions regarding sustainable products. The focus on this micro perspective, however, does not reflect consumers' roles within the transformation towards sustainable consumption. Therefore, the present framework paper puts the included papers into a greater context and evaluates the findings on a meta-level by applying an enhanced transition management theory. The analysis underlines that consumers' limited personal capabilities are an underlying reason for unsustainable practices. Therefore, the active engagement not only of consumers, but also of companies is required if the transformation is to be successful. If companies actively support consumers in making sustainable choices, consumers can engage in sustainable consumption with only low cognitive efforts. On this basis, genuine sustainable choices are enabled. The dissertation provides practical implications by highlighting potential measures which will help to promote sustainable products from niches to mainstream. In sum, the dissertation project enhances academic understanding of consumers´ sustainable purchasing behavior and reveals the potential of integrating such insights into the management of transformations towards sustainable consumption.
This thesis aims at contributing to the better understanding of the roles of international and domestic institutional and governance patterns for corporate sustainability practices. By combining governance and new institutionalism approaches it bridges the gap between the close look at specific corporate sustainability (CS) policies and the broader view on institutional frameworks. The qualitative comparative approach aims to provide deeper insights on the implementation of different governance schemes by transnational corporations ((TNC). Finally, the conclusions might allow for the development of a) recommendations for the balancing of TNCs' CS management between global and domestic requirements, and b) policy recommendations in the field of CS governance. The overarching research question is as follows: What role do national governance patterns play in comparison to global governance practices in shaping the corporate sustainability (CS) management of transnational corporations (TNCs)? In order to further operationalize this research objective, it is structured into three subquestions: (1) What are relevant institutional factors and global governance patterns for corporate sustainability/ Corporate Social Responsibility (CSR)? (2) What are relevant institutional factors and national governance patterns for corporate sustainability/CSR in Germany, the US, and India? (3) How do these national and global governance patterns influence TNCs' CS management? The first two questions aim at tracing the institutional framework and governance patterns at both national and international levels by identifying norms, stakeholder expectations, prevalent modes of governance and actors involved in governance processes. On this basis, the third question targets TNCs' reaction to internationally varying governance patterns. Here, it is of main interest how relevant governance instruments are perceived by business actors and to which extent their sustainability management at the companies' headquarters and subsidiaries reflect global and national institutional and governance patterns. In order to answer these questions, literature research and a structured qualitative analysis have been conducted. The concepts of CS and CSR build the basis to analyze how TNCs and their subsidiaries manage their social and ecological corporate responsibilities. Against this conceptual background, the research question is approached empirically by the means of an international comparison. Three institutionally highly diverse countries were chosen: Germany, India and the US. India, an emerging market economy, was included to increase the diversity of the sample and to close the research gap indicated above. In order to identify the differences in governance for CS in these three countries, document analyses and 42 guideline-based interviews with experts from governments, NGOs, trade unions and trade associations were carried out. At the same time, global governance instruments for corporate sustainability – which are already relatively well researched - were identified by analyzing the relevant secondary literature. In a second step, in order to explore how TNCs strategically deal with the multitude of different governance approaches at their headquarters and subsidiaries, three case studies of Germany-headquartered transnational corporations in the chemical and engineering industries (Siemens, BASF and Bayer) have been conducted.
