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Institut
- Fakultät Nachhaltigkeit (126)
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Increased international compliance with human rights and democracy standards is a core issue for both human rights and democratizing actors as well as for victims of human rights abuse. International human rights organizations (IHROs) are expected to make positive contributions to this end, even though they possess low levels of authority. This authority has been renegotiated multiple times in various reform processes. An oversimplified expectation would have us assume that democracies would want to strengthen IHROs, and that autocracies would seek to weaken them. As the United Nations Human Rights Council (UNHRC) was reformed in 2006, 2007, 2010, and 2011, some autocracies strived to abolish parts of the UNHRC. Other autocracies aimed "merely" to weaken them. Democracies displayed an even larger variance. The question that drives this research work is how we can explain the broad variety of state preferences for strengthening or weakening IHROs. Previous research has mostly concentrated on democracies, leaving autocracies understudied. It also treated countries as black boxes. To account for such shortcomings, first, the author systematically tests the relationship between the UNHRC and its authoritarian and democratic members by means of inferential statistics. Second, he analyzes a bottom-up process inherent to New Liberalism. It scrutinizes the role of domestic societal actors, domestic institutions, as well as pressures on the international stage. The results reveal that societal actors, along with the interplay of wealth and regime type in the international realm, figure as the most important predictors of delegation preferences voiced by autocracies and democracies during the reform of the monitoring bureaucracy Special Procedures of the UNHRC. Societal actors play a more important role in democracies than in autocracies. Institutionalized domestic oversight mechanisms help societal actors to conduct effective lobbying at the domestic level. Oversight mechanisms are more important than the rule of law and electoral institutions. Regarding international coalition building, authoritarian regimes turn out to be better organized than democracies. The author concludes that supporters of strong IHROs shall 1. empower domestic societal actors; 2. disrupt cohesive delegation preferences of authoritarian regimes; and 3. invest in independent domestic oversight mechanisms.oversight mechanisms.
Metals fulfill crucial functions in areas as diverse as renewable energy, digitization and life style appliances, mobility, communication, or medicine. In the context of sustainability, achieving a more sustainable metal use means (i) minimizing the adverse effects associated with metal production and use and (ii) sustaining the availability of metals in a way that benefits present and future generations. Urgent need to act to avoid bottlenecks as well as meeting the challenge of possible conflicts of use among those areas of application calls for appropriate strategy making to intervene in the complex field of metal production and use that involves various, often interlinked operating levels, actors, and spatial and temporal scales. This dissertation focuses on strategies as a means to intervene in a system. It pursues the question, which design features could guide future strategy making to foster sustainability along the whole metal life cycle, and especially, how a better understanding of temporalities, i.e. understanding time in a diverse sense, could improve strategy design and help to bridge the assumed "transformation-material gap". This research converges the results from four research studies. A conceptual part explores the role of temporalities for interventions in complex and interlinked systems, which adds to the conceptual basis, on which the empirical part builds up to explore present and future interventions in metal production and use. The research revealed three essential needs that future strategies must tackle: (i) managing the complex interlinkages of processes and activities on various operational levels and spatial and temporal scales, (ii) providing clear guidance concerning the operationalization of sustainability principles, and (iii) keeping activities within the planet’s carrying capacity and embracing constant change as an inherent system characteristic. In response to these needs, the author developed three guidelines with two design features each (one relating to content, and one to the process of formulating and implementing the strategy) to guide future strategy making. The results show that time matters in this respect. If considered in close relation to space and diversely understood in the sense of temporalities, it serves to (i) understand the impact (duration and magnitude) of an intervention, (ii) recognize patterns of change that go beyond establishing linear, one-dimensional connections, and (iii) design interventions in a way that considers the resilience of a system. These findings can contribute to closer considering our understanding of transformation processes towards sustainability in future interventions in metal production and use.
