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Die Verringerung des Material- und Ressourcenverbrauchs ist eine wesentliche Herausforderung nachhaltiger Entwicklung. Bislang standen und stehen politische Maßnahmen zur Energieeffizienz im Vordergrund. Maßnahmen zur Verbesserung der Materialeffizienz gewinnen jedoch verstärkt an Bedeutung. Der Erfolg oder Misserfolg politischer Instrumente im Umwelt- und Klimaschutzbereich wird maßgeblich davon abhängen, ob die Instrumente die Fähigkeit besitzen, eine Entkoppelung von Lebensqualität und Ressourcenverbrauch zu erzeugen. Insbesondere im Rahmen der Ökodesign-Richtlinie, aber auch anderer Instrumente der Europäischen Union, sind Ansatzpunkte zur politischen Gestaltung einer ressourcenleichten Langfristökonomie angelegt. Die Dissertation wird schwerpunktmäßig die Governance-Instrumente im Produktbereich der Europäischen Union behandeln. Die Dissertation folgt der Theorie, dass die Produkte der Industriegesellschaft einzeln mehr oder weniger harmlos, in ihrer Menge jedoch die Quelle fast aller Umweltprobleme sind. Zur Erstellung der Dissertation sieht das spezifische Methodendesign die Anwendung eines Kriterienkatalogs zur Bewertung der Steuerungsinstrumente für Langfristökonomie im Produktbereich vor. Darüber hinaus werden die Hauptakteure in Form von Interviews befragt.
Die Abhandlung gibt einen ersten Überblick über Entstehung, theoretische Hintergründe und Auswirkungen der finanziellen Bürgerbeteiligung im Rahmen der New Public Governance (NPG) in den deutschen Kommunen. Grundsätzlich kann festgestellt werden, dass die Kommunen in Zukunft vor großen sozialen, ökonomischen und ökologischen Herausforderungen stehen, die für ihre nachhaltige Entwicklung von entscheidender Bedeutung sind. Insbesondere der enge finanzielle Handlungsspielraum vieler Städte und Gemeinden in Kombination mit den Auswirkungen der demographischen Entwicklung und Urbanisierungsprozessen in einzelnen Regionen in Deutschland, bedingt neue Konzepte und innovative Herangehensweisen für die öffentliche Aufgabenerfüllung. Ein Bestandteil dieser neuen Form der Aufgabenerfüllung stellen finanzielle Bürgerbeteiligungsmodelle dar. Diese Modelle vereinen öffentliche, For-Profit- und Non-Profit-Elemente in ihren Strukturen und werden in dem Beitrag näher erläutert. Abschließend wird auf das besondere Verhältnis der Sparkassen und Kreditgenossenschaften in Verbindung mit den finanziellen Bürgerbeteiligungen eingegangen.
Fragestellung und Kontext: Inwieweit lässt Strafe im Rahmen einer pädagogischen Intervention in der öffentlichen Erziehung heute erziehungswissenschaftlich und rechtlich Legitimieren? Im Verlauf der 70er und 90er-Jahre verschwand der Begriff ´Strafe´ weitgehend aus der erziehungswissenschaftlichen Diskussion. Rückblickend lässt sich nachvollziehen, dass u.a. Impulse aus der ´Stigmatisierungsdebatte´ wie auch die Erkenntnisse, die unter dem Stichwort ´Schwarze Pädagogik´ Eingang in die Debatte fanden. Parallel etablierten sich engagierte Initiativen, antiautoritär mit Kindern umzugehen, gar, ´antipädagogisch´ ganz auf Erziehung zu verzichten. Formeln wie ´Therapie statt Strafe´ initiierten bis in das Strafrecht hinein den Willen, Begriff und Praxis des Strafens zu überwinden. Der bisherigen Debatte, im historischen Zusammenhang sind zwei Aspekte bemerkenswert: Erstens: Das, was objektiv als Strafe gewollt war oder subjektiv so empfunden wurde, hat nicht aufgehört zu existieren. Das heißt: Auch wenn der Begriff Strafe (Sanktion, Konsequenz, sachlogische Folge) tabuisiert und aus dem Fachvokabular gestrichen wurde, wird im Erziehungsalltag weiterhin gestraft, wie die Studie von Günder, Reidegeld, Müller-Schlotmann (2009), treffend nachweisen. Zweitens: Es hat bisher keine systematische Auseinandersetzung in den Erziehungswissenschaften mit dem Phänomen ´Strafe´ gegeben. Erst im Jahr 2013 (ZJJ Heft 3/2013 und 01/2014) gab es einen Versuch aus aktueller Perspektive ´Erziehung´ und ´Strafen´ mehrperspektivisch zu diskutieren. In diese Lücke (Theorie und Handlungslogik) stößt die vorliegende Untersuchung. Auf der Grundlage eines historischen Überblicks wird ein Ansatz entwickelt, mit der Intention und der Fragestellung, wie das Strafproblem in der Erziehung, zumal der öffentlichen, fachlich beantwortet (gelöst) werden könnte. In der interdisziplinär angelegten Untersuchung, ausgehend von der Beobachtung, das Strafe ein fester Bestandteil der Erziehung sei. Dieser Logik selbstverständlichen, ja fraglosen Verhaltens wird in der vorliegenden Erörterung nachgegangen. Zu klären ist die Bedeutung sowie der Einfluss der ´Alltagstheorien´ auf mögliche punitive Tendenzen im Erziehungsalltag, welche durch die oben erwähnte Studie aus dem 2009 zweifelsfrei begründet werden. Diesen Ergebnissen soll mit Hilfe wissenschaftlicher Theorien entgegengetreten werden. Aus dem dafür in Betracht kommenden Bezugswissen nimmt die Erziehungswissenschaft und Psychologie einen zentralen Stellenwert ein. Des Weiteren wird die Bedeutung des Rechts: Grundgesetz, Familienrecht sowie das SGB VIII betont. Zu klären ist, welche Sanktionen noch vom gegenwärtigen Recht und dem Stand der Fachdiskussion in der Pädagogik gedeckt seien. Das aus dem gesellschaftspolitischem Erziehungsauftrag und den Hilfen zur Erziehung (§ 27 SGB VIII) ablesbar normative Erziehungsverständnis, sei durch einen hohen Anspruch an Funktionalität, Disziplin und soziale Anpassung geprägt. Die Handhabung des ´Strafproblems in der Pädagogik´ sei, trotz der Reformen in den 1980er und 1990er Jahren nach wie vor wesentlich von Alltagstheorien geprägt (Luedtke 2009). Design: Die vorliegende Erörterung ist eine interdisziplinär angelegte, literaturgestützte Untersuchung, die sich ausschließlich auf vorhandenes Wissen/Theorien bezieht.
