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Institut
- Fakultät Nachhaltigkeit (106)
- Fakultät Wirtschaftswissenschaften (66)
- Frühere Fachbereiche (50)
- Institut für Ökologie (IE) (28)
- Nachhaltigkeitsmgmt./-ökologie (19)
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- BWL (12)
- Institut für Nachhaltige Chemie und Umweltchemie (INUC) (12)
Despite the great progress that has been made in the prophylaxis of oral diseases over the past decades, dental caries and periodontal diseases remain major challenges in the field of dentistry. Biofilm formation on dental hard tissues is strongly associated with the etiology of these oral diseases. Therefore, the process of bioadhesion and biofilm formation on tooth surfaces is of particular interest for dental research. The first stage of bioadhesion on dental surfaces is the formation of the pellicle layer. This mainly acellular film, composed largely of adsorbed proteins, glycoproteins, and lipids, is distinguished from the microbial biofilm (plaque). As the interface between teeth and the oral environment, the pellicle plays a key role in the maintenance of oral health and is of great physiological and pathophysiological importance. On the one hand, the pellicle shows protective properties for the underlying dental hard tissues. On the other hand, it also serves as the basis for dental plaque and therefore, for the development of oral diseases such as caries and periodontitis. Hydrophobic interactions, which are governed by lipophilic substances, are of high relevance for bacterial adherence. Therefore, pellicle lipids, which are a significant constituent of this biological structure, are an interesting target for dental research, as they could modulate oral surfaces, influence microbial interactions, and potentially impede bacterial adherence. Compared to the extensive work on the pellicle´s ultrastructure and protein/amino acid composition, little attention has been given to its lipid profile. Knowledge of the lipid composition of the pellicle may provide insight into several oral pathological states, including caries, dental erosion, and periodontal disease processes and could contribute to novel approaches in preventive dentistry. The principle aim of this thesis was the comprehensive characterization of the fatty acid (FA) profile of the in situ formed pellicle layer. This includes the influence of pellicle maturation on the FA profile as well as intra- and interindividual differences. Furthermore, investigations on the effect of rinses with edible oils on the pellicle´s FA composition were a focus of this work. For these purposes, an analytical method based on a combination of innovative specimen generation and convenient sample preparation with sensitive mass spectrometric analysis was successfully developed and comprehensively validated within this thesis. Pellicle samples were formed in situ on bovine enamel slabs mounted on individual upper jaw splints. After a comprehensive sample preparation, gas chromatography coupled with electron impact ionization mass spectrometry (GC-EI/MS) was used in order to characterize qualitatively and quantitatively a wide range of FA (C12-C24). The individual FA profiles of pellicle and saliva samples collected from ten research participants were investigated. The relative FA profiles of the pellicle samples gained from the different subjects were very similar, whereas the amount of FAs showed significant interindividual variability. Compared to the pellicle´s characteristic FA profile, higher proportions of unsaturated FAs were detected in the saliva samples, highlighting that FAs available in saliva are not adsorbed equivalently to the pellicle layer. This, in turn, shows that pellicle formation is a highly selective process that does not correlate directly with salivary composition. Additionally, pellicle samples collected after 3, 30, 60, 120, and 240 min of intraoral exposure were analyzed. It could be shown that pellicle maturation has only a minor impact on the FA composition. However, the FA content increased substantially with increasing oral exposure time. Modifying the pellicle´s lipid composition by using edible oils as a mouthwash could alter the physicochemical characteristics of the pellicle and strengthen its protective properties by delaying bacterial adhesion. Therefore, the impact of rinses with safflower oil on the pellicle´s FA composition was determined. The application of rinses with safflower oil resulted in an accumulation of its specific FAs in the pellicle, thus representing a possibility for modifying the pellicle´s lipid profile. The present work is the first to apply a validated method that combines in situ pellicle formation, sample preparation, and the comprehensive determination of FAs via a sensitive analytical method. The results provide valuable information regarding the pellicle´s FA composition which closes an existing knowledge gap in pellicle research. A broader knowledge of the lipid composition of the pellicle contributes to the understanding of oral bioadhesion processes and may help facilitate novel approaches in preventive dentistry.
