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This dissertation includes an introduction and five empirical papers focusing on the educational and career decision-making process of individuals in Germany. The five papers embrace different determinants of educational and career decisions including school performance, social background, leisure activities as well as professional expectations, and contribute to the existing literature in this research area. Chapter 2 of this dissertation (written jointly with Christian Pfeifer) begins by analysing the nexus between students’ time allocation and school performance in terms of grades and satisfaction with their own performance in mathematics, the German language and a first foreign language, as well as overall achievement. While previous studies have primarily focused on isolated activities, this chapter looks at the heterogeneity of three important extracurricular activities: student jobs, sports and participation in music. Moreover, the heterogeneity of each activity is addressed by accounting for different types of the particular activity and differences in the number of years the activity has been pursued. For this purpose, data from the German SOEP, as a representative panel survey of private households and people in Germany, in particular cross-sectional survey data of 3388 students who are about 17 years old and enrolled in a German secondary school, were used. The main findings are that having a job as a student is negatively correlated with school performance, whereas participation in sports and music is positively correlated. However, the results reveal heterogeneity in each activity, especially with respect to intensity. Chapter 3 addresses the concrete post-school decision of school students, in particular whether to study or to enter the German VET system. It focuses on individual risk preferences and the social background of individuals and how these determinants affect the ultimate decision to enrol in university or to start an apprenticeship given the same level of qualification. For the empirical approach data from the German SOEP were used, in particular information on individuals’ educational decisions between 2007 and 2013. The results indicate that (i) individual risk preferences do not have an overall effect on the real transition; (ii) privileged individuals are more likely to take up higher education; and (iii) compared to highly educated parents, parents without an academic background are less likely to guide their children into tertiary education, regardless of how much they support their children with their school work. Chapter 4 deals with the reconsideration of educational decisions in terms of early contract cancellations in VET (Vocational Education and Training). In particular, the effects of a second job on the intention to cancel a VET contract early are analysed for apprentices in Germany. To date, the literature in this research area mainly focuses on income as a determinant of early contract cancellation in VET, but is lacking in investigations of the consequences of low income during an apprenticeship, such as the need for a second job. For the empirical approach the representative German firm-level study ‘BIBB Survey Vocational Training from the Trainee’s Point of View 2008’, conducted by the Federal Institute for Vocational Education and Training (BIBB), is used. The survey contains 5901 apprentices that were interviewed during their second year of apprenticeship (205 schools, 340 classes, and 15 common occupations). Furthermore, it includes the design, procedures, basic conditions, and quality criteria of apprenticeships. The applied probit regressions show a higher intention to quit if apprentices require a secondary job to cover their living costs. In Chapter 5, new data on 191 apprentices from a vocational school, located in a northern German federal state, are used to validate the empirical results of Chapter 4. This chapter presents new insights into secondary-job-related burdens during apprenticeship. Due to limitations in the data, the applied empirical approach in Chapter 4 lacks to analyse how holding multiple jobs increases the intention to leave an apprenticeship early. Therefore, Chapter 5 includes the investigations of burdens related to the second job. The results indicate a lower intention to quit the apprenticeship if an apprentice holds a second job to cover living costs. However, secondary jobs are linked to lower quality of training, which, on the other hand, increases the intention to leave the apprenticeship early. Furthermore, the probability of secondary-job-related burdens increases with the number of working hours. Chapter 6 concludes the thesis by investigating subjective determinants of early contract cancellations in VET. It examines ten questions on what apprentices want to achieve and how unfulfilled expectations affect the intention to leave the apprenticeship early. To date, research on early contract cancellation in VET has concentrated on objective determinants, such as income, schooling level, age, gender, or migration background. Hence, the findings of this investigation contributes to the existing research on early contract cancellation. The questions considered include information on the performance, personal development, career development and prospects or position in society and their meaning to apprentices. For the research approach, the ‘BIBB Survey Vocational Training from the Trainee’s Point of View 2008’ is considered again. The probit and ordered probit regressions applied show significant effects of job characteristics that represent job security. The expectation of being retained after an apprenticeship and the encouragement to consistently train further decrease the intention to leave the apprenticeship early. Furthermore, women appear to be more affected by job security signals than men, but they also sort more often into occupations with lower retention probabilities. Consequently, this result may be an indication of occupational segregation rather than a sign of differences between sexes.