Die Arbeit kombiniert innovative Geschäftsmodelle und Effectuation im Kontext von Entrepreneurship vor dem Hintergrund der Resource-based Theory. Im Rahmenbeitrag werden wesentliche Begriffe erarbeitet und die Arbeit eingeordnet. Dabei wird erstmals die Relevanz der Geschäftsmodell-Entwicklung und der Effectuation mithilfe der Resourcebased Theory erklärt. Im Beitrag 1 werden die angesprochenen Konzepte in einer explorativen Studie mit erfahrenen Entrepreneuren aus dem deutschen Gesundheitswesen thematisiert und die Existenz von Effectuation-Strukturen bei der Geschäftsmodell- Entwicklung getestet. Dabei werden unternehmerische Pilotprojekte als neue Strukturen entdeckt und konzeptualisiert. In Beitrag 2 werden die gewonnen Erkenntnisse in zwei Tools zur Geschäftsmodell-Entwicklung übersetzt und in Beitrag 3 im Rahmen einer case study am Beispiel eines Gründungsprojektes angewendet sowie um eine Struktur zur Bewertung von innovativen Geschäftsmodellen ergänzt.
Das Nationale Bildungspanel (NEPS) untersucht wie sich Kompetenzen, unter anderem die mathematische Kompetenz, über die Lebensspanne entwickeln, wie diese die Bildungskarriere beeinflussen und inwiefern die Kompetenzentwicklung von Lerngelegenheiten abhängig ist. Erhoben werden die Daten mit Hilfe eines Multi-Kohorten-Sequenz-Designs, wobei in allen Bildungsetappen verschiedene Instrumente zum Einsatz kommen (Blossfeld & von Maurice, 2011). Um diese Daten sinnvoll nutzen zu können, müssen sie valide Testwertinterpretationen zulassen. Diese Arbeit leistet einen Beitrag zur Validierung der National Educational Panel Study (NEPS)-Testwertinterpretationen, indem der Mathematiktest für die neunte Klassenstufe (K9) umfassend analysiert wurde. Dabei wurde geprüft, ob die Unterschiede in der beobachteten Testleistung die Unterschiede in der mathematischen Fähigkeit wiedergeben, wie diese im NEPS-Rahmenkonzept definiert sind. Für die Validierung wurde eine Argumentationskette für den NEPS-K9-Mathematiktest, angelehnt an den Argument Based Approach von Kane (2013), entwickelt. Für die Auswertung wurde der scientific use file der NEPS-Haupterhebung 2010 verwendet. Die Stichprobe dieser Studie bestand aus 15239 Schülerinnen und Schülern der neunten Jahrgangsstufe. Für die Untersuchung der Zusammenhänge des NEPS-Mathematiktests mit anderen Messungen mathematischer und nicht mathematischer Kompetenz wurde zusätzlich eine Validierungsstudie durchgeführt. Zur Erfassung der mathematischen und naturwissenschaftlichen Kompetenz wurden in dieser Studie neben den NEPS-Testinstrumenten Aufgaben aus dem Programme for International Student Assessment (PISA) und dem IQB-Ländervergleich (LV) eingesetzt. Zusätzlich wurde ein kognitiver Fähigkeitstest verwendet. Insgesamt wurden 80 Schulen mit 1965 Schülerinnen und Schülern der neunten Klassenstufe für die Teilnahme an der Studie ausgewählt. Zur Vorbereitung des Validitätsargumentes wurden Literaturreviews bereits veröffentlichter Analysen und ein Expertenreview zu den Merkmalen der NEPS-Mathematikaufgaben durchgeführt. Des Weiteren wurden die Kompetenzdaten mit Hilfe von Modellen der Item Response Theorie skaliert und dimensional analysiert. Außerdem wurden korrelative Zusammenhänge mit Kriterien mathematischer Kompetenz berechnet. Die Ergebnisse liefern viele Hinweise bezüglich der Validität der Testwertinterpretationen, jedoch wurden auch einige Einschränkungen und weiterer Forschungsbedarf aufgezeigt. Beispielsweise ließ sich die Annahme der Eindimensionalität des NEPS-Mathematiktests nicht bestätigen. Außerdem wären weitere Analysen bezüglich des Zusammenhanges mit geeigneten Kriterien für die Zieldomäne Mathematische Kompetenz für eine Erweiterung der Testwertinterpretationen wünschenswert. Die gefundenen Evidenzen stützen jedoch die Testwertinterpretation ´die Unterschiede in der Rangfolge der beobachteten Testleistung deuten auf Unterschiede in der Rangfolge der Ausprägung der mathematischen Kompetenz, wie diese im Rahmenkonzept definiert wird´. So konnten für die Zieldomäne relevante Teilkompetenzen in den NEPS-Aufgaben identifiziert werden, waren die Bewertungskriterien angemessen und wurden erwartungsgemäße Zusammenhänge mit den Mathematiktests aus dem LV und PISA gefunden. Auf diese Weise konnte eine vollständige Argumentationskette für den NEPS-K9-Mathematiktest entwickelt, sowie Empfehlungen für die Stärkung und Erweiterung der Testwertinterpretation empfohlen werden. Der Argument Based Approach von Kane erwies sich dabei als hilfreicher Ansatz, in welchem die Vorgaben der Standards for Educational and Psychological Testing (American Educational Research Association, American Psychological Association, National Council on Measurement in Education, 2014) berücksichtigt werden konnten.