The effects of habitat fragmentation and land use changes are usually studied by relating patterns of genetic diversity and differentiation to environmental factors, habitat history, landscape structure, or to a combination thereof. However, these three drivers are rarely addressed simultaneously. In addition, these studies are usually carried out in conservation-driven contexts, and therefore tend to concentrate on hyper-fragmented landscapes and on rare or endangered species. However, how habitat fragmentation and land use affect widespread species in more typical landscapes has not been fully investigated. This thesis addresses these two gaps. Abax parallelepipedus, a flightless ground beetle with low dispersal power, was used as a model species to test how environmental factors, habitat history, and landscape structure affect genetic diversity and genetic differentiation in three study regions located across Germany. Although all of the study regions represent fairly typical rural landscapes for central Europe, each consisting of a complex matrix of land uses, they differ from one another in terms of environmental factors, habitat history, and landscape structure, and thus can serve as three test cases. In the first stage of the work, the investigator identified polymorphic microsatellite loci which could potentially be used to study genetic diversity and differentiation in A. parallelepipedus. She then developed PCR and genotyping protocols for two suites of loci, in the end selecting to use the set of 14 fully multiplexed loci for the study. After having developed the needed study system, she genotyped over 3300 beetles from 142 study sites. In her investigation of how environmental factors and habitat history affect genetic diversity and genetic differentiation, and found that genetic diversity was being driven by variables that could be related to population sizes rather than by habitat history. She also did not find evidence of an influence of habitat history on the genetic differentiation patterns. Although populations of A. parallelepipedus in the past were probably smaller due to deforestation, they apparently remained large enough to prevent rapid genetic drift. In addition, the researcher carried out a landscape genetics analysis of the genetic differentiation patterns found in each of her study regions, in which she examined the relationship between genetic differentiation and landscape structure. She tested whether she could find patterns of isolation by distance, isolation by resistance, or isolation by barriers in the study regions. No effects of land use or of fragmentation were found. Based on the importance of population sizes found in the previous study, combined with the beetle's known avoidance of non-wooded areas and its inability to cross roads, the investigator concludes that although there is probably little gene flow across the study regions, large population sizes are preventing the rapid development of genetic differentiation. Models simulating the development of genetic differentiation over time in populations of different starting sizes support this conclusion.
The research aims to assess the sustainability of rural electrification efforts based on off-grid photovoltaic (PV) systems in three Andean countries: Chile, Ecuador, and Peru. Although deployment of off-grid PV solutions for rural electrification began in the early 1990s in the Andean region, most of the projects turned out to be unsustainable and did not last. Prior efforts have addressed the different issues and barriers that plagued these projects and inhibited their sustainability. However, these prior analyses were mostly quantitative; systematic qualitative evaluations have been scarce. In this thesis, the researcher addresses the following research question: "Are the rural electrification programs (based on off-grid PV Systems) in the Andean countries sustainable?" In order to answer this research question, he conducted an exhaustive qualitative document analysis complemented by semi-structured expert interviews. The interviewees included experts from different ministries, project managers from leading Non-Governmental Organizations (NGOs), public and private companies ' representatives, supervisors, and researchers. Although the author also describes several relevant PV-based electrification efforts in the Andean countries, the research was aimed at providing an overall picture of the rural electrification efforts in these countries, rather than measuring the success or failure of specific projects. The gathered information allowed me to assess the sustainability of rural electrification efforts in the Andean countries. This assessment was based on a set of indicators corresponding to the four dimensions of sustainability considered in this thesis: institutional, economical, environmental, and socio-cultural. It was found that Ecuador and Chile have consistently failed to ensure mechanisms for the operation and maintenance of the deployed off-grid systems, which has made these solutions in poor Chilean and Ecuadorian communities inevitably unsustainable. Although Peru has adopted a cross-tariff scheme, the Peruvian case shows that ensuring the funding of off-grid PV solutions is not enough. Peruvian officials appear to be unaware of the importance of local participation (local values and lifestyles are constantly disregarded) and most of the projects have been designed without the participation and engagement of the communities, which has often led to project failures and payment defaults. Although each country has its particular challenges, it was found that the three Andean countries have consistently neglected the importance of strong formal institutions with a flexible and decentralized structure, which in turn significantly compromised the rural electrification effort in these countries.
