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Der hochwassergebundene Sedimenteintrag ist Motor der Bodenbildung in Auen. Der mit dem Sedimenteintrag einhergehende Schadstofftransport in die flussbegleitenden Auen ist Ursache für die Akkumulation von Schadstoffen in den aquatischen und semiterretrischen Systemen. Er wirkt in weiten Teilen der Elbauen nicht nur einschränkend auf die landwirtschaftliche Nutzung des Grünlandes sondern beeinträchtigt daneben auch weitere Schutzgüter, wie z. B. Habitate und Lebensgemeinschaften. Diese Arbeit hatte das Ziel, die Steuergrößen des Sediment- und Schadstoffeintrags anhand von langjährig erhobenen Messdaten zu untersuchen und gleichzeitig die zeitliche und räumliche Verbreitung ausgewählter Schadstoffe als Baustein eines belastungsangepassten Auenmanagements aufzuklären. Dafür wurden eigene Daten über Hochflutsedimente und Böden ebenso ausgewertet wie Daten anderer Autoren. Außerdem lag ein Schwerpunkt der Arbeit in der kombinierten Auswertung von Zeitreihen der Sedimentbelastung von Gewässern und von Auenböden, die eine Grundlage für das Verständnis des elbespezifischen Belastungsmosaiks von Böden mit Schwermetallen und Dioxinen/Furanen darstellt. Zunächst erfolgte eine detaillierte Recherche und Analyse der retentionsfördernden Eigenschaften der Elbauen. Es wurden abschnittsspezifische Flächengrößen, Landnutzungsunterschiede und Flächenbetroffenheiten bei unterschiedlichen Hochwasserzuständen herausgearbeitet. Mit Hilfe der darauf aufbauenden, datenbasierten Analysen über ereignisbezogene Sedimenteinträge in die Elbauen konnten wesentliche Steuergrößen des Sedimenteintrags identifiziert werden. Die Distanz der Standorte zur Elbe ist die wesentliche Kenngröße, sodass die größten Sedimenteinträge in Flussnähe stattfinden. Darüber hinaus ist die Höhe des Sedimenteintrags abflussabhängig. Auf dieser Grundlage wurde ein Ansatz zur Berechnung des großräumigen Sedimenteintrags entwickelt, mit dessen Hilfe die Retentionsfunktion der Auen im Abfluss- und Stofftransportgeschehen der Elbe abgeschätzt werden konnte. Die Sedimentretention der Elbauen hatte im Betrachtungszeitraum zwischen 2003 und 2008 einen Anteil von 7 bis 30 % an den Jahresschwebstofffrachten in Hitzacker. Die Analysen von verschiedenen Zeitreihen der Sediment- und Bodenbelastungen mit Schwermetallen, Arsen sowie Dioxinen/Furanen verdeutlichte, dass die Stoffgruppen ganz unterschiedliche Belastungsentwicklungen durchlaufen haben. Der Schwerpunkt der Dioxinkontamination in Sedimenten und Böden trat in den 1950er bis 1960er Jahren auf, während Metalle im Allgemeinen erst später Belastungsmaxima zeigten. Allerdings konnte mit dem Pb/Zn-Verhältnis ein Metallmuster identifiziert werden, mit dessen Hilfe auch in Oberböden auf der Basis von Metalldaten auf Dioxinbelastungen geschlossen werden konnte. Darüber hinaus wurde unter Kenntnis der spezifischen Belastungshistorien mittels Kategorisierung der Standorteigenschaften Höhenlage, Distanz, Bioturbation und Sedimenteintrag ein Erklärungsschema zur Vorhersage von räumlichen Schadstoffmustern für ausgewählte Metalle und Dioxine/Furane entwickelt. Sowohl die Untersuchungen zum Sedimentationsgeschehen als auch zur Aufklärung des Belastungsmosaiks in den Elbauen ließen Ableitungen von Maßnahmenvorschlägen zur Förderung der Sedimentationsdynamik, des Hochwasserschutzes, zur schadstoffspezifischen Verbesserung der Bodenbelastung als auch zur belastungsangepassten Landnutzung zu.
