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I aim to assess the sustainability of rural electrification efforts based on off-grid photovoltaic (PV) systems in three Andean countries: Chile, Ecuador, and Peru. Although deployment of off-grid PV solutions for rural electrification began in the early 1990s in the Andean region, most of the projects turned out to be unsustainable and did not last. Prior efforts have addressed the different issues and barriers that plagued these projects and inhibited their sustainability. However, these prior analyses were mostly quantitative; systematic qualitative evaluations have been scarce. In this thesis, I address the following research question: ´Are the rural electrification programs (based on off-grid PV Systems) in the Andean countries sustainable?´ In order to answer this research question, I conducted an exhaustive qualitative document analysis complemented by semi-structured expert interviews. The interviewees included experts from different ministries, project managers from leading Non-Governmental Organizations (NGOs), public and private companies´ representatives, supervisors, and researchers. Although I also describe several relevant PV-based electrification efforts in the Andean countries, my research was aimed at providing an overall picture of the rural electrification efforts in these countries, rather than measuring the success or failure of specific projects. The gathered information allowed me to assess the sustainability of rural electrification efforts in the Andean countries. This assessment was based on a set of indicators corresponding to the four dimensions of sustainability considered in this thesis: institutional, economical, environmental, and socio-cultural. I found that Ecuador and Chile have consistently failed to ensure mechanisms for the operation and maintenance of the deployed off-grid systems, which has made these solutions in poor Chilean and Ecuadorian communities inevitably unsustainable. Although Peru has adopted a cross-tariff scheme, the Peruvian case shows that ensuring the funding of off-grid PV solutions is not enough. Peruvian officials appear to be unaware of the importance of local participation (local values and lifestyles are constantly disregarded) and most of the projects have been designed without the participation and engagement of the communities, which has often led to project failures and payment defaults. Although each country has its particular challenges, I found that the three Andean countries have consistently neglected the importance of strong formal institutions with a flexible and decentralized structure, which in turn significantly compromised the rural electrification effort in these countries.