Die Webbasierte Rehabilitationsnachsorge (W-RENA) unterstützt Patienten psychosomatischer Rehabilitation zum einen in der Vorbereitung auf den Transfer von in der Klinik erworbenen Strategien in den poststationären Alltag. Den Kern der Intervention bildet zum anderen die 3-monatige Begleitung über das Internet bei diesem Prozess des Anwendungslernens im Alltag. Damit bietet die W-RENA zugleich auch eine Überbrückung der Wartezeit auf einen ambulanten Therapieplatz, denen Patienten psychosomatischer Rehabilitation häufig ausgesetzt sind. Diese Arbeit fokussiert die Rolle von Selbststeuerungskompetenzen im Rahmen dieses Lerntransfers und prüft, ob die W-RENA hier eine förderliche Funktion einnimmt. Die Messung von Selbststeuerungskompetenzen erfolgte zu 4 Erhebungszeitpunkten mit dem SSI-K3 (Kuhl, 2004). Eindeutige Effekte konnten für die Subskalen Selbstregulation und Selbstzugang nachgewiesen werden. Dass Patienten der W-RENA stationär erlernte Strategien im poststationären Alltag auch 12 Monate nach Entlassung signifikant häufiger anwenden als Patienten der Kontrollgruppe konnte mit dem KFB-EQUA (Schmidt, 2003) nachgewiesen werden.
This dissertation deals with the investigation of success factors in the field of entrepreneurship, especially entrepreneurship training, from a psychological perspective. In particular, I argue that the identification of certain psychological aspects helps to better understand the underlying mechanisms for successful entrepreneurship trainings and thus, enables successful entrepreneurship. In the second chapter I theoretically examined planning as a fundamental action an entrepreneur hast to undertake in order to succeed. Scholars are in disagreement about the question if planning is crucial for the entrepreneurship. Thus, I provide a comprehensive overview of the advantages and disadvantages of planning in entrepreneurship from a psychological perspective. I explain negative aspects (e.g., lack of knowledge, difficulty to predict the future, and inflexibility) as well as positive aspects (e.g., legitimating, action-regulatory, and learning function) about planning in entrepreneurship. Furthermore, I develop a theoretical model that combines both the positive and negative aspects of planning in entrepreneurship. With this theoretical model, I integrate different types of planning (e.g., formal and informal plans) as well as positive and negative functions of planning (e.g., learning or stickiness, inflexibility) to provide a first approximation for a theory of entrepreneurial planning. In the third chapter, to focus on the field of entrepreneurial trainings, I empirically examine the under-researched field of the relation between trainer and trainee. I use the transformational leadership theory (Bass, 1985) and a theory of learning outcome (Kraiger, Ford, & Salas, 1993), to hypothesize that the trainers´ charisma has a positive effect on the trainees´ entrepreneurial self-efficacy. Additionally, I search for possible moderators for the hypothesized trainer-trainee-relationship in an explorative manner, using insight from different research areas (e.g., pedagogy, philosophy). To test the hypotheses, I conducted a 12-week entrepreneurship training by which I had 12 measurement waves across four classes with 161 students and 12 trainers, which lead to 919 observations. In the fourth chapter, to broaden the perspective on the mechanisms within entrepreneurship training, which lead to a successful outcome, I empirically examined the short- and long-term effects of entrepreneurship training on life satisfaction. To do so, I developed a theoretical model based on theories of life satisfaction, that explain the underlying mechanisms of the short- and long-term effects of the entrepreneurship training on life satisfaction. With this model I hypothesize, that entrepreneurship training has a positive short- effect on life satisfaction, which is mediated through entrepreneurial self-efficacy. I furthermore hypothesize, that the long-term effect of the entrepreneurship training is mediated through self-employment. The short term-effect acts like a boost and vanishes over time, whereas the long-term effect holds in the long run. To test these hypotheses, I conducted entrepreneurship training as part of a randomized controlled field experiment with five measurement waves over a total period of 2.5 years. Using discontinuous growth modeling to take into account the temporality of our hypothesized effects we statistically analyzed the 1,092 observations from 312 students. Chapter 5 concludes this dissertation with general discussion of the three chapters.
Despite the great progress that has been made in the prophylaxis of oral diseases over the past decades, dental caries and periodontal diseases remain major challenges in the field of dentistry. Biofilm formation on dental hard tissues is strongly associated with the etiology of these oral diseases. Therefore, the process of bioadhesion and biofilm formation on tooth surfaces is of particular interest for dental research. The first stage of bioadhesion on dental surfaces is the formation of the pellicle layer. This mainly acellular film, composed largely of adsorbed proteins, glycoproteins, and lipids, is distinguished from the microbial biofilm (plaque). As the interface between teeth and the oral environment, the pellicle plays a key role in the maintenance of oral health and is of great physiological and pathophysiological importance. On the one hand, the pellicle shows protective properties for the underlying dental hard tissues. On the other hand, it also serves as the basis for dental plaque and therefore, for the development of oral diseases such as caries and periodontitis. Hydrophobic interactions, which are governed by lipophilic substances, are of high relevance for bacterial adherence. Therefore, pellicle lipids, which are a significant constituent of this biological structure, are an interesting target for dental research, as they could modulate oral surfaces, influence microbial interactions, and potentially impede bacterial adherence. Compared to the extensive work on the pellicle´s ultrastructure and protein/amino acid composition, little attention has been given to its lipid profile. Knowledge of the lipid composition of the pellicle may provide insight into several oral pathological states, including caries, dental erosion, and periodontal disease processes and could contribute to novel approaches in preventive dentistry. The principle aim of this thesis was the comprehensive characterization of the fatty acid (FA) profile of the in situ formed pellicle layer. This includes the influence of pellicle maturation on the FA profile as well as intra- and interindividual differences. Furthermore, investigations on the effect of rinses with edible oils on the pellicle´s FA composition were a focus of this work. For these purposes, an analytical method based on a combination of innovative specimen generation and convenient sample preparation with sensitive mass spectrometric analysis was successfully developed and comprehensively validated within this thesis. Pellicle samples were formed in situ on bovine enamel slabs mounted on individual upper jaw splints. After a comprehensive sample preparation, gas chromatography