Agricultural production of smallholder farmers in Myanmar is facing soil fertility degradation and in consequence, crop yields decline due to the imbalances of nutrient supply. In most cases, all above ground biomass is removed from the fields after harvesting the crops and during land preparation for the next crop. Higher temperatures also stimulate the higher mineralisation rates and released mineral nutrients are lost from fallow lands before sowing the next crops. Regarding the addition of mineral fertilizers, except for cash crops, farmers are reluctant to apply fertilizers for the crops that are sown for household’s self-sufficiency. In the Dry Zone, irrigated agriculture is available in recent years and farmers could overcome water scarcity through irrigation. With the availability of irrigation water, farmers could prolong the cropping period, nevertheless crop yields are decreasing year by year. In recent decades, research findings are indicating the benefits of biochar application for soil fertility improvement and food security. Smallholder farmers can produce biochar from agricultural by-products such as pigeon pea stems, cotton stems and rice husks by using biochar stoves. Large-scale production is possible by producing both biochar and thermal energy simultaneously, such as getting rice husk biochar and producing thermal energy by burning rice husks. By those means, environmental pollution due to the smokes from stubble burnings and the health hazards from smokes arise from kitchens can also be reduced. Present research was conducted to test the effects of the application of biochars produced from different crop residues together with NPK fertilizers on crop yields and soil properties in the rice-chickpea-cotton cropping system of the Central Dry Zone area of Myanmar during 2012 and 2013 cropping seasons at Shwe Daung Farm, Mandalay Division, Myanmar. Effects of biochar applications in combination with NPK fertilizers were compared with NPK fertilizer (without biochar) application and the control (without biochar and NPK fertilizers). Biochars used in the experiments were produced from three kinds of locally available raw materials (rice husk, rice straw and, pigeon pea stem) at temperature above 550°C by using a kiln made from a 200-Liter diesel barrel. Field experiments were conducted on sandy loam soil in the Central Dry Zone of Myanmar. After harvesting rice in 2012, chickpea was sown without application of both organic and inorganic fertilizers. After harvesting chickpea in 2013, cotton was sown on the same experimental plots. Treatments were rice husk biochar (Rh) 20 Mg ha-1 + NPK fertilizers; rice straw biochar (Rs) 20 Mg ha-1 + NPK fertilizers; pigeon pea stem biochar (Ps) 20 Mg ha-1 + NPK fertilizers; rice husk biochar and farmyard manure mixture (Rh biochar + FYM) 10 Mg ha-1 + NPK fertilizers; NPK fertilizers (without biochar); and the control (without fertilizer and biochar). Biochar weights represented fresh biochar weights. Equal rate of NPK fertilizers were applied in all treatments. However, fertilizer rates were different with respect to the crops. In rice experiment, 100:50:50 kg ha-1 rate of Urea (N): Triple Super Phosphate (P): Muriate of potash (K) was applied. In cotton experiment, 100:30:117 kg ha-1 rate of Urea (N): Triple Super Phosphate (P): Muriate of potash (K) was applied. Crop growth data, yield component data and yield data of each treatment were recorded. Soil samples from topsoil (0-0.2 m) were taken before starting the experiments, after harvesting rice and cotton, respectively, and analysed. A biogeochemical model, denitrification decomposition (DNDC) model, was used to estimate soil organic carbon storage and greenhouse gas emissions during crop growing seasons and to quantify the long-term impact of biochar applications on rice, chickpea and cotton yields.The results from soil analyses indicated that although initial soil pH was at 8.0 and pH values of biochars ranged between 8.0 and 10.0 soil pH after two years of biochar application did not increase. pH values were below 8.0. That value was lower than initial soil pH. That could be due to the effect of the change of cropping system from upland to lowland rice cultivation and the effects of biochar additions to the alkaline sandy loamy soil of the experimental site. Although total exchangeable cation value was not significantly different among the treatments, compositions of major cations were significantly different among the treatments. Exchangeable potassium increased in Rs biochar + NPK applied soils. Exchangeable sodium increased in control, and conventional NPK fertilizer applied soils. Reduction of soil bulk density from 1.8 g cm-3 to 1.6-1.7 g cm-3 occurred in biochar treatments compared to control and conventional NPK fertilizer application treatments. Positive changes of total carbon and total nitrogen of soils were found in biochar treatments compared to control and conventional NPK fertilizer application. Application of pigeon pea stem biochar + NPK fertilizers showed the highest crop growth and the highest yield in rice. The highest chickpea yield was obtained from the plot that applied rice husk biochar + NPK fertilizers. Cotton crop growth and yield was the highest in rice husk biochar and farmyard manure