TIME for REFL-ACTION: Interpersonal Competence Development in Project-based Sustainability Courses
(2021)
This dissertation investigates interpersonal competence development in project-based sustainability courses. Visions of a sustainable, safe, and just future cannot be reached by one individual alone. Thus, future change agents need to be able to collaborate and engage with stakeholders, to approach the manifold crises, challenges, problems, and conflicts we are facing together, and to promote and push forward sustainability transitions and transformations. Therefore, this research investigates three project-based sustainability graduate courses by comparing and contrasting teaching and learning outcomes, processes, and environments. A comparative case study approach using a Grounded Theory-inspired research design which triangulates several qualitative methods and perspectives is applied to allow for generalizable insights. Thereby, this dissertation provides empirically-informed insights which are further discussed in relation to selected teaching and learning theories. This leads, first, to a discussion of practical implications within (and beyond) sustainability higher education; and second, provides a theoretical foundation for interpersonal competence development in project-based learning settings – so that educating future change agents can gain momentum. Findings of this research show that embracing conflicts when they occur (i.e. before they provoke cascading effects in the form of further conflicts down-the-road) is an effective strategy to help further develop interpersonal competence. This requires a conflict-embracing attitude. Attitude, in general, seems to be key in interpersonal competence and competence development overall. Self-reflection, if not explicitly required by outside influences (such as instructors), arises naturally from a self-reflective attitude, and is shown to provide the basis for developing interpersonal competence. This research introduces the term "Refl-Action" which stresses the importance of pairing "learning by doing" (as is often the focus in project-based learning settings) with conscious moments of "reflecting about the doing". More specifically, the research presented here identified four learning processes for interpersonal competence development: receiving input, experiencing, reflecting, and experimenting. Based on the empirical data, when the four processes are purposefully combined, following a meaningful sequence attitudes, knowledge, and skills in collaborative teamwork and impactful stakeholder engagement, are fostered (two facets of interpersonal competence). Each of the four learning processes is set in motion through various interactions students engage in during project-based sustainability courses: student-student (labeled "peer"), student-instructor (labeled "deliberate"), student-stakeholder (labeled "professional"), and student-mentor (labeled "supportive") interactions. When these interactions are made explicit subjects of inquiry - i.e. the (inter-)action is linked with (self-)reflection – different learning processes complement one another: Interpersonal competence facets (collaborative teamwork and impactful stakeholder engagement) and domains (attitudes, knowledge, skills) are fostered. While, overall, interactions, processes, and conflicts have been identified as supportive for interpersonal competence development, trust has emerged as another variable inviting further investigation.
Für die lernförderliche Verknüpfung von Theorie und Praxis in der Lehrerbildung bieten sich insbesondere innovative Lerntools wie das Lernarrangement Videokonferenzsystem an. Selten liegt der Fokus bei der Forschung zu Theorie und Praxis allerdings auf den Überzeugungen der Lehramtsstudierenden zu Theorie und Praxis. Man weiß deswegen nur wenig darüber, was Lehramtsstudierende über diese beiden Konzepte denken. In dieser Studie wird deswegen der Frage nachgegangen, welche Überzeugungen Lehramtsstudierende zu Theorie und Praxis haben. Des Weiteren wird anhand des Lernarrangements Videokonferenzsystem untersucht, inwieweit Lehramtsstudierende Verknüpfungen von Theorie und Praxis als solche wahrnehmen und ob sich die Überzeugungen zu Theorie und Praxis nach der Arbeit mit dem Lernarrangement Videokonferenzsystem verändern können. Anhand qualitativer Leitfadeninterviews wurden 54 Lehramtsstudierende der Leuphana Universität Lüneburg zu zwei Messzeitpunkten befragt und anschließend mithilfe der qualitativen Inhaltsanalyse ausgewertet. Die Ergebnisse zeigen, dass die Studierenden theoriekonforme, unvollständige sowie der Theorie widersprechende Überzeugungen zu Theorie und Praxis haben und dass ihnen beide Konzepte wichtig sind. Allerdings wissen die Studierenden häufig nicht, wie sie Theorien nutzen können. Positiv für das Lernen der Studierenden scheint dabei zu sein, wenn diese möglichst viele unterschiedliche Praxiselemente sowie Theorie-Praxis-Verhältnisse in ihrem Studium wahrnehmen. Die Studierenden erkennen das Lernarrangement Videokonferenzsystem als eine Verknüpfung von Theorie und Praxis an. Sie nennen außerdem die grundliegenden Konzepte des Lernarrangements Videokonferenzsystem als lernförderlich. Schließlich scheinen die Überzeugungen der Studierenden zu Theorie und Praxis veränderbar zu sein. Aus den Ergebnissen der Studie lässt sich ableiten, dass eine einfache Erhöhung des Praxisbezugs in der Lehrerbildung nicht zielführend scheint. Es werden aber mehr Konzepte benötigt, die Theorie und Praxis sowie ihre unterschiedlichen Verhältnisse miteinander verbinden. Des Weiteren bedarf es im Studium mehr Kommunikation über sowie Lerngelegenheiten zu Theorie und Praxis.
Understanding that entrepreneurship can be better modeled from a systemic point of view is a primordial aspect that determines the important role of universities in entrepreneurial ecosystems. What makes the ecosystem approach a valuable tool for understanding social systems is that, from a holistic perspective, their behavior seems to have emerging characteristics. This dissertation presents a dual scientific account of the entrepreneurship phenomenon in universities. The work is divided into two equal parts, each of which is composed of two research papers. The narrative of the first half takes on a macro perspective view, consisting of one theoretical and one empirically-based conceptual case study. This part conceptually depicts a systematic approach to entrepreneurialism in higher education, namely an ecosystems perspective. The second half concentrates on the meso- and micro levels of study from the university's point of view, comprising of a case study as historical account for the emergence of the entrepreneurial university, and of a metasynthesis of empirical case studies in entrepreneurial universities, which serves as the basis for the development of entrepreneurial university archetypes. This doctoral work contributes to an in-depth understanding of Entrepreneurship in universities regarding its systemic qualities and archetypal characteristics of entrepreneurial universities. It argues for an ecosystem's perspective on the phenomenon of entrepreneurial activity, highlighting the fundamental role that universities play as the heart of entrepreneurial ecosystems. Furthermore, this research expands on the novel concept of the entrepreneurial university by using extensive case study literature to empirically identify distinct archetypes that better reflect the diverse reality of how universities engage as entrepreneurial actors by way of differentiated entrepreneurial structures, systems, and strategies.