coupled with electron impact ionization mass spectrometry (GC-EI/MS) was used in order to characterize qualitatively and quantitatively a wide range of FA (C12-C24). The individual FA profiles of pellicle and saliva samples collected from ten research participants were investigated. The relative FA profiles of the pellicle samples gained from the different subjects were very similar, whereas the amount of FAs showed significant interindividual variability. Compared to the pellicle´s characteristic FA profile, higher proportions of unsaturated FAs were detected in the saliva samples, highlighting that FAs available in saliva are not adsorbed equivalently to the pellicle layer. This, in turn, shows that pellicle formation is a highly selective process that does not correlate directly with salivary composition. Additionally, pellicle samples collected after 3, 30, 60, 120, and 240 min of intraoral exposure were analyzed. It could be shown that pellicle maturation has only a minor impact on the FA composition. However, the FA content increased substantially with increasing oral exposure time. Modifying the pellicle´s lipid composition by using edible oils as a mouthwash could alter the physicochemical characteristics of the pellicle and strengthen its protective properties by delaying bacterial adhesion. Therefore, the impact of rinses with safflower oil on the pellicle´s FA composition was determined. The application of rinses with safflower oil resulted in an accumulation of its specific FAs in the pellicle, thus representing a possibility for modifying the pellicle´s lipid profile. The present work is the first to apply a validated method that combines in situ pellicle formation, sample preparation, and the comprehensive determination of FAs via a sensitive analytical method. The results provide valuable information regarding the pellicle´s FA composition which closes an existing knowledge gap in pellicle research. A broader knowledge of the lipid composition of the pellicle contributes to the understanding of oral bioadhesion processes and may help facilitate novel approaches in preventive dentistry.
Prospective students´ choice of their university is a topic of rising relevance worldwide. As competition on the higher education market and the resultant fight for students increases, universities need to deal with questions of how, when, and why young people decide where to study. This knowledge forms the basis for developing adequate and effective communication strategies enabling university marketers to recruit the best and most suitable students for their institutions. Despite extensive research on these questions, there still are fundamental gaps like the nonobservance of sense making activities, the neglected role of emotions and higher education policies, the suboptimal choice of research methods as well as problematic theoretical assumptions previous research is based upon. In this dissertation, I address all of these gaps in three complementary articles. In the first paper, I compare American with German research on university choice by focusing on the three aspects of theoretical approaches applied in previous studies, choice factors, and information sources prospective students use. On the basis of this literature review, I identify major research gaps with a focus on, but not limited to, the German context. In the second article, by using the Zaltman Metaphor Elicitation Technique (ZMET), I identify mental models of prospective students that represent their sense making activities. Through this, I get a profound understanding of which rational and especially emotional issues are relevant for the students when they try to make sense of the marketing messages they are confronted with during their university choice process. In the third paper, I challenge the theoretical approaches previous research is based upon by identifying two very different types of decision-makers with their respective choice strategies and logics. Overall, this dissertation contributes to a much more detailed understanding of prospective students´ university choices by identifying their sense-making activities and choice styles, highlighting the role of emotions and context factors, and refining the theoretical foundations university choice research is based upon.
Traditional farming landscapes have been created in coexistence of rural dwellers and local ecosystems over long time spans, and can be considered tightly coupled ´social-ecological systems´ (SES). Since these landscapes typically embody exceptionally high levels of biological diversity and multiple socio-cultural values, their protection is critical from a sustainability perspective. Due to the pressures of globalization and social change, however, rural livelihoods and farmland biodiversity are at risk. While the focus of research is often on the Southern hemisphere, there are traditional farming landscapes in the former socialist countries of Central and Eastern Europe (CEE) which are equally affected by rapid change, and thus deserve particular attention. Since the institutional breakdown of socialism in 1989, the CEE states have not only been confronted with an unprecedented socio-economic and environmental transition. Their integration into the multi-level governance regime of the European Union (EU) further resulted in the transformation of decision-making structures and competition within the EU common market. In light of the profound changes traditional farming landscapes of Central and Eastern Europe are confronted with, they serve as a valuable source of learning about the institutional design necessary to harmonize socio-economic development and biodiversity conservation within regional social-ecological systems worldwide. This thesis is the result of an in-depth analysis of one traditional farming landscape of Central and Eastern Europe, namely Southern Transylvania (Romania). Based on empirical research involving diverse stakeholder groups, this thesis assessed the impact of EU policy on the area, the institutional features characterizing local-level governance in Southern Transylvania, and the barriers and bridges towards sustainable rural development. This thesis finds that while rural dwellers are highly dependent on smallholder farming and local ecosystems for their livelihoods, Southern Transylvania is currently confronted with a range of structural development barriers. These are likely to be exacerbated by a governance system consisting of historically grounded ´elite social networks´, and by EU policies which often do not fit rural realities. The findings of this dissertation underline that entrenched informal institutions, political will, and historical legacies play a critical role for the governance of traditional social-ecological systems since these ´social system features´ do not only mediate how external policies act on the local level. They may further restrict local adaptive and innovation capacities which, however, are critical for the transformation towards sustainable development. This thesis further finds that there are no blueprint solutions for the design of rural development strategies. Instead, (supra-) national policies should take better account of local socio-economic and cultural particularities.