mixture + NPK fertilizer application. The lowest crop growth and yield was obtained from the control in cotton. The results of this study suggested that biochars from different biomass materials had different effects on soil properties and crop yields under different growing conditions and cultivated crops. Although the applied biochars had a high pH, soil pH did not increase after biochar applications. The growth and yield of tested crops were higher than that of the control and conventional NPK fertilizer application. Rice husk biochar and farmyard manure mixture + NPK fertilizer application can be assumed as a suitable soil amendment application under upland crop cultivation. Pigeon pea stems biochar + NPK fertilizers should be applied in rice cultivation. Rice husk biochar + NPK fertilizers and rice husk biochar-farmyard manure mixture + NPK fertilizers showed as the appropriate biochar soil amendments for the study area compared to rice straw biochar + NPK fertilizers and pigeon pea stem biochar + NPK fertilizers. Application of these biochars increased total exchangeable cations, reduced bulk density, increased organic carbon, regulated soil pH and, can easily be accessed by smallholder farmers by promising crop yields for sustainable agricultural production. Rice straw biochar + NPK fertilizers and pigeon pea stem biochar + NPK fertilizers also showed positive influences on soil fertility and crop growth. However, extensive application of those biochars might require large-scale productions and distributions. To obtain the detail information regarding the impact of biochar application on the agro-ecosystem and surrounding atmosphere, further research activities may need to carry out under different agricultural production conditions. When model fitness was tested, it was found that DNDC model was fit for the simulation of crop yields and soil organic carbon under the conditions of the experimental site. Simulation of soil organic carbon dynamics and crop yields for 30 years and 50 years after the addition of biochars in combination with NPK fertilizers showed that such applications could maintain the crop yields at the same level up to 50 years. That could maintain soil organic carbon at a level higher than conventional NPK fertilizer application. Regarding the simulation of GHGs emissions, the model simulated nitrous oxide emission close to actual emissions of agricultural soils of Myanmar. Simulated CH4 emissions from control and conventional NPK fertilizer application variant were consistent with the well-known emissions of Myanmar rice fields. To confirm the accuracy of simulated CH4 emissions from biochar applied soils, it may need field investigations and validations of model results. Simulated effects of rice husk-, rice straw- and pigeon pea stem fresh biomass applications and that of rice husk-, rice straw- and pigeon pea stem biochar applications on rice, chickpea, cotton yields and soil organic carbon (SOC) were compared. Objective of this simulation was to compare the effects of fresh biomass-applications and the application of biochars produced from the same biomass on crop yields and SOC by using DNDC model. The results showed that simulated rice yields of rice husk biochar and rice straw biochar applications were 33% and 31%, respectively, higher than that of pigeon pea green manure applications. However, simulated rice yield from pigeon pea stem biochar application was 4% higher than that of iv pigeon pea stem green manure application. Simulated chickpea yield from pigeon pea green manure treatment was the highest among all of biochar and biomass applications. Simulated cotton yields obtained from fresh biomass applications were lower than that of biochar applications. In estimating the future yields, all crop yields from rice husk and rice straw biomass applications were lower than that of rice husk and rice straw biochar applications in the initial year of simulation. However, in the following years, the yields remained at the same level up to the end of simulated years. In pigeon pea stem green manure application, crop yields were higher than the other treatments since the initial year up to the end of simulated years. Simulated SOC was lower in fresh biomass applications compared to biochar applications.
Das Nationale Bildungspanel (NEPS) untersucht wie sich Kompetenzen, unter anderem die mathematische Kompetenz, über die Lebensspanne entwickeln, wie diese die Bildungskarriere beeinflussen und inwiefern die Kompetenzentwicklung von Lerngelegenheiten abhängig ist. Erhoben werden die Daten mit Hilfe eines Multi-Kohorten-Sequenz-Designs, wobei in allen Bildungsetappen verschiedene Instrumente zum Einsatz kommen (Blossfeld & von Maurice, 2011). Um diese Daten sinnvoll nutzen zu können, müssen sie valide Testwertinterpretationen zulassen. Diese Arbeit leistet einen Beitrag zur Validierung der National Educational Panel Study (NEPS)-Testwertinterpretationen, indem der Mathematiktest für die neunte Klassenstufe (K9) umfassend analysiert wurde. Dabei wurde geprüft, ob die Unterschiede in der beobachteten Testleistung die Unterschiede in der mathematischen Fähigkeit wiedergeben, wie diese im NEPS-Rahmenkonzept definiert sind. Für die Validierung wurde eine Argumentationskette für den NEPS-K9-Mathematiktest, angelehnt