Wood-pastures have been present in Europe for thousands of years. This form of grazed landscape, combining herbaceous vegetation with trees and shrubs, has often co-evolved with its human users into complex social-ecological systems (SES). Wood-pastures are associated with high cultural and biodiversity values and are an example of the sustainable use of resources. However, due to their often relatively labour-intensive management and low productivity, large areas of wood-pastures have been lost over the last century. The loss of these areas means not only the loss of biodiversity on both local and landscape scales, but also the loss of traditional farming and cultural heritage in some regions. Across the European Union, wood-pastures are facing different problems and are embedded in different social systems and ecological environments. Yet they are all affected by global change and common European policies. To understand the challenges for wood-pastures in a changing world, a holistic approach combining different disciplines is needed. This dissertation therefore is analyzing wood-pastures across Europe as a Social-ecological System, combining ecology and social science with the aim to identify the barriers and drivers for wood-pastures persistence into the future.
European species-rich grasslands are threatened both by land use intensification as well as land abandonment. The studies shown in this thesis tested the possible use of ecological knowledge to ensure hay productivity whilst maintaining diversity of grasslands, with a view to informing ecological restoration. The overall approach was to understand interactions between plants, to study diversity effects on productivity, and mainly investigate how plant functional groups that arrive first in the system can create priority effects that influence community productivity both above- and belowground. A grassland field experiment was established and monitored for four years, in order to verify the effects of manipulating the order of arrival of different plant functional groups, as well as the sown diversity level on productivity and methane yield. The overall findings were: a) sowing legumes first created priority effects aboveground (higher biomass) and belowground (lower root length), plants invested less in roots and more in shoots, b) priority effects were more consistent below than aboveground, c) sown diversity did not affect aboveground biomass, d) the order of arrival treatments indirectly affected methane yield by affecting the relative dominance of plant functional groups. Since the researchers lack information on how legumes and non-legumes interact spatially belowground, (particularly related to root foraging) a controlled experiment was performed, using two grass species and one legume. The identity and location of the neighbours played a role in interactions, and the order plants arrived modulated it. When the focal species (grass) was growing with a legume it generally equated to the same outcome as not having a neighbour. Roots from the focal species grew more toward the legume than the grass neighbour, indicating a spatial component of facilitation. Since these studies involved root measurements, a method study was also conducted to verify how comparable and accurate are root length estimates obtained from different techniques. Results showed that the use of different methods can lead to different results, the studied methods did not have the same accuracy, and the automated methods can underestimate the root length. Overall, the results allow to conclude that different groups of plants arriving before others affected above and belowground biomass, roots may be key drivers during the creation of these priority effects, and interaction outcomes between plants depended on neighbour identity and location, modulated by the order they arrive in. The results suggest that priority effects can be used by sowing different species or plant functional groups at different time to steer a community to a desired trajectory depending on the restoration goal. However, there is a need to test contingency, potential, and long term impacts of such possible tools for restoration.
A solid knowledge about nature is essential to understand the consequences of biodiversity loss, the limitation of natural resources and the need for a sustainable development. Inspired by these challenges, the researcher investigated in her dissertation seed predation, an important ecosystem function, as part of citizen science project. As seed predation has only rarely been investigated along urban-rural gradients and to integrate the question if the background (urban vs. rural) of primary school children affects their environmental knowledge, she selected study sites in and around Lüneburg and Hamburg, in Northern Germany. In her ecological experiments, it was found that slugs are important seed predators that independently of urbanization predated about 30% of all seeds in the anthropogenically used landscapes investigated. Also, for the first time, primary school children could be integrated in a citizen science approach into this research and it could be shown that even seven year old children can record data as reliable as a scientist. Finally, the researcher investigated the native species knowledge from the children taking part as citizen scientists in her research, considering possible differences due to their urban or rural background. Contrary to her expectation, the urban or rural background had no significant effect on the species knowledge. However, the work provides a good foundation to transfer the approach of introducing a basic foundation of a taxonomical species concept in primary school to foster further understanding on biodiversity and ecosystem functions.
