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Organophosphorus flame retardants and plasticizers (OPEs) have been utilized for decades as plasticizers and, to a lesser extent, as flame retardants in various consumer products to improve their material properties. The research presented in this thesis investigated the occurrence, distribution and transport of OPEs with a focus on the coastal and estuarine environment. Due to the wide range of physicochemical properties of OPEs, the environmental fate and behaviour of OPEs was investigated over a range of compartments, starting from the atmospheric occurrence to the aquatic phase and the behaviour in sediments. The aim was to gather information on the OPE contamination situation in the coastal and estuarine environments, to identify specific contamination patterns for source assessment and to investigate the distribution behaviour of OPEs between gas- and particle-phases to evaluate their environmental transport mechanism. To achieve these scientific goals, sensitive and robust chemical analytical methods for the detection and quantification of OPEs in a variety of environmental samples using gas-chromatography coupled with tandem mass spectrometry were developed. Water samples were removed along the Elbe and Rhine Rivers to test the hypothesis of whether specific point sources, such as wastewater treatment plants, are the major input pathways for OPE contamination in rivers. A total of 65 water samples, including an intensive measurement campaign during the flood event in 2013 at the Elbe, was taken and analysed for OPEs. No obvious point sources were identified along either of the rivers analysed. No significant increase or decrease in the OPE concentrations or a change in patterns were observed over a transect of over 300 km at the Elbe, with an increase in water discharge of 2.5. This finding suggested that the OPE input in large rivers is primarily driven by diffuse sources, such as surface runoff, or by minor point sources rather than local point sources. To examine the specific pattern of OPE contamination in individual rivers and estuaries, 37 sediment samples from 8 rivers in Europe and China were analysed. With this analytical data, a fingerprint analysis of the OPE patterns identified could be conducted. All the rivers investigated in Europe displayed a very similar fingerprint. In contrast, the fingerprint from China differed significantly from the one in Europe. For example, in China, the OPE restricted in Europe, Tris(2-chloroethly)phosphate, was found to be one of the major OPE components, while Tris(2-butoxyethyl) phosphate, a major compound in Europe, was negligible in China. The investigation showed that the fingerprinting analysis is a useful tool to identify different regions or characterize specific rivers regarding their OPE contamination. In addition, it could be shown that legislative restriction and processes have an impact on local or even EU-wide contamination patterns. At a coastal site next to the German city of Büsum, 58 air samples were taken over one year. Using the newly developed analytical method, it was possible to analyse the gas, as well as the particle phase, of the samples collected with very low detection limits for OPEs. In contrast to expectations, no annual trend in OPE concentrations, phase distributions or patterns was observed, but the investigation of the phase distribution challenged the previous scientific consensus that OPEs occur as primarily bound to particles in the atmosphere. Several compounds were detected in significant amounts in the gas phase. To validate these novel results, a model analysis based on the chemical properties of OPEs was conducted using three different phase distribution models. The results from the environmental data were strongly supported by the simulations, and the formal knowledge could be refuted. Consequently, the atmospheric transport assumptions and estimations about the long-range transport of OPEs have to be reassessed because compounds in the gas phase undergo other types of transport degradation and elimination mechanisms than particle-boundones. The novel findings presented in this thesis challenged an important aspect regarding the perceived scientific knowledge about the behaviour of OPEs in the environment and call on the scientific community to reassess the environmental behaviour of OPEs. The insights presented on the patterns highlight the impact of environmental policies and regulatory mechanisms to work towards the final goal of a good environmental status and the avoidance of adverse effects of discarded chemicals on humans and the environment.