an den Argument Based Approach von Kane (2013), entwickelt. Für die Auswertung wurde der scientific use file der NEPS-Haupterhebung 2010 verwendet. Die Stichprobe dieser Studie bestand aus 15239 Schülerinnen und Schülern der neunten Jahrgangsstufe. Für die Untersuchung der Zusammenhänge des NEPS-Mathematiktests mit anderen Messungen mathematischer und nicht mathematischer Kompetenz wurde zusätzlich eine Validierungsstudie durchgeführt. Zur Erfassung der mathematischen und naturwissenschaftlichen Kompetenz wurden in dieser Studie neben den NEPS-Testinstrumenten Aufgaben aus dem Programme for International Student Assessment (PISA) und dem IQB-Ländervergleich (LV) eingesetzt. Zusätzlich wurde ein kognitiver Fähigkeitstest verwendet. Insgesamt wurden 80 Schulen mit 1965 Schülerinnen und Schülern der neunten Klassenstufe für die Teilnahme an der Studie ausgewählt. Zur Vorbereitung des Validitätsargumentes wurden Literaturreviews bereits veröffentlichter Analysen und ein Expertenreview zu den Merkmalen der NEPS-Mathematikaufgaben durchgeführt. Des Weiteren wurden die Kompetenzdaten mit Hilfe von Modellen der Item Response Theorie skaliert und dimensional analysiert. Außerdem wurden korrelative Zusammenhänge mit Kriterien mathematischer Kompetenz berechnet. Die Ergebnisse liefern viele Hinweise bezüglich der Validität der Testwertinterpretationen, jedoch wurden auch einige Einschränkungen und weiterer Forschungsbedarf aufgezeigt. Beispielsweise ließ sich die Annahme der Eindimensionalität des NEPS-Mathematiktests nicht bestätigen. Außerdem wären weitere Analysen bezüglich des Zusammenhanges mit geeigneten Kriterien für die Zieldomäne Mathematische Kompetenz für eine Erweiterung der Testwertinterpretationen wünschenswert. Die gefundenen Evidenzen stützen jedoch die Testwertinterpretation ´die Unterschiede in der Rangfolge der beobachteten Testleistung deuten auf Unterschiede in der Rangfolge der Ausprägung der mathematischen Kompetenz, wie diese im Rahmenkonzept definiert wird´. So konnten für die Zieldomäne relevante Teilkompetenzen in den NEPS-Aufgaben identifiziert werden, waren die Bewertungskriterien angemessen und wurden erwartungsgemäße Zusammenhänge mit den Mathematiktests aus dem LV und PISA gefunden. Auf diese Weise konnte eine vollständige Argumentationskette für den NEPS-K9-Mathematiktest entwickelt, sowie Empfehlungen für die Stärkung und Erweiterung der Testwertinterpretation empfohlen werden. Der Argument Based Approach von Kane erwies sich dabei als hilfreicher Ansatz, in welchem die Vorgaben der Standards for Educational and Psychological Testing (American Educational Research Association, American Psychological Association, National Council on Measurement in Education, 2014) berücksichtigt werden konnten.
Biodiversity loss could jeopardize ecosystem functioning. Yet, the evidences that support this demonstration have been mostly obtained in aquatic and grassland ecosystems. Howbiodiversity affects ecosystem functioning still remain largely unanswered in forests, particularly in subtropical broad-leaved evergreen forests (EBLF). Tree productivity, among a wealth of forest ecosystem functioning, is of particular interest because it reflects the carbon sink capacity and wood productivity. Biodiversity-productivity relationships have been usually investigated at community level. However, tree-tree interactions occur at small scale. Thus, local neighborhood approach may allow a better understanding of tree-tree interactions and their contributions to the effects of biodiversity on tree productivity / growth rates. This thesis aims to analyze the effects of biodiversity and the abiotic environmental factors on the tree growth rates using both local neighborhood and community-based approaches. Furthermore, tree growth rates vary among different tree species. Functional traits have been related to the species-specific growth rates to understand the effects of species identity. Therefore, I also evaluated the crown- and leaf traits to predict the interspecific difference in growth rates. For a better understanding of the mechanisms that underline the relationships of biodiversity and tree growth rates, data of high solution and along time series is required to scrutinize the tree-tree interactions. Thereupon, I evaluated the applicability of terrestrial laser scanning (TLS) in assessing the tree dendrometrics. This thesis was conducted in the Biodiversity Ecosystem Functioning (BEF)–China experiment, which is located in a mountainous subtropical region in southeast China. A total of 40 native broad-leaved tree species were planted. In the first study, I used the local neighborhood approach to analyze how local abiotic conditions (i.e. topographic and edaphic conditions) and local neighborhood (i.e. species diversity and competition by neighborhood) affect the annual growth rates of 6723 individual trees. The second study used the community approach to partition the effects of environmental factors (i.e. topographic and edaphic), functional diversity according to Rao’s quadratic entropy (FDQ) and community weight mean (CWM) of 41 functional traits on community tree growth rates. The main question of the third study was how the species-specific growth rates are related to five crown- and 12 leaf traits.