The role of tree diversity for individual tree growth, crown architecture and branch demography
(2012)
In the light of the concurrent loss of biodiversity, biodiversity and ecosystem functioning (BEF) research attracted a great deal of attention and emerged as one of the important fields of research in ecology. Since important ecological interactions such as competition occur between individuals, the understanding of individual tree growth was considered to be fundamental for forest related BEF research. Individual tree growth is determined by the above- and belowground interactions of a tree individual with its local neighbourhood. To obtain a deeper understanding of BEF relationships, I broadened the focus from individual tree growth (usually measured as diameter or biomass increment) to the arrangement and dynamics of the above-ground modules of trees in dependence of their local neighbourhood. More precisely, the main objective of the present thesis was to analyse the impact of tree diversity on individual tree growth, crown architectural and branch demographic variables. Thereby I considered crown architectural variables as important indicators of the competition for light. In addition, crown architectural variables impacted ecosystem services such as erosion control. Furthermore, the results of the present thesis contributed to the current discussion on species coexistence theories, which may be differentiated by two opposing views: one that relies on neutral processes and one that implicates a role for meaningful differences in the ecological strategy (niche) of co-occurring species. The studied forest ecosystems were the subtropical broad-leaved evergreen forests of southeast China, which have been under high human pressure due to a long history of intensive land-use. The area is of particular interest for BEF research due to the high species richness of woody plants, including many, yet poorly studied species, and due to the rough terrain with steep slopes, which cause severe soil erosion. The present thesis combines three observational with two experimental studies, applying the local neighbourhood approach along an age gradient from tree saplings to mature trees. In the Gutianshan National Nature Reserve (GNNR), I conducted two observational studies on permanent plots which were chosen according to a space-for-time substitution design. The aim of the first study was to reveal the effects of diversity (species richness, functional diversity) together with other biotic and abiotic variables on morphological growth parameters (crown area, crown displacement and stem inclination) of target trees of four tree species (Castanea henryi, Castanopsis eyrei, Quercus serrata and Schima superba). In the second study, the same target trees together with their neighbours were used to analyse the relation between stand related functional diversity and the horizontal and vertical structure of the canopy. The third study was conducted in a young secondary broad-leaved evergreen forest. Using two target species (Castanopsis fargesii and Quercus fabri), the role of diversity, intra- vs. inter-specific competition and the mode of competition (symmetric vs. asymmetric) on the target individuals was tested by analysing five-year radial growth increments. The two other studies were carried out in an experimentally established plantation, using saplings of four tree species (C. henryi, Elaeocarpus decipiens, Q. serrata and S. superba), which were planted in monoculture, twoand four-species combinations and in three densities. The fourth study focused on mechanisms of coexistence and the role of species richness, species composition, species identity and density on sapling growth. The fifth study tested the effect of sapling density and identity on the througfall kinetic energy, which represents a measure for the erosive power of rain. It was found that functional diversity does affect crown architectural and canopy related parameters of forests in the GNNR. However, no effects of species richness on radial-growth were detected in the younger forest. Since I also did not find strong effects of species richness on saplings in the experimental plantation, diversity effects may evolve at a later age stage. The importance of the diversity effect may be related reversely to that of species identity in an age gradient of forest stands. The findings suggest that different mechanisms of coexistence operate simultaneously but that their relative importance may shift through the life stages of trees. During the sapling stage, species-specific differences in growth and architectural traits support niche theory. In older forest stands, no species-specific differences in growth parameters could be detected. However, I did find effects of functional diversity on horizontal canopy structure. I conclude that mechanisms of coexistence may not only change with forest stand age, but may also differ for distinct traits. The present thesis, being the first to apply the local neighbourhood approach with regard to crown architecture and branch demography within the BEF field of research, stresses the importance of this individual based approach. Although the observed forest systems are very complex, crown architectural and canopy structural variables were found to be affected by diversity. The finding that the degree of erosive power of rain could be elucidated by crown architectural variables, encourages further studies to reveal possible relations between biodiversity and other ecosystem functions or services, which might be mediated by crown architectural and canopy structural variables.
The dissertation analyzes the role of large banks in the context of financial (in)stability. Based on the underlying "too big to fail"-problem (TBTF), the three included papers investigate the reasons for the instability of banking systems on a national and international level. Already in advance, but at least since the years 2007/2008 with the escalation of the financial crisis, especially large banks are under critical supervision of regulators and the society. There exist numerous aspects that should to be taken into account when addressing TBTF which complicates the finding of a solution to the problem. In particular, the thesis investigates three major issues in this context: (1) The contribution of the size of a bank to the development of financial crises or the exposure of large banks to systematic risk and contagious spillovers. (2) The spillover effects from one banking system to another and the importance of banks' foreign asset holdings for the transmission of sovereign risk on foreign banks. (3) The impact of the degree of competition in the German banking market on the stability of the banking system.