Whereas the extant literature discusses what Sustainability-Oriented Innovations (SOIs) are and why firms develop them, little is known about how they are developed. To enable firms to innovate for sustainability, it is essential to know more about the processes underlying SOI development, which are considered as very difficult, with many firms failing. Drawing on several academic papers and relying on qualitative research methods, the thesis uses the Fireworks model to examine how innovation processes unfold at established small and medium-sized enterprises (SMEs). The main contribution of the thesis is to advance the Fireworks model to the context of SOIs unfolding at SMEs. The findings reveal that SOIs unfold in an emergent, somewhat chaotic way, that duration and outcome are uncertain, that the overall journey is composed of multiple intertwined innovation paths, of which several will likely lead to setbacks. To manage this complex process, the thesis suggests to set four management foci: (1) to create a dedicated organizational unit for exploration, (2) to create conditions allowing intelligent learning for efficient exploration, (3) to carry out in-depth investigation of the related technological innovation systems, and (4) to plan carefully the re-integration of the innovation into the core business for commercialization.
Companies are invited to contribute to the United Nations' 17 Sustainable Development Goals (SDGs) and sustainability management accounting (SMA) has an important role to play in achieving them. However, if companies are to address the SDGs and linkages beyond organizational boundaries, SMA needs a broader scope than is conventionally assumed. Therefore, the author advances a multi-level framework that addresses context, action-formation, and transformative contributions (CAT) in the following directions: first, an innovative systematic method that allows screening company-related SDGs and assessing corporate contributions to selected SDGs is introduced; second, management control systems are integrated to support managers in guiding employee behavior to make contributions to the SDGs; and, third, self-reinforcing mechanisms of the path-dependence theory are incorporated to serve as a guide to identifying barriers to individuals and groups becoming involved in SMA. This advanced CAT framework contributes to corporate practice and research by providing a multilevel framework that offers concrete management guidance for SMA to address the SDGs. It also facilitates analysis of both enabling and inhibiting factors at the organizational level. The advanced CAT framework has several implications for SMA: it promotes backcasting from the SDGs for benchmarking purposes, integrates different social, environmental, and economic issues, facilitates future-oriented action and transformation planning, addresses different layers such as the company as well as individuals and groups within it and enables to identify barriers hindering individuals and groups from becoming involved in SMA.
This dissertation addresses the question of how sustainability curricula can be implemented and established in higher education institutions. Universities – as hubs for knowledge generation, innovation, and education – provide a central leverage point for sustainably developing society at large. Therefore, the institutionalization of sustainability curricula is not only socially demanded, but also stipulated in numerous political statements from the international community (e.g., those of the UN and UNESCO) and operationalized via Sustainable Development Goal No. 4: "Quality Education". Previous findings on how such implementation can be successful and what factors support or inhibit the process have come primarily through case studies of individual higher education institutions. These studies have been largely descriptive rather than analytical and leave open questions about the generalizability of their findings. The present dissertation addresses this research gap. Through a meta-study (i.e., an analytical comparison of existing case studies), generalizable findings on the implementation processes of sustainability curricula are explored. In the first step, a case universe was collected in order to provide a database for deeper analyses. In two further analysis steps that built on the case universe from Step 1, certain factors that promote or inhibit the implementation of sustainability curricula (Step 2) and specific implementation patterns (Step 3) were examined. The presented findings add a complementary empirical perspective to the discourse on the establishment of education for sustainable development (ESD) at higher education institutions. First, the case studies that specifically address the implementation processes of sustainability curricula are reviewed and analyzed here for the first time as part of a research landscape. This research landscape reveals where research on such implementation processes has been or is being conducted. On this basis, both researchers and funders can reflect on the status quo and plan further research or funding endeavors. Second, this dissertation offers the opportunity to compare a multitude of individual case studies and thus to develop new and generalizable insights into the implementation of sustainability curricula. The empirical analysis uses 133 case studies to identify key factors that promote or inhibit the implementation of sustainability curricula and to add a complementary perspective to the discourse, which has thus far been dominated by theoretical considerations and individual case studies. The analysis thereby offers a new perspective on generalizable influencing factors that appear to be important across different contexts. Thus far, specific patterns of implementation processes have been infrequently studied, and with few datasets. This dissertation analyzes the complex interplay between over 100 variables and provides one of the first research attempts at better understanding the processes that lead to the deep-rooted and comprehensive implementation of sustainability curricula. Internal and external practitioners of higher education institutions can find examples and evidence that can be useful in planning the next steps of their sustainability curriculum implementation. This dissertation offers generalizable empirical findings on how universities can succeed in recognizing their own responsibility to that end and in realizing this transformation through the implementation of ESD.
