Open Access

El-Salam Canal Project aims at increasing the Egyptian agricultural productivity through agricultural and stock development by irrigating about 263,500 ha gross of new lands. In order to stretch the limited water supply to cover these reclaimed areas, fresh River Nile water is augmented with agriculture drainage water from Hadus and Lower Serw drains to meet crop requirements, especially during summer months (peak demand). With a growing population and intensified industrial and agricultural activities, water pollution is spreading in Egypt, especially in main drains, which receive almost all kinds of wastes (municipal, rural, domestic and industrial wastes). The medical records indicate that significant numbers of waterborne-disease cases (bilharzias, typhoid, paratyphoid, diarrhoea, hepatitis A, B and C) have been reported in many areas in Egypt (MOHP, 2000). The National Water Quality Monitoring Program (NWQMP) in Egypt covers the Nile River, irrigation canals, drains and groundwater aquifers to assess the status of water quality for different water uses and users. The overall objective of this research is to introduce a rationalization technique for the drainage water quality-monitoring network for Hadus drain as a main feeder of El-Salam Canal Project. Later on, this technique can be applied for other parts in the NWQMP. The rationalization process started firstly with assessing and reformulating the current objectives of the network. Then, the monitoring locations were identified using integrated logical and statistical approaches. Finally, a sampling frequency regime was recommended to facilitate proper and integrated information management. The monitoring objectives were classified into three classes: design oriented, short-term and long-term deductible objectives. Mainly, the objectives “assess compliance with standards”, “define water quality problems”, “determine fate and transport of pollutants”, “make waste-load allocations” and “detect possible trends” were considered in the redesign process of the network. A combination of uni-, bi-, and multi-variate statistical techniques supported by spatial and temporal analysis for the important tributaries (key players) in Hadus drain system, were used for locating the monitoring sites. The key players analysis was carried out in the light of monitoring objectives. As a result, the monitoring network was divided into three priority levels (Layers I, II and III) as following: Layer I: It has the highest priority level and includes eight monitoring locations Layer II: It has the second priority level and includes three monitoring locations Layer III: It has the lowest priority level and includes five monitoring locations Using the method proposed by Lettenmaier (1976), the sampling frequencies were initially estimated and then evaluated for 36 water quality parameters, which were collected on monthly basis during the period from August 1997 to January 2005. The evaluation process was carried out by generating new data sets (subsets) from the original data. Then, the common required statistics from the monitoring network were extracted. The information obtained from different data sets was assessed using visual and statistical comparisons. Three integrated validation methods were employed to ensure that any decisions concerning the proposed program would not affect its ability to accomplish the monitoring objectives. These validation methods employed: descriptive statistics, regression analysis and linear multiple regression in an integrated approach. The validation results ensured that excluding the monitoring locations in layer III did not significantly affect the information produced by the monitoring network. Therefore, a monitoring network including only 11 sites (out of 16) representing the layers I and II was recommended. Based on the evaluation of sampling frequencies, it is recommended to have 6 (instead of 12) samples per year for 18 water quality parameters (COD, TSS, TVS, N-NO3, Pb, Ca, Na, Cl, Visib, BOD, Cu, Fe, Mn, pH, TDS, K, SO4_m and DO). The measured parameter SO4m will automatically replace the SO4 (calculated). SAR and Adj. SAR also can be calculated from the other parameters. For the other fifteen parameters (Mg, EC, Br, Ni, Sal, Cd, TN, TP, Temp, Fecal, Coli and N-NH4, Zn, P and Turb), it is recommended to continue with twelve samples per year. These recommendations may ensure significant reduction in the total cost of the monitoring network. This facilitates a fiscal resource, which is a key prerequisite in developing a successful program. The rescued budget can be redirected to achieve better performance in terms of improving the current resources. In addition, a frame of stakeholders-participation mechanism was proposed to not only facilitate a better coordination among the Egyptian Ministries involved in the water sector but also guarantee effective landowners/farmers involvement. However, applying such a mechanism requires more detailed studies of all the previous experiences gained by many projects trying to achieve better integration between objectives, plans and activities for the different environmental institutions in Egypt.

Personally meaningful tourist experiences foster subjective mental wellbeing. Modern, human-centred technologies such as gamified technology have been recognised as a promising means to support tourists in their co-creation of meaningful tourist experiences. However, a deeper understanding and conceptualisation of tourists’ engagement with gamified technologies in the tourist experience has remained absent so far. This study draws on positive psychology as the guiding theoretical lens to conceptualise and explore tourists’ underlying motives for engaging with gamified technology, as well as the gratifications thereof for the tourist experience. In doing so, this thesis identifies how tourists generate meaning through interacting with gamified technology in the tourist experience, thereby fostering the co-creation of meaningful tourist experiences and contributing to subjective mental wellbeing. Being among the first studies to link the concepts of positive psychology, gamified technology, and tourist experiences, the results of this thesis provide rich findings on the underlying motives for tourists to engage with gamified technology during vacation, as well as the gratifications of gamified technology for the creation of meaning in the tourist experience. Using the theoretical lens of positive psychology and achievement motivation theory as the main theoretical underpinning, this study is positioned at the intersection of social psychology, human-computer interaction, and tourism as the field of application. Conceptually, this thesis provides an in-depth understanding of tourists’ engagement with gamified technology, including the socio-psychological motivators for engagement and the outcomes thereof for the tourist experience. This thesis contributes to the theoretical advancement of two principal streams: a) tourists’ motives for engaging with gamified technologies and the gratifications thereof in the vacation context and b) the understanding of motivational affordances of gamified technology in general. The substantial theoretical contribution of this study is the advancement of knowledge as it demonstrates the value of gamified technologies in the tourist experience. The findings eventually provide tourism destinations with nuanced insights into the feature-specific values of gamified technology to contribute to the co-creation of meaningful tourist experiences.