The dissertation project focuses on empirically investigating consumers' attitudes, motivations and purchasing decisions regarding sustainable products. The focus on this micro perspective, however, does not reflect consumers' roles within the transformation towards sustainable consumption. Therefore, the present framework paper puts the included papers into a greater context and evaluates the findings on a meta-level by applying an enhanced transition management theory. The analysis underlines that consumers' limited personal capabilities are an underlying reason for unsustainable practices. Therefore, the active engagement not only of consumers, but also of companies is required if the transformation is to be successful. If companies actively support consumers in making sustainable choices, consumers can engage in sustainable consumption with only low cognitive efforts. On this basis, genuine sustainable choices are enabled. The dissertation provides practical implications by highlighting potential measures which will help to promote sustainable products from niches to mainstream. In sum, the dissertation project enhances academic understanding of consumers´ sustainable purchasing behavior and reveals the potential of integrating such insights into the management of transformations towards sustainable consumption.
Poor quality of freshwaters is a widespread problem. The concept of complexity is a particularly promising concept to analyse and address this problem, and public policy problems more generally. The main reason is the concept's strength in unifying structural features of problems within a more comprehensive structural approach to political problem-solving. So far, however, these possible benefits remained hidden given the lack of a clear understanding of complexity, ultimately hampering a systematic analysis of the implications of complexity for solutions and governance strategies. This study aims at strengthening the value of the concept of complexity for systematic comparative analyses of water-related problems and public policies in general. To achieve this goal, this work is to specify the concept of complexity as well as the implications of complexity for solutions and governance strategies, both from a theoretical and an empirical point of view. To this end, five main basic approaches are applied, referring to underlying premises, the role of an interdisciplinary approach, the European Water Framework as an empirical reference point, the integration of practical knowledge, and the focus on external validity. This dissertation provides a detailed operationalisation of complexity related to the dimensions of goals, variables, dynamics, interconnections, and informational uncertainty. It also shows that freshwater pollution-related problems in Germany differ along these five complexity dimensions. This applies to 37 types of pollution-related problems and four clusters of problems, which refer here to tame, wicked, system complexity, and uncertainty problems. This dissertation suggests that relations between complexity and policy delivery can be both positive and negative and vary along dimensions of complexity and policy delivery. Regarding the analysed freshwater pollution problems, this work also shows various effects of complexity on policy delivery, both along the 37 types of problems, and along four clusters of wicked problems. This dissertation suggests a differentiated theoretical approach to define governance for complex problem-solving, demonstrating that the role of diverse institutions, actors, and interactions differs for solutions along five key dimensions of complexity and different management strategies that are information gathering, modelling, using decision-support tools, prioritising of measures, conflict solving, deciding under uncertainty, and being adaptive and flexible.
Considering the recent success of right-wing populist candidates and parties in the United States and across Europe, there has for some years now been talk among scholars (and the wider public) about a worldwide democratic recession. The younger generations appear to be especially unsupportive of democracy’s liberal principles and more willing to express support for authoritarian alternatives. What these authors overlook, however, is that the publics of advanced industrial societies have experienced an intergenerational value shift. In fact, populations in industrial democracies have become more liberal overall, but not everyone’s mindset is changing at the same speed. It is mainly – but not exclusively – the members of the lower classes that do not keep up. While societies have generally become more liberal, there is increasing alienation between the social classes over these liberal values. Drawing on a more recent trend in social class research with a social cognitive approach, this dissertation contributes to the study of growing anti-democratic tendencies around the world by analyzing the interplay between inequality dynamics and value orientations. The focus lies on investigating the effect socio-cultural polarization (i.e., ideological polarization between social classes) has on civic culture in the mature democracies of the West. The findings suggest that it is not ideological polarization between the social classes that has the greatest negative effect on civic culture, or general civic attitudes and behavior, for that matter. It is the increasing dissent in society about whether the country’s elites are still to be trusted with making the right decisions to increase the average citizen’s quality of life. This difference in opinion manifests itself in a decline in some civic attitudes.
Since the early 2000s, ecosystem services strongly gained significance as a research topic. However, the temporal dimension of ecosystem services has not been taken into consideration, although this should be the basis for a sustainable long-term management of ecosystems and their services. Therefore, the author presents three articles in this thesis that deal with temporal aspects of ecosystem services. In two of them she also present a proposal for a framework for the classification of ecosystem services based on their temporal dynamics. In this dissertation she differentiates between two types of temporal aspects, both of which have in common that change takes place over a certain period of time. The concepts of transformation, transition and regime shift are used to describe changes in social or ecological systems as a whole, for example the transformation towards a more sustainable society. The temporal dynamics, on the other hand, relate to the temporal changes in ecosystem services themselves. The first article focuses on how the literature on ecosystem services incorporates social and ecological change. The second and third articles deal with the temporal dynamics of ecosystem services. While the second article presents a preliminary framework for categorizing the temporal dynamics of ecosystem services, the third article uses this framework to test how the temporal dynamics of ecosystem services are represented in the literature. Based on the insights from the three articles, the author concludes that most of the studies on ecosystem services only focus on one point in time. One reason for this is that most studies are conducted over a maximum of a four-year time span which does not allow to monitor dynamics over longer time spans.
