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The principle of this thesis was to study the environmental fate of three highly used psychotropic drugs and this achieved through: 1) examining the biodegradability of TMI, DMI and CPTX, 2) studying the behaviour of TMP, DMI and CPTX in photodegradation tests using Xe and UV lamps with studying the effect of different environmental conditions on their UV-photodegradation behaviour, 3) monitoring the primary elimination of TMP, DMI and CPTX during photodegradation and biodegradation tests using HPLC, and measuring their degree of mineralization by means of dissolved organic carbon analyser (DOC), 4) elucidating the structures of the transformation products (TPs) which formed during the degradation of TMI, DMI and CPTX by using LC-MS/MS analysis, 5) analysing the biodegradability of their TPs by laboratory tests and in-silico assessments in order to determine the fate and persistence of these TPs in the aquatic environment, 6) conducting in-silico toxicity predictions for the selected psychotropic drugs and their TPs in human (carcinogenicity, genotoxicity and mutagenicity) and in eco-system (toxicity to microorganisms and toxicity in rainbow trouts). As an overall conclusion, the present work demonstrates that a combination of laboratory simulation tests, LC-MS/MS analysis and in-silico tools result in valuable new information regarding environmental fate of three important psychotropic drugs and their TPs. This dissertation also highlights that different environmental conditions such as temperature, initial drug concentration and pH can differently affect the degradation behaviour of pharmaceuticals even when they are highly structurally related. Therefore, one cannot conclude from one pharmaceutical to another but each one needs to be investigated individually and this present a great challenge for risk assessment kinetics of chemicals in the aquatic environment. The results presented here showed that the investigated pharmaceuticals and their TPs can negatively affect the environment which may be harmful to the ecosystem as they might have been present for decades in the aquatic environment without any knowledge of their environmental fate or connected risk. Therefore, further work needs to be done including analysis of environmental samples (e.g., surface waters), as well as laboratory toxicity tests to further expand knowledge on their exact environmental impact.
Excessive fertilizer use leads to nutrient imbalances and losses of these to the environment through leaching, runoff and gaseous emissions. Nutrient use efficiency (NUE) in agriculture is often low and improving it could increase the sustainability of agricultural systems. The main aims of this thesis were to gain a better understanding of plant-soil-microbe interactions in order to improve agricultural NUEs. The studies included experimentally tested how crops respond to addition of high carbon amendments, fertilizer application rates and timing, and crop rotations. Furthermore, methods for measurement of roots were compared and a protocol for measurement of roots was developed. The first experiment simulated an agricultural field using mesocosms. In this setting, the researchers tested the effect of 4 previous crops (precrops), which either had or did not have a symbiosis with arbuscular mycorrhizal fungi (AMF)/rhizobia, on the focal crop (winter barley). They also tested the addition of high carbon amendments (wheat straw/sawdust) for immobilization of residual soil nitrogen (N) at harvest of the previous crop. Overall, the findings were that non-AMF precrops had a positive effect on winter barley yield compared to AMF precrops. Wheat straw reduced N leaching, whereas sawdust addition had a negative effect on the yield of winter barley. The second experiment tested the effect of different fertilizer (N/phosphorus (P)) application timings on plant traits grown in rhizoboxes. Overall, delaying N application had a more detrimental effect on plant biomass than delaying P application. The root system increased its root length initially due to N-deficiency, but was quickly thus N-limited that root length was relatively lower than the control group. Because of the many root related measurements in the second experiment, a step-by-step method for measuring root traits under controlled and field conditions was developed and included in this thesis. This method paper describes precisely how root traits of interest can be measured, and helps with deciding which approach should be taken depending on the experimental design. Additionally, the authors compared the bias and accuracy of several popular root measurement methods. Overall, these results highlight the importance of crop choice in crop rotations and the plasticity of root systems in relation to nutrient application. The results show high carbon amendments could reduce nitrate leaching after the harvest of crops, especially those with high risk of nitrate leaching, although they had only small impacts on yield.