Increasing objections have been formulated towards broadening the security category. Securitisation is used to bring attention to urgent and existential threats that cannot be resolved through ordinary political decisions. During the time of the state of emergency between 2015 and 2017, France strengthened its security forces and introduced generalised surveillance measures to curb the terrorist threat. The purpose of this Bachelor thesis is to problematise the securitisation of terrorism in the French case. To do so, the Just Securitisation Theory by Rita Floyd is used to examine the following research question: Was it just to securitise terrorism in France between 2015 and 2017? Through critical discourse analysis of 54 presidential speech acts and secondary text analysis, this study aims to scrutinise securitising moves and security practices of the French government. The presented results indicate that the justness of securitisation is highly questionable. The analysis shows that the governments set excessive goals of eliminating terrorism and that security measures were misappropriated to fight organised crime instead of terrorism.
Personally meaningful tourist experiences foster subjective mental wellbeing. Modern, human-centred technologies such as gamified technology have been recognised as a promising means to support tourists in their co-creation of meaningful tourist experiences. However, a deeper understanding and conceptualisation of tourists' engagement with gamified technologies in the tourist experience has remained absent so far. This study draws on positive psychology as the guiding theoretical lens to conceptualise and explore tourists' underlying motives for engaging with gamified technology, as well as the gratifications thereof for the tourist experience. In doing so, this thesis identifies how tourists generate meaning through interacting with gamified technology in the tourist experience, thereby fostering the co-creation of meaningful tourist experiences and contributing to subjective mental wellbeing. Being among the first studies to link the concepts of positive psychology, gamified technology, and tourist experiences, the results of this thesis provide rich findings on the underlying motives for tourists to engage with gamified technology during vacation, as well as the gratifications of gamified technology for the creation of meaning in the tourist experience. Using the theoretical lens of positive psychology and achievement motivation theory as the main theoretical underpinning, this study is positioned at the intersection of social psychology, human-computer interaction, and tourism as the field of application. Conceptually, this thesis provides an in-depth understanding of tourists’ engagement with gamified technology, including the socio-psychological motivators for engagement and the outcomes thereof for the tourist experience.
This paper examines whether the attacks on the World Trade Center and the Pentagon on September 11th, 2001 have influenced the job prospects of Arabs in the German labor market. Using a large, representative database of the German working population, the attacks are treated as a natural experiment that may have caused an exogenous shift in attitudes toward persons who are perceived to be Arabs. Evidence from regression-adjusted difference-in-differences-estimates indicates that 9/11 did not cause a severe decline in job prospects. This result is robust over a wide range of control groups and several definitions of the sample and the observation period. Several explanations for this result, which is in line with prior evidence from Sweden, are offered.
The timber shortage led to large scale afforestations on previously agriculturally used land in Central Europe during the 19th and 20th century. Widespread afforestation programs created recent forest ecosystems (i.e. young forest systems in terms of their development history). Despite the positive effect of increasing the forest area of Central Europe, the ecological effects of these land-use changes on forest ecosystems remain poorly understood. In order to increase the understanding of ecosystem processes in forests, an assessment of conceivable shifts in ecosystem functions caused by former land-use changes and forest management is required. By analysing aboveground growth rates of European beech (Fagus sylvatica L.) in response to environmental change drivers, such as climate extremes and nitrogen (N) deposition, the presented thesis aims to assess the role of land-use and management legacies in modulating present responses to drivers of environmental change. To this end, annual radial growth rates of individual trees were measured in mature beech stands. The investigated stands differed either in their land-use history (i.e. ancient forest sites versus recent forests) or their forest management history (i.e. managed forest sites versus short-term and long-term unmanaged forest sites). Measurements of radial growth rates were complemented by analyses of the fine root systems, soil chemical properties and crown projection areas to gain insights into the mechanisms underlying alterations in tree growth. Within the projects of the presented thesis, shifts in the climate-growth relationships driven by land-use and management legacies were analysed. In addition, land-use legacy mediated differences in the climate-nitrogen-growth relationships were assessed. The key findings are: (I) Soil legacy driven alterations in the fine root systems cause a higher sensitivity of radial increment rates to water deficits in summer for trees growing on recent forest sites than for trees growing on ancient forest sites. (II) Management legacies (in terms of tree release) enhance