Restoration and management of abandoned, dry Continental heathland and sandy grassland communities
(2018)
Whereas heathlands in the Atlantic biogeographical region have been in the centre of interest, dry heathland communities in the Continental biogeographical region have been widely neglected. Thereby, the conservation status of both habitat types is listed as unfavourable-bad across the Continental biogeographical region. Surprisingly, no detailed studies are available on cost-efficient and sustainable restoration and management schemes to successfully restore and maintain highly degraded, long-abandoned Continental heaths and sandy grasslands, and thus, to counteract the poor conservation status of the habitat types. This shows the great need for research for the Continental biogeographical region. Thus, the present thesis provides substantial knowledge about the population dynamics of the key plant species of dry heaths Calluna vulgaris (L.) HULL by investigating key processes in the biology of the species as well as about the restoration and management of long-abandoned, dry Continental heathland and sandy grassland communities. In order to better understand the process of successful Continental heathland restoration, I analysed the reproductive potential (seed production, soil seed bank, and germination ability of seeds) of degenerate Calluna stands as well as the effects of single and combined management options on the generative rejuvenation (i.e., recruitment and survival) of Calluna. The results are based on a comprehensive three-year field experiment including the management options year-round, low-intensity cattle and horse grazing, one-time mowing and one-time shallow soil disturbances combined with greenhouse investigations on the soil seed bank content and germination ability of Calluna seeds. The results showed that even after long-term abandonment, seed production of degenerate Calluna stands and the germination ability of seeds proved to be high, being similar to Atlantic heathlands, whereas the soil seed bank is considerably reduced probably due to the dry conditions in the Continental region. In addition, low-intensity grazing with free-ranging robust breeds and the combination with one-time mowing at the beginning of the restoration process is an effective means of supporting the generative rejuvenation of this key plant species in degraded Continental heaths. The second study of this thesis focussed on the first-year establishment of Calluna in managed and unmanaged dry heaths and heaths in mosaics with dry sandy grasslands. The germination ability of seeds of different life-history phases of Calluna was analysed to determine if the predominance of the late life-history phase restricts the rejuvenation process of this key plant species. In addition, beside effects of management measures (year-round, low-intensity grazing, one-time mowing, one-time shallow soil disturbances) the author analysed the most important safe site conditions that possibly influenced the germination and the first-year survival of Calluna. The results of the study combine field experiments with growth chamber investigations. The author found that life-history phase of Calluna did not significantly affect seed germination and thus, the predominance of the degenerate life-history phase does not restrict the rejuvenation process. In addition, the results of the study revealed that grazing and thus trampling intensity must be temporarily and locally enhanced at the beginning of the restoration process of highly degraded heaths to increase safe site availability for successful Calluna establishment. Thereby, shadowing is the most important safe site condition. In the third study, the author investigated the impacts of year-round low-intensity cattle and horse grazing on the development of the highly competitive grass Calamagrostis epigejos (henceforth referred to as Calamagrostis), as well as the vegetation structure and plant species richness of long-abandoned but nutrient-poor dry heathland and sandy grassland communities, their mosaics and Calamagrostis stands. Finally, I assessed the local conservation status of the habitat types after seven years of grazing in comparison to long-abandoned sites. The results are based on a comprehensive field study on two spatial scales (plot-level: 25 square meters, macroplot-level: 1 ha). The author found that grazing successfully reduced the coverage and prevented the further spread of Calamagrostis, while simultaneously maintained or improved characteristic species richness and vegetation structure across the different nutrient-poor vegetation types over time, and thus enhanced the local conservation status of habitat types of community interest. In conclusion, the results of the studies considerably improved the understanding of dry, Continental heathland and sandy grassland restoration and management. They provide evidence that even after long-term management abandonment, year-round low-intensity cattle and horse grazing is a suitable management tool for restoring, maintaining and even improving nutrient-poor heathland and sandy grassland communities. However, at the beginning of the restoration process, additional management measures are necessary to faster restore abandoned habitats, especially highly degraded heaths.