Despite growing research on sustainability transformations, our understanding of how transformative transdisciplinary research can support local actors who foster change towards sustainability is still somewhat limited. To contribute to this research question, the investigator conducted research in a transdisciplinary case study in Southern Transylvania, where non-governmental organizations (NGO) drive sustainability initiatives to foster desired changes (e.g., supporting small-scale farmers or conserving natural and cultural heritage). Interactions with these local actors and reflections on the research question shaped the research of this dissertation. In paper 1, the author conducted a literature review on amplification processes that describe actions, which local actors can apply to increase the impact of their sustainability initiatives. In paper 2, he conducted a literature review on the application of indigenous and local knowledge (ILK) in sustainability transformations research to understand whether this research engages with the conceptualization of transformations from local actors. The results show that ILK is generally applied to confirm and complement scientific knowledge in contexts of environmental, climate, social-ecological, and species change. In paper 3, the author derived principles that provide guidance for how to integrate sustainability initiatives from local actors in transformative transdisciplinary research. Based on his transdisciplinary research with the NGOs in Southern Transylvania and by using systems and futures thinking as an approach for analysis, he derived three principles that provide guidance for the co-design of sustainability intervention strategies that build on, strengthen, and complement existing initiatives from local actors. In paper 4, the author explored empirically how to identify relevant local actors for collaborations that seek to intervene in specific characteristics of a system (e.g., parameters or design of a system). He applied a leverage points' perspective to analyse the social networks of the NGOs in Southern Transylvania that amplify the impact of their initiatives. This dissertation as a whole contributes insights to three recommendations of how transformative transdisciplinary research can support local actors fostering change towards sustainability: First, by conducting research that studies and supports local actors who increase the impact of their sustainability initiatives via amplification processes (Paper 1 and 4); Second, by engaging specifically with the initiatives, networks, and knowledge from local actors, who foster bottom-up, place-based transformations (Paper 1-4); Third, by identifying and collaborating with local actors that are relevant for strategic systems interventions that build on, strengthen, and complement existing initiatives (Paper 3-4).
This doctoral thesis contributes to the vibrant discourse on boundary-crossing collaboration in the German teacher education system. It offers theoretical advancements, programmatic guidelines, and empirical findings which advocate for a transdisciplinary perspective. In order to do so, the framing paper critically links persistent challenges and current reform processes in the teacher education system with theoretical foundations and conceptual positions of transdisciplinarity. Against this backdrop, four articles provide further insights on: a) how to expand the prevalent systematic of innovation and transfer approaches (top-down, bottom-up, cooperative) by a transdisciplinary perspective, b) outlining guiding principles for the realization of transdisciplinary collaboration in the context of a boundary-crossing research and development project, c) providing empirical findings on effect relationships between transdisciplinary dimensions of integration characteristics, and d) identifying empirical types of actors based on specific assessment patterns towards these characteristics.
This thesis analyses how European merger control law is applied to the energy sector and to which extent its application may facilitate the liberalisation of the electricity, natural gas and petroleum industries so that only these concentrations will be cleared that honour the principles of the liberalisation directives. After having discussed the complex micro- and macro-economic considerations which accompany any concentration of business activities, this thesis discusses the merger control regime of the European Community (EC) so as to establish whether the merger control under either Art. 66 Treaty Establishing the European Coal and Steal Community (ECSCT), the case law under Art. 101 and 102 Treaty on the functioning of the European Union (TFEU) and (Art. 81 and Art. 82 Treaty Establishing the European Economic Community (ECT), as it was introduced by the Commission and reviewed by the CJEU, the original Merger Regulation (MR1989) or the amended Merger Regulation of 1997 (MR1997) or the amended Merger Regulation of 2004 (MR2004) facilitate the liberalisation of European electricity and gas markets. Said liberalisation was introduced by the Internal Electricity Market Directive (IEMD), the Hydrocarbons Licensing Directive and the Internal Gas Market Directive (IGMD). The paper focuses on the contestable idea that regulatory amendments - especially the introduction of third party access by means of the directives - only form a first necessary condition for attaining economic alterations whereas pro-active conduct of the marketers is the second and decisive one in order to increase the competitive performance of the European energy supply industries. The analysis is supported by a second argument which relates closely to the ambivalent nature of concentrations: A concentration may be used to increase the process of market opening and the expansion into new markets by pooling of scarce resources. It may also be used as a retro -active means so as to create national champions, increase barriers to market entry of new competitors, enable cross-subsidisation so as to expand dominant positions on heretofore competitive up- and downstream markets.