Open Access

With this dissertation, I present a human resources approach to entrepreneurship through selection and training of small-business owners in developing countries. Entrepreneurship is an important source of employment, innovation, and general economic prosperity (Autio, 2005; Walter et al., 2005; Reynolds et al., 2005; Kuratko, 2003). In developing countries, job creation through business ownership is especially important because job opportunities are limited (Walter et al., 2005; Mead & Liedholm, 1998). Strengthening the small business sector is one of the best ways to reduce poverty and increase economic growth (Birch, 1987). Thus, this dissertation adds to the scientific literature in taking a human resources approach to entrepreneurship: selecting and training entrepreneurs. Selection has widely been researched on in various scientific fields like human resource management, industrial-, work-, and organizational psychology, but only partly focusing on selection of entrepreneurs. Regarding training, there exists a fair amount of studies that focus on entrepreneurship education, but a lot of them suffer from substantial heterogeneity and methodological flaws (Glaub & Frese (2011); McKenzie & Woodruff (2013)). The dissertation combines the ideas of using selection procedures for entrepreneurs with the idea of teaching entrepreneurial skills.

The computational analysis and the optimization of transport and mixing processes in fluid flows are of ongoing scientific interest. Transfer operator methods are powerful tools for the study of these processes in dynamical systems. The focus in this context has been mostly on closed dynamical systems and the main applications have been geophysical flows. In this thesis, we consider transport and mixing in closed flow systems and in open flow systems that mimic technical mixing devices. Via transfer operator methods, we study the coherent behavior in closed example systems including a turbulent Rayleigh-Bénard convection flow and consider the finite-time mixing of two fluids. We extend the transfer operator framework to specific open flows. In particular, we study time-periodic open flow systems with constant inflow and outflow of fluid particles and consider several example systems. In this case, the transfer operator is represented by a transition matrix of a time-homogeneous absorbing Markov chain restricted to finite transient states. The chaotic saddle and its stable and unstable manifolds organize the transport processes in open systems. We extract these structures directly from leading eigenvectors of the transition matrix. For a constant source of two fluids in different colors, the mass distribution in the mixer and its outlet region converges to an invariant mixing pattern. In parameter studies, we quantify the degree of mixing of the resulting patterns by several mixing measures. More recently, network-based methods that construct graphs on trajectories of fluid particles have been developed to study coherent behavior in fluid flow. We use a method based on diffusion maps to extract organizing structures in open example systems directly from trajectories of fluid particles and extend this method to describe the mixing of two types of fluids.

Against the backdrop of aging populations, labor shortages, and a longer healthy life expectancy, there has recently been considerable discussion of the great potential that post-retirement activities hold for individuals, organizations, and society alike. This dissertation consists of three empirical papers investigating the life reality of active retirees in Germany. In addition, framework conditions and motivational structures that need to be considered in creating jobs for this group of workers are examined. The first paper identifies the prerequisites for productivity after retirement age and describes the changed nature of modern-day retirement. Current levels of post-retirement work are quantified by reference to German Microcensus data. The data show that adults continue to engage in paid employment beyond the applicable retirement age, with self-employment and unpaid work in family businesses making up the greatest share of post-retirement activities. Qualitative data collected from 146 active retirees (mean age = 67 years, standard deviation = 4) showed that the changes entailed in retirement include more flexible structures in everyday life. Content analysis revealed that reasons for taking up post-retirement activities were the desire to help, pass on knowledge, or remain active; personal development and contact with others; and a desire for appreciation and recognition. In addition, flexible working hours and the freedom to make decisions are evidently important aspects that need to be taken into account in creating employment activities for silver workers. The second paper extends the findings of the first paper by investigating the differences that respondents experienced between their former career job and their post-retirement activities, drawing on an additional quantitative sample of active retirees (N = 618, mean age = 69 years, standard deviation = 4). Factor analysis revealed differences in four areas: First, differences were identified in person-related variables, such as work ability. Second, differences were perceived in the scope of the job itself with regard to workers’ tasks, skills, or job function. Third, the perceived freedom of time allocation and flexibility in job practice distinguished between the silver job and the former career job. Fourth, differences were noted in perceived responsibility and in the significance of the activity. The third paper further examined how relevant personal motivational goals (achievement, appreciation, autonomy, contact, and generativity) as well as corresponding occupational characteristics of the silver job were related to life and work satisfaction in the quantitative sample (N = 661, mean age = 69 years, standard deviation = 4). Hierarchical regression analyses showed that the motivational goals of achievement, appreciation, autonomy, contact, and generativity significantly predicted life satisfaction, whereas only generativity predicted work satisfaction. With respect to the occupational characteristics, none of the situational predictors influenced life satisfaction, but opportunities to fulfill one’s achievement goals, to pass on knowledge, and to experience appreciation and autonomy predicted work satisfaction. The results suggest that post-retirement workers seem to differentiate between perceived life satisfaction and work satisfaction as two independent constructs. In conclusion, key motives for taking up post-retirement activities were generativity (the wish to help and pass on knowledge), but also personal development, appreciation, autonomy, and contact. The findings indicate that organizations should introduce flexible working hours, and offer silver workers advisory and freelance work. Providing freedom to make decisions and ensuring due appreciation of the contribution made by silver workers will lead to a fruitful interplay of silver workers and organizations. Future research should build on these findings by applying longitudinal designs and drawing on samples of retirees with more diverse educational and financial backgrounds. The papers of this dissertation echo the call for a new, more positive way of looking at the capacities of active retirees.