This cumulative thesis extends the econometric literature on testing for cointegration in nonstationary panel data with cross-sectional dependence. Its self-contained chapters consist of two publications and two publication manuscripts which present three new panel tests for the cointegrating rank and an empirical study of the exchange rate pass-through to import prices in Europe. The first chapter introduces a new cointegrating rank test for panel data where the dependence is assumed to be driven by unobserved common factors. The common factors are first estimated and subtracted from the observations. Then an existing likelihood-ratio panel cointegration test is applied to the defactored data. The distribution of the test statistic, computed from defactored data, is shown to be asymptotically equivalent to that of a test statistic computed from cross-sectionally independent data. The second chapter proposes a new panel cointegrating rank test based on a multiple testing procedure, which is robust to positive dependence between the individual units’ test statistics. The assumption of a certain type of positive dependence is shown by simulations not to be violated in panels with dependence structures commonly assumed in practice. The new test is applied to find empirical support of the monetary exchange rate model in a panel of eight OECD countries. The third chapter puts forward a new panel cointegration test allowing for both cross-sectional dependence and structural breaks. It employs known individual likelihood-ratio test statistics accounting for breaks in the deterministic trend and combines their p-values by a novel modification of the Inverse Normal method. The average correlation between the probits is inferred from the average cross-sectional correlation between the residuals of the individual VAR models in first differences. The fourth chapter studies the exchange rate pass-through to import prices in a panel of nineteen European countries through the prism of panel cointegration. Empirical evidence supporting a theoretical long-run equilibrium relationship between the model’s variables is found by the newly proposed panel cointegration tests. Two different panel regression models, which take both cointegration and cross-sectional dependence into account, provide most recent estimates of the exchange rate pass-through elasticities.

Among all attenuation processes, biodegradation plays one of the most important role and is one of the most desirable processes in the environment especially since products released during this bio-reactions, can be once again reintroduced into the natural element cycles. To assess biodegradation, a variety of biodegradation test procedures have been developed by several international organizations. OECD guidelines for ready biodegradability testing represent one of the most prominent group of internationally used screening biodegradation tests (series 301A-F). These tests are usually very simple in their designs and allow for the fast and cheap screening of biodegradability. However, because of their stringency, the test conditions are not close to simulating environmental conditions and may lead to unrealistic results. To overcome these limitations, OECD introduced simulation tests which are designed to investigate the behavior of chemicals in specified environmentally relevant compartments. Despite the fact that simulation tests give more insight into the fate of chemicals in the environment, they are not applied frequently as they are often tedious, time consuming and expensive. Consequently, there is a need to provide a new biodegradation testing method that would combine complex testing environment as in simulation tests, easiness in handling and good data repeatability as in screening biodegradation tests. Another challenge is an adaption of the existing biodegradation testing methods to new types of samples, i.e. mixtures of transformation products (TPs). The research on the presence of pharmaceuticals in the environment gained momentum in the 1990s; since then, it has been growing. Their presence in the environment is a wellestablished fact. A wide range of pharmaceuticals is continuously detected in many environmental compartments such as surface waters, soils, sediments, or ground waters. After pharmaceuticals reach the natural aquatic environment they may undergo a number of processes such as: photolysis (under direct sunlight), hydrolysis, oxidation and reduction reactions, sorption, biodegradation (by bacteria of fungi), and bioaccumulation. These processes, may cause their elimination from aquatic environment, if reaction is complete, or creation of new compounds i.e., transformation products (TPs). What is more, processes, like chlorination and advanced oxidation processes (AOPs), such as H2O2/UV, O3/UV, TiO2/UV, Fenton, and photo-Fenton, or UV treatment which might be applied in water or wastewater treatment, may also lead to the TPs introduction into aquatic environment. The research on the TPs brings many new challenges. From one side, there is a constant need for the the development of a sensitive and reliable analytical separation, detection, and structure elucidation methods. Additionally, there is a need for the preparation of appropriate assays for the investigation of properties of new compounds, especially those answering the question if TPs pose a higher risk to the aquatic ecosystems than their parent compounds. Among numerous groups of pharmaceuticals, two are of great importance: antibiotics since they might promote emergence and maintenance of antimicrobial resistance in the aquatic environment; and cytostatic drugs. Cytostatic drugs can exert carcinogenic, mutagenic and/or teratogenic effects in animals and humans. The challenges of biodegradation testing presented in this thesis, encompasses these different areas of interest and was divided into three objectives: 1) Identification of the knowledge gaps and data distribution of the two groups of pharmaceuticals antibiotics and cytostatic drugs (article I); 2) Increasing the knowledge on biodegradation of cytostatic drugs and their TPs (articles II, III, and IV) and 3) Establishment of a biodegradation test with closer to simulation tests conditions, that could be affordable and to support better understanding on processes in water sediment interface construction - screening water-sediment test. Further validation of the test with an insight into sorption and desorption processes (articles V and VI).

The doctoral thesis deals with future challenges that the tourism market has to face on a global level. The problem is treated from different perspectives and with different thematic foci. Thematically, the thesis approaches both global changes in the tourism market and further developments of the research methodology. The methodological repertoire includes a Delphi survey in combination with a focus group, mobile ethnography in conjunction with participant observation and contextual interviews, and a quantitative online survey.