The fact that digitalization comes along with a lot of negative effects onto the environment is slightly known in the case of energy consumption by hardware, especially regarding mobile devices, having a limited battery life. However, awareness of environmental issues of software, being the driver of hardware, is mainly missing, even if the research field addressing corresponding issues is growing. Thus, the doctoral thesis at hand addresses the question How to draw (a) developers and (b) usersattention to environmental issues of software? By presenting (a) a calculation method of the carbon footprint of software projects and (b) a concept for an eco-label for software products, evaluated by a user survey, the doctoral thesis provides two strategies how to draw the attention to environmental issues of software. Summarizing, this thesis can act as a basis for further research in bridging from science to society in the context of environmental issues of software. Its findings can be seen as starting points for practical implementations of methods and tools supporting a more environmentally friendly way of developing software and informing about environmental issues of software usage. In order to get the implementation of the research results of the thesis going, it highlights practical implications for diverse groups of stakeholders - researchers, certifiers, public administration and professional purchasers, and environmental associations - that have been identified as being important for the practical implementation of the presented concepts and, thus, represent the target group of the doctoral thesis.
In this dissertation, a multi-proxy study, which included palaeoecological, lithological, geochemical and geochronological methods, was carried out to investigate climatic and environmental changes and their interaction during the Quaternary in formerly glaciated and non-glaciated areas. The information obtained will be used to provide a better understanding of the regional stratigraphic framework and to establish broader regional terrestrial correlations within the global marine isotope stage (MIS) framework. This study was conducted on two key drillings, the Garding-2 research drill core in the German North Sea coastal area of Schleswig-Holstein and the GBY#2 archaeological core at the Gesher Benot Ya'aqov (GBY) site, in the Upper Jordan Valley in Israel. The results of this study are presented in three papers. Papers I and II focus on the study of the Garding-2 core, while the multi-proxy study of the GBY#2 core is presented in Paper III. The results of a variety of analyses conducted on the 240 m long Garding-2 sequence show interglacial-glacial cycles that are mainly controlled by variations in temperature. This sequence is composed of mainly fluvial-shallow marine sediments intercalated by muddy-peaty deposits. Based on the palynological and lithological findings, the Pliocene-Pleistocene transition was observed at 182.87 m. It is overlain by Praetiglian and the subsequent sediments of the Waalian and Bavelian Complexes. The boundary of either the second or third Cromerian Interglacial with younger sediments, which still belong to MIS 19, is marked by the last occurrence of Tsuga at 119.50 m and the development of mixed-deciduous forests. The palynologically equivalent sediments of the Bilshausen Interglacial were found below two Elsterian till layers, at 89.00 m-82.00 m. These sediments showed high and increased percentages of Pinus and Picea and scattered occurrences of Abies and Carpinus, which are similar to the features of the beginning of the Bilshausen or Rhume interglacial. An unconformity occurred at 80.29 m, at the bottom of late Holsteinian deposits, characterised by the occurrences of Fagus and Pterocarya, with low percentages of Abies and Carpinus and the absence of Buxus. These deposits are succeeded by sediments of the Fuhne cold period that shows higher percentages of NAP and occurrences of Ericales, Helianthemum and Selaginella selaginoides, which are unconformably overlain by Drenthian till at 73.00 m-71.00 m. A single peaty sample at 69.25 m with Pinus-Picea-Abies assemblage is correlated with the late Eemian Interglacial. This deposit is overlain by Weichselian glaciofluvial sediments. Middle-late Holocene sediments occurred from 20 m upwards, following a hiatus, which was caused by the Early Holocene transgression. A subsequent thin layer of marine Atlantic sediments is unconformably overlain by marine-tidal flat deposits up to 11.00 m. The first occurrence of Fagus (at 15.97 m) and Carpinus (at 15.03 m), which was optically stimulated luminescence (OSL)-dated to 3130 +/- 260 BP (at 16.22 m, Zhang et al., 2014), gives evidence for a Subboreal age for these deposits. Sandy sediments of the early Subatlantic, which were deposited between 11.00 m and the top of the Garding-2 sequence, indicate that local salt marshes, dunes and tidal flat vegetation expanded during this period. Due to regional features and the peculiarities of the local coastal environment, the expansions of Fagus and Carpinus, which are characteristic for the Subboreal-Subatlantic transition at about 2700 BP in northern Germany, are not clearly reflected in the Garding-2 pollen diagram. In the Mediterranean area, a 50 