In this dissertation, advanced nonlinear control strategies and nonlinear minimum-variance observation are combined, in order to improve the estimation and/or tracking quality within control and fault detection tasks, for several types of systems from the fields of electromobility and conventional drivetrain technology that have some potential for sustainability or performance improvements. The application-specific innovations in terms of nonlinear Kalman filter methods are: * Improved state of charge estimation for Lithium-ion battery cells, powered by a novel self-adaptive EKF that uses a high-order polynomial curve fit as a decomposition of the uncertain nonlinear output equation with intentionally redundant bases, and with a reduced number of polynomial parameters that are adapted online by the EKF itself. * Online estimation of the time delay between two periodic signals of roughly the same shape that have pronounced uncorrelated noise, based on a fractional-order approximation of the transcendent transfer function of the time delay which is used as a model in a novel kind of EKF. * Using two (E)KFs (one for the linear subsystem and one for the nonlinear subsystem of a new kind of multi-stage piezo-hydraulic actuator) in a cascaded loop structure in order to reduce the computation load of the estimation, by appropriate 'interfacing' between the two observers (using one shared system model equation, among other aspects). The innovations in terms of nonlinear control methods are powered by observation, as well: * Sliding mode velocity control of a DC drive that is subject to nonlinear friction and unknown load torques, enhanced by an equivalent control law, and with a new intelligent switching gain adaptation scheme (for reduced control chattering and, thus, less energy consumption and actuator wear), which is powered by Taylor-linearized model predictive control, which in turn requires observer-based disturbance compensation (by a KF with a double-integrator disturbance model) for model-matching purposes in order to function correctly. * Direct speed control of permanent-magnet three-phase synchronous motors that have a high power-to-volume ratio, based on sliding mode control in a rotating d,q coordinate system, with a new equivalent control method that exploits both system inputs and with a secondary sliding surface to ensure compliance with the current-trajectory of maximum efficiency for the required torque, and which works without measurement of the rotor angle (thanks to a new kind of EKF that estimates all states in the stationary α,β coordinate system, as well as the disturbance/load torque and its derivative). In all instances, improvements (compared to methods existing in the literature) in terms of control and estimation performance have been achieved and confirmed using simulation studies or real experiments.

Halogenated flame retardants (HFRs) have been applied since the 1960s in various industrial and consumer products to protect humans as well as private and public possessions. In the past decade polybrominated diphenyl ethers (PBDEs), formerly the major applied HFRs were widely restricted and adopted as Persistent Organic Pollutants (POPs) in the Stockholm Convention due to their adverse effects on humans and the environment as well as their ubiquitous occurrence in the global environment. Besides PBDEs, various alternative HFRs have been applied for decades as well, or were recently developed to replace PBDEs. However, their potential adverse properties, environmental distribution and fate are largely unknown. Therefore, this thesis addresses the global occurrence, distribution and transport of alternative HFRs versus PBDEs in the marine atmosphere and seawater toward the Polar Regions in order to examine their longrange atmospheric transport (LRAT) potential. This thesis presents the first data on alternative HFRs in the atmosphere of the marine environment and the Polar Regions. Alternative brominated flame retardants (BFRs), Dechlorane compounds and PBDEs were investigated in high-volume air and seawater samples taken along several sampling transects in the Atlantic Ocean, Pacific Ocean and Indian Ocean toward the Polar Regions of the Arctic and Antarctic. In addition, three sampling cruises were conducted in the German Bight, North Sea. Several alternative HFRs were detected in the global marine atmosphere and seawater with hexabromobenzene (HBB), pentabromotoluene (PBT), pentabromobenzene (PBBz), 2,3- dibromopropyl-2,4,6-tribromophenyl ether (DPTE) and Dechlorane Plus (DP) being the predominant compounds which were observed in concentrations similar or even higher than PBDEs. Total atmospheric concentrations ranged from <1 pg m-3 over the open oceans up to 42 pg m-3 over the East Indian Archipelago. Seawater concentrations ranged from <1 pg L-1 in open ocean seawater up to 21 pg L-1 in coastal regions, while estuarine concentrations reached up to 6800 pg L-1. Overall, the comparison revealed that alternative HFRs dominate versus PBDEs in air and seawater, both in coastal regions as well as the Polar Regions, showing a shift from PBDEs toward alternative HFR in the marine atmosphere and seawater. The distribution in the global atmosphere was strongly influenced by the proximity to potential source regions and the pathway of the sampled air masses. Highest concentrations were observed in continentally influenced air masses, while low background concentrations occurred during sampling of oceanic remote air masses. In general, Western Europe, East and Southeast Asia but also Africa were identified as source regions for the marine environment, especially for alternative HFRs as well as BDE-209. In contrast, relatively low peak concentrations of the PBDE congeners of the Penta- and OctaBDE mixtures under continental influence were observed, indicating limited emissions of legacy PBDEs. The dry air-seawater gas exchange estimation showed that the atmosphere is a source for seawater resulting in net deposition into the global oceans after atmospheric emissions and transport, both in coastal regions as well as in the open oceans. Besides atmospheric depositions, riverine discharge was shown to act as source for coastal environments. The investigation of sampling transects toward the Polar Regions revealed that several alternative HFRs – in particular HBB, PBT, DPTE, PBBz and DP – undergo LRAT toward the Polar Regions in an extent similar to PBDEs and, therefore, meet the LRAT criterion of POPs under the Stockholm Convention. DP was found to undergo LRAT attached to airborne particles whereby stereoselective LRAT differences were shown for the two DP stereoisomers. With respect to LRAT, the results of this thesis therefore imply that alternative HFRs – in particular HBB, PBT, DPTE and DP – aren’t suitable replacements for PBDEs, but chemicals of emerging global environmental concern and possible future POPs.