the sensitivity of beech’s radial growth to water deficits in spring through changes in crown sizes. (III) Interacting effects of spring water deficits and co-occurring high deposition of reactive N compounds lead to stronger radial growth declines in trees growing in ancient forests. This is likely caused by resource allocation processes towards seed production, which is, in turn, mirrored by decreasing radial growth rates. In this context, high N deposition likely boosts mass fructification in beech trees. Overall, it has been demonstrated that the ecological continuity plays a crucial role in modulating both climate sensitivity and the growth response to interacting effects of water deficits and nitrogen deposition in beech trees. The presented thesis identified a trade-off between the climate sensitivity and maximised growth rates within beech trees, depending on forest history. The results show that the growth of beech in ancient, unmanaged beech forests is less sensitive to water deficits than in recent and managed beech forests. Additionally, interacting effects of spring water deficits and N deposition likely increase the reproductive effort of beech trees, particularly in ancient forests. Thus, the results of this thesis once again underpin the uniqueness of ancient, unmanaged beech forests, whose importance for the conservation of biodiversity has been widely acknowledged. In summary, the presented thesis highlights the need to consider the "ecological memory" of forest ecosystems when predicting responses to current and future environmental changes.
This thesis deals with the influence of sustainability communication on the purchase decision of sustainable tourism products involving German specialist tour operators. Sustainability communication is a challenge, because sustainable tourism is an abstract and vague concept which consumers find it difficult to grasp and about which they are sceptical. The service characteristics of tourism products complicate the decision making stage, which is a high-involvement situation of uncertainty to which sustainable product attributes add complexity. As an introduction, an interdisciplinary theory discussion reveals knowledge gaps in terms of the value-belief-norm theory and the elaboration likelihood model (ELM). The first article, which is the first systematic literature review on the topic, reveals that there is a limited theoretical understanding of sustainability communication, a lack of practical understanding of how to design sustainability messages, and an inadequate set of methodologies for its research. It identifies knowledge gaps concerning: the holistic approach to sustainability communication; its role in the attitude-behaviour gap; an interdisciplinary theoretical understanding focusing on belief-based social psychological theories and theories of persuasion; qualitative methods; and experimental design. The second article investigates the role of sustainability communication in the attitude-behaviour gap, employing the value-belief-norm theory to explain how information is processed by special interest customers. Interview findings show that ineffective sustainability communication is the reason for the gap and that customers unintentionally booked sustainably. The study identifies eight groups of beliefs which explain the processing of sustainability attributes. Sustainability information is effective when it is value-congruent, that is, when customers perceive they can make a difference, they begin to ascribe a responsibility to themselves. The third article investigates how to design an effective sustainability message in tour operator advertising. Drawing on the ELM, the study shows that appeal type does not significantly influence persuasion but the topic presented is important. Cultural sustainability is the sustainability topic that is most persuasive for cultural tourists, while consumer prior knowledge and issue-involvement with the topic promote successful information processing.
The Ili Delta in Kazakhstan is an important ecosystem that offers crucial wetland habitats for several bird species. However, the Ili River, the Ili Delta and the Balkhash Lake are suffering from water shortage due to climate change and human activities. The desertification of the Aral Sea, an obvious point of comparison to the Balkhash region, also involved the degradation of wetland habitats and the related loss of many bird species relying on these habitats. Therefore, water shortage at the Ili Delta may also be the reason for the loss of wetland habitats and bird species. In this study, bird species numbers, species abundances as well as bird diversity at different habitats in the Ili Delta were examined. There are many habitat types provided by the Ili Delta, for example reed bed vegetation, Tugay forest, bare soil floodplains along rivers and steppe. The results of this study showed that the central delta region with habitats of submerged reed vegetation showed the highest number of bird species and the greatest diversity. Threatened bird species at the Ili Delta were also observed only in these wetland habitats. Steppe habitats showed the lowest numbers of bird species and the lowest bird diversity. In general, all habitats at the Ili Delta are important for the ecosystem and essential for the bird species that depend on them for their survival. With expansion of arid steppe habitats due to water shortage, however, previous wetland habitats may be lost. Moreover, bird species that depend on these wetland habitats may also be lost. Therefore, protective measures for the Balkhash region in general and the wetland habitats at the Ili Delta and its distinct avifauna in particular are urgently needed.