In the fourth study, I investigated 438 tree individuals for the congruence between the conventional direct field measurements and TLS measurements. It was found that tree growth rates were strongly influenced by the local topographic and edaphic conditions but not affected by the diversity of local neighborhood. In contrast, results obtained by using the community-based approach showed that FDQ and CWMs of various leaf traits rather than abiotic environmental factors had significant impact on the community means of growth rates. Tree-tree interactions already occur in early life stages of trees, which were evidenced by the significant effect of competition by local neighborhood. These findings imply that the effects of abiotic environmental factors may be more evident at local scale and biodiversity effects may vary at different spatial scales. The species-specific growth rates were found to be related to specific leaf traits but not to crown traits and were best explained by both types of traits in combination. This finding supports the niche theory and provides the evidence for using functional diversity to examine the BEF relationships. The TLS-retrieved total tree height, stem diameter at 5 cm above ground, and length and height of the longest branch were highly congruent with those obtained from direct measurements. It indicates that TLS is a promising tool for high resolution, non-destructive analyses of tree structures in young tree plantations. Being one of very few studies to incorporate the individual tree scale in examining the biodiversity-productivity relationships within the BEF researches, this thesis stresses the importance of using individual-tree based approach, functional diversity and TLS to find the evidences of explanatory mechanisms of the observed biodiversity and ecosystem functioning (e.g. tree growth rates) relationships. Biodiversity effects may evolve along the successional stages. Therefore, incorporating the interaction between biodiversity and time in analyzing BEF relationship is also encouraged.
Die Verringerung des Material- und Ressourcenverbrauchs ist eine wesentliche Herausforderung nachhaltiger Entwicklung. Bislang standen und stehen politische Maßnahmen zur Energieeffizienz im Vordergrund. Maßnahmen zur Verbesserung der Materialeffizienz gewinnen jedoch verstärkt an Bedeutung. Der Erfolg oder Misserfolg politischer Instrumente im Umwelt- und Klimaschutzbereich wird maßgeblich davon abhängen, ob die Instrumente die Fähigkeit besitzen, eine Entkoppelung von Lebensqualität und Ressourcenverbrauch zu erzeugen. Insbesondere im Rahmen der Ökodesign-Richtlinie, aber auch anderer Instrumente der Europäischen Union, sind Ansatzpunkte zur politischen Gestaltung einer ressourcenleichten Langfristökonomie angelegt. Die Dissertation wird schwerpunktmäßig die Governance-Instrumente im Produktbereich der Europäischen Union behandeln. Die Dissertation folgt der Theorie, dass die Produkte der Industriegesellschaft einzeln mehr oder weniger harmlos, in ihrer Menge jedoch die Quelle fast aller Umweltprobleme sind. Zur Erstellung der Dissertation sieht das spezifische Methodendesign die Anwendung eines Kriterienkatalogs zur Bewertung der Steuerungsinstrumente für Langfristökonomie im Produktbereich vor. Darüber hinaus werden die Hauptakteure in Form von Interviews befragt.
Heating is most important part of thermal energy demand, and accounts for large amounts ofenergy consumption in cold regions. Renewable energy sources will be of great importance inorder to cover future energy demands. However, their intermittency is rightly considered asinconvenient. Thus, a more effective management of demand, coupled with efficient storagesystems is required. Based on this perception, thermal systems coupled with electricityproduction have been efficiently designed, they are the so called “combined heat and power”(micro-CHP). Nonetheless, heat losses from the thermal part of their system lead to electricityfluctuation. Therefore, the use of micro-CHP in combination with a volume-efficient and nearlylossless heat storage system to counteract electricity fluctuations is a viable solution.The heat storage system in this work is based on reversible thermochemical reactions, suchas dehydration and hydration of inorganic salts, which exhibits very high energy density (up to628 kWh·m-3 of storage material). The chosen inorganic salt (SrBr2·6H2O) reacting with purewater vapour operates within a closed system. The objective of this work is to design a systemthat thermodynamically matches the combination with micro-CHP. Therefore, investigationshave been performed from the material at micro-scale to the system at lab-scale. Models weredeveloped on the basis of heat and mass transfer with chemical reaction and were done in orderto numerically analyse the system. Experiments were additionally performed to consolidate thenumerical tools for future studies. Characterization experiments have been designed and tested.Thermo-physical properties (thermal conductivity, specific heat capacity, permeability, chemicalkinetics) of the reactive salt were then determined to be used as parameters into the sodeveloped models.The numerical simulations lead to the time-space evolution of heating fluid, reactive bedtemperatures and reactor pressure. The originality of this study is to model the coupled heat andmass transfer with chemical reaction on a 3D geometry to be close to the reality. Results help tonumerically and experimentally analyse the thermochemical heat storage performances. Thebed energy density is experimentally found to be 531 kWh·m-3 of salt hydrate. Based on thecondensation temperature during the experimentation, a reactor energy density of 140 kWh·m-3and a storage capacity of 65 kWh with a thermal efficiency of 0.78 are obtained. This systemproves the recovery capacity of more than 2/3 of the input energy. Various aspects of design andrecommendation for optimisation aspect that could help during prototype development aretaken into account and addressed. Comparison simulation-experiment is then performed anddiscussed, showing encouraging results, even if limited at lab-scale.