Die Herausforderung produzierender Unternehmen, wachsenden Kundenanforderungen in globalisierten Märkten gerecht zu werden, führt zu einer Abkehr von partiellen Optimierungsmaßnahmen und althergebrachten Unternehmensstrukturen. Als zentrales Element zur Steigerung der Wettbewerbsfähigkeit haben sich in der betrieblichen Praxis Ganzheitliche Produktionssysteme etabliert. Zentrale Herausforderung für das eigenständige Einführen und Anwenden Ganzheitlicher Produktionssysteme besteht darin, den Ansatz umfassend zu überblicken und eine geeignete Konzeption für das eigene Unternehmen sicherzustellen. Um Ganzheitliche Produktionssysteme als Optimierungsansatz für Lohn- und Auftragsfertigungsbetriebe zugänglich zu machen und einen Beitrag zur Wettbewerbssicherung dieser Branche zu leisten, verfolgt diese Dissertation das Ziel, ein Modell zur umfassenden Konfiguration Ganzheitlicher Produktionssysteme für kleine und mittlere Lohn- und Auftragsfertigungsbetriebe im Bereich der Herstellung von Metallerzeugnissen zu entwickeln.
In the discourse on pharmaceuticals in the environment, hardly any attention has been paid to anticancer drugs. Because of their none-selective modes of action, that is, because they affect both cancerous and healthy cells, these drugs are regarded as potentially carcinogenic, genotoxic, mutagenic, and teratogenic substances. It is, however, not known how and to what extent these substances affect organisms and the environment in the long run. For this reason, this dissertation evaluated, addressing several endpoints and using organisms from different trophic levels and in silico predictions, the fate (bio- and photo degradation) and ecotoxicity of these substances. Four anticancer drugs (cyclophosphamide (CP), 5-fluorouracil (5-FU), methotrexate (MTX), and imatinib (IM) were selected. None of these anticancer compounds can be classified as ´readily biodegradable,´ a classification that indicates that biodegradation will only play a minor role in the elimination of these compounds and that they cannot be removed by the conventional processes used in sewage treatment plants and will most likely remain in the water cycle. Despite the high degrees of mineralization achieved in advanced (photo)oxidation processes, it was not possible to fully mineralize the compounds, a result that indicates that transformation products were created during these reactions. The ecotoxicity assays performed with V. fischeri indicated that 5-FU was, of all the substances tested, likely to be the most toxic (very toxic), followed by MTX (toxic) and IM (toxic/harmful), whereas CP was nontoxic. MTX presented the highest phytoxicity activity in the Lactuca sativa assay, followed by 5-FU, IM, and CP. The results of the tests performed with A. cepa showed cytotoxic (5-FU, MTX, and CP) and genotoxic effects (5-FU, CP, and IM) and mutagenic activity (5-FU, MTX, CP, and IM) of the compounds. Photo transformation products (PTPs) of CP, MTX, and 5-FU were nontoxic towards V. fischeri. However, some PTPs formed during the photodegradation of 5-FU led to positive mutagenic and genotoxic alerts in several in silico models. Not one of the compounds examined in this dissertation is likely to be fully eliminated from the water cycle by (natural) photolysis and/or advanced oxidation. Moreover, some of the treatments resulted in the formation of stable intermediates that were even less biodegradable than parent compounds. This finding shows that it is not enough to focus on primary elimination because TPs are not necessarily better biodegradable than their respective parent compounds. As indicated by the genotoxic and mutagenic positive alerts presented by different in silico models, the PTPs observed here are likely to require, despite their lower toxicity in comparison to the parent compounds, screening after treatments.
Biodiversity loss could jeopardize ecosystem functioning. Yet, the evidences that support this demonstration have been mostly obtained in aquatic and grassland ecosystems. Howbiodiversity affects ecosystem functioning still remain largely unanswered in forests, particularly in subtropical broad-leaved evergreen forests (EBLF). Tree productivity, among a wealth of forest ecosystem functioning, is of particular interest because it reflects the carbon sink capacity and wood productivity. Biodiversity-productivity relationships have been usually investigated at community level. However, tree-tree interactions occur at small scale. Thus, local neighborhood approach may allow a better understanding of tree-tree interactions and their contributions to the effects of biodiversity on tree productivity / growth rates. This thesis aims to analyze the effects of biodiversity and the abiotic environmental factors on the tree growth rates using both local neighborhood and community-based approaches. Furthermore, tree growth rates vary among different tree species. Functional traits have been related to the species-specific growth rates to understand the effects of species identity. Therefore, I also evaluated the crown- and leaf traits to predict the interspecific difference in growth rates. For a better understanding of the mechanisms that underline the relationships of biodiversity and tree growth rates, data of high solution and along time series is required to scrutinize the tree-tree interactions. Thereupon, I evaluated the applicability of terrestrial laser scanning (TLS) in assessing the tree dendrometrics. This thesis was conducted in the Biodiversity Ecosystem Functioning (BEF)–China experiment, which is located in a mountainous subtropical region in southeast China. A total of 40 native broad-leaved tree species were planted. In the first study, I used the local neighborhood approach to analyze how local abiotic conditions (i.e. topographic and edaphic conditions) and local neighborhood (i.e. species diversity and competition by neighborhood) affect the annual growth rates of 6723 individual trees. The second study used the community approach to partition the effects of environmental factors (i.e. topographic and edaphic), functional diversity according to Rao’s quadratic entropy (FDQ) and community weight mean (CWM) of 41 functional traits on community tree growth rates. The main question of the third study was how the species-specific growth rates are related to five crown- and 12 leaf traits.
In the fourth study, I investigated 438 tree individuals for the congruence between the conventional direct field measurements and TLS measurements. It was found that tree growth rates were strongly influenced by the local topographic and edaphic conditions but not affected by the diversity of local neighborhood. In contrast, results obtained by using the community-based approach showed that FDQ and CWMs of various leaf traits rather than abiotic environmental factors had significant impact on the community means of growth rates. Tree-tree interactions already occur in early life stages of trees, which were evidenced by the significant effect of competition by local neighborhood. These findings imply that the effects of abiotic environmental factors may be more evident at local scale and biodiversity effects may vary at different spatial scales. The species-specific growth rates were found to be related to specific leaf traits but not to crown traits and were best explained by both types of traits in combination. This finding supports the niche theory and provides the evidence for using functional diversity to examine the BEF relationships. The TLS-retrieved total tree height, stem diameter at 5 cm above ground, and length and height of the longest branch were highly congruent with those obtained from direct measurements. It indicates that TLS is a promising tool for high resolution, non-destructive analyses of tree structures in young tree plantations. Being one of very few studies to incorporate the individual tree scale in examining the biodiversity-productivity relationships within the BEF researches, this thesis stresses the importance of using individual-tree based approach, functional diversity and TLS to find the evidences of explanatory mechanisms of the observed biodiversity and ecosystem functioning (e.g. tree growth rates) relationships. Biodiversity effects may evolve along the successional stages. Therefore, incorporating the interaction between biodiversity and time in analyzing BEF relationship is also encouraged.