Air quality models are important tools which are utilized for a large field of application. When combined with data from observations, models can be employed to create a comprehensive estimation of the past and current distribution of pollutants in the atmosphere. Moreover, projections of future concentration changes due to changing emissions serve as an important decision basis for policymakers. For the determination of atmospheric concentrations of air pollutants by means of numerical modelling it is essential to possess a model which is able to create anthropogenic and biogenic emissions with a temporally and spatially high resolution. The emission data is needed as input for a chemistry transport model which calculates transport, deposition, and degradation of air pollutants. To evaluate the impact of changing emissions on the environment a flexible emission model with the capability to create diverse emission scenarios is needed. Further, it is important to always take into account a variety of different species to properly represent the major chemical reactions in the atmosphere (e.g. ozone chemistry, aerosol formation). Currently there are only a few high resolution emission datasets available for Europe. The amount of substances included in these datasets, however, is limited. Moreover, they can not be used as basis for the creation of new emission scenarios. To enable the creation of emission scenarios in the course of this doctoral thesis the American emission model SMOKE was adopted and modified. On the basis of a multitude of different georeferenced datasets, official statistics, and further model results the newly created emission model “SMOKE for Europe” is capable of creating hourly emission data for the European continent with a spatial resolution of up to 5x5km2. In order to demonstrate the universal applicability of the emission model the carcinogenic species benzo[a]pyrene (BaP) was exemplarily implemented into the model. BaP belongs to the group of polycyclic aromatic hydrocarbons. Because of its high toxicity the European Union introduced an annual target value of 1 ng/m3 in January 2010. SMOKE for Europe was used to create a variety of emission scenarios for the years 1980, 2000, and 2020. These emission scenarios were then used to determine the impact of emission changes on atmospheric concentrations of BaP and to identify regions which exceed the European target value. Additionally the impact of different legislation and fuel use scenarios on the projected atmospheric concentrations in 2020 was investigated. Furthermore, additional use cases for a flexible emission model are pointed out. The SMOKE for Europe model was used to simulate the transport of volcanic ash after the eruption of the Icelandic volcano Eyjafjallajokull in March 2010. By comparison of modelled concentrations for different emission scenarios with observations from remote sensing and air plane flights distribution and concentration of the volcanic ash over Europe was estimated. The results of this thesis have been presented in four scientific papers published in international peerreviewed journals. The papers are reprinted at the end of this thesis.

Entrepreneurship is an important means for economic development and poverty alleviation . Due to the relevance of entrepreneurship, scholars call for research that contributes to the understanding of successful business creation. In order to best understand new venture creation, research needs to investigate barriers of entrepreneurship. A barrier that has received wide attention in the literature on new venture creation is capital requirements. Scholars argue that capital requirements are an entry barrier for new venture creation, as most people who start businesses have difficulties in acquiring the necessary amount of capital needed for starting the businesses. Particularly in developing countries, scholars and practitioners regard improvements in access to capital as a major solution to support new venture creation. However, besides improving access to capital, there are alternative solutions that help to deal with the problems of capital requirements and capital constraints in the process of new venture creation. In this dissertation, I argue that a possible means to master capital requirements and capital constraints in business creation is action-oriented entrepreneurship training. I draw on actionregulation theory (Frese & Zapf, 1994), theories supporting an interactionist approach (Endler & Edwards, 1986; Terborg, 1981) and on theories about career development (Arthur, 1994; Briscoe & Hall, 2006) to reason that action-oriented entrepreneurship training allows for handling capital requirements and capital constraints with regard to business creation. Specifically, I argue that action-oriented entrepreneurship training helps to deal with financial requirements and capital constraints in two ways: First, the training reduces the negative effect of capital constraints on business creation through the development of financial mental models. Second, the training supports finding employment and receiving employment income, which enable businesses creation.

The research presented here examines the ways the products and practices of digital game-based language learning (DGBLL) shape access to foreign language learning. Three different studies with different methodologies and foci were carried out to examine the affordances of various aspects of DGBLL. The emphasis in all three cases, two of which are empirical and one of which is a theoretical investigation, is on developing a better understanding of the affordances of DGBLL to derive implications for English Foreign Language (EFL) teacher education. In the first study, the focus is on constructing and implementing an evaluative framework to examine the pedagogical, linguistic, and ludic affordances of DGBLL tools. Analysis reveals that many dedicated DGBLL applications incorporate content, pedagogy, and game elements that are limited in their ability to reflect contemporary understandings of foreign language learning or generate motivation to pursue game-related goals. As such, they call into question existing typologies of DGBLL and emphasize the need for competent educators who can effectively align the selection of specific DGBLL tools with given language learning objectives. In order to understand the preexisting knowledge and attitudes that need to be addressed to develop such competence, the second study examines pre-service English foreign language (EFL) teachers’ beliefs and behaviors regarding DGBLL. The quantitative analysis reveals positive correlations between gameplaying and EFL skills and language learning strategies, and between gaming behaviors and beliefs about DGBLL. At the same time, low rates of gameplaying behaviors and negative correlations between prior digital media usage and attitudes towards DGBLL suggest the need for substantial theoretical and practical teacher preparation that takes into account underlying assumptions about gameplaying and foreign language learning. The third study examines the basis of these assumptions, relying on Bourdieu’s notion of habitus to illuminate the foundation of these beliefs and his notion of linguistic capital to consider the potential impact of a non-gameplaying habitus on some language learners. Such differential acceptance of efficacious DGBLL in formal school settings may inhibit access to significant forms of capital, and requisite linguistic and digital competencies. While all three studies are limited in their scope, they hold important implications for teacher education. Given the nature of the applications analyzed, it becomes clear that, not only are particular applications appropriate for specific objectives; it must also be the role of teacher education to enhance pre-service teachers’ (PST) abilities to understand these nuances and select media accordingly. This can only take place when PSTs’ situated existing beliefs and behaviors, as illuminated by this research, are taken into account and addressed accordingly. Finally, this education must necessarily include initiatives to develop an understanding of issues of equity in access, participation, and outcomes as regards DGBLL.

When screening projects for potential investment placements, Venture Capitalists have to base their decision on the information provided in the business plan. The aim of this study is to make VCs aware of the influence of various factors which are discussed in business plans, such as the management team and risk minimising strategies. In order to do this, the business plans of four companies which received investment placements were analysed. The analysis revealed the two main success factors to be industrial experience and a filled product pipeline. The results also suggested that the business plan in its current form may not cover all the information needed for an optimal result. However, since this work is only a first approach further research needs to be carried out.