The significance of selecting suitable talent A company’s success is significantly influenced by the professionalism and quality of decision-making, especially selecting decisions to hire suitable talent. The term “talent” can be taken to mean as someone who has talent (talent as the sum of one’s abilities) and someone who is a talent. Leadership talent makes a difference in organizational success, has the potential to succeed as a leader, and thus will hold corresponding pivotal positions. In this book, we focus on the selection and acquisition of leadership talent, since such talent is more difficult to find in the market and, at the same time, more challenging to select. Selecting these talented individuals is one of the most critical components of effective organizations. Hardly any other corporate decision has such significant effects on corporate success as talent selection. Recruiting and personnel selection are also the first steps in promoting capability building and creating successful teams. For example, Warren Buffet, renowned for his investing prowess, says, “I have only two jobs. One is to attract and keep outstanding managers to run our various operations”. This highlights the need for an effective and efficient personnel selection process and to improve the diagnostic performance of such procedures. In addition, the increasing diversity of applicants, global competitiveness, and the lack of qualified personnel in specific labor and job markets also increase the importance of high-quality personnel selection processes.

The world wide population growth and the increasing water scarcity endanger more and more the human society. Water saving measures alone will not be sufficient to solve all associated problems. Therefore, people in arid countries might come back to any kind of water available. In this context the way people regard wastewater must change in terms that it has to be recognized as a water resource. The reuse of wastewater, treated and untreated, for irrigation purposes in agriculture is already established in some semi-arid and arid countries. Countries with absolute water scarcity like Israel might not only be forced to reduce their water consumption, but even to transfer reused water to other sectors. Concerns of authorities and the general public about potential health risks are completely understandable. The health risks of wastewater are mainly originating from pathogens which are negatively correlated with its treatment. Therefore, the quality of a wastewater effluent derived from mechanical-biological treatment can be further improved by additional treatment steps like soil aquifer treatment (SAT). This process is adopted at the Israeli Shafdan facility in the south of Tel Aviv. Conventionally treated wastewater is applied on surface basins from where it percolates into the coastal plain aquifer which supplies approximately one quarter of Israel ́s drinking water. After a certain residence time in the subsurface the water is recovered by wells surrounding the recharge area. Although the pumping regime creates a hydraulic barrier to the pristine groundwater, concerns exist that a contamination of the surrounding drinking water wells could occur. So far, little is known about the removal of organic trace pollutants during the SAT process in general and for the Shafdan site in particular. Consequently, the need arose to study the purification power of the SAT process in terms of the removal of organic trace pollutants. For this purpose reliable wastewater tracers are essential to be able to differentiate between degradation and sorption processes on the one hand and dilution with pristine groundwater on the other hand. Based on their chemical properties, their worldwide usage in a variety of foodstuffs and beverages, and first data about the fate and occurrence of sucralose, artificial sweeteners came into the focus as promising tracer candidates. Thus, in the present work an analytical method for the simultaneous determination of seven commonly used artificial sweeteners in different water matrices, like surface water and wastewater, was developed (see chapter 2). The method is based on the solid phase extraction (SPE) of the analytes by a styrene-divinylbenzene (SDB) copolymer material, and the analysis by liquid chromatography-electrospray ionization tandem mass-spectrometry (LC-ESI- MS/MS). The sensitivity in negative ionization mode was considerably enhanced by postcolumn addition of the alkaline modifier tris(hydroxymethyl) aminomethane. In potable water, except for aspartame and neohesperidine dihydrochalchone, absolute recoveries >75 % were obtained for all analytes under investigation, but were considerably reduced due to matrix effects in treated wastewater. The widespread distribution of the artificial sweeteners acesulfame, saccharin, cyclamate, and sucralose in the aquatic environment was proven. Concentrations in two German wastewater treatment plant (WWTP) influents ranged up to 190 μg/L for cyclamate, several tens of μg/L for acesulfame and saccharin, and about 1 μg/L for sucralose. For saccharin and cyclamate removal rates >90 % during wastewater treatment were observed, whereas acesulfame and sucralose turned out to be very persistent. As a result of high influent concentrations and low removal rates in WWTPs, acesulfame was the dominant sweetener in German surface waters with concentrations up to 2.7 μg/L. The detection of acesulfame and sucralose in recovery wells in the Shafdan SAT site in Israel in the μg/L range was a promising sign for their possible use as anthropogenic