The importance of a social perspective on the relationships between humans and nature has longbeen acknowledged. The field of social-ecological systems research in particular is striving toachieve a holistic understanding of human-nature relationships by balancing social andecological perspectives. Here I sought to develop a social understanding of the Saxon area inCentral Romania, by exploring aspects of human-nature relationships as seen from theperspective of local people. To this end, I employed the concepts of social-ecological systems(SES), ecosystem services (ES) and cultural landscapes to assess perceptions of locals throughempirical case studies.I first conducted a literature review to acquire an overview of a particular type of human-naturerelationship mediated by non-consumptive use and non-use values (“cultural ecosystemservices”). Second, to isolate and address the interaction from the social system to the ecologicalsystem, I investigated the different ways locals perceived the role of landscapes in SouthernTransylvania. I conceptually mapped these landscape preferences by revealing their potentialland use and management implications. Third, to approach the human-nature relationship fromthe ecological system to the social system, I studied the flow of ES to disaggregated humanbeneficiaries. Specifically, I studied which factors, beyond ecosystem processes and functions,influenced nature derived human well-being from the perspective of potential beneficiaries. Iconceptualised the mediating role of a range of contextual factors underpinning the currentdistribution of ES, with regard to the relation between ES and human well-being. Fourth, inorder to explore an example of bidirectional human-nature relationship, I studied the particularcase of human-carnivore coexistence and the suite of mechanisms shaping it.Despite building throughout this thesis a more complex and in-depth understanding of the humandimensions of the studied system, I chose four main cross-cutting themes to explain the human-nature connection in Southern Transylvania. These four themes may serve as pillars of a sociallyminded understanding, as well as potential research and policy foci. First, the values held bylocals are key for understanding the endemic human-nature relationships and should not beoverlooked in future social-ecological assessments or policy interventions. Second, the culturallandscape of Southern Transylvania is both a physical and virtual space of social-ecologicalinteraction fostering human-nature experiences and social-ecological knowledge integration.Third, the identified diversity of the social system in terms of landscape aspirations and ESbeneficiaries is expanding the range of human-nature connections, but at the same time, may infuture be a source of conflict or disconnection if not managed appropriately. Finally, small-scalefarmers, through their interactions with the land and resultant belief system, play a major role inmaintaining the human-nature relationships, but their values and lifestyle are threatened.
To improve the properties of thermochemical heat storage materials, salt mixtures were evaluated for their heat storage capacity and cycle stability as part of the innovation incubator project "Thermochemical battery" of the Leuphana university Lüneburg. Based on naturally occurring compound minerals, 16 sulfates, 18 chlorides and 5 chloride multi-mixtures, 18 bromides and 5 intermixtures between sulfates, chlorides and bromides were synthesized either from liquid solution or by dry mixing for TGA/DSC screening before continuing the heat storage evaluation with five different measurement setups at a laboratory scale. The TGA/DSC analysis served as a screening process to reduce the number of testing materials for the upscaled experiments. The evaluation process consisted of a three-cycle dehydration/hydration measurement at Tmax=100°C and Tmax=200°C. In case of the bromide samples a measurement of hydration conditions with Tmax=110°C and a water flow at e=18.68mbar, were added to the procedure to detect the maximum water uptake temperature. Also, a single dehydration to a temperature of Tmax=500°C was implemented to observe melting behavior and to easier calculate the samples’ stages of hydration from the remaining anhydrous mass. Materials which showed high energy storage density and improved cycle stability during this first evaluation were cleared for multi-cycle measurements of 10 to 25 dehydration and hydration cycles at Tmax = 100 to 120°C and the evaluations at m=20 to 100g scale. An estimate for the specific heat capacities at different temperatures of the materials which passed the initial stage was calculated from the TGA/DSC results as well. The laboratory scale measurement setup went through five stages of refining, which led to reducing the intended maximum sample mass from m=100g to m=20g. A switch from supplied liquid water to water vapor as the used reactant was also implemented in exchange for improved dehydration conditions. Introducing a vacuum pump for evaporating the water limited the influence of outside heat sources during hydration and in-situ dehydration was enabled as to not disturb the state the samples were settling in between measurements. Baseline calculation from blanc measurements with glass powder and attempts to calculate the specific heat capacity cp of the tested materials by 6 applying the Joule-Lenz-law to the measurement apparatus was another step of method development. The evaluation process of the laboratory scale tests at the final setting consisted of 1 to 5 cycle measurements of in-situ dehydration and hydrations with applied vacuum for t=30 minutes at p~30mbar. Upscaling the sample mass to m=20g allowed for a close observation of different material behaviors. Agglomeration, melting and dissolving of the m=10mg samples during the TGA/DSC analysis can be deducted from the recorded measurement curves and the state of the sample after measurement. However, at laboratory scale the visible volume changes, observed sample consistency after agglomeration and an automatic removal of molten and dissolved sample mass during the measurement allowed for a better characterization and understanding of the magnitude of the actual changes. This was done