Metals fulfill crucial functions in areas as diverse as renewable energy, digitization and life style appliances, mobility, communication, or medicine. In the context of sustainability, achieving a more sustainable metal use means (i) minimizing the adverse effects associated with metal production and use and (ii) sustaining the availability of metals in a way that benefits present and future generations. Urgent need to act to avoid bottlenecks as well as meeting the challenge of possible conflicts of use among those areas of application calls for appropriate strategy making to intervene in the complex field of metal production and use that involves various, often interlinked operating levels, actors, and spatial and temporal scales. This dissertation focuses on strategies as a means to intervene in a system. It pursues the question, which design features could guide future strategy making to foster sustainability along the whole metal life cycle, and especially, how a better understanding of temporalities, i.e. understanding time in a diverse sense, could improve strategy design and help to bridge the assumed "transformation-material gap". This research converges the results from four research studies. A conceptual part explores the role of temporalities for interventions in complex and interlinked systems, which adds to the conceptual basis, on which the empirical part builds up to explore present and future interventions in metal production and use. The research revealed three essential needs that future strategies must tackle: (i) managing the complex interlinkages of processes and activities on various operational levels and spatial and temporal scales, (ii) providing clear guidance concerning the operationalization of sustainability principles, and (iii) keeping activities within the planet’s carrying capacity and embracing constant change as an inherent system characteristic. In response to these needs, the author developed three guidelines with two design features each (one relating to content, and one to the process of formulating and implementing the strategy) to guide future strategy making. The results show that time matters in this respect. If considered in close relation to space and diversely understood in the sense of temporalities, it serves to (i) understand the impact (duration and magnitude) of an intervention, (ii) recognize patterns of change that go beyond establishing linear, one-dimensional connections, and (iii) design interventions in a way that considers the resilience of a system. These findings can contribute to closer considering our understanding of transformation processes towards sustainability in future interventions in metal production and use.
European species-rich grasslands are threatened both by land use intensification as well as land abandonment. The studies shown in this thesis tested the possible use of ecological knowledge to ensure hay productivity whilst maintaining diversity of grasslands, with a view to informing ecological restoration. The overall approach was to understand interactions between plants, to study diversity effects on productivity, and mainly investigate how plant functional groups that arrive first in the system can create priority effects that influence community productivity both above- and belowground. A grassland field experiment was established and monitored for four years, in order to verify the effects of manipulating the order of arrival of different plant functional groups, as well as the sown diversity level on productivity and methane yield. The overall findings were: a) sowing legumes first created priority effects aboveground (higher biomass) and belowground (lower root length), plants invested less in roots and more in shoots, b) priority effects were more consistent below than aboveground, c) sown diversity did not affect aboveground biomass, d) the order of arrival treatments indirectly affected methane yield by affecting the relative dominance of plant functional groups. Since the researchers lack information on how legumes and non-legumes interact spatially belowground, (particularly related to root foraging) a controlled experiment was performed, using two grass species and one legume. The identity and location of the neighbours played a role in interactions, and the order plants arrived modulated it. When the focal species (grass) was growing with a legume it generally equated to the same outcome as not having a neighbour. Roots from the focal species grew more toward the legume than the grass neighbour, indicating a spatial component of facilitation. Since these studies involved root measurements, a method study was also conducted to verify how comparable and accurate are root length estimates obtained from different techniques. Results showed that the use of different methods can lead to different results, the studied methods did not have the same accuracy, and the automated methods can underestimate the root length. Overall, the results allow to conclude that different groups of plants arriving before others affected above and belowground biomass, roots may be key drivers during the creation of these priority effects, and interaction outcomes between plants depended on neighbour identity and location, modulated by the order they arrive in. The results suggest that priority effects can be used by sowing different species or plant functional groups at different time to steer a community to a desired trajectory depending on the restoration goal. However, there is a need to test contingency, potential, and long term impacts of such possible tools for restoration.