markers. As acesulfame and sucralose showed a pronounced stability in WWTPs and were detected in recovery wells of the SAT site in Israel it became worthwhile to assess their tracer suitability compared to other organic trace pollutants suggested as anthropogenic markers in the past (see chapter 3). Therefore, the prediction power of the two sweeteners was evaluated in comparison with the antiepileptic drug carbamazepine (CBZ), the X-ray contrast medium diatrizoic acid (DTA) and two benzotriazoles (1H-benzotriazole (BTZ) and its 4-methyl analogue (4TTri)). The concentrations of these compounds and their ratios were tracked from WWTPs with different treatment technologies, to recipient waters and further to river bank filtration (RBF) wells. Additionally, acesulfame and sucralose were compared with CBZ during advanced wastewater treatment by SAT in Israel. Only the persistent compounds acesulfame, sucralose, and CBZ showed stable ratios when comparing influent and effluent concentrations of four German WWTPs with conventional wastewater treatment. However, by the additional application of powdered activated carbon in a fifth WWTP CBZ, BTZ, and 4-TTri were selectively removed resulting in a pronounced shift of the concentration ratios towards the nearly unaffected sweeteners. Results of a seven months monitoring program along the rivers Rhine and Main showed an excellent correlation between CBZ and acesulfame concentrations (r2 = 0.94), and still good values when correlating the concentrations with both benzotriazoles (r2 = 0.66 - 0.82). In RBF wells acesulfame and CBZ were again the compounds with the best concentration correlation (r2 = 0.85).

Wind energy is expected to become the largest source of electricity generation in Europe’s future energy mix with offshore wind energy in particular being considered as an essential component for secure and sustainable energy supply. As a consequence, future electricity generation will be exposed to an increasing degree to weather and climate. With planning and operational lifetimes of wind energy infrastructure reaching climate time scales, adaptation to changing climate conditions is of relevance to support secure and sustainable energy supply. Premise for success of wind energy projects is the ability to service financial obligations over the project lifetime. Though, revenues(viaelectricity generation) are exposed to changing climate conditions affecting the wind resource, operating conditions or hazardous events interfering with the wind energy infrastructure. For the first time, a procedure is presented to assess such climate change impacts specifically for wind energy financing. At first, a generalised financing chain for wind energy is prepared to(qualitatively) trace the exposure of individual cost elements to physical climate change. In this regard, the revenue through wind power production is identified as the essential component within wind energy financing being exposed to changing climate conditions. This implies the wind resource to be of crucial interest for an assessment of climate change impacts on the financing of wind energy. Therefore, secondly, a novel high-resolution experimental modelling framework with the non-hydrostatic extension of the regional climate model REMO is set up to generate physically consistent climate and climate change information of the wind resource across wind turbine operating altitudes. With this setup, enhanced simulated intra-annual and inter-annual variability across the lower planetary boundary layer is achieved, being beneficial for wind energy applications, compared to state-of-the-art regional climate model configurations. In addition, surrogate climate change experiments with this setup disclose vertical wind speed changes in the lower planetary boundary layer to be indirectly affected by temperature changes through thermodynamically-induced atmospheric stability alterations. Moreover, air density changes are identified to occasionally exceed the net impact of wind energy density changes originating from changes in wind speed. This supports the consideration of air density information (in addition to wind speed) for wind energy yiel assumptions. Thirdly, the generated climate and climate change information of the wind resource are transferred to a simplified but fully-fledged financial model to assess the financial risk of wind energy project financing with respect to changing climate conditions. Sensitivity experiments for an imaginary offshore wind farm located in the German Bight reveal the long-term profitability of wind energy project financing not to be substantially affected by changing wind resource conditions, but incidents with insufficient servicing of financial obligations experience changes exceeding -10% to 14%. The integration of wind energy-specific climate and climate change information into existing financial risk assessment procedures would illustrate a valuable contribution to enable climate change adaptation for wind energy. In particular information about intra-annual and inter-annual variability change of the wind resource originating from changing climate conditions permit the quantification of additional financial risk associated to debt repayment obligations and, subsequently, enable the development of suitable preventive economic measures. Though, additional efforts in combination with future technical development are necessary to provide essential additional information about the bandwidth of climate change and uncertainties associated to such sector-specific climate and climate change information.