Agricultural production of smallholder farmers in Myanmar is facing soil fertility degradation and in consequence, crop yields decline due to the imbalances of nutrient supply. In most cases, all above ground biomass is removed from the fields after harvesting the crops and during land preparation for the next crop. Higher temperatures also stimulate the higher mineralisation rates and released mineral nutrients are lost from fallow lands before sowing the next crops. Regarding the addition of mineral fertilizers, except for cash crops, farmers are reluctant to apply fertilizers for the crops that are sown for household’s self-sufficiency. In the Dry Zone, irrigated agriculture is available in recent years and farmers could overcome water scarcity through irrigation. With the availability of irrigation water, farmers could prolong the cropping period, nevertheless crop yields are decreasing year by year. In recent decades, research findings are indicating the benefits of biochar application for soil fertility improvement and food security. Smallholder farmers can produce biochar from agricultural by-products such as pigeon pea stems, cotton stems and rice husks by using biochar stoves. Large-scale production is possible by producing both biochar and thermal energy simultaneously, such as getting rice husk biochar and producing thermal energy by burning rice husks. By those means, environmental pollution due to the smokes from stubble burnings and the health hazards from smokes arise from kitchens can also be reduced. Present research was conducted to test the effects of the application of biochars produced from different crop residues together with NPK fertilizers on crop yields and soil properties in the rice-chickpea-cotton cropping system of the Central Dry Zone area of Myanmar during 2012 and 2013 cropping seasons at Shwe Daung Farm, Mandalay Division, Myanmar. Effects of biochar applications in combination with NPK fertilizers were compared with NPK fertilizer (without biochar) application and the control (without biochar and NPK fertilizers). Biochars used in the experiments were produced from three kinds of locally available raw materials (rice husk, rice straw and, pigeon pea stem) at temperature above 550°C by using a kiln made from a 200-Liter diesel barrel. Field experiments were conducted on sandy loam soil in the Central Dry Zone of Myanmar. After harvesting rice in 2012, chickpea was sown without application of both organic and inorganic fertilizers. After harvesting chickpea in 2013, cotton was sown on the same experimental plots. Treatments were rice husk biochar (Rh) 20 Mg ha-1 + NPK fertilizers; rice straw biochar (Rs) 20 Mg ha-1 + NPK fertilizers; pigeon pea stem biochar (Ps) 20 Mg ha-1 + NPK fertilizers; rice husk biochar and farmyard manure mixture (Rh biochar + FYM) 10 Mg ha-1 + NPK fertilizers; NPK fertilizers (without biochar); and the control (without fertilizer and biochar). Biochar weights represented fresh biochar weights. Equal rate of NPK fertilizers were applied in all treatments. However, fertilizer rates were different with respect to the crops. In rice experiment, 100:50:50 kg ha-1 rate of Urea (N): Triple Super Phosphate (P): Muriate of potash (K) was applied. In cotton experiment, 100:30:117 kg ha-1 rate of Urea (N): Triple Super Phosphate (P): Muriate of potash (K) was applied. Crop growth data, yield component data and yield data of each treatment were recorded. Soil samples from topsoil (0-0.2 m) were taken before starting the experiments, after harvesting rice and cotton, respectively, and analysed. A biogeochemical model, denitrification decomposition (DNDC) model, was used to estimate soil organic carbon storage and greenhouse gas emissions during crop growing seasons and to quantify the long-term impact of biochar applications on rice, chickpea and cotton yields.The results from soil analyses indicated that although initial soil pH was at 8.0 and pH values of biochars ranged between 8.0 and 10.0 soil pH after two years of biochar application did not increase. pH values were below 8.0. That value was lower than initial soil pH. That could be due to the effect of the change of cropping system from upland to lowland rice cultivation and the effects of biochar additions to the alkaline sandy loamy soil of the experimental site. Although total exchangeable cation value was not significantly different among the treatments, compositions of major cations were significantly different among the treatments. Exchangeable potassium increased in Rs biochar + NPK applied soils. Exchangeable sodium increased in control, and conventional NPK fertilizer applied soils. Reduction of soil bulk density from 1.8 g cm-3 to 1.6-1.7 g cm-3 occurred in biochar treatments compared to control and conventional NPK fertilizer application treatments. Positive changes of total carbon and total nitrogen of soils were found in biochar treatments compared to control and conventional NPK fertilizer application. Application of pigeon pea stem biochar + NPK fertilizers showed the highest crop growth and the highest yield in rice. The highest chickpea yield was obtained from the plot that applied rice husk biochar + NPK fertilizers. Cotton crop growth and yield was the highest in rice husk biochar and farmyard manure mixture + NPK fertilizer application. The lowest crop growth and yield was obtained from the control in cotton. The results of this study suggested that biochars from different biomass materials had different effects on soil properties and crop yields under different growing conditions and cultivated crops. Although the applied biochars had a high pH, soil pH did not increase after biochar applications. The growth and yield of tested crops were higher than that of the control and conventional NPK fertilizer application. Rice husk biochar and farmyard manure mixture + NPK fertilizer application can be assumed as a suitable soil amendment application under upland crop cultivation. Pigeon pea stems biochar + NPK fertilizers should be applied in rice cultivation. Rice husk biochar + NPK fertilizers and rice husk biochar-farmyard manure mixture + NPK fertilizers showed as the appropriate biochar soil amendments for the study area compared to rice straw biochar + NPK fertilizers and pigeon pea stem biochar + NPK fertilizers. Application of these biochars increased total exchangeable cations, reduced bulk density, increased organic carbon, regulated soil pH and, can easily be accessed by smallholder