Whereas the extant literature discusses what Sustainability-Oriented Innovations (SOIs) are and why firms develop them, little is known about how they are developed. To enable firms to innovate for sustainability, it is essential to know more about the processes underlying SOI development, which are considered as very difficult, with many firms failing. Drawing on several academic papers and relying on qualitative research methods, the thesis uses the Fireworks model to examine how innovation processes unfold at established small and medium-sized enterprises (SMEs). The main contribution of the thesis is to advance the Fireworks model to the context of SOIs unfolding at SMEs. The findings reveal that SOIs unfold in an emergent, somewhat chaotic way, that duration and outcome are uncertain, that the overall journey is composed of multiple intertwined innovation paths, of which several will likely lead to setbacks. To manage this complex process, the thesis suggests to set four management foci: (1) to create a dedicated organizational unit for exploration, (2) to create conditions allowing intelligent learning for efficient exploration, (3) to carry out in-depth investigation of the related technological innovation systems, and (4) to plan carefully the re-integration of the innovation into the core business for commercialization.
This thesis analyses how European merger control law is applied to the energy sector and to which extent its application may facilitate the liberalisation of the electricity, natural gas and petroleum industries so that only these concentrations will be cleared that honour the principles of the liberalisation directives. After having discussed the complex micro- and macro-economic considerations which accompany any concentration of business activities, this thesis discusses the merger control regime of the European Community (EC) so as to establish whether the merger control under either Art. 66 Treaty Establishing the European Coal and Steal Community (ECSCT), the case law under Art. 101 and 102 Treaty on the functioning of the European Union (TFEU) and (Art. 81 and Art. 82 Treaty Establishing the European Economic Community (ECT), as it was introduced by the Commission and reviewed by the CJEU, the original Merger Regulation (MR1989) or the amended Merger Regulation of 1997 (MR1997) or the amended Merger Regulation of 2004 (MR2004) facilitate the liberalisation of European electricity and gas markets. Said liberalisation was introduced by the Internal Electricity Market Directive (IEMD), the Hydrocarbons Licensing Directive and the Internal Gas Market Directive (IGMD). The paper focuses on the contestable idea that regulatory amendments - especially the introduction of third party access by means of the directives - only form a first necessary condition for attaining economic alterations whereas pro-active conduct of the marketers is the second and decisive one in order to increase the competitive performance of the European energy supply industries. The analysis is supported by a second argument which relates closely to the ambivalent nature of concentrations: A concentration may be used to increase the process of market opening and the expansion into new markets by pooling of scarce resources. It may also be used as a retro -active means so as to create national champions, increase barriers to market entry of new competitors, enable cross-subsidisation so as to expand dominant positions on heretofore competitive up- and downstream markets.
The Macro Polity Revisited
(2021)
This dissertation includes six articles tied together by the overarching question of how changes in public opinion, economics and public policy co-evolve in mature democracies, with a focus on redistributive (in seven European democracies) and secessionist preferences (in Catalonia and Scotland). The theoretical inspiration derives from three sources: 1. the Macro Polity model by Erikson, MacKuen/Stimson, 2. the Thermostatic Responsiveness model by Soroka and Wlezien, and 3. the literature on representation gap models by Gilens, Elsaesser and others. The Macro Polity and Thermostatic Responsiveness models come with an optimistic undertone, emphasizing that public policies adapt to public opinion, producing the policy-opinion congruence that defines responsive government. The Representation Gap model, by contrast, is more pessimistic in highlighting that the preferences of low-income groups are generally worse represented in public policies than the preferences of middle-income and especially high-income groups. While there is evidence in favor of these models for the majoritarian political systems in the US, Canada and the UK, less is known about the validity of these models in proportional democracies of continental Europe. The contributions in this dissertation address this research gap by integrating the three models and combining nearly 500 surveys to study the evolution of European public opinion at the national and subnational level.