This thesis aims at contributing to the better understanding of the roles of international and domestic institutional and governance patterns for corporate sustainability practices. By combining governance and new institutionalism approaches it bridges the gap between the close look at specific corporate sustainability (CS) policies and the broader view on institutional frameworks. The qualitative comparative approach aims to provide deeper insights on the implementation of different governance schemes by transnational corporations ((TNC). Finally, the conclusions might allow for the development of a) recommendations for the balancing of TNCs' CS management between global and domestic requirements, and b) policy recommendations in the field of CS governance. The overarching research question is as follows: What role do national governance patterns play in comparison to global governance practices in shaping the corporate sustainability (CS) management of transnational corporations (TNCs)? In order to further operationalize this research objective, it is structured into three subquestions: (1) What are relevant institutional factors and global governance patterns for corporate sustainability/ Corporate Social Responsibility (CSR)? (2) What are relevant institutional factors and national governance patterns for corporate sustainability/CSR in Germany, the US, and India? (3) How do these national and global governance patterns influence TNCs' CS management? The first two questions aim at tracing the institutional framework and governance patterns at both national and international levels by identifying norms, stakeholder expectations, prevalent modes of governance and actors involved in governance processes. On this basis, the third question targets TNCs' reaction to internationally varying governance patterns. Here, it is of main interest how relevant governance instruments are perceived by business actors and to which extent their sustainability management at the companies' headquarters and subsidiaries reflect global and national institutional and governance patterns. In order to answer these questions, literature research and a structured qualitative analysis have been conducted. The concepts of CS and CSR build the basis to analyze how TNCs and their subsidiaries manage their social and ecological corporate responsibilities. Against this conceptual background, the research question is approached empirically by the means of an international comparison. Three institutionally highly diverse countries were chosen: Germany, India and the US. India, an emerging market economy, was included to increase the diversity of the sample and to close the research gap indicated above. In order to identify the differences in governance for CS in these three countries, document analyses and 42 guideline-based interviews with experts from governments, NGOs, trade unions and trade associations were carried out. At the same time, global governance instruments for corporate sustainability – which are already relatively well researched - were identified by analyzing the relevant secondary literature. In a second step, in order to explore how TNCs strategically deal with the multitude of different governance approaches at their headquarters and subsidiaries, three case studies of Germany-headquartered transnational corporations in the chemical and engineering industries (Siemens, BASF and Bayer) have been conducted.
Transforming the International Food Supply – Sustainable Practices in Small Intermediary Businesses
(2021)
The global food system faces many complex challenges, and there is general agreement that a transformation is needed. While localizing food has been proposed as a means to this end, changing global food supply chains may also lead to sustainable food systems. Because most food systems today have an international dimension and are likely to remain connected, on one way or another, to other ones across the globe, it is necessary to find solutions to problems such as exploitation or environmental degradation. Addressing this challenge and the related gap in the literature, this study examines the emerging practices of small intermediary food businesses, which act between agricultural producers and consumers, and may have the potential to advance sustainability in international food supply. Including a systematic review of the literature on food systems change (Study#1), this dissertation adopts a transformational sustainability research methodology, which is solution-oriented, aims to integrate system, target and transformation knowledge, and is characterized by a transdisciplinary research practice. It conceptualizes challenges of international food supply and empirically investigates entrepreneurial solution approaches to address these challenges (Study#2). Two transdisciplinary research projects with small coffee businesses located in Germany, Mexico, and the U.S. were conducted to examine how these approaches could be implemented (Study#3, Study#4, Workshop reports 1+2). Overall, this study shows that challenges in international food supply chains can be conceptualized as negative effects of large geographical and relational distances. It also identifies five entrepreneurial solution approaches specified by twelve sustainability-oriented design principles to address these negative effects. Creating relational proximity between supply chain actors, that is, strong relationships based on knowledge and care, seems to be a key factor to advance sustainability in international food supply.The results also suggest that by building such strong relationships and changing the fundamental principles of international food trade, small intermediary businesses could be important agents in food system transformations.