Networks of social relationships are becoming increasingly important in today’s business environment. By cooperating in such structures players seek to overcome the shortcomings of the alternative forms of exchange, namely markets and hierarchies, and to realise (greater) information benefits. This is done through the reduction of complexities and uncertainties, as well as by increasing the speed of information flows and decision-making within networks. Traditional network research has focused on company networks and neglected the assessment of the underlying constituents of social networks. Studies concerned with the use of social ties for economic goals are generally not scientific and lack the theoretical foundation ti guide such an analysis. For these reasons it is the aim of this research paper, based on a theoretical framework, to systematically examine the underlying factors that lead to successful co-operations within a social network seeking to reach a common goal. The results of the current qualitative research study indicate that the factors suggested in the literature as significant for successful networking (e.g. common base; common language; mutual goals; sympathy for each other; a general interest in social contacts, combined with the necessary skills to act within social contexts) do indeed impact this type of co-operation as proposed. In addition to what is put forward in the literature it became evident that all successful individuals have a passion, besides their business activities, such as music, art or sports. This ardour also serves as a platform on which valuable contacts are established and maintained.

With this dissertation, I present a human resources approach to entrepreneurship through selection and training of small-business owners in developing countries. Entrepreneurship is an important source of employment, innovation, and general economic prosperity (Autio, 2005; Walter et al., 2005; Reynolds et al., 2005; Kuratko, 2003). In developing countries, job creation through business ownership is especially important because job opportunities are limited (Walter et al., 2005; Mead & Liedholm, 1998). Strengthening the small business sector is one of the best ways to reduce poverty and increase economic growth (Birch, 1987). Thus, this dissertation adds to the scientific literature in taking a human resources approach to entrepreneurship: selecting and training entrepreneurs. Selection has widely been researched on in various scientific fields like human resource management, industrial-, work-, and organizational psychology, but only partly focusing on selection of entrepreneurs. Regarding training, there exists a fair amount of studies that focus on entrepreneurship education, but a lot of them suffer from substantial heterogeneity and methodological flaws (Glaub & Frese (2011); McKenzie & Woodruff (2013)). The dissertation combines the ideas of using selection procedures for entrepreneurs with the idea of teaching entrepreneurial skills.

Traditional farming landscapes typically support exceptional biodiversity. They evolved as tightly coupled social-ecological systems, in which traditional human land-use shaped highly heterogeneous landscapes. However, these landscapes are under severe threats of land-use change which potentially pose direct threats to biodiversity, in particular through land-use intensification and land abandonment. Navigating biodiversity conservation in such changing landscapes requires a thorough understanding of the drivers that maintain the social-ecological system. This dissertation aimed to identify system properties that facilitate biodiversity conservation in traditional farming landscape, focusing specifically on birds and large carnivores in the rapidly changing traditional farmland region of Southern Transylvania, Romania. In order to identify these properties, I first examined the effects of local and landscape scale land-use patterns on birds and large carnivores and how they may be affected by future land-use change (Chapters II-V). Second, to gauge the role of particular traditional land-use elements for biodiversity I focused on the conservation value of traditional wood pastures (Chapters VI-VIII). Third, I took a social-ecological systems approach to understand how links between the social and ecological parts of the system affect human-bear coexistence (Chapters IV and IX). Bird diversity was supported by the broad gradients of woody vegetation cover and compositional heterogeneity. Land-use intensification, and hence the loss of woody vegetation cover and homogenization of land covers, would thus negatively affect biodiversity. This was especially evident from predictions on the distribution of the corncrake (Crex crex) in response to potential future land cover homogenization. Here, a moderate reduction of land cover diversity could drastically reduce the extent of corncrake habitat. Further results showed that the brown bear (Ursus arctos) would mainly be affected by land-use change through the fragmentation of large forest blocks, especially if land-use change would reduce habitat connectivity to the presumed source population in the Carpathian Mountains. Moreover, this dissertation revealed that large carnivores (brown bear and wolf, Canis lupus) may have important and often ignored roles in structuring the ecosystem of traditional farming landscapes by limiting herbivores. Wood pastures were found to have a high conservation value. The combination of low-intensity used grasslands with old scattered trees provided important supplementary habitat for different forest species such as woodpeckers and the brown bear. Worryingly, current management of wood pastures differed from traditional techniques in several aspects, which may threaten their persistence in the landscape. The majority of people had a positive perception on human-bear coexistence. The use of traditional sheep herding techniques combined with the tolerance of some shepherds to occasional livestock predation facilitated coexistence in a region where both carnivores and livestock are present. More generally, the genuine links between people and their environment were important drivers of people´s positive views on coexistence. However, perceived failures of top-down managing institutions could potentially erode these links and reduce people´s tolerance towards bears. Through the consideration of two different animal taxa, this dissertation revealed six important system properties facilitating biodiversity conservation in traditional farming landscapes. Similar proportions of the main land-use types (arable land, grassland, and forests) support species richness at the regional scale possible through habitat connectivity and continuous spill-over between land-use types. Heterogeneous landscapes can further support biodiversity through complementation and supplementation of habitat at the landscape scale. Gradients of woody vegetation cover and heterogeneity, supported biodiversity at both local and landscape scales possibly through the provision of a wide range of resources. The heterogeneous character of the landscape is tightly linked to traditional land-use practices, which also maintain specific traditional land-use elements and facilitate human-carnivore coexistence. Top-down limitation of large carnivores on herbivores possibly enhances vegetation growth and tree regeneration. The genuine links between humans and nature support human-bear coexistence, and these links may form the core of people´s values and sustainable use of natural resources.