for the first time, particularly for mixed salts. Of the original number of 62 samples, 4 mixtures which passed the initial TGA/DSC screening namely {2MgCl2+ KCl}, {2MgCl2+CaCl2}, {5SrBr2+8CaCl2} and {2ZnCl2 + CaCl2} were chosen for further evaluation. The multi-cycle TGA/DSC measurements of {2MgCl2+ KCl}, {2MgCl2+CaCl2} and {5SrBr2+8CaCl2} showed an improved cycle stability for all three materials over the untreated educts. Of the four materials {2ZnCl2 + CaCl2} displayed the strongest deliquescence during hydration in the upscaled experimental setup. {2MgCl2+CaCl2} proved to be the most stable material regarding the heat storage density. The {MgCl2} content of the mixture is likely to partially or completely react to {Mg(OH)Cl} at temperatures of T>110°C, which however does not impede the heat storage density. {5SrBr2+8CaCl2} displayed a low melting point in hydrated state, causing a fast material loss. This makes it an undesirable storage material. A lower heating rate may still help to avoid an early melting. The {2MgCl2+KCl} mixture was the most temperature stable of the mixtures showing no melting or dissolving behavior. A reaction of the {MgCl2} component of the mixture to {Mg(OH)Cl} was not observed within the applied temperature range of T=25 to 200°C.
The Macro Polity Revisited
(2021)
This dissertation includes six articles tied together by the overarching question of how changes in public opinion, economics and public policy co-evolve in mature democracies, with a focus on redistributive (in seven European democracies) and secessionist preferences (in Catalonia and Scotland). The theoretical inspiration derives from three sources: 1. the Macro Polity model by Erikson, MacKuen/Stimson, 2. the Thermostatic Responsiveness model by Soroka and Wlezien, and 3. the literature on representation gap models by Gilens, Elsaesser and others. The Macro Polity and Thermostatic Responsiveness models come with an optimistic undertone, emphasizing that public policies adapt to public opinion, producing the policy-opinion congruence that defines responsive government. The Representation Gap model, by contrast, is more pessimistic in highlighting that the preferences of low-income groups are generally worse represented in public policies than the preferences of middle-income and especially high-income groups. While there is evidence in favor of these models for the majoritarian political systems in the US, Canada and the UK, less is known about the validity of these models in proportional democracies of continental Europe. The contributions in this dissertation address this research gap by integrating the three models and combining nearly 500 surveys to study the evolution of European public opinion at the national and subnational level.
This thesis analyses how European merger control law is applied to the energy sector and to which extent its application may facilitate the liberalisation of the electricity, natural gas and petroleum industries so that only these concentrations will be cleared that honour the principles of the liberalisation directives. After having discussed the complex micro- and macro-economic considerations which accompany any concentration of business activities, this thesis discusses the merger control regime of the European Community (EC) so as to establish whether the merger control under either Art. 66 Treaty Establishing the European Coal and Steal Community (ECSCT), the case law under Art. 101 and 102 Treaty on the functioning of the European Union (TFEU) and (Art. 81 and Art. 82 Treaty Establishing the European Economic Community (ECT), as it was introduced by the Commission and reviewed by the CJEU, the original Merger Regulation (MR1989) or the amended Merger Regulation of 1997 (MR1997) or the amended Merger Regulation of 2004 (MR2004) facilitate the liberalisation of European electricity and gas markets. Said liberalisation was introduced by the Internal Electricity Market Directive (IEMD), the Hydrocarbons Licensing Directive and the Internal Gas Market Directive (IGMD). The paper focuses on the contestable idea that regulatory amendments - especially the introduction of third party access by means of the directives - only form a first necessary condition for attaining economic alterations whereas pro-active conduct of the marketers is the second and decisive one in order to increase the competitive performance of the European energy supply industries. The analysis is supported by a second argument which relates closely to the ambivalent nature of concentrations: A concentration may be used to increase the process of market opening and the expansion into new markets by pooling of scarce resources. It may also be used as a retro -active means so as to create national champions, increase barriers to market entry of new competitors, enable cross-subsidisation so as to expand dominant positions on heretofore competitive up- and downstream markets.
Whereas the extant literature discusses what Sustainability-Oriented Innovations (SOIs) are and why firms develop them, little is known about how they are developed. To enable firms to innovate for sustainability, it is essential to know more about the processes underlying SOI development, which are considered as very difficult, with many firms failing. Drawing on several academic papers and relying on qualitative research methods, the thesis uses the Fireworks model to examine how innovation processes unfold at established small and medium-sized enterprises (SMEs). The main contribution of the thesis is to advance the Fireworks model to the context of SOIs unfolding at SMEs. The findings reveal that SOIs unfold in an emergent, somewhat chaotic way, that duration and outcome are uncertain, that the overall journey is composed of multiple intertwined innovation paths, of which several will likely lead to setbacks. To manage this complex process, the thesis suggests to set four management foci: (1) to create a dedicated organizational unit for exploration, (2) to create conditions allowing intelligent learning for efficient exploration, (3) to carry out in-depth investigation of the related technological innovation systems, and (4) to plan carefully the re-integration of the innovation into the core business for commercialization.