m long core of GBY#2, was drilled at the Acheulian site of Gesher Benot Ya'akov. The GBY#2 core provides a long Early-Middle Pleistocene geological, environmental and climatological record, which also enriches the knowledge of hominin-habitat relationships documented at the margins of the Hula Palaeo-lake. The sediment sequence of GBY#2 is under- and overlain by two basalt flows that are 40Ar/39Ar dated: two samples at the bottom of the core dated to 1195 +/- 67 ka (at 48.30 m) and 1137 +/- 69 ka (at 45.30 m), and another one at the top dated to 659 +/- 85 ka (at 14.90 m). With the additional chronological identification of the Matuyama Brunhes Boundary (MBB) and the correlation with the GBY excavation sites, the sedimentary sequence of GBY#2 provides the climatic history during the late part of the mid-Pleistocene transition (MPT, 1.2 Ma-0.5 Ma). Multi-proxy analyses including those of pollen and non-pollen palynomorphs, macro botanical remains, molluscs, ostracods, fish, amphibians and micromammals provide evidence for lake and lake-margin environments during MIS 20 and MIS 19. During MIS 20, relatively cool semi-moist conditions were followed by a pronounced dry phase. During the subsequent MIS 19, warm and moist interglacial conditions were characterised by Quercus-Pistacia woodlands in this area. The depositional environment changed from an open water lake during MIS 20 to a lake margin environment in MIS 19. This finding is at odds with changing climate conditions from relatively dry to moist. This discrepancy could be explained by the prograding pattern of the lake shore due to the infilling of the basin, which resulted in shallower water. Climatic changes during the Late Tertiary and the Quaternary in the high latitude regions in northwest Europe and during the Early-Middle Pleistocene in the mid latitude regions of the Middle East follow the patterns of global climatic changes, which are mainly controlled by orbital obliquity (+/-41 ka cycle) during the Early Pleistocene and by orbital eccentricity (+/-100 ka cycle) during the MPT (1.2 Ma-0.5 Ma) and the younger periods of the Quaternary. The results of this study also provide reliable evidence for long distance correlation of stratigraphic and climatic events of the Quaternary, which extends knowledge of regional and global impact of climatic fluctuations on the environment.
The German energy system is under transformation. The so-called Energiewende (in English, Energy turn) relies, among other things, on renewable energies for building a more sustainable energy system. Regions (Landkreise) are one relevant level where different administrative bodies make decisions and plans both for the implementation and for the use of renewable energies. However, in order to realize the goals of the Energiewende, developments in the wider society are necessary. This is why scientific research can and should foster such developments with more research on the social aspects of energy-related topics. The present work contributes to the understanding of transition processes towards a sustainable use of regional renewable energy by focusing on the role of contextual conditions, practical experiences, and temporal dynamics in the implementation and use of renewable energy in German regions. In this way, this work wants to contribute fostering the development of regional energy transition strategies for the realization of the Energiewende. The conceptual background for this piece of transformation research lies in three bodies of literature dealing respectively with transitions of socio-technical systems, transformations of socioecological systems, and time ecology. From a critical engagement with this literature, three main results have emerged. First, an evidence-based, spatially distinct analysis of contextual conditions for the use of renewable energy in all German regions has resulted in the identification of nine types of regions, so-called energy context types. Second, empirical research on practices in regional settings learned from the knowhow of actors from regional administration has shown that political and economic conditions are crucial as well as that process management, exchange, and learning are helpful for renewable energy implementation. Third, conceptual work about a deeper understanding of the temporal dimensions of transformation processes has made it possible to point out a three-step approach to include temporal dynamics into sustainability transformations management - the time-in-transformations-approach. The literature suggests that regions need to be treated individually; but developing an energy transition strategy for each region individually would be extremely resource intensive. Overall, this work outlines a compromise for a more efficient approach towards regional energy transition strategies which still considers the individuality of regions. As a result, the author suggests to develop generic regional energy transition strategies that are adapted to each of the nine energy context types of German regions, that include the experiences of practitioners, and that consider temporal dynamics of transformation processes. Transdisciplinary research is a promising approach to meet many of the challenges for the realization of the Energiewende.