farmers by promising crop yields for sustainable agricultural production. Rice straw biochar + NPK fertilizers and pigeon pea stem biochar + NPK fertilizers also showed positive influences on soil fertility and crop growth. However, extensive application of those biochars might require large-scale productions and distributions. To obtain the detail information regarding the impact of biochar application on the agro-ecosystem and surrounding atmosphere, further research activities may need to carry out under different agricultural production conditions. When model fitness was tested, it was found that DNDC model was fit for the simulation of crop yields and soil organic carbon under the conditions of the experimental site. Simulation of soil organic carbon dynamics and crop yields for 30 years and 50 years after the addition of biochars in combination with NPK fertilizers showed that such applications could maintain the crop yields at the same level up to 50 years. That could maintain soil organic carbon at a level higher than conventional NPK fertilizer application. Regarding the simulation of GHGs emissions, the model simulated nitrous oxide emission close to actual emissions of agricultural soils of Myanmar. Simulated CH4 emissions from control and conventional NPK fertilizer application variant were consistent with the well-known emissions of Myanmar rice fields. To confirm the accuracy of simulated CH4 emissions from biochar applied soils, it may need field investigations and validations of model results. Simulated effects of rice husk-, rice straw- and pigeon pea stem fresh biomass applications and that of rice husk-, rice straw- and pigeon pea stem biochar applications on rice, chickpea, cotton yields and soil organic carbon (SOC) were compared. Objective of this simulation was to compare the effects of fresh biomass-applications and the application of biochars produced from the same biomass on crop yields and SOC by using DNDC model. The results showed that simulated rice yields of rice husk biochar and rice straw biochar applications were 33% and 31%, respectively, higher than that of pigeon pea green manure applications. However, simulated rice yield from pigeon pea stem biochar application was 4% higher than that of iv pigeon pea stem green manure application. Simulated chickpea yield from pigeon pea green manure treatment was the highest among all of biochar and biomass applications. Simulated cotton yields obtained from fresh biomass applications were lower than that of biochar applications. In estimating the future yields, all crop yields from rice husk and rice straw biomass applications were lower than that of rice husk and rice straw biochar applications in the initial year of simulation. However, in the following years, the yields remained at the same level up to the end of simulated years. In pigeon pea stem green manure application, crop yields were higher than the other treatments since the initial year up to the end of simulated years. Simulated SOC was lower in fresh biomass applications compared to biochar applications.
Der hochwassergebundene Sedimenteintrag ist Motor der Bodenbildung in Auen. Der mit dem Sedimenteintrag einhergehende Schadstofftransport in die flussbegleitenden Auen ist Ursache für die Akkumulation von Schadstoffen in den aquatischen und semiterretrischen Systemen. Er wirkt in weiten Teilen der Elbauen nicht nur einschränkend auf die landwirtschaftliche Nutzung des Grünlandes sondern beeinträchtigt daneben auch weitere Schutzgüter, wie z. B. Habitate und Lebensgemeinschaften. Diese Arbeit hatte das Ziel, die Steuergrößen des Sediment- und Schadstoffeintrags anhand von langjährig erhobenen Messdaten zu untersuchen und gleichzeitig die zeitliche und räumliche Verbreitung ausgewählter Schadstoffe als Baustein eines belastungsangepassten Auenmanagements aufzuklären. Dafür wurden eigene Daten über Hochflutsedimente und Böden ebenso ausgewertet wie Daten anderer Autoren. Außerdem lag ein Schwerpunkt der Arbeit in der kombinierten Auswertung von Zeitreihen der Sedimentbelastung von Gewässern und von Auenböden, die eine Grundlage für das Verständnis des elbespezifischen Belastungsmosaiks von Böden mit Schwermetallen und Dioxinen/Furanen darstellt. Zunächst erfolgte eine detaillierte Recherche und Analyse der retentionsfördernden Eigenschaften der Elbauen. Es wurden abschnittsspezifische Flächengrößen, Landnutzungsunterschiede und Flächenbetroffenheiten bei unterschiedlichen Hochwasserzuständen herausgearbeitet. Mit Hilfe der darauf aufbauenden, datenbasierten Analysen über ereignisbezogene Sedimenteinträge in die Elbauen konnten wesentliche Steuergrößen des Sedimenteintrags identifiziert werden. Die Distanz der Standorte zur Elbe ist die wesentliche Kenngröße, sodass die größten Sedimenteinträge in Flussnähe stattfinden. Darüber hinaus ist die Höhe des Sedimenteintrags abflussabhängig. Auf dieser Grundlage wurde ein Ansatz zur Berechnung des großräumigen Sedimenteintrags entwickelt, mit dessen Hilfe die Retentionsfunktion der Auen im Abfluss- und Stofftransportgeschehen der Elbe abgeschätzt werden konnte. Die Sedimentretention der Elbauen hatte im Betrachtungszeitraum zwischen 2003 und 2008 einen Anteil von 7 bis 30 % an den Jahresschwebstofffrachten in Hitzacker. Die Analysen von verschiedenen Zeitreihen der Sediment- und Bodenbelastungen mit Schwermetallen, Arsen sowie Dioxinen/Furanen verdeutlichte, dass die Stoffgruppen ganz unterschiedliche Belastungsentwicklungen durchlaufen haben. Der Schwerpunkt der Dioxinkontamination in Sedimenten und Böden trat in den 1950er bis 1960er Jahren auf, während Metalle im Allgemeinen erst später Belastungsmaxima zeigten. Allerdings konnte mit dem Pb/Zn-Verhältnis ein Metallmuster identifiziert werden, mit dessen Hilfe auch in Oberböden auf der Basis von Metalldaten auf Dioxinbelastungen geschlossen werden konnte. Darüber hinaus wurde unter Kenntnis der spezifischen Belastungshistorien mittels Kategorisierung der Standorteigenschaften Höhenlage, Distanz, Bioturbation und Sedimenteintrag ein Erklärungsschema zur Vorhersage von räumlichen Schadstoffmustern für ausgewählte Metalle und Dioxine/Furane entwickelt. Sowohl die Untersuchungen zum Sedimentationsgeschehen als auch zur Aufklärung des Belastungsmosaiks in den Elbauen ließen Ableitungen von Maßnahmenvorschlägen zur Förderung der Sedimentationsdynamik, des Hochwasserschutzes, zur schadstoffspezifischen Verbesserung der Bodenbelastung als auch zur belastungsangepassten Landnutzung zu.