In the discourse on pharmaceuticals in the environment, hardly any attention has been paid to anticancer drugs. Because of their none-selective modes of action, that is, because they affect both cancerous and healthy cells, these drugs are regarded as potentially carcinogenic, genotoxic, mutagenic, and teratogenic substances. It is, however, not known how and to what extent these substances affect organisms and the environment in the long run. For this reason, this dissertation evaluated, addressing several endpoints and using organisms from different trophic levels and in silico predictions, the fate (bio- and photo degradation) and ecotoxicity of these substances. Four anticancer drugs (cyclophosphamide (CP), 5-fluorouracil (5-FU), methotrexate (MTX), and imatinib (IM) were selected. None of these anticancer compounds can be classified as ´readily biodegradable,´ a classification that indicates that biodegradation will only play a minor role in the elimination of these compounds and that they cannot be removed by the conventional processes used in sewage treatment plants and will most likely remain in the water cycle. Despite the high degrees of mineralization achieved in advanced (photo)oxidation processes, it was not possible to fully mineralize the compounds, a result that indicates that transformation products were created during these reactions. The ecotoxicity assays performed with V. fischeri indicated that 5-FU was, of all the substances tested, likely to be the most toxic (very toxic), followed by MTX (toxic) and IM (toxic/harmful), whereas CP was nontoxic. MTX presented the highest phytoxicity activity in the Lactuca sativa assay, followed by 5-FU, IM, and CP. The results of the tests performed with A. cepa showed cytotoxic (5-FU, MTX, and CP) and genotoxic effects (5-FU, CP, and IM) and mutagenic activity (5-FU, MTX, CP, and IM) of the compounds. Photo transformation products (PTPs) of CP, MTX, and 5-FU were nontoxic towards V. fischeri. However, some PTPs formed during the photodegradation of 5-FU led to positive mutagenic and genotoxic alerts in several in silico models. Not one of the compounds examined in this dissertation is likely to be fully eliminated from the water cycle by (natural) photolysis and/or advanced oxidation. Moreover, some of the treatments resulted in the formation of stable intermediates that were even less biodegradable than parent compounds. This finding shows that it is not enough to focus on primary elimination because TPs are not necessarily better biodegradable than their respective parent compounds. As indicated by the genotoxic and mutagenic positive alerts presented by different in silico models, the PTPs observed here are likely to require, despite their lower toxicity in comparison to the parent compounds, screening after treatments.
Traditional farming landscapes have been created in coexistence of rural dwellers and local ecosystems over long time spans, and can be considered tightly coupled ´social-ecological systems´ (SES). Since these landscapes typically embody exceptionally high levels of biological diversity and multiple socio-cultural values, their protection is critical from a sustainability perspective. Due to the pressures of globalization and social change, however, rural livelihoods and farmland biodiversity are at risk. While the focus of research is often on the Southern hemisphere, there are traditional farming landscapes in the former socialist countries of Central and Eastern Europe (CEE) which are equally affected by rapid change, and thus deserve particular attention. Since the institutional breakdown of socialism in 1989, the CEE states have not only been confronted with an unprecedented socio-economic and environmental transition. Their integration into the multi-level governance regime of the European Union (EU) further resulted in the transformation of decision-making structures and competition within the EU common market. In light of the profound changes traditional farming landscapes of Central and Eastern Europe are confronted with, they serve as a valuable source of learning about the institutional design necessary to harmonize socio-economic development and biodiversity conservation within regional social-ecological systems worldwide. This thesis is the result of an in-depth analysis of one traditional farming landscape of Central and Eastern Europe, namely Southern Transylvania (Romania). Based on empirical research involving diverse stakeholder groups, this thesis assessed the impact of EU policy on the area, the institutional features characterizing local-level governance in Southern Transylvania, and the barriers and bridges towards sustainable rural development. This thesis finds that while rural dwellers are highly dependent on smallholder farming and local ecosystems for their livelihoods, Southern Transylvania is currently confronted with a range of structural development barriers. These are likely to be exacerbated by a governance system consisting of historically grounded ´elite social networks´, and by EU policies which often do not fit rural realities. The findings of this dissertation underline that entrenched informal institutions, political will, and historical legacies play a critical role for the governance of traditional social-ecological systems since these ´social system features´ do not only mediate how external policies act on the local level. They may further restrict local adaptive and innovation capacities which, however, are critical for the transformation towards sustainable development. This thesis further finds that there are no blueprint solutions for the design of rural development strategies. Instead, (supra-) national policies should take better account of local socio-economic and cultural particularities.