One of the Colombian strategies to diversify and decarbonize the energy sector is encouraging the use of non-conventional renewable resources (NCRR). This thesis measures the environmental rebound effect (ERE) when increasing the shares of wind power into the Colombian power grid in the residential (household) sector. For doing so, a process-based Life Cycle Assessment (P-LCA), an environmental extended input output (EEIO) model and re-spending models (almost ideal demand system AIDS) were applied. Direct rebound effect was measured thought the elasticity price of the electricity demand; furthermore, the environmental savings for increasing the shares of wind power into the grid were calculated via P-LCA. For doing so, a P-LCA for a wind farm in Colombia was performed, whereas the information for other energy resources (Hydro, Coal, Gas, Solar and Thermal) where collected from Ecoinvent 3.4 database. To calculate the environmental indirect rebound effect the monetary savings obtained for the environmental efficiency were calculated. For doing so, an AIDS was applied to obtain the marginal budget shares (MBS). Combining the MBS obtained with the EEIO model the monetary savings were translated into environmental indicators. The ERE is presented for ten impact categories (climate change (CC), acidification (A), ecotoxicity (E), marine eutrophication (MEUT), terrestrial eutrophication (TEUT), carcinogenic effects (CE), non-carcinogenic effects (NCE), ozone layer depletion (OD), photochemical ozone creation (POC), and respiratory effects, inorganics (RES)). Moreover, a sensitive analysis was conducted to measure the variability of the ERE to different values of the direct rebound effect and different percentages of price efficiency. The results show that the inclusion of the environmental rebound effect has generally a non-negligible impact on the overall environmental indicators across all studied years. Such impacts ranging across impact categories from 5% (eutrophication) and 6,109% (photochemical oxidant creation) for the combined model, whereas for the single model the values fall on the ranges of 1% (eutrophication) and 9,277% (photochemical oxidant creation). Further, a sensitivity analysis of the elasticity price of the electricity and the price of the electricity reveals that the ERE varies in different ways, specifically, changes in these parameters could vary the impacts, respectively, by up to about <1% and 38%. Backfire effects are present for 8 of the 10 environmental impacts studied in different magnitudes across the years, depending meanly of the savings available to re-invest.
The agreement on the 17 Sustainable Development Goals (SDGs) by the UN General Assembly in September 2015 was a milestone in the common history of international development and sustainability governance. However, in order to be effective, it is necessary to identify and to define suitable instruments that can be applied in order to fulfill the ambitious goal catalogue. Therefore, the underlying thesis examines the concept of Village Savings and Loan associations (VSLAs) with regard to its mechanisms that operate towards an attainment of the respective goal category. VSLAs are self-government, autonomous and democratically organized Microfinance Institutions (MFIs). They consist of a maximum of 25 mostly female members, who know and trust each other. The work is carried out within a qualitative-empirical research design applied in central Cameroon, which has to some extent exemplary character for sub-Saharan Africa. In this manner, guided experts interviews were conducted with VSLA-presidents as well as with field officers that are creating and accompanying VSLAs. A first part addresses the historical evolution of the SDGs and the theoretical and actual implications of Microfinance and the VSLA-methodology. After considering the methodological proceeding, the results are presented, discussed and summarized in a conclusion. All in all, 22 mechanisms for the attainment of nine SDG-categories are identified and described. Of particular importance is the key role of the credits to trigger fruitful activities that generate financial wealth, economic growth and employment. Furthermore, the savings of the members are an important factor for the school enrollment of the members´ children. Additionally, a combination of the credits and the solidarity fund improves the medical treatment of the members and their families. In contrast to that, direct mechanisms supporting the nutritional situation or gender equality in the research field are found to have a limited importance. Moreover, none of the identified mechanisms targets the environmental sphere of the SDG-catalogue. This is weighty in light of an increasing noticeability of the impacts of climate change for the involved population group. Nonetheless, the VSLA-concept is a simple way to effectively address the social and the economic aspects of the SDG-catalogue. In this manner, a further development of the instrument could include the canalization of the capital of international de-velopment cooperation through the VSLAs as democratic and transparent grassroots-institutions.