To improve the properties of thermochemical heat storage materials, salt mixtures were evaluated for their heat storage capacity and cycle stability as part of the innovation incubator project “Thermochemical battery” of the Leuphana university Lüneburg. Based on naturally occurring compound minerals, 16 sulfates, 18 chlorides and 5 chloride multi-mixtures, 18 bromides and 5 intermixtures between sulfates, chlorides and bromides were synthesized either from liquid solution or by dry mixing for TGA/DSC screening before continuing the heat storage evaluation with five different measurement setups at a laboratory scale. The TGA/DSC analysis served as a screening process to reduce the number of testing materials for the upscaled experiments. The evaluation process consisted of a three-cycle dehydration/hydration measurement at Tmax = 100°C and Tmax = 200°C. In case of the bromide samples a measurement of hydration conditions with Tmax = 110°C and a water flow at e = 18.68mbar, were added to the procedure to detect the maximum water uptake temperature. Also, a single dehydration to a temperature of Tmax = 500°C was implemented to observe melting behavior and to easier calculate the samples’ stages of hydration from the remaining anhydrous mass. Materials which showed high energy storage density and improved cycle stability during this first evaluation were cleared for multi-cycle measurements of 10 to 25 dehydration and hydration cycles at Tmax = 100 to 120°C and the evaluations at m = 20 to 100g scale. An estimate for the specific heat capacities at different temperatures of the materials which passed the initial stage was calculated from the TGA/DSC results as well. The laboratory scale measurement setup went through five stages of refining, which led to reducing the intended maximum sample mass from m = 100g to m = 20g. A switch from supplied liquid water to water vapor as the used reactant was also implemented in exchange for improved dehydration conditions. Introducing a vacuum pump for evaporating the water limited the influence of outside heat sources during hydration and in-situ dehydration was enabled as to not disturb the state the samples were settling in between measurements. Baseline calculation from blanc measurements with glass powder and attempts to calculate the specific heat capacity cp of the tested materials by 6 applying the Joule-Lenz-law to the measurement apparatus was another step of method development. The evaluation process of the laboratory scale tests at the final setting consisted of 1 to 5 cycle measurements of in-situ dehydration and hydrations with applied vacuum for t = 30 minutes at p ~ 30mbar. Upscaling the sample mass to m = 20g allowed for a close observation of different material behaviors. Agglomeration, melting and dissolving of the m = 10mg samples during the TGA/DSC analysis can be deducted from the recorded measurement curves and the state of the sample after measurement. However, at laboratory scale the visible volume changes, observed sample consistency after agglomeration and an automatic removal of molten and dissolved sample mass during the measurement allowed for a better characterization and understanding of the magnitude of the actual changes. This was done for the first time, particularly for mixed salts. Of the original number of 62 samples, 4 mixtures which passed the initial TGA/DSC screening namely {2MgCl2+ KCl}, {2MgCl2+CaCl2}, {5SrBr2+8CaCl2} and {2ZnCl2 + CaCl2} were chosen for further evaluation. The multi-cycle TGA/DSC measurements of {2MgCl2+ KCl}, {2MgCl2+CaCl2} and {5SrBr2+8CaCl2} showed an improved cycle stability for all three materials over the untreated educts. Of the four materials {2ZnCl2 + CaCl2} displayed the strongest deliquescence during hydration in the upscaled experimental setup. {2MgCl2+CaCl2} proved to be the most stable material regarding the heat storage density. The {MgCl2} content of the mixture is likely to partially or completely react to {Mg(OH)Cl} at temperatures of T > 110°C, which however does not impede the heat storage density. {5SrBr2+8CaCl2} displayed a low melting point in hydrated state, causing a fast material loss. This makes it an undesirable storage material. A lower heating rate may still help to avoid an early melting. The {2MgCl2+KCl} mixture was the most temperature stable of the mixtures showing no melting or dissolving behavior. A reaction of the {MgCl2} component of the mixture to {Mg(OH)Cl} was not observed within the applied temperature range of T = 25 to 200°C.

Panic disorder is a common anxiety disorder, which is associated with high subjective burden as well as a high cost for the health economy. According to the National Treatment Guideline S3, cognitive behavior therapy is recommended as the most effective psychological treatment. However, many people in need do not have access to cognitive behavior therapy. Internet-based interventions have proven to be an effective way to provide access to evidence-based treatment to those affected, thereby reducing gaps in care. For anxiety disorders, such as panic disorder and agoraphobia, a good effectiveness of internet-based interventions has been proven in numerous international studies. However, the internet has changed over the last few years: mobile technologies have considerable potential to further improve the adherence and effectiveness of internet-based interventions. Against this background, we developed the hybrid online training

The process perspective provides a unifying framework that has substantially contributed to our understanding of entrepreneurship. However, much of the research up to now has neglected this process oriented conception of entrepreneurship. There is therefore a need for studies that take the inherent dynamic processes into account and analyze the underlying mechanisms when researching entrepreneurship. This dissertation aims to improve our understanding of the entrepreneurial process. Specifically, this dissertation focuses on new venture creation and the processes of sustainable opportunity identification and opportunity deviation. Chapter 1 provides a general introduction that highlights the theoretical contributions of this dissertation and gives an overview over the conducted studies. Chapter 2 argues for a process model of entrepreneurship that places entrepreneurs and their actions center stage. The model combines different perspectives and levels of analysis and provides an integrative framework for researching new venture creation. In chapter 3 we establish and test a theoretical model of sustainable opportunity identification. The chapter explains how younger generations identify sustainable opportunities. The findings indicate that sustainable opportunity identification is a process with two transitions from problem to solution identification and from solution identification to sustainable opportunity identification. These transitions are contingent on awareness of consequences and entrepreneurial attitude. Chapter 4 offers insights into how deviation from the original opportunity increases the performance of entrepreneurial teams. The findings indicate that entrepreneurial teams with a high level of error orientation set themselves higher goals when deviating from their original opportunity. Higher goals then lead to higher team performance. Chapter 5 summarizes the overall findings and outlines the general theoretical and practical implications. Each chapter thus contributes to the process perspective by focusing on how different phases of the entrepreneurial process unfold and develop over time. Thereby, this dissertation advances our understanding of entrepreneurship as a process.