This thesis deals with the influence of sustainability communication on the purchase decision of sustainable tourism products involving German specialist tour operators. Sustainability communication is a challenge, because sustainable tourism is an abstract and vague concept which consumers find it difficult to grasp and about which they are sceptical. The service characteristics of tourism products complicate the decision making stage, which is a high-involvement situation of uncertainty to which sustainable product attributes add complexity. As an introduction, an interdisciplinary theory discussion reveals knowledge gaps in terms of the value-belief-norm theory and the elaboration likelihood model (ELM). The first article, which is the first systematic literature review on the topic, reveals that there is a limited theoretical understanding of sustainability communication, a lack of practical understanding of how to design sustainability messages, and an inadequate set of methodologies for its research. It identifies knowledge gaps concerning: the holistic approach to sustainability communication; its role in the attitude-behaviour gap; an interdisciplinary theoretical understanding focusing on belief-based social psychological theories and theories of persuasion; qualitative methods; and experimental design. The second article investigates the role of sustainability communication in the attitude-behaviour gap, employing the value-belief-norm theory to explain how information is processed by special interest customers. Interview findings show that ineffective sustainability communication is the reason for the gap and that customers unintentionally booked sustainably. The study identifies eight groups of beliefs which explain the processing of sustainability attributes. Sustainability information is effective when it is value-congruent, that is, when customers perceive they can make a difference, they begin to ascribe a responsibility to themselves. The third article investigates how to design an effective sustainability message in tour operator advertising. Drawing on the ELM, the study shows that appeal type does not significantly influence persuasion but the topic presented is important. Cultural sustainability is the sustainability topic that is most persuasive for cultural tourists, while consumer prior knowledge and issue-involvement with the topic promote successful information processing.
The timber shortage led to large scale afforestations on previously agriculturally used land in Central Europe during the 19th and 20th century. Widespread afforestation programs created recent forest ecosystems (i.e. young forest systems in terms of their development history). Despite the positive effect of increasing the forest area of Central Europe, the ecological effects of these land-use changes on forest ecosystems remain poorly understood. In order to increase the understanding of ecosystem processes in forests, an assessment of conceivable shifts in ecosystem functions caused by former land-use changes and forest management is required. By analysing aboveground growth rates of European beech (Fagus sylvatica L.) in response to environmental change drivers, such as climate extremes and nitrogen (N) deposition, the presented thesis aims to assess the role of land-use and management legacies in modulating present responses to drivers of environmental change. To this end, annual radial growth rates of individual trees were measured in mature beech stands. The investigated stands differed either in their land-use history (i.e. ancient forest sites versus recent forests) or their forest management history (i.e. managed forest sites versus short-term and long-term unmanaged forest sites). Measurements of radial growth rates were complemented by analyses of the fine root systems, soil chemical properties and crown projection areas to gain insights into the mechanisms underlying alterations in tree growth. Within the projects of the presented thesis, shifts in the climate-growth relationships driven by land-use and management legacies were analysed. In addition, land-use legacy mediated differences in the climate-nitrogen-growth relationships were assessed. The key findings are: (I) Soil legacy driven alterations in the fine root systems cause a higher sensitivity of radial increment rates to water deficits in summer for trees growing on recent forest sites than for trees growing on ancient forest sites. (II) Management legacies (in terms of tree release) enhance the sensitivity of beech’s radial growth to water deficits in spring through changes in crown sizes. (III) Interacting effects of spring water deficits and co-occurring high deposition of reactive N compounds lead to stronger radial growth declines in trees growing in ancient forests. This is likely caused by resource allocation processes towards seed production, which is, in turn, mirrored by decreasing radial growth rates. In this context, high N deposition likely boosts mass fructification in beech trees. Overall, it has been demonstrated that the ecological continuity plays a crucial role in modulating both climate sensitivity and the growth response to interacting effects of water deficits and nitrogen deposition in beech trees. The presented thesis identified a trade-off between the climate sensitivity and maximised growth rates within beech trees, depending on forest history. The results show that the growth of beech in ancient, unmanaged beech forests is less sensitive to water deficits than in recent and managed beech forests. Additionally, interacting effects of spring water deficits and N deposition likely increase the reproductive effort of beech trees, particularly in ancient forests. Thus, the results of this thesis once again underpin the uniqueness of ancient, unmanaged beech forests, whose importance for the conservation of biodiversity has been widely acknowledged. In summary, the presented thesis highlights the need to consider the "ecological memory" of forest ecosystems when predicting responses to current and future environmental changes.