Fire plays an important role in the earth system by influencing ecosystems and climate, but climate in turn also influences fire. The system became more complex when humans started using fire as a tool. Understanding the interaction between humans, fire and climate is the major aim of paleofire research. Understanding changes in these three aspects in the past will help predicting future climate, fire and human interactions. The use of lake sediment cores as natural archives for reconstructing past fire activity by counting charcoal particles is well established. This present dissertation is dedicated to the evaluation and application of specific organic molecular markers for biomass burning: levoglucosan, mannosan and galactosan were used as proxies for reconstructing past fire activity in lake sediments thorough the entire Holocene. First, a new analytical method was developed using high-performance anion exchange chromatography combined with mass spectrometry to separate and detect these three monosaccharide anhydrides in lake sediments. The suitability of this analytical method was proven by comparing the levoglucosan, mannosan and galactosan results in selected lake sediment samples from Lake Kirkpatrick, New Zealand and by correlating the results with macroscopic charcoal. Furthermore, the method was successfully applied to a lake sediment core from Lake Petén Itzá, Guatemala to reconstruct regional Holocene fire history. The analyses of levoglucosan were combined with fecal sterols to reconstruct late Holocene human fire interactions at Lake Trasimeno, Italy, demonstrating low fire activity during the Roman period. This combination of studies proves that these molecular markers are valid fire proxies in sediments from multiple locations around the globe. Comparison of levoglucosan, mannosan and galactosan concentrations with macroscopic charcoal trends in Lake Kirkpatrick and Lake Petén Itzá, suggests that the molecular markers represent more regional fire history and low temperature fires in contrast to macroscopic charcoal, which is a local fire proxy. In addition, vegetation changes (Lake Kirkpatrick and Lake Petén Itzá) and charcoal morphotypes (Lake Petén Itzá) were compared to the levoglucosan/mannosan and levoglucosan/(mannosan+galactosan) ratios suggesting that these ratios may be a suitable tool to track burned fuel. Biodegradation tests demonstrate the potential degradation of levoglucosan, mannosan and galactosan if dissolved in water, but findings in ancient sediment samples suggest that particle-bound levoglucosan, mannosan and galactosan can be buried in sediments over millennial time scales. Although uncertainties still exist, the results of this research suggests that organic molecular markers are a suitable regional fire proxy and isomer ratios may help understand changes in burned vegetation.
The future of forests is closely linked to climate change and energy transition because the preconditions for forest management are changed through climate and energy policies (Beland Lindahl and Westholm 2012). Forest management has multiple objectives, and different stakeholders have competing interests in forests. A strong dichotomy between environmental and economic interests has characterized forest policy and most conflicts about forests in the past (Winkel and Sotirow 2011). Climate change and energy transition modify this established conflict line because new conflicts related to climate mitigation, climate adaptation, and renewable energies have blurred the clear opposition between environmental and economic interest (Mautz 2010). In the context of the new challenges of climate change and energy transition, the need for effective, efficient and legitimate forest governance is gaining a new importance. Based on 86 qualitative interviews about forest conflicts and forest governance in five qualitative case studies, theoretical approaches focusing on multi-level and multi-scale governance are merged with the field of environmental and natural resource conflict research in this thesis. Forest conflicts and their governance are a multi-level and multi-scale issue. However, not so much is known about how collective and individual state and non-state actors act in complex governance systems and how they perceive governance systems. In order to contribute to the understanding of these knowledge gaps, this thesis tests the applicability of three theoretical perspectives on multiple scales and levels of decision-making (multi-level governance, polycentricity, politics of scale) to fruitfully study forest conflicts. Furthermore, the thesis provides empirical insights about forest conflicts in the face of energy transition and climate change. Based on the theoretical and empirical findings, this thesis provides practical recommendations to policy makers and practitioners on how to improve governance in forestry and the management of other natural resources. For example, this thesis shows the importance of considering different actor constellations in participatory processes at different governance levels, and that not every actor will react the same way to a certain method of decision-making. Furthermore, this thesis illustrates how trust building measures, such as enhanced communication between stakeholders, transparency in decision-making and forest education can reduce the risk of destructive conflict escalation. This thesis also demonstrates that energy transition and the discussion about climate change are sources of new conflicts, can change old conflicts, and add new, additional levels to forest governance. Thus, climate change and energy transition cause further fragmentation of forest governance and make forest governance more multi-level, create additional venue-shopping opportunities, and bring new actors into forest governance, causing new power constellations in the policy field. Forest governance is in a reconfiguration process which can be conceptualized as shift towards multi-level governance. Level choice and the relation of state and non-state actors in decision-making are important aspects of governance, thus the theoretical approach has yielded valuable insights in forest conflicts and the importance of scale construction in conflict discourses can be illustrated. Different levels are associated with different functions, strengths, and weaknesses of stakeholders; the perceptions of appropriate scale choice are often based on frames. The empirical findings have shown that level choice is often a normative and/or cultural decision, often no objective ´best´ decision-making level exists. Some actors consider different competing, overlapping, and nested decision-making levels to be an opportunity for interest realization; others feel helpless and overwhelmed in complex, multi-level systems. Different re-scaling strategies (up-scaling, down-scaling, fit re-scaling) are applied by actors to realize their interests. Non-state actors have an important function in linking processes from different levels. However, multi-level governance and related concepts have their limits for the explanation of forest conflict processes because some important factors cannot be captured with this approach. For example, social-psychological factors and conflict frames are important for the understanding of conflict development and governance and at a local level individual action and the relations between individuals crucially set the preconditions for the governance of conflicts.