Organophosphorus flame retardants and plasticizers (OPEs) have been utilized for decades as plasticizers and, to a lesser extent, as flame retardants in various consumer products to improve their material properties. The research presented in this thesis investigated the occurrence, distribution and transport of OPEs with a focus on the coastal and estuarine environment. Due to the wide range of physicochemical properties of OPEs, the environmental fate and behaviour of OPEs was investigated over a range of compartments, starting from the atmospheric occurrence to the aquatic phase and the behaviour in sediments. The aim was to gather information on the OPE contamination situation in the coastal and estuarine environments, to identify specific contamination patterns for source assessment and to investigate the distribution behaviour of OPEs between gas- and particle-phases to evaluate their environmental transport mechanism. To achieve these scientific goals, sensitive and robust chemical analytical methods for the detection and quantification of OPEs in a variety of environmental samples using gas-chromatography coupled with tandem mass spectrometry were developed. Water samples were removed along the Elbe and Rhine Rivers to test the hypothesis of whether specific point sources, such as wastewater treatment plants, are the major input pathways for OPE contamination in rivers. A total of 65 water samples, including an intensive measurement campaign during the flood event in 2013 at the Elbe, was taken and analysed for OPEs. No obvious point sources were identified along either of the rivers analysed. No significant increase or decrease in the OPE concentrations or a change in patterns were observed over a transect of over 300 km at the Elbe, with an increase in water discharge of 2.5. This finding suggested that the OPE input in large rivers is primarily driven by diffuse sources, such as surface runoff, or by minor point sources rather than local point sources. To examine the specific pattern of OPE contamination in individual rivers and estuaries, 37 sediment samples from 8 rivers in Europe and China were analysed. With this analytical data, a fingerprint analysis of the OPE patterns identified could be conducted. All the rivers investigated in Europe displayed a very similar fingerprint. In contrast, the fingerprint from China differed significantly from the one in Europe. For example, in China, the OPE restricted in Europe, Tris(2-chloroethly)phosphate, was found to be one of the major OPE components, while Tris(2-butoxyethyl) phosphate, a major compound in Europe, was negligible in China. The investigation showed that the fingerprinting analysis is a useful tool to identify different regions or characterize specific rivers regarding their OPE contamination. In addition, it could be shown that legislative restriction and processes have an impact on local or even EU-wide contamination patterns. At a coastal site next to the German city of Büsum, 58 air samples were taken over one year. Using the newly developed analytical method, it was possible to analyse the gas, as well as the particle phase, of the samples collected with very low detection limits for OPEs. In contrast to expectations, no annual trend in OPE concentrations, phase distributions or patterns was observed, but the investigation of the phase distribution challenged the previous scientific consensus that OPEs occur as primarily bound to particles in the atmosphere. Several compounds were detected in significant amounts in the gas phase. To validate these novel results, a model analysis based on the chemical properties of OPEs was conducted using three different phase distribution models. The results from the environmental data were strongly supported by the simulations, and the formal knowledge could be refuted. Consequently, the atmospheric transport assumptions and estimations about the long-range transport of OPEs have to be reassessed because compounds in the gas phase undergo other types of transport degradation and elimination mechanisms than particle-boundones. The novel findings presented in this thesis challenged an important aspect regarding the perceived scientific knowledge about the behaviour of OPEs in the environment and call on the scientific community to reassess the environmental behaviour of OPEs. The insights presented on the patterns highlight the impact of environmental policies and regulatory mechanisms to work towards the final goal of a good environmental status and the avoidance of adverse effects of discarded chemicals on humans and the environment.