Entrepreneurship is an important means for economic development and poverty alleviation . Due to the relevance of entrepreneurship, scholars call for research that contributes to the understanding of successful business creation. In order to best understand new venture creation, research needs to investigate barriers of entrepreneurship. A barrier that has received wide attention in the literature on new venture creation is capital requirements. Scholars argue that capital requirements are an entry barrier for new venture creation, as most people who start businesses have difficulties in acquiring the necessary amount of capital needed for starting the businesses. Particularly in developing countries, scholars and practitioners regard improvements in access to capital as a major solution to support new venture creation. However, besides improving access to capital, there are alternative solutions that help to deal with the problems of capital requirements and capital constraints in the process of new venture creation. In this dissertation, I argue that a possible means to master capital requirements and capital constraints in business creation is action-oriented entrepreneurship training. I draw on actionregulation theory (Frese & Zapf, 1994), theories supporting an interactionist approach (Endler & Edwards, 1986; Terborg, 1981) and on theories about career development (Arthur, 1994; Briscoe & Hall, 2006) to reason that action-oriented entrepreneurship training allows for handling capital requirements and capital constraints with regard to business creation. Specifically, I argue that action-oriented entrepreneurship training helps to deal with financial requirements and capital constraints in two ways: First, the training reduces the negative effect of capital constraints on business creation through the development of financial mental models. Second, the training supports finding employment and receiving employment income, which enable businesses creation.
Uranine (sodium fluorescein, UR) has been routinely used in hydrological research to monitor surface and subsurface water flow, transport and mixing processes since the end of nineteenth century. Based on such obtained data, further conclusions can be drawn on the spread and behavior of pollutants (partly on models). Use of UR for qualitative (visual) studies of underground contamination is common, however data available on its environmental behavior (e.g., conversion, degradation or formation and fate of the transformation products, TPs) are incomplete or not readily comparable. UR observations of biodegradation are still speculative. S-metolachlor (SM) is a popular worldwide chloroacetamide herbicide, which highly correspond to the global pesticide use. It is offered on the French market as an effective multicrop herbicide against annual grasses and certain broadleaf weeds under the trade name Mercantor Gold (MG). Photodegradation contributes to the fate of SM in the aquatic environment. TPs were already found in surface and groundwater. However, further fate and assessment of the TPs was not done. Moreover, adjuvants in MG´s formula can affect the solubility, biodegradation, photolysis and sorption properties of the active compound SM. TPs can have different properties (e.g. more mobile, toxic or present at higher concentrations) that enable them to reach the environmental compartments not affected by the parent compound (PC) itself. To assess the ecological impact of pesticides, tracers, and their respective TPs on water organisms, their behavior can be investigated in laboratory screening biodegradation tests. Yet, incomplete data was available on SM, MG and UR transformation or their photo- TPs´ fate in surface and water-sediment systems. The combination of photolysis with aerobic biodegradation in order to identify persistent photo-TPs could provide new insight into the environmental behavior of the selected compounds. Therefore, principle of this thesis was to 1) identify the impact of MG´s adjuvants on the biodegradation, photolysis (Xe lamp) and sorption compared to the SM alone, 2) examine the photolysis and biodegradability of UR 3) monitor the primary elimination (photolysis) of the PCs by HPLC (-UV, -FLD) and measure the degree of mineralization by means of nonpurgeable organic carbon (NPOC) 4) elucidate the photo-TPs of SM, MG and UR by using LCMS/ MS 5) analyze biodegradability of the photo-TPs in order to determine their fate and persistence in aquatic environment 6) conduct in silico toxicity predictions (pesticides) in human (carcinogenicity, genotoxicity and mutagenicity) and eco-toxicity (microtoxicity, bioconcentration factor and toxicity in rainbow trouts). SM, MG and UR were found not readily biodegradable in Closed Bottle test (CBT), Manometric Respiratory test (MRT) and in water-sediment test (WST). Chemical analysis of photolysis samples showed higher elimination of SM in MG compared to SM alone whereas UR displayed high primary elimination rate in general. The overall low degree of mineralization indicated that abundant photo-TPs were formed. Furthermore, the photo-TPs were found not biodegradable in performed biodegradation tests. Only small degradation rates for UR could be observed in the CBT and WST. Additionally, in the MRT and WST new bio-TPs were generated from the photo-TPs of SM and SM in MG. Obtained results suggest that the MG formulation did not significantly affect the biodegradation, however it influenced the diffusion of the active substance (SM) to sediment and potentially affected the photolysis efficiency, which might result in faster formation of photo-TPs in the environment. In silico predictions showed that for many endpoints, biotransformation might lead to an increased toxicity in humans and to water organisms compared with the parent compound SM. No indications were found for UR toxicity. Still, target-oriented investigations on long term impacts of photo-TPs from UR are warranted. The present work demonstrates that a combination of laboratory tests, analytical analysis and in silico tools result in valuable information regarding environmental fate of the TPs from selected compounds. Furthermore, it was shown that photo-TPs formed in the aquatic environment should be taken into account not only the parent compound and its decay.