Entrepreneurs and entrepreneurial firms are a frequent research topic in psychological research. However, the focus of this research has largely been on the entrepreneur as a person and on the entrepreneurs’ strategy for the business. By contrast, the entrepreneur as a leader and the entrepreneurial firm as a work environment for employees have received little attention. Therefore, this dissertation aims to integrate theoretic thoughts from organizational behavior research into entrepreneurship research. Specifically, I will focus on novelty creation within entrepreneurial firms and organizational phenomena which provide a context for employees in novelty creating activities. This dissertation adds to the literature as it provides insight in the effects of work environment facets on employees’ engagement in novelty creating activities in entrepreneurial businesses. In three empirical chapters, I will focus first on the effects of entrepreneurial orientation on efficiency of employee work in innovation projects. Second, I will look at a facet of organizational culture, the error management culture, and its effects on individual learning of employees. Last, I will focus on occupational roles of employees within small businesses and effects of these roles on responses to a questionnaire and on work in innovation projects. In all three empirical chapters I test my hypotheses in a sample of N = 40 entrepreneurial businesses and employees within these businesses. For my chapter on occupational roles this sample is complemented by two additional samples of college students. In sum, results indicate that the entrepreneurial business in all three chapters exerts significant influences on employee work. Furthermore, I show that employee participation in novel activities is positive for entrepreneurial businesses (Chapter 2: Correlation between employees’ and entrepreneurs’ evaluation of innovation project effectiveness: r = .44; p < .01; Chapter 3: Correlation between organizational level leaning and organizational growth in sales: r = .35; p < .01). Therefore, I suggest that research on the entrepreneurial firm as a context for work may contribute to our knowledge on success factors in entrepreneurship, and may therefore be a relevant direction of future research. Especially, it may be fruitful to investigate aspects of work in which entrepreneurial firms may differ from other, less entrepreneurial organizations.

It is understood among research and policy makers that addressing unsustainable individual consumption patterns is key for the vision of sustainable development. Education for Sustainable Consumption (ESC) is attributed a pivotal role for this purpose, aiming to improve the capacity of individuals to connect to and act upon knowledge, values and skills in order to respond successfully and purposefully to the demands of sustainable consumption. Yet despite growing political, scientific, and educational efforts to foster more sustainable consumption practices through ESC, and increasing awareness about the negative ecological and socio-economic impacts of individual consumer behavior in the general population, little has been achieved to substantially change behavioral patterns so far. As part of the explanation for this shortcoming, it has been argued that current ESC practices have neglected the personal dimension of sustainable consumption, especially the affective-motivational processes underlying unsustainable consumption patterns. Against this background, this cumulative thesis is guided by the question how personal competencies for sustainable consumption can be defined, observed, and developed within educational settings. Special attention is given to mindfulness practices, describing the practice of cultivating a deliberate, unbiased and openhearted awareness of perceptible experience in the present moment. These practices have received growing attention within ESC as a means to stimulate competencies for sustainable consumption. Drawing upon an explorative, qualitative research methodology, the thesis looks at three different mindfulness-based interventions aiming to stimulate competencies for sustainable consumption, reaching out to a total number of 321 participants (employees and university students). In this thesis, I suggests to define personal competencies for sustainable consumption as abilities, proficiencies, or skills related to inner states and processes that can be considered necessary or sufficient to engage with sustainable consumption (SC). These include ethics, self-awareness, emotional resilience, selfcare, access to and cultivation of personal resources, access to and cultivation of ethical qualities, and mindsets for sustainability. It is argued that these competencies directly relate to those challenges individuals face when attempting to consume in a way that corresponds to their sustainability-related intentions or engage in SC-related learning activities. It provides evidence that the cultivation of (some of) these competencies allows individuals to overcome (some of) these challenges. The thesis holds that the observation of personal competencies benefits from a combination of different methodological and methodical angles. When working with self-reports as empirical data, a pluralistic qualitative methods approach can help overcoming shortcomings that are specifically related to individual methods while increasing the self-reflexivity of the research. This is especially important in order to reduce the risk of looking for desired outcomes and misinterpreting statements of the inquired population. This risk can also be diminished by discussing and adjusting interim findings with this population. Moreover, it is suggested to let learners analyze their own personal statements in groups, applying scientific methods. The products of the group analyses represent data based on an inter-subjectively shared perspective of learners that goes beyond self-estimation of personal competencies. In terms of developing personal competencies for SC, it can be concluded that mindfulness practice alone is not sufficient to build personal competencies for SC. While it can stimulate generic personal competencies, individuals do not necessarily apply these competencies within the domain of their consumption. Furthermore, even though the practice increases individuals’ self-awareness for current inner states and processes, practitioners do not seem to become aware of and reflect upon the more latent, personal predispositions out of which the current sensations occur. Nevertheless, mindfulness practice can play an important role in ESC, insofar as it lays the inner foundation to engage with sustainability-related issues. More precisely, it allows learners to experience the relevance of their inner states and processes and the influence they have on actual behaviors, leading to a level of selfawareness that would not be accessible solely through discursive-intellectual means. Furthermore, participants experience mindfulness practice as a way to develop ethical qualities and access psychological resources, entailing stronger emotional resilience and improved well-being. In order to unleash its full potential for stimulating personal competencies for SC, however, the findings of the thesis suggest that mindfulness practice should be (a) complemented with methodically controlled self-inquiry and (b) related to a specific behavioral change. In this vein, self-inquiry-based and self-experience-based learning – two pedagogical approaches developed during the period of research for this thesis – turned out to be promising pedagogies for educational settings striving to stimulate the development of personal competencies for SC. Overall, the thesis makes a novel contribution to the field of competency-based ESC by suggesting personal competencies for sustainable consumption as important and desirable learning outcomes of ESC practices Furthermore, it provides specific pedagogies and learning activities in order to achieve these learning outcomes. As such, the thesis answers to general calls from education for sustainable development scholars to take the inner, affective-motivational dimension of individuals into consideration and makes a first suggestion as to how this can be systematically achieved.