Personally meaningful tourist experiences foster subjective mental wellbeing. Modern, human-centred technologies such as gamified technology have been recognised as a promising means to support tourists in their co-creation of meaningful tourist experiences. However, a deeper understanding and conceptualisation of tourists' engagement with gamified technologies in the tourist experience has remained absent so far. This study draws on positive psychology as the guiding theoretical lens to conceptualise and explore tourists' underlying motives for engaging with gamified technology, as well as the gratifications thereof for the tourist experience. In doing so, this thesis identifies how tourists generate meaning through interacting with gamified technology in the tourist experience, thereby fostering the co-creation of meaningful tourist experiences and contributing to subjective mental wellbeing. Being among the first studies to link the concepts of positive psychology, gamified technology, and tourist experiences, the results of this thesis provide rich findings on the underlying motives for tourists to engage with gamified technology during vacation, as well as the gratifications of gamified technology for the creation of meaning in the tourist experience. Using the theoretical lens of positive psychology and achievement motivation theory as the main theoretical underpinning, this study is positioned at the intersection of social psychology, human-computer interaction, and tourism as the field of application. Conceptually, this thesis provides an in-depth understanding of tourists’ engagement with gamified technology, including the socio-psychological motivators for engagement and the outcomes thereof for the tourist experience.
Despite the great progress that has been made in the prophylaxis of oral diseases over the past decades, dental caries and periodontal diseases remain major challenges in the field of dentistry. Biofilm formation on dental hard tissues is strongly associated with the etiology of these oral diseases. Therefore, the process of bioadhesion and biofilm formation on tooth surfaces is of particular interest for dental research. The first stage of bioadhesion on dental surfaces is the formation of the pellicle layer. This mainly acellular film, composed largely of adsorbed proteins, glycoproteins, and lipids, is distinguished from the microbial biofilm (plaque). As the interface between teeth and the oral environment, the pellicle plays a key role in the maintenance of oral health and is of great physiological and pathophysiological importance. On the one hand, the pellicle shows protective properties for the underlying dental hard tissues. On the other hand, it also serves as the basis for dental plaque and therefore, for the development of oral diseases such as caries and periodontitis. Hydrophobic interactions, which are governed by lipophilic substances, are of high relevance for bacterial adherence. Therefore, pellicle lipids, which are a significant constituent of this biological structure, are an interesting target for dental research, as they could modulate oral surfaces, influence microbial interactions, and potentially impede bacterial adherence. Compared to the extensive work on the pellicle´s ultrastructure and protein/amino acid composition, little attention has been given to its lipid profile. Knowledge of the lipid composition of the pellicle may provide insight into several oral pathological states, including caries, dental erosion, and periodontal disease processes and could contribute to novel approaches in preventive dentistry. The principle aim of this thesis was the comprehensive characterization of the fatty acid (FA) profile of the in situ formed pellicle layer. This includes the influence of pellicle maturation on the FA profile as well as intra- and interindividual differences. Furthermore, investigations on the effect of rinses with edible oils on the pellicle´s FA composition were a focus of this work. For these purposes, an analytical method based on a combination of innovative specimen generation and convenient sample preparation with sensitive mass spectrometric analysis was successfully developed and comprehensively validated within this thesis. Pellicle samples were formed in situ on bovine enamel slabs mounted on individual upper jaw splints. After a comprehensive sample preparation, gas chromatography coupled with electron impact ionization mass spectrometry (GC-EI/MS) was used in order to characterize qualitatively and quantitatively a wide range of FA (C12-C24). The individual FA profiles of pellicle and saliva samples collected from ten research participants were investigated. The relative FA profiles of the pellicle samples gained from the different subjects were very similar, whereas the amount of FAs showed significant interindividual variability. Compared to the pellicle´s characteristic FA profile, higher proportions of unsaturated FAs were detected in the saliva samples, highlighting that FAs available in saliva are not adsorbed equivalently to the pellicle layer. This, in turn, shows that pellicle formation is a highly selective process that does not correlate directly with salivary composition. Additionally, pellicle samples collected after 3, 30, 60, 120, and 240 min of intraoral exposure were analyzed. It could be shown that pellicle maturation has only a minor impact on the FA composition. However, the FA content increased substantially with increasing oral exposure time. Modifying the pellicle´s lipid composition by using edible oils as a mouthwash could alter the physicochemical characteristics of the pellicle and strengthen its protective properties by delaying bacterial adhesion. Therefore, the impact of rinses with safflower oil on the pellicle´s FA composition was determined. The application of rinses with safflower oil resulted in an accumulation of its specific FAs in the pellicle, thus representing a possibility for modifying the pellicle´s lipid profile. The present work is the first to apply a validated method that combines in situ pellicle formation, sample preparation, and the comprehensive determination of FAs via a sensitive analytical method. The results provide valuable information regarding the pellicle´s FA composition which closes an existing knowledge gap in pellicle research. A broader knowledge of the lipid composition of the pellicle contributes to the understanding of oral bioadhesion processes and may help facilitate novel approaches in preventive dentistry.