The Ili Delta in Kazakhstan is an important ecosystem that offers crucial wetland habitats for several bird species. However, the Ili River, the Ili Delta and the Balkhash Lake are suffering from water shortage due to climate change and human activities. The desertification of the Aral Sea, an obvious point of comparison to the Balkhash region, also involved the degradation of wetland habitats and the related loss of many bird species relying on these habitats. Therefore, water shortage at the Ili Delta may also be the reason for the loss of wetland habitats and bird species. In this study, bird species numbers, species abundances as well as bird diversity at different habitats in the Ili Delta were examined. There are many habitat types provided by the Ili Delta, for example reed bed vegetation, Tugay forest, bare soil floodplains along rivers and steppe. The results of this study showed that the central delta region with habitats of submerged reed vegetation showed the highest number of bird species and the greatest diversity. Threatened bird species at the Ili Delta were also observed only in these wetland habitats. Steppe habitats showed the lowest numbers of bird species and the lowest bird diversity. In general, all habitats at the Ili Delta are important for the ecosystem and essential for the bird species that depend on them for their survival. With expansion of arid steppe habitats due to water shortage, however, previous wetland habitats may be lost. Moreover, bird species that depend on these wetland habitats may also be lost. Therefore, protective measures for the Balkhash region in general and the wetland habitats at the Ili Delta and its distinct avifauna in particular are urgently needed.
Vergleich von Menschenbildern in der protestantischen Theologie und gegenwärtigen Sozialpädagogik
(2015)
Viele Betriebsgastronomien in Deutschland sehen sich vor die Herausforderung steigender Gästeansprüche, zunehmenden Kostendrucks und oftmals auch konkurrierender Speisenanbieter gestellt. Hinzu kommt in vielen Betrieben die Forderung der Gäste oder des Managements nach einem Angebot gesundheitsfördernder Speisen und Getränke. Dieses kann z. B. durch die Deutsche Gesellschaft für Ernährung e. V. (DGE) zertifiziert werden. Die innerbetriebliche Umsetzung und Kommunikation des erweiterten, gesundheitsfördernden Speisenangebotes muss indes gesteuert werden. Hierfür bietet sich die Erstellung einer Balanced Scorecard nach Kaplan und Norton an. Diese berücksichtigt neben finanzorientierten Kennzahlen auch ausdrücklich qualitative Ziele und stellt deren wechselseitige Einflüsse in Ursache-Wirkungs-Ketten dar. Die vorliegende Bachelorarbeit spezifiziert eine Balanced Scorecard auf die Anforderungen einer Betriebsgastronomie, die ein DGE-zertifiziertes Speisenangebot etablieren möchte. Zu diesem Zweck werden für die vier Perspektiven einer Balanced Scorecard strategische Ziele vorgeschlagen und deren Ursache-Wirkungs-Beziehungen grafisch in einer Strategy Map dargestellt. Die ebenfalls durchgeführte empirische Untersuchung DGE-zertifizierter Betriebe zeigt, dass durch die Einführung eines gesundheitsfördernden Speisenangebotes die Mitarbeiterzufriedenheit und Mitarbeitergesundheit positiv beeinflusst werden kann. Zudem ist eine Steigerung des Umsatzes durch die Gewinnung neuer Gäste und den Zusatzverkauf komplementärer Produkte möglich.