In recent years, especially since 2015, Germany and other European countries have accepted high numbers of refugees. The social and vocational integration of these refugees and of those yet to come represents a challenge. (Social) entrepreneurship is one means to achieve this goal, to fully tap into the potential of refugees and to give them a chance to make a living in host countries. This dissertation examines the potential of vocational integration of refugees through (social) entrepreneurial activities. It includes a detailed literature review and suggests possible direction in the emerging field of refugee (social) entrepreneurship. This dissertation shows that to foster refugee (social) entrepreneurship, the identification and evaluation of specific and potential needs for support is essential. Incubators in particular have a high potential for supporting refugee entrepreneurs, in part it is possible for them to address some of the challenges faced by this target group, which differ from those of locals or migrant entrepreneurs. More specifically, this dissertation aims to answer two research questions: (1) What are relevant (social) entrepreneurial concepts that can contribute to the vocational integration of refugees? (2) What are the distinct contributions of and challenges faced by refugees when it comes to their vocational integration through (social) entrepreneurial activities? Analyzing select practical cases, this dissertation has several important implications for researchers who seek to bridge the gap between academia and society in the context of refugee entrepreneurship and refugee social entrepreneurship research. The findings presented here are also relevant for practitioners, for example those working at business incubators, who aim to facilitate the vocational and social integration of refugees in general and refugees with entrepreneurial aspirations in particular.

The study empirically examines the long-term export behaviour of about 200 young technology-oriented companies from Germany and the UK. These firms were contacted by means of two surveys, in 1997 and 2003. In this study, three dimensions of firms’ international engagements are examined econometrically: foreign market entry and exit, degree of internationalisation (i.e., export-sales ratio), and the change of sales modes in international markets. Moreover, the causal relationship between a firm’s status of internationalisation and its performance (measured by the firm’s labour productivity as well as its employment and sales growth rates) is analysed.

I aim to assess the sustainability of rural electrification efforts based on off-grid photovoltaic (PV) systems in three Andean countries: Chile, Ecuador, and Peru. Although deployment of off-grid PV solutions for rural electrification began in the early 1990s in the Andean region, most of the projects turned out to be unsustainable and did not last. Prior efforts have addressed the different issues and barriers that plagued these projects and inhibited their sustainability. However, these prior analyses were mostly quantitative; systematic qualitative evaluations have been scarce. In this thesis, I address the following research question: ´Are the rural electrification programs (based on off-grid PV Systems) in the Andean countries sustainable?´ In order to answer this research question, I conducted an exhaustive qualitative document analysis complemented by semi-structured expert interviews. The interviewees included experts from different ministries, project managers from leading Non-Governmental Organizations (NGOs), public and private companies´ representatives, supervisors, and researchers. Although I also describe several relevant PV-based electrification efforts in the Andean countries, my research was aimed at providing an overall picture of the rural electrification efforts in these countries, rather than measuring the success or failure of specific projects. The gathered information allowed me to assess the sustainability of rural electrification efforts in the Andean countries. This assessment was based on a set of indicators corresponding to the four dimensions of sustainability considered in this thesis: institutional, economical, environmental, and socio-cultural. I found that Ecuador and Chile have consistently failed to ensure mechanisms for the operation and maintenance of the deployed off-grid systems, which has made these solutions in poor Chilean and Ecuadorian communities inevitably unsustainable. Although Peru has adopted a cross-tariff scheme, the Peruvian case shows that ensuring the funding of off-grid PV solutions is not enough. Peruvian officials appear to be unaware of the importance of local participation (local values and lifestyles are constantly disregarded) and most of the projects have been designed without the participation and engagement of the communities, which has often led to project failures and payment defaults. Although each country has its particular challenges, I found that the three Andean countries have consistently neglected the importance of strong formal institutions with a flexible and decentralized structure, which in turn significantly compromised the rural electrification effort in these countries.

The dissertation contains four journal articles which are embedded within a framework manuscript that interconnects the individual articles and provides relevant background information. The dissertation’s overall objective is to provide a multilayered and critical in-depth engagement with the timely phenomenon of integrated reporting (IR), a new reporting concept that is envisaged to revolutionize firms’ present reporting infrastructure. While extant corporate reports (e.g., annual financial- and CSR report) often are criticized for being disconnected and to suffer from a lack of coherence, IR intends to provide all information that is material to a firm’s short-, medium- und long-term value creation within one single, succinct document. To contribute to a set of previously defined relevant research gaps in literature, the dissertation makes use of a combined empirical-quantitative and explorative-qualitative research design. The first article entitled ‘Determinants of materiality disclosure quality in integrated reporting: Empirical evidence from an international setting’ investigates a set of different IR-, corporate governance and financial accounting-specific factors that are expected to determine European and South African firms’ materiality disclosure quality. To this purpose, an original, hand-collected materiality disclosure score was developed. The second article ‘Managers’ incentives and disincentives to engage with integrated reporting, or why managers might not adopt integrated reporting: an exploratory study in a nascent setting‘ explores IR perceptions of SME managers that have not embarked on IR, but are potential candidates to do so in future. Based on a review of extant literature, the article develops a theoretical framework to subsequently discuss motives for and barriers to IR adoption. The critical discussion contributes to the academic debate on incentives for and barriers to voluntary IR adoption. The third article named ‘Does it pay off? Integrated reporting and cost of debt: European evidence’ investigates whether voluntary IR adoption among European firms is associated with lower cost of public debt. While earlier studies suggest that IR leads to lower information asymmetries, increases analyst forecasts, and decreases cost of equity, corresponding evidence for the debt market is largely missing. Subsequent analyses test as to whether such an association is even more pronounced by a firm’s environmental, social and governance (ESG) performance or its belonging to an environmentally sensitive industry. The fourth article ‘Do nonprofessional investors value the assurance of integrated reports? Exploratory evidence’ uses an experimental design to investigate nonprofessional investors’ reactions to an IR assurance. To this purpose, two separate experiments with two different groups of nonprofessional investors were carried out: one with Masters students and one with managers of large corporations. Results help to answer the question as to whether an IR assurance as well as its determinants, namely the assurance provider and the assurance level, affect nonprofessional investors’ financial decision-making. In the second step, subsequent in-depth interviews reveal an IR assurance-critical attitude among managers, who draw upon their practical experience with assurance engagements.

The principle of sustainability contains two objectives of justice regarding the conservation and use of ecosystems and their services: (1) global justice between different people of the present generation ("intragenerational justice"); (2) justice between people of different generations ("intergenerational justice"). International sustainability policy attaches equal normative importance to both objectives of justice. Accordingly, environmental philosophers ethically justify that people living today and people living in the future have equal rights to certain basic goods, including ecosystems and their services (e.g. Feinberg 1981, Visser’t Hooft 2007). Whereas ideal theories of sustainability and justice do not recognize interdependencies between intragenerational and intergenerational justice, conflicts in attaining the justices possibly arise in policy implementation. Identifying and preventing such conflicts is fundamental to devise an ethically legitimate, politically consistent and actually effective sustainability policy. This dissertation systematically investigates conflicts between intragenerational and intergenerational justice in the use of ecosystem services. Human wellbeing depends on the services provided by ecosystems. Yet, humans substantially degrade world’s ecosystems, and therewith cause the loss of important ecosystem services (MEA 2005: 26ff.). The idea of sustainability demands to use ecosystem services in accordance with the two objectives of intragenerational justice and intergenerational justice. Reality, however, is far from attaining these objectives: Both today’s global poor and future persons are, resp. will be, disproportionately affected by the loss of vital ecosystem services (MEA 2005: 62, 85). Especially severe affected are the rural poor who directly depend on local ecosystem services for food, income and health. The political discourse on the relationship between the objectives of intra- and intergenerational justice in the use of ecosystem services (‘justice-relationship’) is blurred. Further, the political discourse lacks a common understanding of justice in ecosystem-use and a systematic reflection on the actual ‘justice-relationship’, such as on the factors that cause conflicts between the two justices. In this dissertation, I investigate the ‘justice-relationship’ along three central questions: • What conception(s) of justice can adequately address the distribution of access rights to ecosystem services? • How must sustainability policy be designed to enhance both intragenerational and intergenerational justice in the use of ecosystem services? • (How) Can economics be helpful for characterizing and assessing trade-offs between the two justices? I approach these questions both generally and by the example of a case study, the MASIPAG farmer network in the Philippines. Methodologically, I combine a normative and a positive analysis of the relationship between intra- and intergenerational justice in the use of ecosystem services: The normative analysis serves the explication, justification and reflection of the norms underlying the ‘justice-relationship’; the positive analysis serves the description of the ‘justice-relationship’ in the sustainability discourse and in practical contexts, as well as the provision of explanations on the determinants of the ‘justice-relationship’. As methodological approach, I apply the “comprehensive multi-level approach” as developed by Baumgärtner et al. (2008) – investigating the ‘justice-relationship’ simultaneously on the three levels of (i) concept, (ii) model and (iii) case study.

In 2013, the European Commission adopted the so called ´Entrepreneurship 2020 Action Plan´ to ease the creation of new ventures and to support the takeover of existing firms. The goal is to create a supportive environment for entrepreneurs to thrive and grow (European Commission 2013). This shows that the European Union puts its efforts to support small firms as they are seen as means for Europe´s sustainable economic growth. However, the successful processes of growth and investment are complex and depend on different determinants. The present thesis focuses on the firm level and analyzes in three independent articles: how small firms invest over time, how new ventures grow and which variables influence growth, how small firms grow after business takeover and which variables influence growth. The framework that connects these articles forms the content-related focus on the early stage of development of small firms and the methodological and analytical approaches that comply with up-to-date and adequate statistical analysis techniques. Supported by an extensive dataset, which is the foundation of all three articles, it is possible to investigate empirically different open research questions using bivariate and multivariate analysis techniques. Thus, this thesis also serves the research needs for more multivariate analyses for small firms, for which so far mainly cross-sectional studies have been conducted.

Since 2000, data generation has been growing rapidly from various sources, such as Internet usage, mobile devices and industrial sensors in manufacturing. As of 2011, these sources were responsible for a 1.4-fold annual data growth. This development influences practice and science equally and led to different notations, one of the most popular one is Big Data. Besides organization with a business model based solely on Big Data, companies have started to implement new technologies, methodologies and processes in order to deal with the influx of data from different sources and structures and benefit the most of it. As the progress of the implementation and the degree of professionalism regarding data analysis differs amongst industries and companies, latter ones are faced with a lack of orientation regarding their own stage of development and existing relevant capabilities in order to deal with the influx of data as only a few best practices exist. Therefore, this research project develops a maturity model for the assessment of companies capabilities in the field of data analysis with a focus on Big Data. Basis for the model development is a construction model, developed along the criteria of Design Science Research. The developed model contains the different levels of maturity and related measurements for the evaluation of a companies Big Data capabilities with a focus on topics along the dimensions data and organization. The developed model has been evaluated based an application to different companies in order to ensure the practical relevance. The structure of the thesis is the following: In a first step, a structured literature review is carried out, focussing on existing maturity models in the field of Big Data and nearby fields as Business Intelligence and Performance Management Systems. Based on the identified white spots, a design science research oriented construction model for the maturity model development is designed. This model is applied subsequently.